TERNARY PHASE

DIAGRAM
Bata Tahan Api & Terak
Semester Genap 2021
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What are ternary phase diagram?

Diagrams that represent the equilibrium between

the various phases that are formed between
three components, as a function of temperature.
Normally, pressure is not a viable variable in
ternary phase diagram construction, and is
therefore held constant at 1 atm.
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Gibbs Triangle
An Equilateral triangle on which the pure
components are represented by each corner.

Concentration can be expressed as

either “wt. %” or “at.% = molar %”.

XA+XB+XC = 1

Used to determine
the overall composition
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Overall Composition
 5

Overall Composition
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Ternary Isomorphous System

Isomorphous System: A system (ternary in this case) that

has only one solid phase. All components are totally
soluble in the other components. The ternary system is
therefore made up of three binaries that exhibit total solid
solubility.
The Liquidus surface: A plot of the temperatures
above which a homogeneous liquid forms for any
given overall composition.
The Solidus Surface: A plot of the temperatures below
which a (homogeneous) solid phase forms for any
given overall composition.
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Ternary Isomorphous System

TC

TB

TA
 8

Ternary Isomorphous System

TC TC

TB TB

TA TA
 9

Ternary Isomorphous System

TC

TB
TB
TC
TA

TA
 10
Ternary Isomorphous System

TC

TB

TA
 11
Ternary Isomorphous System
Isothermal section

TC

TB

TA
 12

Ternary Isomorphous System

Locate overall composition using Gibbs triangle
13
 Ternary Eutectic System
(No Solid Solubility)

TA TA
TC
TB

TA

TB

TB
TA

25
TC TC
 15
Ternary Eutectic System
(No Solid Solubility)

Liquidus projection
TA TC

TB
 16
Ternary Eutectic System
(No Solid Solubility)

TA
TC

TB
 17
Ternary Eutectic System
(No Solid Solubility)

TA
TC

TB
 18
Ternary Eutectic System
(No Solid Solubility)

TA
TC

TB
 19
Ternary Eutectic System
(No Solid Solubility)

TA
TC

TB
 20
Ternary Eutectic System
(No Solid Solubility)

TA
TC

TB
 21
Ternary Eutectic System
(No Solid Solubility)

TA
TC

TB
 22
Ternary Eutectic System
(No Solid Solubility)

T= ternary eutectic temp.

A C

L+A+C

L+A+B L+B+C

B
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Ternary Eutectic System
(with Solid Solubility)
 Ternary Eutectic System
(with Solid Solubility)

TB TC

TA

36
 Ternary Eutectic System
(with Solid Solubility)

TB
TC

TA

37
 Ternary Eutectic System
(with Solid Solubility)

TB

TC

TA

38
 Ternary Eutectic System
(with Solid Solubility)

TB

TC

TA

39
 Ternary Eutectic System
(with Solid Solubility)

TC
TB

TA

40
 29
Ternary Eutectic System
(with Solid Solubility)

TB
TC

TA
 30
Ternary Eutectic System
(with Solid Solubility)

• T= ternary eutectic temp.

•C

• L+β+γ
L+α+β L+α+γ
 Ternary Eutectic System
(with Solid Solubility)

TB

TC

TA

정해솔 학생 제공 자료 참조: 실제 isothermal section의 온도에 따른 변 43

화
 Ternary Eutectic System
3) Solidification Sequence: liquidus surface

44
 Ternary Eutectic System
* Vertical section

* The horizontal lines are not tie lines. (no

compositional information)
* Information for equilibrium phases at
different tempeatures 45
TUGAS
• Carilah jurnal/buku referensi/etc yang membahas terkait
slag system suatu proses peleburan
• Berikan potongan diagram fasa terner dari sistem slag
tersebut.
• Jelaskan sistem slag dari proses peleburan berdasarkan
diagram fasa tsb
• Tugas dikumpulkan Senin, 17 Mei 2021 Pukul 07.29
• You may work with group under 4 persons!
• Assignment format in PDF