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Section – A
1. BCD
Sol. Using KVL
q
10 3 0 q3 30C
3
Current through the battery is zero initially as the capacitors are fully charged in steady
state and not allow to flow current through it.
10
Current through the battery after closing the switch is =2A .
2+3
q
Charge on 2μF capacitor after closing the switch is 2 2 q 8C
2
2. BC
Sol. 30 3T 3a3 ....... i
20 2T 2a2 ....... ii
Constrained relation
3a3 2a2 0 .... iii
3 10 T 2 10 T 0
30 3T 20 2T 0
T 10 Newton
So a3 0
3. ACD
Sol. w1t – w2t = 2pN
2 2 NT1 T2
t t 2N t whereN 1,2,3,.......
T1 T2 T2 T1
t 49.5sec, 99sec,198sec, 297sec, .......
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AITS-FT-VII (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 2
4. ABC
5. BD
Sol. Figure shows that the magnetic field B is
present on the right-hand side of AB.
The electron (e) and proton (p) moving
on straight parallel paths with the same
velocity enter the region of uniform
magnetic field. Therefore, both will come
out travelling on parallel paths.
The time taken by proton.
distance arc angle×radius 2θ×Rp
tp = = = =
speed speed speed v
2 mp v 2mp
=
v eB eB
The time taken by electron is
te
2 2 R e 2 2 me v 2 2 m e
v v eB eB
6. BD
7. A
8. C
9. D
10. A
Section – B
11. 0.80
2k
Sol. Minimum time period of a physical pendulum T=2π , where k is radius of gyration
g
ma2
and a is side of square k 8cm
6
Time=0.8sec
12. 21.00
Sol. I1 +I2 =11I0 ...... i
2
I1 - I2 =I 0 ...... ii
2
I1 I2 mI0 ..... iii
Solving (i), (i) and (iii) gives
m = 21
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3 AITS-FT-VII (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023
13. 0.45
9
Sol. RPQ = =0.45ohm
20
14. 1200.00
2 2
Sol. Speed of sound along the line wave reaching observer 260 100
V 240m / s
V
Apparent f f0
V Vs
240
f 1000
240 40
f 1200Hz
15. 35.00
n1 / 2 10 n1 5
Sol. so,n1 n2 7
n2 / 2 4 n2 2
So minimum frequency f
n1 n2 v 7 196
2 2 14 0.01
f = 35 Hz
16. 7.00
1 q
Sol. If q be the charge of the metal sphere corresponding to the potential V, then V
4 0 R
Or q 4 0R V
3
1 10
q 9 1 5.5 10 10 C
9 10 2
q
t 7.00
0.80 6.25 1010 1.6 10 19
17. 0.12
18. 50.00
Sol. As the electric field is zero inside the inner most shell so V-E. r V=0
So, the potential of inner shell will be equal to the potential at the centre irrespective of
charge on shells.
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AITS-FT-VII (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 4
Chemistry PART – II
Section – A
19. A, C
Sol. SiCl4 is hydrolyzed completely.
20. ABC
Sol. X ClO2 Y Cl2O6 Z NaClO2
2HClO3 +SO2
2ClO2 +H2 SO4
ClO2 +3O3
Cl2O6 +2O2
2ClO2 +H2O2 2NaOH
2NaClO2 +2H2O+O2
21. ABD
Sol. CH3 Me O O O
Me O O
S O S
S O S O
'A' 'B' 'C' 'D' NH2 'E'
Cl NH2 NH
O
-
O S O O O
Cl
22. ACD
23. BD
Sol. A.O. is a single e wave function.
Area of the plot for r<52.9 pm is smaller than the area of the plot of r>52.9pm.
At higher atomic number every of 3d<4s
1 1 21
E25 RhcZ 2 2 2 RhcZ 2
2 5 100
1 1 3
E24 RhcZ 2 2 2 RhcZ 2
2 4 16
28
E25 E24
25
24. C
Sol. From the Grahm’s law d = 16 cm.
d 40
d 16
24 d 10
25. B
Sol. Fe 3 is precipitated by conc. NH3 but Zn2+ is not precipitated by conc. NH3.
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5 AITS-FT-VII (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023
26. B
Sol. (A) IIIrd law states lim S 0 for Perfectly Crystalline solid.
T0
27 A
Sol. C6H5 COCH3 ismeta-directing& deactivating
28. A
Sol. PV=n RT
Section – B
29. 0.77
1.68 3 1.21 2 1.035 2
Sol. E 0.77
7
30. 100.00
Sol. 201x =101
x 100
31. 18.20
Sol. Ca3 PO 4 2 + 8Mg
Ca3P2 +8MgO
0.8mole
Mg PO 3 2
MgO + P2O 5
0.8mole 0.1mole
32. 14.14
Sol. s= CH3 COO + CH3 COOH
H+ 10-3
s =Ksp 1+ =2×10-10 1+ -9 2 104 200 106
2
Ka 10
s 14.14 103
33. 0.35
pB 10
Sol. Keq. = = =5
pA 2
20
Keq.'= =10
2
ΔG°100K R 100ln5 1 log5 log5 1 0.3
0.35
ΔG°200K R 200ln10 2 log10 2 2
34. 3.81
Sol. A 0.28 mole Benzene
B 0.14 mole Cumene
C 0.14 × 0.4 = 0.056 mole
D 0.028 mole = 0.028 × 136g = 3.808g = 3.81g
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AITS-FT-VII (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 6
35. 16.29
3
Sol. 2As O2 As2O3 U 100 KJ / mole
2
Solid Black Solid
3
H = 100 8.3 10 3 298 103.7101
2
As As H 60KJ / mole
(Gray) Black
3
2As O2 As2O3 H 120 103.7101 16.2899KJ /mole
Gray 2 Solid
36. 5.00
Sol. C3H8 +6H2O 3CO2 +20H+ +20e
20H+ +5O2 +20e 10H2O
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7 AITS-FT-VII (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023
Section – A
37. A, B
Sol. A, B
Y
VC = 3 units, CO = 9 units
AN MN
As per property: AV VN and 2
AV VC
1 N
9,3
OM 6 tan , AC CM 3 cot 9 3 2 tan V
tan θ
1 θ
X
m 1 or m A C M O
2
Eqn of Axis can be
y 3 1 x 9
or
1
y 3 x 9
2
38. A, B, C
x2 y2
Sol. Ellipse be 1 (a > b)
a2 b 2
Y
P'
O(0, 0)
X’ F2(ae, 0) F1(ae, 0) X
Q'
Y’
F1Q = a + ae = 3 b2 = a2(1 e2) a2e2 = a2 b2
F1P = a ae = 2
2a = 5 b2= 6
4x 2 y 2
Ellipse is 1
25 6
x2 y2
Similarly Ellipse (s) in other case ax 1
4 3
x2 y 2
1 here PQ will be 5, 7, 17
9 8
39. C, D
Sol. log2(f(x)) log2(f(y)) (x y)2
Suppose y = x + h and Limit h0
d f x
dx
log2 f x 0
f x
0 ...(1)
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AITS-FT-VII (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 8
40. B, D
Sol. Using the condition in the problem
1
Pn = Pn 1 Pn 2 n 3
2
n
2 1 1
Pn =
3 3 2
41. A, B
Sol. T= a b c cosα sinθ 1
a b c cosα sinθ2
a b c cosα sinθ3
Y 2 ab b c c a
2 a b sin1 b c sin2 c a sin3
Y 2 1 1 1 1 1 1 1
4 + + cos
T cos a b c a b c 2
42. A, B, D
z2 z 3
Sol. 1st option – chord Z3 Z2 is to line joining and 1.
2
z3
z2
θ
θ
O 1,0
z1
43. C
44. B
45. A
/4
Sol. Clearly I1 + I2 = 2 e – 1 and I3 = 1/2.
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9 AITS-FT-VII (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023
46. B
Sol. (I) A1 + B1 = (A + B)1 (A1 + B1)(A + B) = 1
I + A1B + B1A = 0 P = A1 B
1 2
I+P+P =0P+P +1=0
P2 + P3 + P = 0
P3 = I |P| = 1
|A1B| = 1 |A| = |B|
0 0 1 0 0 1 1 0 0
2
(II) B = 0 1 0 0 1 0 0 1 0 I
1 0 0 1 0 0 0 0 1
(III) In A2, A3, . . A20, and A20 + B
C22, C23, C32, C33 remains same
2.8 2.8 2.8 2.8 1 1 1 1 1
(IV) a22b18 + a22b28 + . . . +a28b58 = ... 1 ...
1.4 4.7 13.16 3 4 4 7 3 16
16 15
5
3 16
Section – B
47. 7400.00
Sol. Apparently 2f = 2 a21 a22 a23 ..... a22019 (2a1a3 + 2a2a4 + 2a3a5 + . . . . . . +2a2017a2019)
2017
2f = a21 a22 a2018
2 2
a 2019 ai2 ai 2 ...(1)
i1
48. 4.93
Sol. We know that
n
1
r 0
r n k
C r n r 0
n
if k n
if k n
2024 10 4 10 4
= 4.938
2025 2025
49. 498.00
Sol. Identifying A All permutations except 0 at first place = 600
B not 0 after 2 and not 4 after 3
C 0 after 2 and not 4 after 3
D not 0 after 2 and 4 after 3
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AITS-FT-VII (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 10
50. 9.65
Sol. Analyzing the given figure y = 2x y = 2x
y
m 2, 2,2 2, 2 2
(0, 2)
2, 2
2
x x
2 2(1, 0) 2
(1, 0)
y
4 3
51. , 0.76 or 0.77
9
Sol. Let radius of S = 0 be r where r > 0
S (x 1)2 + (y r)2 = r2
2
y2 2
1 y 2ry 0
4
2
r=
y 2
4
. . . (1)
32y
Equ. (1) must have only one positive solution
2
Suppose f(y) =
y 2
4
y0
32y
3
4 4 4 4
y2 + 4 = y 2 4 4 y2
3 3 3 3
3
1 4 4 3
f(y) = 16 y 2 .
32y 3 9
r 4 3 Assuming r > 4 3
9 9
If r > 4 3 then, f(y) changes continuously with y and becomes arbitrary when y 0+ or
9
y
2 3 2 3
Equ. (1) has both solutions 0, and , 0
3 3
1 2 3
Hence r 4 3 is only consider solution and , is unique common point.
9 3 3
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11 AITS-FT-VII (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023
52. 5.33
Sol. Suppose ln(x) = a, ln(y) = b, ln(z) = c
Since x, y, z > 1
Hence a + (c/b) = 3, b + (c/a) = 4
ab + c = 3b = 4a
Suppose a = 3u, b = 4u (u > 0) then
c = 4a ab = 12u 12 u2
u u 2 2u 3 2
3
16
ln x lnz = ac = 3u.12u(1 u) = 18u2(u 2u) 18 18
3 3 3
1
53. 0.57 or 0.58
3
Sol. Apparently angle S1PS2 is greatest if P is point of contact of tangency of circle S1, S2, P
on the lie
y = 2x.
Suppose A is origin (0, 0).
APS1 = AS2P and APS1 AS2P
S 1P AP also AP2 = AS .AS
1 2
S 2P S 2P
PS1 SA 3 1
1
PS2 S2A 9 3
54. 48.31
Sol. f(x) + f(x + 1) + … + f(x + 10)
= |ex 1| + |e x 2| + … |ex 11|
11
f x dx 65 4ln2 7e
0
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