Vidyamandir Classes

Solutions to JEE Advanced Final Practice Test-2 | Paper-2 | 2021

PHYSICS
MULTIPLE CORRECT ANSWERS TYPE
R IR 8 4
1.(AC) Since, cos     
Z IZ 10 5
Also lxC  lX L  XC  X L
Current will be leading

In a LCR circuit V  VL  VC 2  VR2   6  122  82  10

V  10; Which is less than voltage drop across capacitor.

2.(AC) Area = work done  P0V0  RT0

3 9 11
u  1 R  4 R0  T0   u  RT0  Q RT0 .
2 2 2
3.(AB) N A 2  N B 9  N A  4.5 N B

g sin  2s 2h
4.(BC) a  ,t  ( s sin   h)
k 2 a a sin 
1 2
R
2 k2 2
For A, mR 2  mk 2  2

3 R 3
g sin 60 3 3 g
 aA  
2 10
1
3
2h
3 3g 3 40h
tA   
10 2 9g
2 k2 2
For B, mR 2  mk 2  2

5 R 5
g sin 30 5 g 2h 56h
 aB   ; tB  
2 14 5g 1 5g
1 
5 14 2
 tB  t A  k A  k B  mgh

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2
1 12 v  5
k A  mv A2  mR 2  A   mv A2
2 23  R 6
2
1 12 v  7 5 2 7 25
k B  mvB2  mR 2  B   mvB2  mv A  mvB2  vB  vA
2 25  R  10 6 10 21

Temperature difference
5.(AC) Heat current 
Total thermal resistance
l 0.16 2
Thermal resistance of the first rod, R1    K/W
K1 A 400 10  104 5 
l 0.16 1
Thermal resistance of the second rod, R2    K/W
K2 A 
160 20  10 4
 2

T1  T2 200  20
So, the heat current, H    200 W
R1  R2  2 1 
  
5 2
Let the temperature of the junction be T
Then, since the heat current through both rods must be equal,
200  T T  20 200  T T  20
    T  120 oC
R1 R2 2 1
   
 
5  2
200  120
The temperature gradient in the first rod   5 o C/cm
16
120  20
The temperature gradient in the second rod   6.25 o C/cm
16

6.(AC) According to Newton’s second law of motion

t
dL a

dt
or  dt  L f  Li   4qE 2
dt  L f
0

qB0
qa2 B0  2ma2  
2m

7.(BCD)
Q0
Maximum current through the inductor is I max 
LC
10  103
When only switch k1 is closed then I max   10mA
5  2 101
10  103
When only switch k 2 is closed then I max   5mA
10  2 101
When both the switches are closed then maximum current through L2 is
L1
I 2  Q0  5mA
L2 ( L1  L2 )C

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dP
8.(AD) As pressure gradient changes  ( g  a).
dy
So buoyant force also changes as it is due to pressure difference. But as body also accelerates with lift so
the fraction of volume submerged does not change and the extra buoyant force will provide the resultant
force ' ma ' to the body.

9.(A) For energy to be completely potential

    3n  1    3n  1 
cos  t    1  t   n  t     sec.
 3 3  3    300 

10.(A) For energy to be completely kinetic

 
cos  t    0
 3
   6n  5 
t    2n  1  t   sec.
3 2  600 

11.(D) During charging

During discharging

1 2

2 3

12.(D) During Discharging if V PQ V

V 2V
V1  V2  ; V3 
3 3

 
V2  2
Total heat generated H    3R dt  V
2
dt
  3R
 2 
V / 32 dt  1 H1 1
Heat generated in R1 H1   V  
2
dt
R 9R H 6

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13.(0.52)
Let the initial velocity of the shell be u
2u sin 45 gT
 T  u
g 2
Let the velocity of the gun immediately afterwards be v
Conserving momentum in the horizontal direction:
M   24M  u gT
0    u cos 45     v   v 
 25   25  24 2 48
Distance between the gun and the shell at the instant of landing,
u 2 sin 90 u 2 gT 2 gT 2 gT 2  25  2
D  vT        gT  0.52 gT 2
g g 48 2 48  48 
 4  R 3   4   R    3R
3 3
14.(6) The total charge on the charged spherical shell, Q   2          R3      
 3 2   3   2    2
   
For points outside it, the charged spherical shell will behave like a point charge Q fixed at the origin
We can find the work done by finding the initial and final potential energy of the system
3R
The initial situation is that a point charge Q is kept on the axis of the dipole at a distance from it. So,
2
for writing the potential energy, we can use the result for the electric potential at a point on the axis of a
dipole. We note that the point charge Q is closer to the negative charge of the dipole, so the potential at the
location of Q will be negative.
Similarly, the final condition can be seen as a point charge Q kept on the equator of a dipole, and we can
use the result for the electric potential on the equator of a dipole to find the final potential energy.
 
 
Therefore, the initial potential energy, 
U1  Q 
p    pQ
 3R  
2
90 R 2
 40   
  2  
And, the final potential energy, U 2  Q  0   0

pQ  p  3R3  1 p  R
So, the work done, W  U 2  U1     
90 R 2  90 R 2   2  6 0
15.(3)

When the disc is on the verge of slipping

f max  N    F0  Mg 

f max   F0  Mg 
acm  
M M

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 F0 .R    Mg  F0  .R
 
I 1
MR 2
2
For pure rolling : acm  R
  Mg  F0  F0 R    Mg  F0  .R 3Mg F  2  3 
 R  F0   0 3
M 1
MR 2 2  3 Mg
2
16.(600)
2S cos  2  7.5 102 15 102
h0   4
  3  102 m  30mm
r0g 5 10 10 103
5
h0  30 
h0 r0  hr  r r0     0.5  0.6 mm
h  25 
17.(8) Maximum speed, vM  6  5   30 m/s
Therefore, 30   2 T  5   0  T  20 s
So, the total time for which the car moved is 20 s.
Distance travelled between t = 0 and t = 5,
1
D1   6  5  75 m
2
2
Distance travelled between t = 5 and t = 20,
1
D2  30 15   2 15  225 m
2
2
Since D1  D2 , we can be sure that the instant t  T0 lies between t = 5 and t = 20
So, equating the distance travelled between t = 0 and t  T0 to the distance travelled between t  T0 and

 2 T0  52  30   2 T0  5  20  T0    2  20  T0 2

1 1
t  T , 75  30 T0  5 
2 2
30T0  75  T0  5   2  20  T0    20  T0  30T0  75   20  T0   T0  5 
2 2 2 2 2
 

 T02  40T0  250  0  T0  20  5 6

So, to the nearest integer, T0  8s

18.(0.43) Place  m and m particle at the vacant corner

Assume the  m particle and the rest seven particles as system (1)
a a a
The total mass of system (1) is m1  8m an the position vector of its com is r1  iˆ  ˆj  kˆ and assume
2 2 2
m particle as system (ii)

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m2  m, r2  aiˆ  ajˆ  akˆ

m1r1  m2 r2
8m  
a ˆ a ˆ a ˆ
2 2 2 

i  j  k    m  aiˆ  ajˆ  akˆ  3a ˆ 3a ˆ 3a ˆ
 rcm    rcm  i j k
m1  m2 8m   m  7 7 7

19.(8) Let the acceleration of the blocks be a1 , a2 and a3 respectively, all assumed upwards
Let the mass of A be m
Then, 2T  mg  ma1
T  3g  3a2 ; T  2 g  2a3
2T T T
Therefore, a1   g ; a2   g ; a3   g
m 3 2
But we know that a2  a3  2a1
T  T   2T  4g 24mg
   g     g   2   g  T 
 3   2   m  5 4  5m  24 

6 m
But, for the block B to accelerate upwards, a2  0
T 24mg
 g 0  T  3g   3g  m8
3  5m  24 
Alternative solution
It is quite intuitive that if the block A is heavier, the block B will accelerate upwards, and if A is lighter, B
will accelerate downwards. Thus, there exists a value of the mass of A for which B remains at rest (while A
and C accelerate), and this is the value that we need to find. We can find it by replacing a2  0 in the
equations.

20.(41.18)
R1 40 2
Initially,  
R2 60 3
After raising the temperature of R1 , let the length AJ (in cm) for which the galvanometer shows zero reading
be x
R1 1   0.0005100   x

R2 100  x
R1 x
 1.05 
R2 100  x
2 x
   1.05 
3 100  x
Solving, we get x  41.18 cm

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Chemistry
MULTIPLE CORRECT ANSWERS TYPE
1.(AC) CN  and NO  are isoelectronic, have the same bond order of 3.
2.(ACD)
Option (A) is correct because in the limit of large volume, both intermolecular force and molecular volume
becomes negligible in comparison to volume of gas.
Option (B) is wrong statement because in the limit of large pressure Z  1.
Option (C) is correct statement. For a van der Waals’ gas, coefficients are independent of temperature.
Option (D) is correct statement because attractive forces dominate in low pressure region.

3.(BD) Diamond has a three-dimensional network structure, a hard substance where graphite is soft due to layered
structure.
In graphite, only three valence electrons are involved in bonding and one electron remain free giving
electrical conductivity. In diamond, all the four valence electrons are covalently bonded hence, insulator.
Diamond is better thermal conductor than graphite. Electrical conductivity is due to availability of free
electrons, thermal conduction is due to transfer of thermal vibrational energy from one atom to another
atom. A compact and precisely aligned crystals like diamond thus facilitate better movement of heat.
In graphite C  C bond acquire some double bond character, hence, higher bond order than in diamond.

4.(ABC)
The structures of these oxides are

(A), (B), (C) have N  N bonds.

5.(ABD)
Ag  is precipitated by HCl only while all others are precipitated by passing H 2S in the presence of HCl.
6.(BCD)
E,F and G are not resonance structures because movement of hydrogen between E and F are involved.
E,F and E,G are tautomers in which E is keto form and both F and G are enol form of the same E .
F and G are geometrical isomers.
F and G are distereomers as they are stereo isomers but not related by mirror image relationship.
7.(A)

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8.(C) Reaction proceeds via diazonium salt with neighboring group participation.

9.(B) L  M At constant V  isochoric, N  K also.

1
10.(C) By Boyle’s law at constant temperature, P 
V
By Charles’ law at constant pressure, V  T
Process taking place at
Constant temperature – isothermal
Constant pressure – isobaric
Constant volume – isochoric
Constant heat =- adiabatic
KL At constant p, volume increase thus, heating
LM At constant V, pressure decreases thus, cooling
MN At constant p, volume decreases thus, cooling
NK At constant V, pressure increases thus, heating
11-12
11.(B) 12.(B)

CH MgBr H SO ,


3

 
2 4 
H /H 2O


Q    
O
3 OH
Zn  H O 2 aldol

13.(7) It is a case of simultaneous solubility of salts with a common ion. Here, solubility product of CuCl is much
greater than that of AgCl, it can be assumed that Cl  in solution comes mainly from CuCl.
Cl   K sp  CuCl   103
 
Now, for AgCl, K sp  1.6  1010  Ag   Cl     Ag    103

  Ag    1.6  107  1.6  10 x  x7

 
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 Vidyamandir Classes

14.(0) Rate of reaction is constant with time. So the order of the reaction is zero
15.(75) In P4 , all phosphorus are sp 3 -hybridised and has 75% p  character.

16.(4) PCl5  SO 2  POCl3  SOCl2

PCl5  H 2 O  POCl3  2HCl
2PCl5  H 2SO 4  SO 2Cl 2  2POCl3  2HCl
6PCl5  P4 O10  10POCl3

17.(6) mmol of complex  30  0.01  0.3

Also, 1 mole of complex [Cr  H2O5 Cl]Cl2 gives only two moles of chloride ion when dissolved in
2
solution Cr  H2O5 Cl Cl2  Cr  H2O5 Cl  2Cl
 mmol of Cl  ion produced from its 0.3 mmol  0.6
Hence, 0.6 mmol of Ag  would be required for precipitation
 0.60 mmol of Ag  0.1M  V  in mL  V  6 mL

18.(5) Ligand is


19.(3) 
H
H O

2

O OH 
20.(1)  3
Zn  H O
 

2

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MATHEMATICS

MULTIPLE CORRECT ANSWERS TYPE

1.(ABC)
Because f is continuous for all x, the intermediate value theorem implies that the graph of f must
intersect the x  axis. The graph must also intersect the y axis since f is defined for all x , in particular at
x  0, as f need not be differentiable. Hence A, B and C need not be correct.

2.(ABD)
Clearly if f  x   a  x    x    then g  x   b  x    x   
 h( x)  k ( x  ) 2 ( x  ) 2  h( x)h( x)  2k ( x  )3 ( x  )3 (2 x    )
d
So distinct roots of (h( x)h( x))  0, are 4.
dx
3.(BC)
2
ln(1  2 x)
Let I  1  x2
dx
0

Put x  tan   dx  sec2  d ; when x  2,   tan 1  2 

tan 1 2
I  ln(1  2 tan ) d  ....(1)
0
Applying properties
tan 1 2 tan1 2
I   1
ln 1  2 tan(tan 2  ) d    
  2  tan   
ln  1  2 

 d
 1  2 tan   
0 0

tan 1 2 tan 1 2
I  ln 5 d  
 ln (1  2 tan ) d 
0 0
I

2 I  tan 1 2.ln 5
1
I  tan 1 2.ln 5  tan 1 2.ln 5
2
Hence a  2 and b  5

4.(BCD)
, , ,  are in AP with common difference d , then
    d ,     2d and     3d ……….(i)
Given, , ,  are roots of x3  x2  ax  b  0, then
      1 ………..(ii)
      a …..(iii)
  b ……(iv)
Also, , ,  are the roots of x3  4 x 2  mx  n  0, then
      4 …………(v)

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      m …….(vi)
  n …..(vii)
From equation (i) and (ii), we get
3  3d  1 ……..(viii)
And from equation (i) and (v), we get
3  6d  4 ………(ix)
From equation (viii) and (ix), we get
2
d  1,   
3
Now, from equation (i) we get,
1 4 7
  ,   , and  
3 3 3
From equation (iii), (iv), (vi) and (vii), we get
2 8 13 28
a   ,b  , m  , n  
3 27 3 27
a  m  5, n  b  a  2 and b  m  n  3
 1
 1  tan 
 sin1  1   1  sin1  2     1   1  
5.(BC) tan 1  1
   tan 
1
   tan    
 cos1   cos1   1  tan 1   4 2 2 4
 2

   32 
2cos1 x  cos1 2 x 2  1  2cos 1  4 / 5   cos 1   1
 25 
  
cos 2cos 1  4 / 5 
7
25

6.(ABD)
Co-ordinates of P, Q, R are  a cos2, b sin 2  ,  a cos 2, b sin 2  &  a cos 2 , a sin 2  respectively.
Equation of PQ is
x y
cos       sin       cos      …..(i)
a b
Similarly, equation of chord QR will be
x y
cos      sin      cos     …..(ii)
a b
If (i) passes through one of the focus  ae, 0  then (ii) will pass though other focus  ae,0 
ae
 cos       0  cos     
a
i.e., e cos       cos      …..(iii)
ae
and, cos      0  cos    
a
i.e., e cos      cos     …..(iv)
cos      cos     
On dividing (iii) by (iv), 
 cos     cos    

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 Vidyamandir Classes

cos      cos    
 
cos       cos    
By componendo & dividendo
2cos  cos  2sin  sin 

2sin  sin  2cos  cos 
 cot 2   tan  tan  ..…(v)
 tan ,cot , tan  are in G.P.
cos2  sin 2  cos2   sin 2  1
From (v),   
sin  sin  cos  cos  sin  sin   cos  cos  cos     
cos  cos  sin  sin 
 sin 2    cos2  
cos      cos     

x2 y2
7.(AD) Equation of the ellipse is  1
a 2 b2
Equation of the parabola with focus S  ae, o  and directrix x  ae  0 is y 2  4aex
2b 2
Now length of L.R. of the ellipse is and that of the parabola is 4ae.
a
For the two latus rectum to be equal,

We get
2b 2
 4ae 

2a 2 1  e 2   4ae  1  e 2  2e
a a
 e 2  2e  1  0 ….(i)
 e  2 1
4 4
1  sin 2 x
8.(ABC) v   dx   (sec
2
x  2 tan x) dx  tan x  2ln  sec x   0 4  1  ln 2   0  1  ln 2
0
cos 2 x 0
4
cos 2 x 2 tan x
Again u   1  sin 2 x
dx ; Putting sin 2 x 
1  tan 2 x
0
4 4 4
dx
 1  tan( 4)  x 2
dx dx
u  1  tan x  2 tan x
2
  (1  tan x) 2

0 0 0
4 4
dx (1  tan x )2 1
  1  tan x 
2
  4
dx  v
4
1 
0 0

 1  tan x 

1
4  1  4
 4
u   (1  2 tan x  tan x)dx     2ln sec x  tan x  x 
2
4  4  4
0

 0 0

1  2  1
   (ln 2)  1    (ln 2)  1
4 4 2 4 4
1 v
Hence u  (ln 2)  1 and v  1  ln 2  ; 4
4 u

VMC | 2021 | Solutions 12 JEE Adv. Practice Test-2 | Paper-2

 Vidyamandir Classes

9.(D) Let S denote the set of points inside a square with corners
 a, b  ,  a, b  1 ,  a  1, b  ,  a  1, b  1  X

1
Let P denotes the set of points in S with distance less than from any corner point. (observe that the
4
1
area of P is equal to the area inside a circle of radius ). Thus a coin, whose centre falls in S , will cover
4
a point of X if and only if its centre falls in a point of P.
2
1
 

   
area of p 4
Hence, p 
area of S 1 16

10.(D) Let the length of the circumference is 2s. Let x denote the clockwise arc length of PQ and let y denote
the clockwise are length of PR.

Thus, 0  x  2s and 0  y  2s
Let A denotes the subset of S for which any of the following conditions holds:
(i) x, y  s (ii) x  s and y  x  s
(iii) x, y  s (iv) y  s and x  y  s
Then, A consists of those points for which P, Q and R lie on a semi-circle. Thus,

area of A 3s 2 3
p  
area of S 4s 2 4
ba ab
sin cos
11.(A) We have
sin b  sin a

cos c
 2 2   cot c  cot a  b  cot c  c  a  b
cos b  cos a  sin c a b ab 2 2
sin sin
2 2
VMC | 2021 | Solutions 13 JEE Adv. Practice Test-2 | Paper-2
 Vidyamandir Classes

1 1 2
 2
12.(C) Here b
2
a  c3  1  1  2 .
1 1 1 b a c

b a c2
1
 n  n r  r
x
13.(3) We have lim   1r n Cr 
x 0    n r

Ck . x .2  x 2  x
k k
  

 r 0  k 0 
1
 n r x
 
lim   1 nCr 1  2 x 
x 0 
r nr
x2  x   
 r 0 
1

   x
n x n
 lim 1  2 x  x 2  x   lim 1  3x  x 2
x0 
  x0

3x x2 .n lim f  x . g  x  

lim  g x 
 e x 0 x
 e3n  lim 1  f  x    e x 0 
 x 0 
 e3n 3

14.(1) Equation of the auxiliary circle is x 2  y 2  a 2 ….(1)

x  y
Equation of tangent at a point p  a cos , b sin  is   cos     sin   1 ….(ii)
a b
Which meets the auxiliary circle at point A and B.
 Equation of pair of lines OA and OB is obtained by making homogeneous (i) with the help of (ii) as
2
x 2
y 
x  y  a  cos   sin  
2 2
a b 
2 xya sin  cos   a 2 2  2
 1  cos  x2 2
  1  sin  y  0
b  b 
But AOB  90
 Coefficient of x 2  coefficient of y 2  0
 a2 
 1  cos2   1 
a2 2
b2
sin   0   
sin2  1  2   1  0  a 2  b2 sin 2   b2
 b 
 a 2e2 sin2   a 2 1  e2    e 1  sin 2   1
15.(2)

k
OBk  k , AOBk 
2n
1 k 1
Sk  k sin (using   ab sin  )
2 2n 2

VMC | 2021 | Solutions 14 JEE Adv. Practice Test-2 | Paper-2

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 
n
k k x
 Sk  2n2  sin 2n  2n  n sin 2n  2 0 x.sin 2 dx
1 k 1 k 1 1
 L  lim
n n 2
k 1 n 1 n 1

1  2 x  1  2 2  x   2
1 1
x 2 1
  x cos
2  

2 0   0
cos dx   0  .  sin    2 .
2  2    2 0  
16.(5250)
2 2
4a
 (sin x  a cos x)3 dx 
2  x cos x dx  2
0 0
2 2
Let I1   (sin x  a cos x) dx   (sin x  a3 cos3 x  3a sin 2 x cos x  3a 2 sin x cos2 x )dx
3 3

0 0
2 2 2 2
  sin 3 x dx  a 3  cos3 x dx  3a  sin 2 x cos x dx 3a 2  sin x cos
2
x dx
0 0 0 0
2 2
2 2
  a3    3a  (1  cos 2 x) cos x dx  3a 2  sin x(1  sin
2
x) dx
3 3 0 0
2
3

 1  a3  3a   2


1 
3


3a 2


1 
2  2 2a 3
3
  3 aa
 3
2

2a 3 2
I1   a2  a 
3 3
2 2
2
I2   x · cos x dx  x sin x
II
0
  sin x dx
0 I 0
2
I 2  x sin x  cos x 0
 2
I2  1 
2 2
2a 3
2 4a   2 2a 3 2
I  a2  a   .   a2  a   2
3 3 2 2 3 3
2a 3 2
  a2  a   2  2a 3  3a 2  3a  2  6  2a 3  3a 2  3a  4  0
3 3
3 3
a1  a2  a3  
2
  a1a2 
2
 a12  4  2   a12  1000  4  250  21  5250
9 6 21 21
  1000
4

17.(3.14) f '  x   f 2  x   1
 f 2  x   1   f '  x  in  a, b 
f ' x 
1  in  a, b 
1  f 2  x
b b f ' x
 a dx   a 1  f 2  x dx
    
b  a  (tan 1  f  x  a        b  a   
b

 2  2 
VMC | 2021 | Solutions 15 JEE Adv. Practice Test-2 | Paper-2
 Vidyamandir Classes

18.(9) Let the angle between a and b is  and a  b and c is 

 a b c   6
 
 sin  cos   1  sin   1, cos   1    90,   0
 a , b and c are mutually perpendicular.
Again, b c dˆ   0
4 0 1
3 3
 0 9 c .dˆ  0  c .dˆ  
2
1 c .dˆ 1

We have, a.b  0

1 0 0
2 3 3 27 9
(a  c )  dˆ  0 9 9 
2 4 4
3 3
0 1
2
2

   
2 2 3 3 27
 a  c   dˆ  a.dˆ c  c .dˆ a  a 
2 4
2 36 2
So, (a  c )  dˆ   a  c   dˆ  9
4
ALTERNATIVELY :
2 2
Use the formula | u  v |2  | u  v |2  | u |2 | v |2 to get ( a  c )  dˆ   a  c   dˆ  a  c  9
2

19.(255)
xn  1   x  1  x  2   x  3 ......... x  n 
By Putting x  2,
2n  1   2  1  2  2 ......... 2  n1 

 2  1 2   2 ......... 2   n1  2n  1  2n  1.

28  1  255
 2 2
 1 1

1
20.(2) Here, S   12        ....... 
k 1 K
2
 2   3

 1K 1 2 1
2
1
2
t  K2
 1        ...................
 2   3
k 1

 1   1   1 

2 2 

2
S S
S  t  2.          ........    2. 
 2   4   6 
 
 4 2

S S
 t  2
2 t

VMC | 2021 | Solutions 16 JEE Adv. Practice Test-2 | Paper-2