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FIITJEE

ALL INDIA TEST SERIES


JEE (Advanced)-2023
FULL TEST – VII
PAPER –1
TEST DATE: 23-04-2023

ANSWERS, HINTS & SOLUTIONS


Physics PART – I

Section – A
1. BCD
Sol. Using KVL
q
10  3  0  q3  30C
3
Current through the battery is zero initially as the capacitors are fully charged in steady
state and not allow to flow current through it.
10
Current through the battery after closing the switch is =2A .
2+3
q
Charge on 2μF capacitor after closing the switch is  2  2  q  8C
2
2. BC
Sol. 30  3T  3a3 .......  i 
20  2T  2a2 .......  ii 
Constrained relation
3a3  2a2  0 ....  iii 
3 10  T   2 10  T   0
30  3T  20  2T  0
T  10 Newton
So a3  0

3. ACD
Sol. w1t – w2t = 2pN
2 2 NT1 T2
t t  2N  t   whereN  1,2,3,....... 
T1 T2 T2  T1
t  49.5sec, 99sec,198sec, 297sec, .......

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AITS-FT-VII (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 2

4. ABC

5. BD

Sol. Figure shows that the magnetic field B is
present on the right-hand side of AB.
The electron (e) and proton (p) moving
on straight parallel paths with the same
velocity enter the region of uniform
magnetic field. Therefore, both will come
out travelling on parallel paths.
The time taken by proton.
distance arc angle×radius 2θ×Rp
tp = = = =
speed speed speed v
2  mp v  2mp
=  
v  eB  eB
The time taken by electron is

te 
 2   2  R e   2  2   me v    2   2  m e
v v  eB  eB
 

6. BD

7. A

8. C

9. D

10. A

Section – B

11. 0.80
2k
Sol. Minimum time period of a physical pendulum T=2π , where k is radius of gyration
g
ma2
 and a is side of square k  8cm
6
 Time=0.8sec

12. 21.00
Sol. I1 +I2 =11I0 ......  i
2
 I1 - I2  =I 0 ......  ii 
2
  I1  I2   mI0 .....  iii 
Solving (i), (i) and (iii) gives
m = 21

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3 AITS-FT-VII (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023

13. 0.45
9
Sol. RPQ = =0.45ohm
20

14. 1200.00
2 2
Sol. Speed of sound along the line wave reaching observer   260   100 
V  240m / s
 V 
Apparent f  f0  
 V  Vs 
 240 
f  1000  
 240  40 
f  1200Hz

15. 35.00
n1  / 2 10 n1 5
Sol.    so,n1  n2  7
n2  / 2 4 n2 2

So minimum frequency f 
n1  n2  v  7 196
2 2  14 0.01
f = 35 Hz

16. 7.00
1 q
Sol. If q be the charge of the metal sphere corresponding to the potential V, then V 
4 0 R
Or q   4  0R  V
3
 1  10
q 9  1  5.5  10 10 C
 9  10  2
q
t  7.00
0.80  6.25  1010  1.6  10 19

17. 0.12

18. 50.00
 
Sol. As the electric field is zero inside the inner most shell so V-E. r  V=0
So, the potential of inner shell will be equal to the potential at the centre irrespective of
charge on shells.

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AITS-FT-VII (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 4

Chemistry PART – II

Section – A

19. A, C
Sol. SiCl4 is hydrolyzed completely.

20. ABC
Sol. X  ClO2 Y  Cl2O6 Z  NaClO2
2HClO3 +SO2 
2ClO2 +H2 SO4
ClO2 +3O3 
 Cl2O6 +2O2
2ClO2 +H2O2  2NaOH 
2NaClO2 +2H2O+O2

21. ABD
Sol. CH3 Me O O O
Me O O
S O S
S O S O
'A' 'B' 'C' 'D' NH2 'E'
Cl NH2 NH
O
-
O S O O O

Cl

22. ACD

23. BD
Sol. A.O. is a single e  wave function.
Area of the plot for r<52.9 pm is smaller than the area of the plot of r>52.9pm.
At higher atomic number every of 3d<4s
1 1  21 
E25  RhcZ 2  2  2   RhcZ 2  
2 5  100 
1 1 3
E24  RhcZ 2  2  2   RhcZ 2 
2 4  16
28
E25  E24
25

24. C
Sol. From the Grahm’s law d = 16 cm.
d 40
  d  16
24  d 10

25. B
Sol. Fe 3 is precipitated by conc. NH3 but Zn2+ is not precipitated by conc. NH3.

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5 AITS-FT-VII (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023

26. B
Sol. (A) IIIrd law states lim S  0 for Perfectly Crystalline solid.
T0

27 A
Sol. C6H5 COCH3 ismeta-directing& deactivating

28. A
Sol. PV=n RT

Section – B

29. 0.77
1.68  3  1.21 2  1.035  2
Sol. E   0.77
7

30. 100.00
Sol. 201x =101
x  100

31. 18.20
Sol. Ca3  PO 4 2 + 8Mg 
 Ca3P2 +8MgO
0.8mole

 Mg PO 3 2
MgO + P2O 5 
0.8mole 0.1mole

32. 14.14
Sol. s=  CH3 COO   +  CH3 COOH
 H+    10-3 
s =Ksp 1+    =2×10-10 1+ -9   2  104  200  106
2

 Ka   10 
 
s  14.14  103

33. 0.35
pB 10
Sol. Keq. = = =5
pA 2
20
Keq.'= =10
2
ΔG°100K R 100ln5 1 log5 log5 1  0.3
     0.35
ΔG°200K R 200ln10 2 log10 2 2

34. 3.81
Sol. A  0.28 mole Benzene
B  0.14 mole Cumene
C  0.14 × 0.4 = 0.056 mole
D  0.028 mole = 0.028 × 136g = 3.808g = 3.81g

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AITS-FT-VII (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 6

35. 16.29
3
Sol. 2As  O2  As2O3 U  100 KJ / mole
2
Solid Black Solid

3 
H = 100    8.3  10 3  298   103.7101
2 
As  As H  60KJ / mole
(Gray) Black

3
2As  O2  As2O3 H  120  103.7101  16.2899KJ /mole
Gray 2 Solid

36. 5.00
Sol. C3H8 +6H2O  3CO2 +20H+ +20e
20H+ +5O2 +20e  10H2O

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7 AITS-FT-VII (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023

Mathematics PART – III

Section – A

37. A, B
Sol. A, B
Y
VC = 3 units, CO = 9 units
AN MN
As per property: AV  VN and 2
AV VC
1  N
  9,3
 OM  6 tan  , AC  CM  3 cot   9  3  2 tan    V
 tan   θ

1 θ
X
 m  1 or m  A C M O
2
 Eqn of Axis can be
 y  3  1 x  9 
or
1
 y  3  x  9 
2

38. A, B, C
x2 y2
Sol. Ellipse be   1 (a > b)
a2 b 2
Y
P'

O(0, 0)
X’ F2(ae, 0) F1(ae, 0) X

Q'

Y’
F1Q = a + ae = 3 b2 = a2(1  e2)  a2e2 = a2  b2
F1P = a  ae = 2
2a = 5  b2= 6
4x 2 y 2
Ellipse is  1
25 6
x2 y2
Similarly Ellipse (s) in other case ax  1
4 3
x2 y 2
   1 here PQ will be 5, 7, 17
9 8

39. C, D
Sol. log2(f(x))  log2(f(y))  (x y)2
Suppose y = x + h and Limit h0
d f  x 
dx
 
log2  f  x    0 
f  x
0 ...(1)

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AITS-FT-VII (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 8

If x = y + h and Limit h0


d f  x 
dx
 
log2  f  x    0 
f x 
0 ...(2)

From (1) to (2) we get


f(x) = 0

40. B, D
Sol. Using the condition in the problem
1
Pn = Pn 1  Pn 2  n  3
2
n
2 1 1
 Pn =    
3 3 2

41. A, B
  
Sol. T= a b c cosα sinθ 1
  
 a b c cosα sinθ2
  
 a b c cosα sinθ3
     

Y  2 ab  b  c  c  a 
     

 2 a b sin1  b c sin2  c a sin3 
Y 2  1 1 1   1 1 1  1
       4  +  +   cos  
T cos  a b c   a b c  2
   

42. A, B, D
z2  z 3
Sol. 1st option – chord  Z3  Z2  is  to line joining and 1.
2

z3
z2
θ
θ
O 1,0 
z1

2nd option – angle by chord  Z3  Z2  at 1,0  is double of angle at  0,0


4th option – Ptolemy’s theorem

43. C

44. B

45. A
/4
Sol. Clearly I1 + I2 = 2 e – 1 and I3 = 1/2.

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9 AITS-FT-VII (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023

46. B
Sol. (I) A1 + B1 = (A + B)1  (A1 + B1)(A + B) = 1
 I + A1B + B1A = 0  P = A1 B
1 2
I+P+P =0P+P +1=0
 P2 + P3 + P = 0
 P3 = I  |P| = 1
 |A1B| = 1  |A| = |B|
 0 0 1   0 0 1  1 0 0 
2     
(II) B = 0 1 0  0 1 0   0 1 0   I
1 0 0  1 0 0  0 0 1 
(III) In A2, A3, . . A20, and A20 + B
C22, C23, C32, C33 remains same
2.8 2.8 2.8 2.8  1 1 1 1 1 
(IV) a22b18 + a22b28 + . . . +a28b58 =   ...   1     ...  
1.4 4.7 13.16 3  4 4 7 3 16 
16 15
  5
3 16

Section – B

47. 7400.00
Sol. Apparently 2f = 2  a21  a22  a23  .....  a22019   (2a1a3 + 2a2a4 + 2a3a5 + . . . . . . +2a2017a2019)
2017
 2f =  a21  a22  a2018
2 2
 a 2019     ai2  ai 2 ...(1)
i1

Since, a1,a2 and ai+2  ai) are all non-negative integers


2
 a21  a1 , a22  a2  ai1  ai   ai2  ai for i = 1, 2, 3, ..... 2016
2016 2016
 a12  a22    a i 2  a i 2  a1  a 2    ai 2  ai 2 = a2017 + a2018 ...(2)
i 1 i1

 2f  a2017 + a2018 + (a2019 a2017)2 + a 22018  a 2019


2

As a2019 = 99 and a2018  a2017 > 0


1
 2 2
 f  2a2017   99  a2017   a2017
2
 99 2 
 f  (a2017  49)2 + 7400
 fminimum = 7400

48. 4.93
Sol. We know that
n

  1 
r 0
r n k

C r n  r   0
n
if k  n
if k  n
2024  10 4 10 4
 = 4.938
2025 2025

49. 498.00
Sol. Identifying A  All permutations except 0 at first place = 600
B  not 0 after 2 and not 4 after 3
C  0 after 2 and not 4 after 3
D  not 0 after 2 and 4 after 3

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AITS-FT-VII (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 10

No. of such permutations = n  A   3 n B       


n C n D
4 2 2
3 96 72
 600   24   = 498
4 2 2

50. 9.65
Sol. Analyzing the given figure y = 2x y = 2x
y


m  2,  2,2 2, 2 2 
(0, 2)
 2, 2 
2
x x
2  2(1, 0) 2
(1, 0)

y

4 3
51. , 0.76 or 0.77
9
Sol. Let radius of S = 0 be r where r > 0
S  (x  1)2 + (y  r)2 = r2
2
 y2  2
  1   y  2ry  0
 4 
2

 r=
y 2
 4
. . . (1)
32y
Equ. (1) must have only one positive solution
2

Suppose f(y) =
y 2
 4
y0
32y
3
4 4 4 4
 y2 + 4 = y 2    4 4 y2   
3 3 3 3
3
1 4 4 3
 f(y) =  16 y 2 .   
32y 3 9

 r  4 3 Assuming r > 4 3
9 9
If r > 4 3 then, f(y) changes continuously with y and becomes arbitrary when y  0+ or
9
y
 2 3 2 3 
 Equ. (1) has both solutions  0,  and  , 0
 3   3 
1 2 3 
Hence r  4 3 is only consider solution and  ,  is unique common point.
9 3 3 

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11 AITS-FT-VII (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023

52. 5.33
Sol. Suppose ln(x) = a, ln(y) = b, ln(z) = c
Since x, y, z > 1
Hence a + (c/b) = 3, b + (c/a) = 4
ab + c = 3b = 4a
Suppose a = 3u, b = 4u (u > 0) then
c = 4a  ab = 12u  12 u2
 u  u   2  2u 3  2
3
16
ln x lnz = ac = 3u.12u(1  u) = 18u2(u  2u)  18    18   
 3   3  3
 

1
53. 0.57 or 0.58
3
Sol. Apparently angle S1PS2 is greatest if P is point of contact of tangency of circle S1, S2, P
on the lie
y = 2x.
Suppose A is origin (0, 0).
APS1 = AS2P and APS1  AS2P
S 1P AP also AP2 = AS .AS
 1 2
S 2P S 2P
PS1 SA 3 1
 1  
PS2 S2A 9 3

54. 48.31
Sol. f(x) + f(x + 1) + … + f(x + 10)
= |ex  1| + |e x  2| + … |ex  11|
11
  f  x  dx  65  4ln2  7e
0

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