Vidyamandir Classes

illuminati
Advanced Chemistry Assignment | JEE Advanced
Physical Chemistry
SINGLE CORRECT ANSWER TYPE

1. 50 mL of 20.8 % w/v BaCl2 (aq) and 100 mL of 9.8 % w/v H2 SO4 (aq) solution are mixed. The
molarity of SO24  in final solution is :
(A) 0.66 M (B) 0.5 M (C) 1M (D) 0.33 M

2. The minimum volume of HCl of specific gravity 1.2 and 3.65 % by weight, needed to produce
1.12 L Cl 2 at 1 atm and 273 K by the following reaction :
MnO2  HCl  MnCl2  H2 O  Cl2
(A) 200 mL (B) 166.7 mL (C) 333.3 mL (D) 267 mL

3. In the permanganate titration, the solution of reductant is made acidic by adding dilute
H2 SO4 , rather than HCl or HNO3 because :
(A) HCl is a reducing agent and it gets oxidised resulting into decrease in the volume of
KMnO4 equivalent to the reducing agent under estimation
(B) HNO3 is an oxidising agent and it gets reduced resulting into increase in the volume of
KMnO4 equivalent to the reducing agent under estimation
(C) H2 SO4 (dil) is neither an oxidizing agent nor a reducing agent
(D) All of these

4. 2 litres of an acidified solution of KMnO4 , containing 1.58 g of KMnO4 per litre, is

decolourised by passing sufficient amount of SO2 gas. If whole of the sulphur from x g of
FeS2 is converted into SO2 to be used in above reaction, calculate the value of x :
(A) x  1.5 (B) x 3 (C) x  4.5 (D) x 6

5. A certain volume of hydroxyl amine (NH2OH) solution was boiled with an excess of FeCl 3
3
solution to cause the reduction of Fe ions according to the reaction :
3 2
Fe  NH2 OH  Fe  N2 O  H  H2 O
The resulting solution was estimated for Fe2  ions with 0.5 M K 2Cr2O 7 solution in acidic
medium. If the volume of K 2 Cr2 O7 solution and NH2OH solution used are found to be equal,
what is the molarity of NH2OH solution :
(A) 1.5 M (B) 3M (C) 0.75 M (D) 1M

VMC | Chemistry 1 ACA | JEE Advanced

 Vidyamandir Classes

6. Find sum of total moles of KMnO4 needed for oxidation of following [(i) to (iv)]
(i) 1 mol of FeC2O4 in acidic medium
(ii) 1 mol of I in basic medium
(iii) 2 mol of ferrous ammonium sulphate in acidic medium
(iv) 2.5 mol Na 3 AsO3 in acidic medium
(A) 4 (B) 6 (C) 8 (D) None of these
7. In 1L saturated solution of CuCl, 0.1mol AgCl is added. K sp of AgCl  1.6  10 10. If the

resultant concentration of Ag  in the solution is 1.6  10 7 , then K sp for CuCl is :

(A) 1.6  10 3 (B) 10 3 (C) 10 6 (D) 1.6  10 6

8. The pH of a 0.01 M acid HX is 2 and pH of 0.01 M salt ACl is also 2. What conclusions can be
drawn from this information ?
(A) HX is a weak acid and AOH is strong base
(B) HX is a strong acid and AOH is strong base
(C) HX is a strong acid and AOH is very weak base
(D) HX is a strong acid and A  undergoes partial hydrolysis

9. 40 mL of 0.35 M NaOH solution is added to 50 mL of 0.6 N H3 PO4 solution. The pH of the

mixture would be about: ( K a ,K a and K a are 103 ,10 8 and 10 12 respectively).
1 2 3

(A) 11.82 (B) 3.6 (C) 12.18 (D) 7.82

10. The solubility product of As2 O3 is 10.8  10 9. It is 50 % dissociated in saturated solution.
The solubility of salt is :
(A) 10 2 M (B) 2  10 2 M (C) 5  10 3 M (D) 5.4  10 9 M

11. At 298 K the standard free energy of formation of H2 O(ℓ ) is  257.20 kJ / mole while that of its

ionisation into H  ion and hydroxyl ions is 80.35 kJ / mole, then the emf of the following cell
at 298 K will be : (take F  96500 C)

H2 (g,1 bar)|H (1M)||OH (1M)|O2 (g,1 bar)

(A) 0.40 V (B) 0.50 V (C) 1.23 V (D)  0.40 V

12. A galvanic cell is composed of two chlorine electrodes, one of which is a standard one. In which
of the following solutions should the other electrode be immersed to get maximum e.m.f.
(K sp of PbCl2  1.2  10 5 , of AgCl  1.8  10 10 , of Hg 2 Cl2  1.4  1018 )

(A) 0.1 M HCl (B) Saturated solution of PbCl2 in water

(C) Saturated solution of AgCl in water (D) Saturated solution of Hg 2Cl2 in water

13. One gm metal M2  was discharged by the passage of 1.81  10 22 electrons. What is the atomic
weight of metal ?
(A) 33.35 (B) 133.4 (C) 66.7 (D) 55

VMC | Chemistry 2 ACA | JEE Advanced

 Vidyamandir Classes

14. The conductivity of a solution which is 0.2 M in AgNO3 and 0.1M in Ba(NO3 )2 is :

[  6  10 3 Sm 2 mol 1,   13  10 3 Sm 2 mol 1 and   7  10 3 Sm 2 mol1 ]

(Ag  ) (Ba 2  ) 
(NO3 )

(A) 5.3 Sm 1 (B) 4.3 Sm 1 (C) 3.3 Sm 1 (D) 2.3 Sm 1

15. Which of the following (B) reagents when added (A) reagent drop by drop, result in the given
variation of molar conductance ?
A B
(A) HCl + NaOH
(B) NaCl + AgNO3
(C) NaOH + HCOOH
(D) BaCl2 + Ag 2 SO4

16. For the following V-T plot for a gas undergoing a process from state A to state B, select the
correct alternative(s)
(A) Pressure constantly increases
(B) Pressure first increases, then decreases
(C) Final pressure is less than initial pressure
(D) Pressure first decreases then increases

17. In which of the following cases, the work done in an ideal gas system with constant moles ‘n’
be represented by  nRT ?
(A) Isochoric reversible heating (B) Isobaric reversible expansion
(C) Isothermal reversible expansion (D) Adiabatic irreversible expansion

18. At temperature above 85 K, decarboxylation of acetic acid becomes a spontaneous process

under standard state conditions. What is the standard entropy change (in J/K-mol) of the

reaction : CH3COOH (aq)  CH4 (g)  CO2 (g)

Given : H f [CH3COH(aq)]   484kJ / mole

H f [CO2 (g)]   392kJ / mole

Hf [CH 4 (g)]   75 kJ / mole

(A) 100 J/K mole (B) 200 J/K mole (C) 300 J/K mole (D) 400 J/K mole

19. A monoatomic ideal gas at 1200 K is expanded adiabatically from 1 L to 8 L, such that its final
temperature is 280 K. which of the following statements is/are true for this process?
(A) This is free adiabatic expansion
(B) This is reversible adiabatic expansion
(C) This is irreversible adiabatic expansion
(D) This is an impossible process

VMC | Chemistry 3 ACA | JEE Advanced

 Vidyamandir Classes

20. The enthalpy of formation of C2 H6 is  84 kJ / mol. For C3 H8 , it is 105 kJ / mol. What is the
enthalpy of formation of n-pentane?
(A) Data is insufficient (B) 147 kJ / mol
(C) 187 kJ / mol (D) 114 kJ / mol

21. In hcp (ABAB…..) and ccp ( ABCABC…) structures made up of spheres of equal size, the
volume occupied per sphere (including the empty spaces (a = radius of sphere)
(A) 5.66 a3 (B) 1.33 a3 (C) 2.66 a3 (D) 7.40 a3

22. What is the maximum number of layers of atoms in closed packed planes that will lie within
2
two imaginary parallel planes having a distance between them of 13 R in the copper crystal
3
(FCC)? Consider the atoms to be within the parallel planes if their centres are on or within the
two parallel planes. [R = radius of sphere]
(A) 5 (B) 6 (C) 7 (D) 8

23. The number of atoms in 100 g of an FCC crystal with density d 10 gm cm 3 and cell edge of
200 pm is equal to :
(A) 3 1025 (B) 5  1024 (C) 1  1025 (D) 2  1025

24. Ionic solid B A  crystallizes in rock salt type of structure. 1.32 gm ionic solid salt B  A  is
dissolved in water to make one litre solution. The pH of the solutions is measured to be 6.0. If
the length of face diagonal in the unit cell of B A  be 600 2pm . Calculate the density of

ionic solid. [(T = 298 K), Kb for BOH is 10 5 , N A  6.022  10 23 , HA is strong acid]
(A) 5g/cc (B) 4 g /cc (C) 4.5 g/cc (D) 5.5g/cc

25. The given isotherm was observed for a monoatomic gas at certain
temperature. Which of the following is CORRECT?
(A) The gas is behaving ideally
(B) The gas is above its critical temperature
(C) In the horizontal QR, the pressure is more than critical pressure
(D) The gas shows negative deviation from ideal behaviour in PQ and QR

26. 10 ml of gaseous hydrocarbon is exploded with 100 ml oxygen. The residual mixture on cooling
is found to measure 95 ml, of which, 20 ml is absorbed by KOH and remaining by alkaline
pyrogallol. It is known that alkaline pyrogallol absorbs O 2. Predict the formula of hydrocarbon :
(A) C2 H6 (B) C2 H 4 (C) C2 H 2 (D) C 4 H8

27. If the number of molecules of SO 2 (atomic weight = 64) effusing through an orifice of unit area
of cross-section in unit time at 0C and 1 atm pressure is n, the number of He molecules
(atomic weight = 4) effusing under similar conditions at 273C and 0.25 atm is :
n n
(A) (B) n 2 (C) 2n (D)
2 2
VMC | Chemistry 4 ACA | JEE Advanced
 Vidyamandir Classes

28. A gas ‘X’ undergoes physisorption on charcoal. If the magnitude of enthalpy change and
entropy change were observed to be 20 kJ/mol and 75 J / mol K, then the temperature range
at which adsorption takes place spontaneously is :
(A) T = 2875 K (B) T  287.5 K (C) T  287.5 K
(D) At any temperature adsorption will be spontaneous

29. At 70 K, the adsorption of N 2 gas at iron surface obeys Freundlich adsorption. The
experimental data is :
P(bar) 4 25 64
x
0.2 0.5 0.8
m
x
Where is the mass of N2 in gram, adsorbed per gram of iron at P bar pressure. The mass of
m
N2 gas adsorbed by 5g of Fe at 36 bar and 70 K is :
(A) 0.6 g (B) 3g
(C) 0.8 g (D) Cannot be found from given data

30. Which of the following statements is NOT CORRECT?

(A) Higher is the gold number of a lyophilic sol, lesser is its coagulating power.
(B) An electrolyte can coagulate both positive sol and negative sol.
(C) Impurities present in a colloid makes it more stable.
(D) Dialysis is a process to remove impurities of ions and molecules from a solution colloid

31. Equal volumes of 0.1 M solution of NaCl and 5 M solution of NaCl are kept in a closed vessel
(see figure) and temperature is maintained constant. After equilibrium has been established,
assuming that volumes are additive, which of the following is (are) true?
(A) Volume of 0.1 M solution is lesser than its
original volume
(B) Volume of 0.1 M solution is greater than its
original volume
(C) Volume of 5 M solution is lesser than its
original volume
(D) No change occurs at all.

32. ‘V1’ ml of an aqueous urea solution having osmotic pressure as 2.4 atm is mixed with ‘V 2’ ml of
another aqueous urea solution having osmotic pressure as 4.6 atm at same temperature. What
V1
will be value of if resulting solution after mixing has osmotic pressure as 2.95 atm.
V2

(A) 1 (B) 1.5 (C) 2 (D) 3

VMC | Chemistry 5 ACA | JEE Advanced

 Vidyamandir Classes

33. The vapour pressure of two pure liquids X and Y which form an ideal solution are 200 and 300
mm of Hg respectively at 300 K. A liquid solution of ‘X’ and ‘Y’ in which the mole fraction of ‘X’
is 0.5 is contained in a cylinder closed by a piston on which pressure can be varied :
(A) Only if pressure above solution is less than 200 torr, vapour phase can exist.
(B) Only if pressure above solution is less than 300 torr, vapour phase can exist.
(C) Only if pressure above solution is more than 200 torr, liquid phase exist.
(D) Only if pressure above solution is less than or equal to 250 torr, vapour phase can
exist.

34. A student prepares 2 M, 50 mL HCl solution in water. He drops some of the solution which he
compensates with pure water, the resultant solution was found to be isotonic with 3.2 M urea
solution. How much of the original solution (in mL) was dropped ?
(A) 5 (B) 10 (C) 15 (D) 20

35. A solution containing large amount of A and water is steam distilled. The condensate hence
obtained contained 0.25 mole fraction of A. The external pressure at which distillation is
performed is : ( PW   740 torr and temperature is same.)
(A) 760 torr (B) 791.3 torr (C) 986.67 torr (D) 886.9 torr

36. What is the % decrease in vapor pressure with respect to solution when saturated solution of
Ag3 PO4 is prepared:
3
 3  12
Given : K sp of Ag 3 PO4     10 (Assume no hydrolysis)
 16 

(A) 6  104 (B) 1.5  104 (C) 9  104 (D) 18  104

37. How many grams of sucrose (molecular mass = 342) should be dissolved in 100 gm water in
order to produce a solution with 105°C difference between the freezing point and boiling point
at 1 atm?
K f  2 K kg / mol and K b  0.5 K kg / mol 

(A) 34.2 g (B) 68.4 g (C) 17.1 g (D) 342 g

38. Which one of the following statement is false?

(A) Raoult’s law states that the vapor pressure of a component over a solution is
proportional to its mole fraction in solution
(B) The osmotic pressure () of a solution is given by the equation   CRT (C = molarity of
solution)
(C) The correct order of osmotic pressure for 0.01 M aqueous solution of each compound is
BaCl2  KCl  HF
(D) Two glucose solutions of same molality prepared in different solvents will have the
same boiling point elevation.

VMC | Chemistry 6 ACA | JEE Advanced

 Vidyamandir Classes

39. The Henry’s law constant for dissolution of a gas in aqueous medium is 3 × 10 4 atm. At what
5
partial pressure of the gas (in atm) the molality of gas in aqueous solution will be ?
900
(A) 10–4 atm (B) 3 atm (C) 0.3 atm (D) 10 atm

40. Addition of water to which of the following equilibria causes it to shift in the backward
direction?

(A) CH3 NH2 (aq)  H2O( ℓ) ↽ ⇀ CH3 NH3 (aq)  OH  (aq)

(B) AgCl(s) ↽ ⇀ Ag  (aq)  Cl  (aq)

(C) HCN(aq)  H2O  ℓ  ↽ ⇀ H O  (aq)  CN  (aq)

3
3
(D) Cr(dien)2  (aq)  3H2 O( ℓ)  3Cl  (aq) ↽ ⇀ Cr(H 2O)3 Cl 3  (aq)  2die n(aq)

41. A 57°C, gaseous dinitrogen tetraoxide is 50% dissociated. Calculate the standard free energy
change per mole of N2O4 (g) at this temperature and at 1 atm initial pressure of N2O4 .

 R  8.3 JK 1mol 1,ln 10  2.3, log 2  0.3, log 3  0.48 

(A) – 756 J mol– (B) – 856 J mol– (C) – 656 J mol– (D) None of these

42. For the equilibrium CaCO3 (s) ↽ ⇀ CaO(s)  CO2 (g), the pressure of CO2 depends on

(A) The mass of CaCO3 (s)

(B) The mass of CaO(s)
(C) The masses of both CaCO3 (s) and CaO(s)

(D) Temperature of the system

43. For the reaction, NH4 HS(s) ↽ ⇀ NH3 (g)  H2S(g) K p  1225 (torr)2

In a vessel, NH3 (g) at a partial pressure of 50 torr and H2 S(g) at a partial pressure 20 torr is
taken. After a long time, the total pressure of gas in the vessel becomes:
(A) 80 torr (B) less than 70 torr
(C) 70 torr (D)  76 torr

44. Two moles of gas A 2 are mixed with two moles of gas B 2 in a flask of volume 1 lit. If at
equilibrium 0.5 moles of A2 are obtained. Then find out K p for reaction:

A 2 (g)  B2 (g) ↽ ⇀ 2AB(g)

(A) 12 (B) 9 (C) 4 (D) 36

45. For which of the following reactions, K p  K c at 298 K:

(A) XeF6 (g) ↽ ⇀ Xe(g)  3F (g) (B) N 2 (g)  O 2 (g) ↽ ⇀ 2NO(g)

2

1 3
(C) N (g)  H2 (g) ↽ ⇀ NH3 (g) (D) CO(g)  H2O(g) ↽ ⇀ CO2 (g)  H 2 (g)
2 2 2

VMC | Chemistry 7 ACA | JEE Advanced

 Vidyamandir Classes

46. Which of the following is true when equal volume of 0.04 M NaCl solution is mixed with 0.1
M K[Ag(CN)2 ] . Given : (K inst [Ag(CN)2 ] )  4  10 19 , K sp (AgCl)  2.8  10 10 and 3 5  1.7)

(A) More K[Ag(CN)2 ] will be formed (B) AgCl will be precipitated

(C) There is no change in concentration of K+

(D) None of these

47. A solid crystallises as cubic close packing of O2  ions. A x  ions occupy 25% of the tetrahedral
voids and B y  ions occupy 50% of the octahedral voids. The suitable values of ‘X’ and ‘y’ are :
(A) x = 1, y = 3 (B) x = 2, y = 1 (C) x = 3, y = 2 (D) x = 1, y = 2

48. for the two reactions

Reaction I : A  B
Reaction II: C  D
Following curves are plotted which of the following is
incorrect option :
2 3
(A) (t100% )reaction I  (t100% )reaction II (B) [A] = [C] at t  minutes
3 4
(C) When [B] = [A] at that time [C] = [D]
1
(D) If both [A]o and [C]o are 1 M then (t 50% )I  (t 50% )II .
3
49. Following data of osmotic pressure ( ) is obtained when different moles C17 H35COONa are

mixed in 1 L solution at 25o C :

Moles 0 0.01 0.02 0.03 0. 04


(moles/litre) 0 0.02 0.04 0.058 0.076
RT
Select the incorrect nature of mixture at different concentration.
(A) Upto 0.02 M concentration, the mixture is true solution
(B) After 0.03 M concentration, the mixture is a colloidal
(C) At 0.04 M concentration, the mixture is homogeneous
(D) The critical micelle concentration (CMC) of C17 H35COONa may be 0.03 M.

50. 1 mole of a compound Co(NH3 )5 Cl2 Br gives 2 moles of curdy white precipitate, when treated
with excess of AgNO3 solution. Which of the following is incorrect about the compound?

(A) The compound may be represented as [Co(NH3 )5 Br]Cl2

(B) The Van’t Hoffs factor (i) is 3, when   1.0

(C) The boiling point of 1M – aq. Solution of Co(NH3 )5 Cl 2 Br should be triple of its value,
when it were non-electrolyte
(D) None of these

VMC | Chemistry 8 ACA | JEE Advanced

 Vidyamandir Classes

MULTIPLE CORRECT ANSWER TYPE

51. For the reaction

' p ' HNO2  ' c ' KMnO4  ' r ' H2 SO4  ' s ' HNO3  ' t ' MnSO4  ' u ' K 2 SO4  3H2 O
Which of the following is/are true ?
(A) H2 SO4 is reducing agent
(B) HNO2 is reducing agent
(C) p  q  r  10
Molar mass
(D) Equivalent weight of HNO3 in the reaction is
2

52. The pH of 0.1 M solution of a weak base is 11. On diluting the solution, select the INCORRECT
statement(s) :
(A) pH increases (B) [OH  ] increases

(C)  decreases (D) Number of H  ions in solution increases

53. Which is/are correct statements ?

(A) H2 PO2 and HCO3 are amphiprotic species

(B) Equivalent weight of H3 PO4 can be equal to its molar mass depending on the reaction

(C) KMnO4 has maximum equivalent weight in acidic medium

(D) Oxidation state of H in H2 is more than that in NaH

54. On electrolysis, in which of the following, O2 would be liberated at the anode?

(A) dilute H2 SO4 with Pt electrodes

(B) aqueous AgNO3 solution with Pt electrodes

(C) dilute H2 SO4 with Cu electrodes

(D) aqueous NaOH solution with Fe cathode & Pt anode

55. Mark out the correct statement(s) regarding electrolytic molar conductivity:
(A) It increases as temperature increases
(B) It experiences resistance due to vibration of ions about mean position
(C) Increase in concentration decreases the electrolytic molar conductivity of both strong
as well as weak electrolyte
(D) Greater the polarity of solvent, greater is the electrolytic molar conduction

56. Which of the following are CORRECT statements ?

(A) Vander Waals constant ‘a’ is a measure of attractive force
(B) van der Waals constant ‘b’ is also called co-volume or excluded volume
(C) ‘b’ is expressed in L mol 1
(D) ‘a’ is expressed in atm L2 mol 2

VMC | Chemistry 9 ACA | JEE Advanced

 Vidyamandir Classes

57. The origin of charge on colloidal solution is :

(A) Self dissociation (in soaps and detergents)
(B) Electron capture during Breding’s arc method
(C) Selective adsorption of ion on their surface
(D) It is due to addition of protective colloids

58. Consider the process carried out for an ideal gas.

One by one, stoppers S1, S2, S3 ……… are
removed slowly and the gas expands to V2 L
with final pressure P2 and final temperature T2.
Which of the following is/are correct for the
above process ?
(A) T1 = T2 (B) P1 = P2 (C) U1 = U2 (D) w = 0, q = 0

59. Which of the following statement(s) is/are false ?

1
(A)  r S for reaction Cl2 (g)  Cl (g) is positive
2
(B) E  0 for combustion of CH4(g) in a sealed container with rigid adiabatic system
(C) G is always zero for a reversible process in a closed system

(D) G for an ideal gas reaction is a function of pressure

60. The vander waal’s equation of state for a non-ideal gas can be
PV V a
rearranged to give   for 1 mole of gas. The
RT V  b VRT
constants a and b are positive numbers. When applied to H2 at
80K, the equation gives the curve as shown in the figure. Which of
the following is/are CORRECT :
V a
(A) The two terms and are never equal
(V  b) VRT
V
(B) At 80 atm, the two terms 1  and a/VRT are equal
(V  b)
(C) At a pressure greater than 80 atm, the term V/(V – b) is greater than (a/VRT + 1)
a
(D) At 60 atm, the term V/(V–b) is smaller than 1 
VRT
61. A substance ‘A’ has the following variation of vapor pressure with temperature for its solid
state and liquid state. Identify the options which are correct:
2000
Given for solid A : log10 P  4 
T
1500
For liquid A : log10 P  3.5 
T
Where P is in mm of Hg and T in K
(A) Triple point temperature of substance ‘A’ is 1000 K
(B) Hsub will be approximately 9.212 Kcal/mol
(C) Hfusion will be approximately 9.212 Kcal/mol

(D) H vap will be approximately 6.909 Kcal/mol

VMC | Chemistry 10 ACA | JEE Advanced

 Vidyamandir Classes

62. The vapour pressure of two pure liquids A and B which form an ideal solution are 500 and 800
torr respectively at 300 K. A liquid solution of A and B for which the mole fraction of A is 0.60
is contained in a cylinder closed by a piston on which the pressure can be varied. The solution
is slowly vaporized at 300 K by decreasing the applied pressure.
1. The composition of vapour when first bubble formed is :
(A) y A  0.6 ; y B  0.4 (B) y A  0.48; y B  0.52
(C) y A  0.52; y B  0.48 (D) y A  0.5; y B  0.5

2. What is the composition of last droplet of liquid remaining in equilibrium with vapour ?
(A) x A  0.6 ; x B  0.4 (B) x A  0.5; x B  0.5
(C) x A  0.7 ; x B  0.3 (D) x A  0.3; x B  0.7

63. 10 ml of FeC2O4 solution requires 30 ml of 0.4 M KMnO4 solution in acidic medium for

titration. 25 ml of the same FeC2O4 solution is mixed in some water to make a solution
containing 900 g of water. Which of the following is/are true for this solution?
(Kf for water = 1.8/K kg/mol)
(A) Freezing point of the solution is 0.2 K
(B) The RLVP of the solution is 2 × 10–3
(C) Osmotic pressure of the initial FeC2O4 solution is 49.2 atm at 300 K.

(D) Osmotic pressure of the initial KMnO4 solution (without acid) is 19.68 atm at 300 K.
64. Consider the following statements :
(i) An increase in pressure (caused by decrease in volume) at equilibrium results in
increase in molar concentration of each gaseous substance involved at new
equilibrium.
(ii) An increase in pressure (caused by decrease in volume) at equilibrium results in
increase in no. of moles of each gaseous substance involved.

(iii) For the reaction A(s) ↽ ⇀ B(g)  C(g) starting with A only at constant temperature,

total pressure at equilibrium (of B(g) and C(g)) is not affected by changing the volume of
container.

(iv) H2O(l) ↽ ⇀ H O(g); on temperature increase, KP of this reaction is increase.

2

Tick the correct statement(s)

(A) (i) (B) (ii) (C) (iii) (D) (iv)

65. 0.1 M urea and 0.1 M NaCl aqueous solutions of same volume are separated by semi-
permeable membrane. Identify the correct statement(s).
(A) No water will flow across the membrane
(B) Water will flow from I to II
(C) Water will flow from II to I
(D) Both solutions will be isotonic in the end

VMC | Chemistry 11 ACA | JEE Advanced

 Vidyamandir Classes

66. The freezing point of a 0.08 molal aqueous solution of NaHSO4 is  0.372o C . Which of the
following is/are correct for the given solution? Assume no hydrolysis and m  M .
( K f of water = 1.86 K kg/mole)
(A) 0.2 moles of ions are present in 1 kg solvent
(B) Degree of dissociation of HSO4 is 0.6

(C) Dissociation constant for the reaction HSO 4 ↽ ⇀ H   SO24  is 4  10 2

9
(D) RLVP of the given solution is
2509

67. A nonvolatile solute ‘X’ completely dimerises in water, if the temperature is below 3.72o C and
the solute completely dissociates as X  Y  Z , if the temperature is above 100.26o C . In
between these temperature, (including both temperature) ' X ' is neither dissociated nor
associated. One mole of ‘X’ is dissolved in 1 kg water.
Given : K b of water = 0.52 K, Kg mol–1 ; Kf of water = 1.86 K, Kg mol–1
Which of the following statement(s) is/are true regarding the solution?
(A) the freezing point of solution is 1.86o C
(B) the boiling point of solution is 101.04oC
(C) When the solution is cooled to 7.44 o C , 75% of water present initially will separate as
ice
(D) When the solution is heated to 102.08oC , 50% of water present initially will escape
out as vapour.
ASSERSION & REASON TYPE

(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for

Statement-1
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for
Statement-1
(C) Statement-1 is True, Statement -2 is False
(D) Statement-1 is False, Statement-2 is True

68. Statement-1: If KIO3 reacts with excess KI in acidic medium, and the produced I2 is titrated
with hypo solution, then milliequivalents of KIO3 used and hypo used are equal.
Statement-2: According to law of equivalence, in a chemical reaction, milliequivalents of all
the reactants are equal and also equal to milliequivalents of each product.

69. Statement-1 : The pH of a 0.003 M aqueous solution of NH4 CN can be approximately

1
calculated using the formula : pH  (pK w  pK a  pK b )
2
Given : K a (HCN)  4  10 10 & K b (NH3 )  2  10 5
Statement-2 : The degree of hydrolysis (h) of NH4 CN in its 0.003 M aqueous solution comes
out to be greater than 0.1 and so, its value cannot be neglected with respect to 1.

VMC | Chemistry 12 ACA | JEE Advanced

 Vidyamandir Classes

70. Statement-1 : Eocell  0 for a chloride ion concentration cell.

RT [Cl  ]LHS
Statement-2 : For this concentration cell, Ecell  ln
nF [Cl  ]RHS

71. Statement-1 : Gases like N2, O2 behave as ideal at high temperature and low pressure.
Statement-2 : Molecular interaction diminishes at high temperature and low pressure.

72. Statement-1 : Tyndall effect is due scattering of light & not shown by true solution.
Statement-2 : In a true solution there are no particles of sufficiently large diameter to scatter
light and hence the beam is invisible

73. Statement-1 : In ZnS crystal, Zn2  ions are placed at 50% of tetrahedral voids (at alternate
positions) created by S2  ion in c. c. p. lattice
Statement-2 : Ratio of number of S2  ion and number of tetrahedral voids is 2 : 1 where as
ratio of number of S2  ion and number Zn2  ion is 1 : 1 in zinc blende.

74. Statement-1:Binary ideal solution boils at temperature which is lower then normal boiling
point of more volatile component and higher then the normal boiling point of less volatile
component.
Statement-2: For any composition of ideal mixture, its boiling temperature is in between the
normal boiling points of pure component.

75. Statement-1: At ice ↽ ⇀ water equilibrium, on increasing the pressure freezing point of
water decreases.
Statement-2: Ice have low density so equilibrium shift in forward direction when pressure is
increased.
76. Statement-1: Relative lowering of vapour pressure in a solution is equal to mole fraction of
solute in solution.
Statement-2: In ideal solution Hmix  0 and Vmix  0

77. Statement-1 : Knowing K a of CO2 , pH can be determined of an aqueous solution of Na 2CO3

1

of known concentration.
Statement-2 : Only first hydrolysis of CO23  ion is significant because for most of dibasic
acids, K a1  K a 2 .

VMC | Chemistry 13 ACA | JEE Advanced

 Vidyamandir Classes

COMPREHENSION TYPE

Comprehension-1

For a reaction : aA  bB  cC  dD

Three students stated different ways of determining limiting reagent.

Student 1 : Calculate the minimum moles of ‘A’ needed to completely consume ‘B’, and if available
amount of ‘A’ exceeds what is needed, then ‘B’ is limiting reagent other wise ‘A’ will be
limiting reagent.
Student 2 : Calculate the ratio of the moles of the reactants initially taken, then compare it to
theoretical mole ratio (according to stochiometry of the reaction). If the theoretical ratio
exceeds ratio of moles actually taken, then reactant in numerator will be limiting
reagent.
Student 3 : Calculate the amount of product (any one of the product) that can be obtained if each
reactant is completely consume and that reactant is limiting reagent which has
produced least mass of product. Assume that atleast one of A or B is the limiting
reagent.
Now answer the following two questions :

78. Which student(s) has/have defined limiting reagent correctly ?

(A) Student-1 (B) Student-2 (C) Student-3 (D) All of these

79. If Student 3 in first experiment finds that when 1 mole of ‘A’ reacted with excess of reagent ‘B’
and in second experiment when 1 mole of ‘B’ reacted with excess of reagent ‘A’, then in the
later experiment mass of the product produced was greater. Then which should be the limiting
reagent when 1 mole each of A and B are reacted:
(A) A (B) B (C) None (D) Cannot be predicted

Comprehension-2

Zelina, is working in the chemistry lab of her school. She is provided with 4 containers of large
capacity by the lab assistant.
Container 1 contains 2L of ‘2.8 V’ H2 O2
Container 2 contains 2 L of ’16.8 V’ H2 O2
Container 3 contains sufficient amount of water
Container 4 is empty
She has been asked by her teacher to prepare H2O2 solution using the components of container 1, 2
or 3 (partially or completely) and store it in container 4.
Now answer the following two questions :

80. The volume of water required by Zelina to prepare maximum volume of 2.55 % (w/v)
H2 O2 solution is:

(A) 0.33 L (B) 1L (C) 0.67 L (D) 2L

VMC | Chemistry 14 ACA | JEE Advanced

 Vidyamandir Classes

81. Zelina prepared a 12.6 V H2 O2 solution and mixed it with excess of Kl solution and titrated the

9
liberated l2 with M hypo solution. Find the maximum volume (in L) of hypo solution that
7
could have been consumed in above process:
(A) 5.44 L (B) 5L (C) 4.67 L (D) 2.5 L

Comprehension-3
K sp of Cr(OH)3 , Al(OH)3 and Fe(OH)3 are 7  10 31, 2  10 33 and 6.4  10 38 respectively.

82. What is the equilibrium constant of the following reaction?

Fe3  (aq)  3H2 O ↽ ⇀ Fe(OH)3 (s)  3H (aq)

10 4 1038 1024
(A) 6.4  10 4 (B) (C) (D)
6.4 6.4 6.4

83. What will happen when FeCl 3 is added to a suspension of Al(OH)3 ?

(A) Colour of suspension remains same

(B) Colour of suspension changes to reddish brown
(C) Precipitate of AlCl3 will produce

(D) FeCl 3 will not show any reaction

84. What is the maximum moles of Fe2 (SO4 )3 that can be added in 2L water without precipitating
Fe(OH)3 ?

(A) 6.4  10 17 (B) 1.28  10 17 (C) 3.2  10 17 (D) 1.28  10 10

Comprehension-4

The cell potential for the unbalanced chemical reaction:

Hg 22   NO3  H3 O   Hg 2   HNO2  H2O

Under standard state conditions is E ocell  0.02 V

2.303RT
Given : NO3  3H3O   2e   HNO2  4H2O, E o  0.94 V and  0.06.
F
Now answer the following two questions :

85. At what pH will the cell potential be zero if the concentration of other components are equal to
one?
1 1 2 2
(A) (B) (C) (D)
6 3 3 9
86. How many moles of electrons pass through the circuit when 0.6 mole of Hg 2  and 0.30 mole

of HNO2 are produced in the cell that contains 0.5 mole of Hg 22  and 0.40 mole of NO3 at the
beginning of the reaction :
(A) 0.6 mole (B) 0.8 mole (C) 0.3 mole (D) 1 mole

VMC | Chemistry 15 ACA | JEE Advanced

 Vidyamandir Classes

Comprehension-5
The speed of a molecule of a gas changes continuously as a result of collisions with other molecules
and with the walls of the container. The speeds of individual molecules therefore change, but it is
expected that the distribution of molecular speed does not change with time.
A direct consequence of the distribution of speeds is that the average kinetic energy is constant for a
given temperature.
1 1 2 1 2 1 2  1 1
KE   mv1  mv1  ......  mv N   m(v12  ........ v 2N )  m V 2
N2 2 2  2N 2

1 1  1  dN i  dN i
Alternatively it may be defined as KE   m
N  2
 dN i v2i   2 m   N
. v 2i  where
 N
is the
i   i 
fraction of molecules having speeds between v i and v i  dv and as proposed by Maxwell
3/2
dN  m 
 4   exp (–mv2/2kT).v2.dv
N  2KT 
 1 dN 
The plot of   is plotted for a particular gas at two different.
 N dv 
Temperatures against ‘v’ as shown.
The majority of molecules have speeds which cluster around v MPS in the middle of the range of v. The
area under the curve between any two speeds v1 and v2 is the fraction of molecules having speed
between v1 and v2. The speed distribution also depends on the mass of the molecules. As the area
under the curve is the same (equal to unity) for all gas samples, samples which have the same v MPS
will have identical Maxwellian plots. On the basis of the above passage answer the questions that
follow.

87. For the following graph drawn for two different samples of gases at two different temperatures
T1 and T2, which of the following statements is necessarily true :
(A) If T2 > T1. MA is necessarily greater than MB
(B) If T1  T2 , MB is necessarily greater than MA
T2 T1
(C) 
MB MA
(D) Nothing can predicted

88. If two gases ‘A’ and ‘B” and at temperature TA and TB respectively have identical maxwellian
plots, then which of the following statements are true?
(A) TB = TA
(B) MB = MA
TA MB
(C) 
TB MA
(D) Gases A and B may be O2 and SO2 at 27°C and 327°C respectively,

VMC | Chemistry 16 ACA | JEE Advanced

 Vidyamandir Classes

Comprehension-6
A reaction is spontaneous if free energy change, G , for the reaction is negative. The question arises,
how we can explain the spontaneity of reversible reactions. Let us take the example of dissociation
equilibrium of N2 O4 ↽ ⇀ 2NO2 (g) . The variation of free energy with the fraction of N 2 O4
dissociated under standard conditions is shown in the figure below :

89. The standard free energy change for the conversion of 1 mole of N2O4 into 2 moles of NO2 is :
(A) 5.40 kJ (B) 5.40kJ
(C) (5.40 + 0.84) kJ (D) (5.40 + 2 × 0.84) kJ
90. When 1 mole of N2O4 changes into the equilibrium mixture, the value of G is :
(A) 0.84 kJ (B) 0.84kJ (C) 5.40  0.84 kJ (D) 0.84  5.40 kJ
91. When 2 moles of NO2 change into equilibrium mixture, the value of G is :
(A) (5.40 + 0.84) kJ (B) (5.40 – 0.84)kJ
(C) (–5.40 – 0.84) kJ (D) –5.40 kJ

Comprehension-7
Zeta potential is a scientific term for electro kinetic potential in colloidal dispersions. It is usually
denoted by using greek letter zeta ( ) it is the potential difference between dispersion medium and
stationary layer of fluid attached to the dispersed particle.

92. What does a high value of zeta potential indicate :

(A) High degree of repulsion between colloidal particles and medium
(B) High degree of repulsion between colloidal particles
(C) Easy coagulation
(D) Electrically unstable colloid
93. Zeta potential approaches zero :
(A) in acidic medium (B) basic medium
(C) at pH = 7 (D) at pH of isoelectric point

Comprehension-8
Minerals having the formula AB2O4 and crystallizing in cubic system with O2  ion forming fcc and
A 2  and B3  occupying octahedral and tetrahedral sites are generally terms as spinals.
Spinals are mainly two types : normal and inverse. In normal spinals, A 2  occupy one tetrahedral
void and B3  occupy two octahedral voids per fcc unit cell of O2  . But in inverse spinal, A2+ occupy 1
octahedral void and B3+ occupy one tetrahedral and one octahedral void per fcc unit cell of O2– ion.

VMC | Chemistry 17 ACA | JEE Advanced

 Vidyamandir Classes

94. MgAl2O4 is having normal spinal structure. Mg2+ and Al3+ are isoelecronic then which of the
following statements is CORRECT for MgAl2O4?
(A) Mg2+ being larger in size fits in octahedral void
(B) Al3+ being larger in size fits in octahedral void
(C) Al3+ occupy tetrahedral and octahedral void equally
(D) Mg2+ occupy tetrahedral void irrespective of the larger size than Al3+.

95. Some spinals have distribution of A2+ and B3+ ions in tetrahedral and octahedral voids. If the
 
formula is (A1 x B x )  A x B y  O4 then y is :
 
 2 2
x
(A) 1 (B) x (C) 1 (D) 2x
2
Comprehension-9
Properties such as boiling point, freezing point and vapour pressure of a pure solvent change when
solute molecules are added to get homogeneous solution. These are called colligative properties.
Application of colligative properties are very useful in day-to-day life. One of its example is the use of
ethylene glycol and water mixture as anti-freezing liquid in the radiator of automobiles.
A solution M is prepared by mixing ethanol and water. The mole fraction of water in the mixture is 0.9
Given:

 
Freezing point depression constant of water K fwater  1.86 K kg mol1

Freezing point depression constant of ethanol K ethanol

f  
 2.0 K kg mol 1

 
Boiling point elevation constant of water K bwater  0.52 K kg mol1


Boiling point elevation constant of ethanol K ethanol
b 
 1.2 K kg mol 1

Standard freezing point of water = 273 K

Standard freezing point of ethanol = 155.7 K
Standard boiling point of water = 373 K
Standard boiling point of ethanol = 351.5 K
Vapour pressure of pure water = 32.8 mm Hg
Vapour pressure of pure ethanol = 40 mm Hg
Molecular weight of water = 18 g mol–1
Molecular weight of ethanol = 46 g mol–1
In answering the following questions, consider the solution to be ideal dilute solutions and solutes to
be non-volatile and non-dissociative.

96. The freezing point of the solution M is :

(A) 354.4 K (B) 261.52 K (C) 234.2 K (D) 150.9 K

97. The difference in the vapor pressure of solution M and N is :

(solution N is prepared by adding ethanol in water till mole fraction of ethanol becomes 0.9)
(A) 5.76 torr (B) 6.48 torr (C) 36 torr (D) 32 torr

VMC | Chemistry 18 ACA | JEE Advanced

 Vidyamandir Classes

Comprehension-10

When non-volatile solute is added into water the resulting vapour pressure gets decreased in
proportion to the amount of solute added. This is given by Raoult’s law. Answer the following
questions.

98. To observe 1% decrease in the vapour pressure upon addition of 1 m mol of solute (i = 1) the
amount of water needed is :
(A) 100 mol (B) 99 mol (C) 0.1 mol (D) 0.099 mol

99. Which of the following will decrease the vapour pressure of water by maximum amount for the
same quantity of water ?
(A) 1g NaCl (B) 1g KCl (C) 1g Na2SO4 (D) 1g Urea

Comprehension-11

Phase diagrams provide information about the physical states of matters for different pressures and
temperatures. A general PT phase diagram is shown (Answer the following questions) :

100. Consider the statements :

I. Substance expands upon fusion.
II. Substance occurs in liquid state for P  P1 and T  T1 .
Identify the correct option.
(A) Both I and II are correct (B) Both I and II are incorrect
(C) Only I is correct (D) Only II is correct

101. It is known that substance sublimes at 2 atm and 400 K. Then the correct option is :
(A) P1  2 atm and T1  400 K (B) P1  2 atm and T1  400 K
(C) P1  2 atm and T1  400 K (D) P1  2 atm and T1  400 K

102. A solid-liquid equilibrium mixture is subjected to high pressure then the following is observed :
(A) Freezing point decreases (B) Amount of liquid increases
(C) Sublimation takes place (D) Amount of solid increases

VMC | Chemistry 19 ACA | JEE Advanced

 Vidyamandir Classes

Comprehension-12
Dehydration of salts is an important class of heterogenous reaction. The salt hydrates often dissociate
in steps to form a number of intermediate hydrates according to the prevailing pressure of moisture in
contact with the solid hydrates. Thus copper sulphate pentahydrate on dissociation yields trihydrates,
monohydrates and then the anhydrous salts in the above order as follows.

103. The ratio of equilibrium constant between pentahydrate and trihydrate and equilibrium
between trihydrate and monohydrate is :
(A) 1.9 (B) 2.9 (C) 8.6 (D) 5.6

104. Which of the following conditions is favourable for dehydration of CuSO4  5H2O under

equilibrium system CuSO4 .5H2 O(s) ↽ ⇀ CuSO4 (s)  5H2 O(g)

(i) PH O (in air)  7.8 torr (ii) PH O (in air)  5.6 torr
2 2

(iii) PH O (in air)  0.8 torr (iv) PH O (in air)  7.8 torr
2 2
The correct option is :
(A) (iv) (B) (i), (ii) (C) (iii) (D) (i), (ii), (iii)
Comprehension-13
Two liquids A and B mix to from an ideal binary liquid solution, On adding now volatile solid solute C
to the solution, A starts polymerizing into a hexamer non volatile soluble solid ' A 6 ' following zero

order kinetics, with a rate constant  10 1 moles/min. If initially 10 moles of A and 20 moles of B were
taken to form liquid solution and 5 moles of C were added then answer the following questions based
on above information and data given below :
[Data : Vapor pressure of pure A = 100 torr, Vapour pressure of pure B = 90 torr]

105. The vapour pressure of the solution 1 hrs. after solid C is added will be given by :
220 2200 2200
(A) torr (B) 98 torr (C) torr (D) torr .
3 29 24
106. Which of the following statements is incorrect regarding the above process?
(A) the vapor pressure will keep on decreasing initially
(B) the vapor pressure will become constant 100 min. after addition of C
(C) Two hours after addition of C, the vapor pressure will become 72 torr
(D) Four hours after addition of C, the vapor pressure will become 67.5 torr

VMC | Chemistry 20 ACA | JEE Advanced

 Vidyamandir Classes

107. If C is not added so there is no polymerization of A, then mol fraction of A in vapour phase will
be :
(A) 5/14 (B) 9/14 (C) 1/3 (D) 2/3

MATRIX MATCHING TYPE

108.

Column-I Column-II

50 mL of 3M HCl solution + 150 mL of

(A) (p) 4.17 m
1 M ZnCl2 solution

An aqueous solution of NaCl with mole

(B) (q) [Cl  ]  3 M
fraction of NaCl as 0.1

(C) 20% (w/w) propanol (C3 H7 OH) solution (r) [H ]  0.75 M

(D) 10.95% (w/v) HCl solution (s) 6.1 m

109. Given that:

K a (CH3COOH)  2  10 5 ,K a (C2 H5 COOH)  8  106 , K a (ROH)  3  1013

K1(H2CO3 )  4  107 , K 2 (H2 CO3 )  4  1011, log 2  0.3 ; 1.12  1.06

Match the entries in Column-I with Column-II

Column-I Column-II

(A) 0.1 M CH3COONa and 0.1 M (C2 H5 COO)2 Ba (p) 4 < pH < 6

(B) 0.1 M NaHCO3 (q) 6 < pH < 10

(C) 0.1 M aq. ROH (r) Acidic solution

(D) 10 3 M aq. RONa (s) Basic solution

110.

Column-I Column-II

(A) AgBr (p) Solubility in water is more than expectation

Solubility in acidic solution is more than that

(B) AgCN (q)
in pure water

Solubility in strongly basic solution is more

(C) Fe(OH)3 (r)
than that in pure water

Solubility decreases in presence of common

(D) Zn(OH)2 (s)
anion

VMC | Chemistry 21 ACA | JEE Advanced

 Vidyamandir Classes

111. Match the following electrochemical cells at 25o C in Column-I with their characteristics in
Column -II
Given : Eo  0.76 V, E o  0.81 V, E 0   0.01 V
Zn2  /Zn Ag/ Ag  D /D2

K sp (AgCl)  10 10 , K sp (AgBr)  5  10 13

Column-I Column-II

Pt(s)|H2 (g)|KOH(aq)||HCl(aq)|H 2 (g)|Pt(s)

(A) (1 atm) (0.01 M) (0.01M) (1 atm)
(p) Concentration cell

(B) Zn(s)|Zn 2  (aq)|| Ag  (aq)| Ag(s) (q) E cell  0

(0.1 M) (0.1 M)

(C) Pt(s)| D2 (g) |D (aq)||H  (aq)| H 2 (g) |Pt(s) (r) Cell reaction is at equilibrium
(0.1atm) (0.1M) (0.01M) 0.001atm

Ag(s)| AgBr(s)| Br  (aq) ||Cl  (aq)| AgCl(s)| Ag(s) cell will have the same emf as
(D) (510 4 M) (0.1M) (s) the one made up of standard
electrodes.

Diluting each electrode

solution to double volume
would not affect the emf of
(t)
cell (for gases, involved,
assume no change in partial
pressures)

112. Note : In answering this problem, do not neglect vanderwaal’s forces in condersed state of
matter.

Column I Column II
(X) (Y)
1 (p) Enthalpy of formation of Y.
(A) H2 (g)  H(g)
2
(q) X and Y are allotropes
(B) C(graphite)  C(Diamond)

(C) S(rhombic)  S(g) (r) X and Y are two different phases.

2 (s) The enthalpy change can be used to

(D) O3 (g)  O2 (g) calculate bond energy in X (without
3
other data)

VMC | Chemistry 22 ACA | JEE Advanced

 Vidyamandir Classes

113. Match the following

Column I Column II

(p) Have these cell parameters a = b = c

(A) Simple cubic and face-centred cubic
and     

(q)
(B) Cubic and rhombohedral Are two crystal systems

(r) Have only two crystallographic angles

(C) Cubic and tetragonal
of 90°.

(D) Hexagonal and monoclinic (s) Belong to same crystal system

114. Match the following

Column I Column II
(Name of method by which
sol is prepared)

(A) As2 O3  H2 S  As2 S3 (sol)  H2O (p) Hydrolysis

(B) AuCl3  HCHO  H2O  Au(sol)  HCOOH  HCl (q) Double decomposition

(C) FeCl3  H2 O  Fe(OH)3 (sol)  HCl (r) Reduction

FeCl3
(D) Fe(OH)3 (Fresh ppt) Fe(OH)3 (sol) (s) Peptization
(little)

115. Match the process given in column-1 performed on an ideal gas sample with changes in
column-II.

Column I Column II

Isothermal expansion against constant external

(A) (p) S univ  0
pressure

Free expansion against vacuum under isothermal

(B) (q) Ssys  0
conditions.

(C) Reversible adiabatic compression (r) Ssurr  0

Free expansion against vacuum under adiabatic

(D) (s) Ssys  0
conditions

(t) Gsys  0

VMC | Chemistry 23 ACA | JEE Advanced

 Vidyamandir Classes

116. 1 mole of X is added in 1 kg water. Volume is nearly 1L. To this mixture, small amount of Y is
added such that it act as limiting reagent. Match the effect of addition of Y in column I with
entries in column II.

Column-I Column-II
(X) + (Y)

(A) KCN + AgCN (s) (p) Boiling point increase

(B) CuS (s) + Conc. HNO3 (q) Freezing point does not increase

CH3 COOH + Ba  OH 2
(C)    0.1 (r) Osomotic pressure is unchanged

(D) HgI2 + KI (s) Vapor pressure decreases

117. Match the process given in column-1 performed on an ideal gas sample with changes in
column-II.

Column I Column II

NH4 HS (s) ↽ ⇀ NH3 (g)  H2 S (g) Kc

(A) (p) Kp 
RT

N 2 (g)  O2 (g) ↽ ⇀ 2NO(g) Kp

(B) (q) Kc 
RT

1 3 Kp  Kc
(C) N 2 (g)  H2 (g) ↽ ⇀ NH3 (g) (r)
2 2

(D) 2NOBr (g) ↽ ⇀ 2NO(g)  Br2(g) (s) K p  K c (RT)2

118. Match the process given in column-1 performed on an ideal gas sample with changes in
column-II.
Column I Column II
1
(A) 0.1 mole AlCl3 added in 89.8 mole solvent and RLVP  (p) i=2
450
0.1 mole HCOOH added in 2 L water, making 2 L solution and 1
(B) (q) 
  1.5 atm 3
40 g of a solute having molar mass 2000 amu dissolved in water 1
(C) to make a solution of volume 1 L and its osmotic pressure is (r) 
5
measured to be 0.025 atm
The freezing point of a solution containing 0.1 mole of
K 4 [Fe(CN)6 ] in 2 kg water is – 0.35 K in comparison to –0.1 K, 1
(D) (s) i
when 0.1 mole of urea is added in 3 kg water. For 2
K 4 [Fe(CN)6 ] solution

VMC | Chemistry 24 ACA | JEE Advanced

 Vidyamandir Classes

119. PA , PB , PC are vapor pressure of pure A, B and C.

X A  mole fraction of A in liquid phase
YA  mole fraction of A in vapor phase

Column I Column II
Equimolar solution of A, B and C behaving ideally,
(A) (p) YA  YC
PA  PB  PC

Equimolar solution of A and C behaving ideally,

(B) (q) X B  YB
PA  PC

High boiling point azeotrope of B and C at molar

(C) (r) YC  X C
composition 2 :1 respectively ; PB  PC

Ideal solution containing one mole each of A and B

(D) and 2 mole of C. PA  200 torr, PB  100 torr, (s) YA  YC
PC  300 torr

(t) YB  YC

120. The standard reduction potential data at 25 oC is given below.

E o (Fe3  , Fe2  )  0.77 V; E o (Fe2  ,Fe)  0.44 V;
E o (Cu2  ,Cu)  0.34 V; E o (Cu  ,Cu)   0.52 V;
E o (O2 (g)  4H   4e   2H2 O)  1.23 V; E o (O2 (g)  2H2O  4e   4OH  )  0.40V
E o (Cr 3  ,Cr)  0.74 V; E o (Cr 2  ,Cr)  0.91 V;
Match Eo of the rebox pair in List I with the values given in List Ii and select the correct
answer using the code given below the lists:
Column I Column II

(A) E o (Fe3  ,Fe) (p) 0.36V

(B) E o (4H2O ↽ ⇀ 4H   4OH  ) (q) 0.4V

(C) E o (Cu2   Cu  2Cu  ) (r) 0.04V

(D) E o (Cr 3  ,Cr 2 ) (s) 0.83V

SUBJECTIVE/INTEGER TYPE

121. (a) ‘a’ moles of K 2Cr2O7 are needed in acidic medium for the oxidation of 9 moles of
ethanol to acetic acid.
(b) an unknown metal chloride undergoes reduction reaction with Mg producing metal and
MgCl 2 . Experiments show that 52.4 gm of metal chloride reacts with 9.6 g of Mg
according to above reaction. The equivalent weight of metal in the given metal chloride
b
is 'b'. Report your answer as  
a
 

VMC | Chemistry 25 ACA | JEE Advanced

 Vidyamandir Classes

122. Determine the concentration of H3 O  ion (in mol/L) in a solution containing 2  10 3 M HOCl

& 2  10 4 M NaOCl . Given : Dissociation constant of HOCl  1.5  10 4 .

Report your answer after multiplying by 10,000.

123. An organic compound contains C, H and O atoms. One molecule of the compound contains H-
atoms equal to 66.67% of total atoms and mass ratio of C to O is 3 : 2. If the molecular
formula of the compounds is C x H y O z , what is the value of X + Y + Z. (Given vapour density of

compounds is 23 g/mol)

124. How many of the following statements is/are correct?

(i) The discharging of lead storage battery constitutes a galvanic cell
(ii) During charging of lead storage battery, anode is negatively charge
(iii) The mass lost at anode is equal to mass gained at cathode in any galvanic cell
(iv) E cell is intensive quantity and is independent of temperature

(v) The overall reaction in an electrolytic cell need not always look like a redox reaction
(vi) If E ocell of a cell reaction is negative, then the reaction is non-spontaneous under all
conditions

125. Pure water is saturated with pure solid AgCl. A silver rod is place in the solution and the
potential is measured against normal calomel electrode at 25o C . This experiment is then
repeated with a saturated solution of AgI. If the difference in potential in the two cases is
0.177V, the ratio of solubility product (K sp ) of AgCl and AgI at the temperature of the

experiment is 10x. Determine the value of x.

126. 200 mL of 0.1 M aqueous solution of acetic acid is mixed with equal volume of equimolar HCl
solution at 27o C . If 1 g of NaOH is added to this, then the [H  ] in final solution

is x  10  y (represented in scientific notation). Find x + y. K a of acetic acid = 2  10 5

127. A certain amount of Dichloroacetic acid (CHCl2 COOH) is oxidized to CO2 ,H2O and Cl2 by 300
gram-equivalents of KMnO4 in acidic medium. How many moles of barium hydroxide are
required to completely neutralize the same amount of acid ?

128. If the density of methanol is 0.793 kg L –1, what is its volume needed for making 0.0027 m 3 of
its 0.22 M solution?

129. During the preparation of H2 S2 O8 (peroxydisulphuric acid) using H2 SO4 electrolytically,

O2 gas also releases at anode as by product. When 10.304 L of H2 releases at cathode and
2.24 L O2 at anode at STP, the weight of H2 S2O8 produced in gram is :
(Round it off to nearest whole number)

VMC | Chemistry 26 ACA | JEE Advanced

 Vidyamandir Classes

130. The density of gas A is twice that of a gas B at the same temperature. The molecular weight of
gas B is thrice that of A. The ratio of the pressure acting on A and B will be :

131. KCl has NaCl type face centred cubic crystal structure and CsF has CsCl type cubic crystal
structure. Calculate the ratio of densities of CsF and KCl. It is given that the molar mass of
CsF is twice that of KCl and edge length of KCl unit cell is 2 times that for CsF.

132. One mole of a monoatomic ideal gas is taken from a and b by expansion along two paths
denoted by the solid and dashed line, as shown in the graph below. If w A is work done along
|w A |
solid line path and wB is work done along dotted line path then find .
| wB |

133. A cubic unit cell contains ‘ A x  ' ions at the corners and ‘ B y  ' ions at the centre of each face.
(i) The difference of coordination number A and B = p
(ii) If all atoms along one of the C 4 axis are removed, then the formula becomes A q B r .

Find p × q/r.

134. 1 g of charcoal adsorbs 100 mL of 0.5 CH 3COOH to form mono layer and there by the molarity
of CH3COOH reduces to 0.49 M. Calculate the surface area of the charcoal adsorbed by each
molecule of CH3COOH. Surface area of charcoal  3.01  102 m 2 / gm . Give your answer by
multiplying with 1019.

135. The nonstoichiometric oxide of iron called Wustite has empirical formula Fe xO. It has a density
of 5.75 g/CH3, a cubic unit cell with cell constant of 431 pm and an FCC arrangement of
oxygen atoms. Find the percentage of occupied iron sites (Fe = 56)

136. The compression factor (compressibility factor) for 1 mole of a van der Waals’ gas at 727°C and
100 atmosphere pressure is found to be 0.5. Assuming that the volume of gas molecules is
negligible, calculate the van der Waal’s constant a. [R = 0.082 atm × litre/mol K].

137. The average energy required to break a P – P bond in P 4(s) into gaseous atoms is 53.2 kcal
mol–1. The bond dissociation energy of H 2(g) is 104.2 kcal mol –1 : Hf of PH3(g) from P4(s) is
5.5 kcal–1. The P–H bond energy in kcal mol–1 is [Neglect presence of Vander Waals forces in
P4(s)]

VMC | Chemistry 27 ACA | JEE Advanced

 Vidyamandir Classes

138. The difference between H and E on a molar and magnitude basis for the combustion of n-
octane at 25C would be :

139. By how many of the following ways, the concentration of CO 2 can be altered at equilibrium?

CO(g)  H2 O(g) ↽ ⇀ CO2 (g)  H2 (g) H   ve

(A) By increasing temperature (V = constant)

(B) By decreasing volume (T = constant)
(C) By increasing volume (T = constant)
(D) By adding more CO(g) (V, T = constant)
(E) By removing H2(g) (V, T = constant)
(F) By adding inert gas (P, T = constant)
(G) By adding inert gas (V, T = constant)

140. 20 g of naphthoic acid (C11H8O2) is dissolved in 50 g of benzene (K f = 1.72 K kg mol–1). If the

Van’t Hof factor (i) of naphthoic acid is 0.5 then the value of depression in freezing point (K)
will be :

141. The freezing point of an aqueous solution containing 0.1 mol/kg of KCN was –0.38°C. Then
gradually increasing moles of Hg(CN)2 are added and freezing point is measured. The freezing
point increased to a maximum of –0.285°C and then again decreased. What is the value of x, if
the following reaction takes place? Hg(CN)2 (aq)  x(CN  )(aq)  Hg(CN) xx  2 (aq)

142. Dissolving 1 mole of camphor (C10H16O) in one mole of an equimolar mixture of acetophenone
(A) (PA  600 torr) and benzophenone (B) (PB  400 torr) fails to change its vapor pressure.
However, adding x moles of (non-volatile) anthracene to this solution lowers its vapor pressure
to 200 torr. If vapor pressure of pure camphor is 100 y (torr) find (x + y).

143. Vapour pressure of an equimolar mixture of benzene and toluene at a given temperature was
found to be 80 mm of Hg. If vapour above the liquid phase is condensed in a beaker, vapour
pressure of this condensate at the same temperature was found to be 100 mm of Hg. If the
pure state vapour pressure of benzene and toluene is respectively x and y. Then determine
x  2y
value of :
50

144. A current of dry air passed (in sequence) through a vessel having pure water then through a
vessel having 0.2 M NaCl aqueous and finally through a vessel having 0.2 M Urea aqueous
solution. Consider three variables a (for pure water vessel), b(for NaCl vessel) and c (for Urea
vessel). Take the value of the variable to be 10 if loss of mass is observed in a vessel, 5 if gain
in mass is observed for a vessel and 0 if no change in mass of the vessel is observed. Report
your answer as (a + 2b + 3c).

VMC | Chemistry 28 ACA | JEE Advanced

 Vidyamandir Classes

145. Consider the equilibrium, Ni(s)  4CO(g) ↽ ⇀ Ni(CO)4 (g) K p  0.125 atm3

If equal number of moles of CO and NI(CO)4 (ideal gases) are mixed in a small container fitted
with a piston, if the maximum total pressure is P (in cm of Hg) to which this mixture must be
brought in order to just precipitate out metallic Ni then report your answer as P/4.

146. Equilibrium constant for the given reaction is K  1020 at temperature 300 K

A(s)  2B (aq) ↽ ⇀ 2C(s)  D (aq) K  1010

Calculate the equilibrium concentration of B(in mol/L) starting with mixture of 1 mole of A and
½ mole/litre of B in a container of volume 1L at 300 K
(Give your answer by multiplying it with 10 12)

147. 1.15 grams of a mixture of NO2 and N2O4 at equilibrium has a pressure of 0.82 atm, at
temperature 600 K in a container of volume 1 litre. Calculate degree of dissociation of N 2O4
assuming that all the NO2 present comes from N 2O4 by the equilibrium

N 2 O4 (g) ↽ ⇀ 2 NO2 (g)

[Take R = 0.082 lit-atm mol–1 K–1]. (Write your answer after multiplication with 100)

148. A metal ‘A’ exists in the bcc structure having uncovered length along the edge equal to 1.2 Å. If
molar mass of the metal is 307.2 gm/mole then calculate density of the crystal in g/mL
[Use : N A  6  1023 and 3  1.7 ]

149. Total number of isomers (including stereoisomers) for the complex [Pd(NH3 )(H2O)(NO 2 )2 ] are:

150. How many of the following elements have  f Ho  0 at 298 K?

O2 (g) , Monoclinic Sulphur, Diamond, Red phosporous, O3 (g) , Cl2 (g) , Rhombic shuphur,
Br2 (g), O(g), I2 ( ℓ), H2 (g), Liquid sodium, Fe(s), Black phosphorus.

151. The equilibrium partial pressure of N 2 O4 (g) and NO2 (g) are 4 and 2 atm, respectively. Now, at
constant temperature, the equilibrium pressure of system is increased to 60 atm. The new
equilibrium partial pressure of N 2 O4 (g) becomes:

VMC | Chemistry 29 ACA | JEE Advanced

 Vidyamandir Classes

Answer Key for Advanced Chemistry Assignment

Physical Chemistry | JEE Advanced
1 2 3 4 5 6 7 8 9 10 11 12
D B C B A A C C D A B D
13 14 15 16 17 18 19 20 21 22 23 24
C A C B B B D B A C B B
25 26 27 28 29 30 31 32 33 34 35 36
D C A C B C A D D B C C
37 38 39 40 41 42 43 44 45 46 47 48
B D B D A D C D A B A C
48 50 51 52 53 54 55 56 57 58 59 60
C C BCD ABC BD ABC ACD ABCD ABC ACD BCD ACD
61 62-(1) 62-(2) 63 64 65 66 67 68 69 70 71
BD B C BD CD BD ACD ABD D B B A
72 73 74 75 76 77 78 79 80 81 82 83
A C D A C D D A C B B B
84 85 86 87 88 89 90 91 92 93 94 95
A D A C D A B C B D D C
96 97 98 99 100 101 102 103 104 105 106 107
B C D A C D D A C A C A
108 109 110
Ar;Bs;Cp;Dq A  q, s ; B  q, s ; C  q, r ; D  s A  s ; B  p, q ; C  q, s ; D  q, r
111 112 113
A  p, q ; B  q ; C q, s, t ; D  p, r, t A  p, s ; B  p, q, r ; C  p, r ; D  s A  p, s ; B  q ; C  q ; D  q, r
114 115 116
A  p, s, t ; B  p, r, s, t ; C q, r ; A  r, q ; B  p, s, q ; C p, s, q ;
A  q ; B  r ; C p ; D  s
D  p, r, s, t D  p, s, q
117 118 119
A  s ; B  r ; C p ; D  q A  p, q ; B  r ; C s ; D  q A  p ; B  r ; C q, t ; D  r
120 121 122 123 124 125 126 127 128
A  r ; B  s ; C p ; D  q 5 4 9 2 6 11 25 24
129 130 131 132 133 134 135 136 137 138 139 140
50 6 4 5 8 5 95 17 77 11 3 2
141 142 143 144 145 146 147 148 149 150 151
2 8 4 50 76 50 33 2 7 7 53

VMC | Chemistry 30 ACA | JEE Advanced