Solutions to JEE Advanced - |JEE 2022 | Paper - 2

PHYSICS
 V V   Vs  gt 
1.(AC) f   s  f0  f    f0
 Vs   vs 
f 0 gt
 f  f0 
Vs
Hence it is straight line
 V  10  30 
2000  1000  s 
 Vs 
 Vs  300m / s

2.(AB)


2
mV
qV0 B  0

R
mV0 m 2mV0
R at t  ,y
qB qB qB
1 qE 2  2m 
z  ut  at 2  0  t T  qB 
2 m  
qE 2
z1  T
m
qE
z2   2T 
2

mv 2 qBr
3.(AC)  qvB  v   5.27 105 m / s ; m  9.11031 kg
r m
1 2
Kinetic energy of electron  mv  126.3  10 J  0.8eV ; q  1.9 1019 C
21

2
The energy of the emitted photon when electron jumps form n  3 to n  2 ; r  10 103 m
 13.6   13.6 
   2     2   1.89eV
 3   2 
Work function  E  K max  1.89  0.8  1.09eV

1
 1 1 1 u v 1
4.(AC)    
v u f uv f
uv  100 f  1600
 u  20cm and 80 cm (v  80 cm and 20 cm respectively)
5.(AD) Dipole moment of the two bigger arcs is
 /4

 dP1  
 /4

dq 2 3R cos  
 /4

 dP1  
 /4
6R 2 cos d  ( dq  ( 3R)d )

 /4
P1  6R  cos d 
2

 /4

 6 2R 2
Similarly for smaller arcs the dipole moment is
P2  2 2 R 2

Pnet  P12  P22  4 5R2

3 9 3 3
6.(ABC) D  1m, d  5  10 m,   500  10 m, t1  2 10 m, t2  1.5  10 m
t1 D
Shift due to the first slab, y1   1  1  20cm
d
tD
Shift due to the 2nd slab, y2    2  1 2  12cm
d
Net shift  20 12  8cm
st
Shift will be towards the 1 slab.
7.(C) mg  lVsub g
0V0  l (1 h)
0 (1)  l  h
As cube is pushed, water rises
500 h
  h  0.5m
1000 1
If it is pushed by x, water level rises by x. So it is submerged by 2 x.
To dip completely, we need to push it by 0.25 m only. Then buoyant force becomes constant.

8.(C) Wman  Wg  WB  0 (by WET)

Wman  500 10  0.5  WB  0
WB  Wgravity on liq.

2
 0.25 3 0.5 
WB     10  g   0.5  2 x  dx   103  g   dx  
 0 0.25 

WB  104 0.5  0.25  0.252   0.5  0.25  

 
 1 1 1    2  1  4  10
4
7
WB  104       104
 8 16 4  16 16
 7 1 3
 Wman  104     104  1875 J
16 4  16
d
9.(C)  E.dl  dt  E.2R  R 2 2 B0t (E: induced electric field)

 E  B0 Rt ; B    dQE  R  QB0 R 2t
Torque due to magnetic field should be just equal to torque due to friction.
 QB R 
 f  mgR   0  mgR  QB0 R 2
 mg 
B   f  QB0 R 2t  QB0 R 2  t  1s

10.(D) Angular acceleration after t  1s

I  B   f

 mR    QB R t  QB R
2
0
2
0
2

QB0
  t  1
m
w t
QB0
 d 
0
m   t  1 dt
1

QB0 t2 1
  2 t  2
m  
2QB0
At t  3s,  
m
11.(D), 12.(C)
w  w12  w23  w31  2  3, (3P0 )(3V0 )  P0 V 
1
  4 P0  2V0   nRT ln  3  P0 8V0 
2
 4 PV0 0  9 PV
0 0 ln 3

  9ln 3  4  PV
0 0

 3R 
n  .T   w
Q
  
2
C
nT nT

3
 3R 4 PV
  0 0 ( 8P0V0  nRT from 1  2)
2 n T
3R PV
  0 0
2 n  2T0 
3R R
   2R
2 2
Q123  n  2R  T12    w23 
 n  2R 8T0   nR  9T0  ln  3
 nRT0 16  9ln 3
w  9 ln 3  4 
  
Q123  9 ln 3  16 

  X  XC 
1.(0)  tan 1  L   R  XC
4  R 
XC '  4XC X L '  2 X L  4 X C R '  2R
 X ' X C ' 
 '  tan 1  L 0
 R' 
2.(126) For just submerged, densities should be equal
or  200  10  g  wV g at 20C
at new temperature,
 w 
 200  10  m g    V 1  3T  g
 1  T 

wV  m  wV
1  3T 
1  T 
Binomial approximation,
 wV 1   3    T  ; m  wV    3  T

m   210  1.5 104  3 105   5  m  126 gm

3.(8) Let charge supplied by battery is q.

Apply KVL
CV
q
2 q
 V
C C
CV
 2q  CV
2
CV CV
2q  ;q 
2 4

4
 CV 2
Energy supplied by battery  q  V  ; Energy consumed by capacitors  U f  Ui
4
 1  3V 2 1  V 2   1  V  2  9CV 2 CV 2 CV 2 3CV 2
  C    C      C    0    
 2  4  2  4    2  2   32 32 8 16
CV 2 3CV 2 CV 2 CV 2
Heat loss    
4 16 16 28

4.(6) N1  2 N 2
N0e1t  2 N0e2t
1 1 1
  
t T2 T1

5.(25)

Lg
mg  2YAT  T 
2Y 
50 103  8 10
 T   25C
2  0.2  2 1011  2 106

T 2 I
6.(4) t 
4 4 PE
4t 2
I pE
2

5
 CHEMISTRY
1.(CD) (A) False E 0
F2 / F
 maximum so can not be oxidized.

(B)  H   Cl aq HCl is good conductor due to ions.

False: HCl aq  
(C)  2HCl   O nascent oxygen
True : H2 O  Cl2 
(D) True: Chlorine being more reactive displaces iodine from KI. Iodine is absorbed by starch and thus
blue colour is developed
2KI  Cl2 
 2KCl  I 2
I 2  Starch 
 Blue colour

2.(AD) Four different groups

3.(C)

4.(AC)

5.(CD) Highest reducing power of Li is due to large heat of hydration.

6.(CD)

7.(C)

6
8.(C)

9.(C) EMF to be positive, the correct representation of the cell (a concentration cell) will be as follows:
Pt, H 2 15 atm  HCl H 2  3atm  , Pt Oxidation at LHE:

H2 15 atm  
 2H   2e (Oxidation)
Reduction at RHE :
2H   2e 
 H 2 ( 3atm ) (Reduction)
Overall change:
H 2 15 atm  
 H 2  3 atm 
EMF of a concentration cell is given by the expression
0.059 C 0.059 P
E cell  log 2  log 2 , P2  P1
n C1 2 P1
0.059 15
 log  0.0206V
2 3
However, for the cell given: E cell  0.0206V

RT PRight
10.(B) Ecell  Ecell 
0
ln
nF PLeft

11.(A)
12.(D) The compound (X) is an unsymmetrical anhydride because it produces two different carboxylic acids on
hydrolysis. An unsymmetrical anhydride RCOOCOR ' on reduction with excess of LiAlH 4 yields two
primary alcohols RCH 2OH and R 'CH 2OH. The only primary alcohol that gives positive iodoform test is
CH3CH 2OH. So, the compound (Y) is CH3CH 2OH. Obviously, the other 1 alcohol (Z) is
CH3CH 2CH 2OH because the total number of carbon atoms is five. Thus, the structure of the compound (X)
is CH3COOCOCH 2CH3 . On hydrolysis, it produces acetic acid and propionic acid.

1.(3) Number of compound which can be reduced by NaBH 4  3

7
 (i)  C2 H5  CH 2 OH
 NaBH 4 

(ii)  NaBH 4 
 C2 H5CH 2 OH

(iii)  NaBH 4 


2.303 100
2.(5) k1  log for 96.875% (C) reacted
t1 3.125
2.303 100
k2  log for 50% (A) reacted
t2 50
Since t 2  t1
k1 ln 32
  5
k 2 ln 2

3.(37) A  B   Pr oduct
d A
  k A
dt
d A
  1.85  104   A  … (i)
dt
Assuming the reaction to be of second order
d A
  k '  A  B
dt
d A
  k '  A  0.1 … (ii)
dt
Dividing Eq. (i) by (ii), we get
1.85 104
1
k '  0.1
 k '  1.85 103 L mol1s1
rate  1.85 103  0.01 .02
 3.7 107
 37 108

8
4.(6)

(A) Total structural monochloro product =4

(B) Total isomer (including stereo) = 6
5.(12 or 34) Number of homopolymer = 3 polythene, PVC, Teflon
Number of copolymer polymer  4

6.(1.73)
K4 Mn  CN 6  Mn 2  3d5

CN  strong field

Unpaired e  1
Magnetic moment  1 3BM
 1.732BM

9
 MATHEMATICS
1.(AB)
9 cos12 x  cos 2 2 x  1  6 cos6 x cos 2 x  6 cos 6 x  2 cos 2 x  0
3cos x  1  cos 2 x   0 cos2 x  3cos4 x  2   0
2
 6

 cos x  0
 2
x  n  , n  I Or cos 4 x 
2 3
2 2
cos x   4 ; x  m  cos 1 4 ,m I
3 3
2.(ABD)
Let any point on the line through P be x    r cos , y  2  r sin .
x2 y2

Put this in  1 and xy  0.
9 4
PA PD  PB  PC  2 sin 2  5cos 2  13
 13  42  25   6

3.(AC)
Differential coefficient of f  x  w.r.t.
x 1
sin 1 x  2 at x  it is 2
x 2
f '  0   2; f '  0   2
 f is not derivable at x  0

sin x
4.(ABC) f  x  
x
5.(ABCD)
Equation of tangent at P is x  y  4
Clearly mirror image of R  5,5  lies on line PQ.
Now mirror image R ' or R
 ' 5  ' 5 2  5  5  4 
   4
1 1 2
   ',  '   1,9 
Let PM cuts the axis at T ; As M is midpoint of PT
 T is  3, 7 

We know that SP  ST and SMP 
2

10
 1
Equation SP  y  3    x  1
3
 x  3 y  10  0
Let S  10  3,  
7 93
Again TS || PQ    3
13  3 1  1
 focus is  2, 4
6.(AD)
h '  x   f  x   h " x   f '  x 
h 1  0, f 1  f ' 1  h ' 1  h " 1  g 1
f  g  x   x
f '  g  x   .g '  x   1  g ' 1  1
G  x   x 2 .g  x   x.h  g  x  
G '  x   x 2 g '  x   2 x.g  x   h  g  x    x.h '  g  x   .g '  x 
 2 x.g  x   h  g  x  
G "  x   2.g  x   x.g '  x 
G ' 1  2 g 1  h  g 1   2 g 1  h 1  2
G " 1  2.g 1  g ' 1  3

7.(C) y  mx  a 2 m 2  b 2 ; k  mh  a 2 m2  b2
 k  mh   a 2 m2  b 2
2

m2  h2  a 2   2mhk  k 2  b2  0  m1  tan 1 , m2  tan 2 

k 2  b2 y 2  b2  y b   xa
m1m2  2  tan 1 tan 2  4  4    4 
h  a2 x a
2 2
 xa   y b 
2hk
8.(A) m1  m2 
h  a2 2

And cot 1  cot 2  

1 1
  
tan 1 tan 2
2hk
tan 1  tan 1
   h 2  a2  
2 2

tan 1 tan 2 k b
h2  a 2
 2hk    k 2  b2  ; 2 xy    y 2  b2 

11
 g  t   lim 1  a tan x 
t/x
9.(C)
x 0
1 tan x
g  t   e x0 x
l im a tan x l im ta
 e x0 x

g  t   eta  e ta
g  x   eax
a  2, g  x   e2 x
g  2   e4

 x ea / x , x0
10.(C) f  x  
 x  ax  x , x  0
2 3

lim f  x   lim x  ax 2  x3  0
x  0 x 0

lim f  x   lim x ea / x  0 (only when a  0, otherwise limit does not exist)

x  0 x 0

f  0  0
a  [0, ]

11.(D), 12.(A)

1 1

  

f ' x   d   d  0 g    d   0 g      d  
0
1  x cos  0
1  x cos  

2
 2 f ' x   d
0
1  x cos 2 
2

 

d d sec2  d 
x 2 2
dt
f ' x    2   2   2 2
0
1  x cos 
2 2
0
1  x cos 
2 2
0
1  tan   x
2 2
0
t  1  x2

 1
1 t  
2  tan    f  x    sin 1 x  k
1 x 
2
1  x 0
2
1  x2

ln 1
But f  0    cos   f  x    sin 1 x
0

 2 2       
Range of f  x    ,   range of sin 1 x   ,  
 2 2    2 2 
f  x  is differentiable in the interior of its domain and f '  x   0 has no solution.
Hence f  x  has no critical points

12
1.(3) Let perpendicular distance of P from the line be h

1
2
h5  6  2 1  (as PAB  6  2 1 
 h
12  2 1 
5

Now distance of tangent parallel to AB i.e. 4 y  3x  12 2, from line AB is

12  2 1
5
There are just three such points.


2.(3) Let C be the centre of the circle & let AOB 
2
 2
In OAC , cos 
2 5
 3
In ABC , a cos 
2 2
4a
 3
5

 1 tan  
3.(2) A  1,0  , B   0, tan   , C  , ,
2 2 
 2 tan 2  tan 3   tan  
B'   , 
 1  tan  1  tan  
2 2

ABB '
2
BB ' C '
4.(2) 2nd equation has solution
1 1
| x | or | y |
2 a
Total possible solutions
1 3
| x | , | y | {4 points}
2 2
1 1
| x |  1, | y | {4 points}
a a
1 1
| x |  1, | y | {4 points}
a a
For 8 possible points
1 3
  3a  2
a 2
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5.(5)
Let d .a  cos y a b c   d . b  c
    
[as d . a  b  c  0 ] 
 cos y  

d. b  c  …(1)
a b c 
 

Similarly sin x 

d. b  a  ….(2)
a b c 
 
d . a  c 
 2 …(3)
a b c
Adding these we get sin x  cos y  2  0
 sin x  cos y  2
 sin x  1, cos y  1

 x   4n  1 , y   2n  1 
2

Since we want minimum value of x  y , so x   ,y
2 2

2
52
 x y 
2 2
5
4
6.(5)
 t2  t 2 1 x t2
Equation of normal at point T  t ,  to C is y  x t  y   1
 2 2 t t 2
If circle S touches curve C at T .
  x  t  , y t   must lie on normal
 x t  t 2
 y t    1
t 2
Also distance of centre of circle from T equals radius = distance of centre of circle form x-axis.
2
 t2 
 x t   t    y t      y t 
2 2

 2

x t  

t 1 t 2 1  .y t   t 2
1 t 2 1
2 2
1
1 1
 x t  y t   t 3 t 2  1 ; lim  t 3 t 2  1dt
4 r 0 4
r

2 1
2

 4 z  1z 2 dz 
1
Let 1  t  z  2tdt  2 zdz
2
 lim 2
t 0 30
1t 2

14