FIITJEE

ALL INDIA TEST SERIES

JEE (Advanced)-2023
PART TEST – I
PAPER –1
TEST DATE: 20-11-2022

ANSWERS, HINTS & SOLUTIONS

Physics PART – I

Section – A

1. A, B, D
dx
Sol.   0.1 x
dt
0 
dx
9
x 
 0.1 dt   = 60 sec
0

0.1 x 0.1
  rad/s
x x
0.1 2
a = v = 0.1 x  0.01 m/s
x

2. A, C
Sol. Speed of the object will remain constant because tension
is always perpendicular to the velocity. r
r (/2)  
So angular momentum about O = mv0 sin   mv 0r  
sin 
mv 0mv 02 2 O v0
 5 kg-m /sec
Tmax

3. B, C
Sol. For the bigger disc C1r14  fdtr1  0

For the smaller disc C2r24  fdtr2  0 
L1 r1
So, 1r13  2r23 and 
L 2 r2

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AITS-PT-I (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 2

4. A, C, D
J
Sol. In both situations vC 
m
J
In situation-(ii),  
m

5. B, D
Sol. Hmax
B  Hmax
A  Hmax
C (as shown clearly)
So, uBy  uyA  uCy
Vertical component of initial velocity of each particle will decide the time taken.
So, t C  t A  tB

6. B
Sol. For COM position, m1x1 = m2x2
Where m1 and m2 are masses of left and right part of the rod and x 1, x2 are their respective
position of centre of mass.
Simultaneously, m1x1 = m2x2
and I1  I2 
1 2 1 2
and I1  I2 
2 2

7. C
Sol. (I) 0 = 100v + 50(v + 3) (COLM) 3 m/s
v = 1 m/s
1 1
So, work done by man = (100)(1)2  (50)(2)2  150 J v
2 2
(II) W N + W mg =  K.E. (WET)
1 1
W N  (2)(10)2  (2) (5)2  (15)2 
2 2  
W N =  100 J
(III) Unstable equilibrium points are x = 10 m, 30 m
Stable equilibrium point is x = 20 m
1
So, Ui = 0, and Uf =  (10)4  100 J
100
W conservative force = Ui  Uf = 100 J
 5R 3R  mgR
(IV) W ext = Uf  Ui = mg     100 J
 8 8  4

8. B
Sol. In case-(I)
at  x
1
y  at 2
2
1 2 x 2
y a 2
2 a
2 x 2
y
2a

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 3 AITS-PT-I (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023

9. A
Sol. 3 kg block will be at rest. (so friction between S2 and D = tension in the string connect to block D)
Considering A + B + C in a system
T  6 = 3a, 20  2T = 2a1 and a = 2a1
8 2
So, a  m/s
7
So, there will be slipping between blocks A and B.
Now consider (B + C) in a system
T  6  1 = 2a
20  2T = 2a2 and a = 2a2
So, T  7 = 4a2
20  2T = 2a2
2
So, a = 1.2 m/s

10. C
mR2  mR2 mR2 mR2 
Sol. Case –I : 0      
2  2 4 4
 
0
  3 rad/s
2
Case –II:   0  6 rad/s
mR2 R
Case –III: 0  mv  (mR2 )
2 2
8
So, 3     7 rad/s
2
mR2 R  1
Case –IV: 0  mv    mR2 
2 2 2
8
3    5 rad/s
4

Section – B

11. 4.50 (range 4.40 to 4.60)

Sol. (F) (2) = (N) (1)  N = 2F (N is normal between rods)
 1
and (N)    (F1 )(2)
2
F
So, F1 
2

12. 60.60 (range 60.00 to 61.00)

0.01L 100L
Sol. Total time taken = 
0.0001v v
100L
Total number of collision with moving wall in the said movement   50
 2L 
v 
 v 
In each collision with the movable wall speed of the sphere increases by 0.0002 v.
So, final speed of sphere = v + 50  0.0002v = 1.01 v = 60.60 m/s

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AITS-PT-I (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 4

13. 2.50 (range 2.40 to 2.60)

Sol. from torque equilibrium about O F
 1 
F  mg  mg
22 2
mg
F N
4 30

mg

O

mg

14. 1.41 (range 1.35 to 1.45)

Sol.  Ndt  mv cos  (v  2gh)

mv sin   mv cos  3 1 4 50

So, v f   2gh     2 m/s
m 5 2 5 5

15. 7.46 (range 7.40 to 7.50)

Sol. xB  x A  x 2A  h2  L xB
dxB dx A xA dx A uA
  0 xA
dt dt x 2A  h2 dt
uB 1 2  uB
So, uA    A B
1  cos  3 2 3
1
2 h
 uA = 7.46 m/s

16. 2.43 (range 2.35 to 2.55)

2
1  1 
Sol. yCM  (10)    0.05 m
2  10 
2
So, hCM  1   0.05  1.62 m
3
1.62  3
So, y 2m   2.43 m
2

17. 58.80 (range 57.00 to 59.00)

Sol. Assume the bloc M at rest, we see that both smaller cubes are applying net zero resultant
horizontal force on the larger block.
So, N = Mg + mg (cos2 37 + cos2 53) = Mg + mg

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 5 AITS-PT-I (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023

18. 2.00 (range 1.95 to 2.05)

Sol. mg cos 53 = 0.5 N
2
mg sin 53 + N = m r
mg(0.6)
So, mg(0.8)   m 2r
0.5
 8 6
So, g     2r
 10 5 
So, 10  2 = 2r
20
So,    2.00 rad/s
5

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AITS-PT-I (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 6

Chemistry PART – II

Section – A

19. B, D
Sol. XeF4  sp3 d2  Square planar and nonplanar
H2 O2  sp3  open book structure. Nonplanar and polar
XeF5  Pentagonal planar and non  polar
XeF5  Square pyramidal non  planar polar

20. C, D
Sol. O O O
O
Cr Cr C
O O
O O
H
O O
All Cr - O bonds are not equivalent All C - O bonds are not equivalent
O
O F
O
F F
Xe
S
O O
O F F
F

All Xe - O bonds are equivalent due to resonance sp3d2 hybridisation

21. A, B, C
Sol. r = 0, R(r) = 0 so its true for p-orbital, Azimuthal quantum number is 1.
6r r 2
R  r   0, o  2  0
a ao
One radial node is observed at r  6ao distance.
So, its true for 3p-orbital.
In Px orbital nodal plane is in yz plane and p-orbital accommodate only 2-electron.

22. A, C, D
3 3
Sol. Tetrahedral will be formed by sp -hybridisation. Other three can be formed by distorted sp d
hybridisation. i.e.
XeF2 andI3  are sp d but linear shape.
3

3
BrF3 is sp d but bent T-shaped.
SF4 is sp3d but see-saw shaped.

23. A, C
Sol. In CrO38 Cr has +5 oxidation state.
KO2 is also colorful.

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 7 AITS-PT-I (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023

24. A, B, C
Sol. In option (D) if we add inert gas at constant pressure and temperature. Equilibrium will get
disturbed and more in backward direction.

25. A
Sol. For reaction A  Product
Using the given formula we can solve all the options
 A o   A t
For zero order reaction t 
k
1  A o
For first order reaction t  n
k  A t

1 1 1 
For second order reaction t    
k   A t  A o 

26. B
Sol. Correct answer is I→P, R, S; II→P, S, T; III→P, R, S; IV→P, Q,R, S

27. C
Sol. Correct order is I→R,S; II→R; III→Q, S; IV→P

28. D
Sol. Correct answer is I→Q; II→P; III→S; IV→R

Section – B

29. 1.00
Sol. SiO2 is neutral and Na has unit +ve charge AlO2 should have unit – ve charge to balance the
charge of molecule.
x(1) + y(– 1) + 136(0) + 250(0) = 0
x=y
x
 1.00
y

30. 9.09
Sol. CH3 COOH  NaOH  CH3 COONa  H2 O
0.60 V 0.20  3V 0.60V
0.60V 3
CH3 COONa  4V

20
M

pH at 25oC for salt of WA + SB is

1
pH  7   pK a  log  salt  
2
1 3 
pH  7   5  log 
2 20 
1
 7   5  0.82 
2
1
 7   4.18 
2
 7  2.09
= 9.09

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AITS-PT-I (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 8

31. 1.50
Sol. N

N sp

N sp2

C sp2

sp2
2
sp N N

sp2
C C
N N
2 N N N
N sp
N sp2 sp2
sp
sp sp2
Maximum 6 bond can lies in same plane and sp2 centre are 9.
x  9, y  6
x 9
   1.50
y 6

32. 1.50
Sol. Balance reaction is
ClO3  6I  6H2 SO 4  3I2  Cl  6HSO4  3H2 O
x = 6, y = 6, z = 3

33. 6.93
Sol. NH4 HS  s   NH3  g  H2 S  g
2x xy x
1 3
NH3  g  N2  g   H2  g
2 2
y 3y
xy
2 2
Given,
3y
2–x=1  0.75
2
 1
x=1 y 
2
 1  1  1
x1  K C1   .     
 2  4 8
3 1
 3 2  1  2
8 8 3 3 
   
y1  K C 2  
 1  16 
 
 
4

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 9 AITS-PT-I (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023

1
a  NH3   M
4
1
H2 S  2 M
1
b  N2   M
8
3
H2   8 M
y1 3 3 8 8
   4 3
x1  a  b  16 1 3
 4  1.732
= 6.928
= 6.93

34. 1.33
K1K 3
Sol. K  overall    104 sec 1
K2
A1 A 3
A  overall    2  105 sec 1
A2
Ea  overall   Ea1  E a3  Ea2  15 kJ
K.A 2  104  105
  1.33
Ea 15

35. 18.48
Sol. MgCl2  2NH3  2H2 O  Mg  OH2  s   2NH4 Cl
Mg  OH2  s   Mg2   2OH
NH4 2 SO4 is acidic so it will dissolved Mg  OH2 solid which is formed in mix. When all
2+
Mg  OH2 will re-dissolve the conc. of Mg ions in the final solution will become equal to its initial
conc.
0.70  0.2
NH3  in mix initially  1.0
 0.14 M

0.30  0.2
Mg2  in mix initially   0.06 M
  1.0
When Mg2   0.06

K SP 6  10 12
OH  
    105 M
Mg2   0.06
 
NH4  OH  K b NH3 
  
For NH3 K b   NH4  
NH3  OH 
 
2  10 5  0.14
NH4    0.28 M
  105
Mole of NH4   0.28

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AITS-PT-I (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 10

0.28
Mole of NH4 2 SO4 needed   0.14
2
Mass of NH4 2 SO 4  132  0.14
= 18.48 g.

36. 37.50
Sol. A  aq  2B  aq   C  aq
t0 a 0 0
a a
t  10 min a a
2 2
3a 3a 3a
t  20 min a
4 2 4
t 0 2a a
Let the normality of ‘T’ is N and initial volume of ‘T’ is used x ml
At t = 0 Meq. of A = Meq. of T
a  2n  N  x … (1)

At t = 10 min Meq. of (A + B + C) = Meq. of T

a a
 2n  a  n   2n  40  N … (2)
2 2
At t = 20 min Meq. of (A + B + C) = Meq. of T
a 3a 3a
 2n  n   2n  N  y … (3)
4 2 4
At t =  min Meq. of (B + C) = Meq. of T
2a  n  a  2n  N  z … (4)
80 140 160
Solving these equilibrium x  ml, y  ml, z  ml
3 3 3
yz
Value of  37.5 .
x

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 11 AITS-PT-I (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023

Mathematics PART – III

Section – A

37. B, C, D
3
Sol. f  x 
 2sin2  
2x 2  x   
2
 2x  x 
Using AM  GM
2sin2 
2x 2  x  1 1
 2x 2  x   2sin2   2  3  2 2 sin   f  x   3 cosec 
2 2f  x  3
22
3 1
 f  x   |cosec | = 2  |sin | =
2 2

38. A, B
1
1
 f te
t
Sol. Put x = 0  dt 
0 a
x
1
 f  t  dt  e
x
  ae2x   ex  22x , differentiating we get, f  x   e x  2e2 x
0 a

39. A, B, C
Sol. (x – y) f(x + y) – (x + y) f(x – y)= 2y(x – y)(x + y)
f v f u 
Let x – y = u, x + y = v  uf(v) – v(f(u) = (v – u)uv  v  u  k
v u
 f(x) = kx + x2  f(1) = 2  k = 1  f(x) = x2 + x

40. D
dy dy ay
Sol. x a y  a , on differentiating axa 1y  x a 0  
dx dx x
ay1
Tangent at point (x1, y1) is y  y1    x  x1 
x1
2
1 a  a  1 1 a
Area =    x1   area is constant if a = 1
2 a

41. A, D
Sol. f(x)  0, F(x) = f(x) as f(x)  c F(x)  F(x) – c F(x)  0
d  cx
 e cx  F  x   c  e cxF  x   0   e  F  x   0
dx
 e cx  F  x  is an increasing function
 
 e cx  F  x   e c 0  f  0   F(x)  0  f(x)  0  f(x) = 0
d x
Also,  e g  x    0  e x g  x  is a decreasing function
dx
 e–xg(x) < e–(0)g(0)  g(x) < 0 (as g(0) = 0)
Thus, f(x) = g(x) has one solution x = 0 also, |x 2 + x – 6| = f(x) + g(x) = g(x)  no solution

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AITS-PT-I (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 12

42. B, C
Sol. Solution of differential equation is  sin2 x  y   sin x  y 2   cos x  cos2 x   0

43. D
1 1
2 2
  f  x   8x  f  x   16x  dx    f  x   4x 
4 2 2 4 2 2 2
Sol. (I)  0  f (x) = 4x
0 0

4x 3
(II) f   x     f(x) = 0 at x = 0 and f(x) changes sign around it
2 1 x4
x  x  f  1
(III) g  x   x 2   f u  du   f  x     t 2 dt  and g(1) = 1  g 1  6 
1  0  3
1 0 t 1
1 dt 1 e 1 3
(IV) I2     t   dt  I1 (Let –x = t)
3 0 e 2t  3 1 1 t 3e

44. C

Sol. (I) f(x) is discontinuous at x  ,
2
1
  3x  1   3
(II) A    x 3/2    dx 
0  2  20
2 2
1
(III) Required area = 2  xdx    x 2  2x  2  dx 
1 1
3
1 1 1
n  1 n2 
(IV) In   x n 1  x 2 dx = n 1 2
 x  x 1  x dx = 0  x 1  x 2  1  x 2 dx
0 0 3 0
n 1 n 1 I n 1
= In  2  In  n 
3 3 In  2 n  2

45. B
3 1
Sol. (I) For f  x   x3  x 2  x   f(x) + f(1 – x) = 1  f(f(x)) + f(1 – f(x)) = 1
2 4
3 /4
 I  f  f  x  dx
1/ 4
..... (1)
3 /4
I  f  f 1  x   dx
1/ 4
..... (2)
3 /4
1 1
Adding equation (1) and (2), we get 2I   f  f  x    f 1  f  x    2
1/ 4
 I
4
1
1
(II) Area  A     2x  x 2  x n  dx   n = 5
0 2
11
(III) f(x) + f(–x) = 1  S 
2
1/7
3 
(IV) f  x     x7  and f(f(x)) = x
2 

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 13 AITS-PT-I (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023

46. D
Sol. (I) Put 2y = y  f(x + y) = f(x) + f(y) + 2xy partially differentiate with respect to x
f(x + y) = f(x) + 2y put x = 1, y = –1  f(1) – f(0) = 2
3  1
(II) Let lim f  x    , then   3 =1
x  2
1 1
(III) f(x) + f(x + ) = 2  f  x   f  x     1 also af(x) + bf(x + c) = 1
2 2
1
On comparing a = b = , c = 
2
(IV) f(x + y) = 3yf(x) + 2xf(y) ..... (1)
Put x = 1 in equation (1) f(1 + y) = 3yf(1) + 2f(y)
x
y  x  f(1 + x) = 3 f(1) + 2f(x) ..... (2)
Now, put y = 1 in equation (1)
x
f(1 + x) = 3f(x) + 2 f(1) ..... (3)
From equation (2) and (3), we get f(x) = 3x – 2x

Section – B

47. 2023.00
Sol. f(x) – f(y)  ln x – ln y + x – y ..... (1)
x  y and y  x
f(y) – f(x)  ln y – ln x + y – x
 f(x) – f(y)  ln x – ln y + x – y ..... (2)
From equation (1) and (2), f(x) – f(y) = (ln x + x) – (ln y + y)
1  1 
 f(x) = ln x + x  g  x   1   g    2023
x  2022 

48. 5.00
x 2x 
Sol. sin 3 = 3 sin  – 4 sin3  = sin (1 + 2 cos 2)  sin x  sin 1  2cos 
3 3 
x x
  2x 
sin  sin  2  1  2cos 2  and so on multiplying all
3  3  3 
 x   2x 
sin  n  n  1  2cos r 
 x  n  2x  sin x  3   3  sin x
sin x  sin  n    1  2cos r    lim   f(x) =
 3  r 1  3  x n  x  r 1 3 x
 n
3 
Thus |x f(x)| + ||x – 2| – 1| = |sin x| + ||x – 2| – 1| is not differentiable at 5 points in (0, 3)

49. 4.50
2 2
Sol. I    3x 2  6x  4  cos  x 3  3x 2  4x  2  dx    3x  3  cos  x 3  3x 2  4x  2  dx
0 0
Let I = I1 + I2
2
3
I1    cos t  dt = 2 sin 2 (where t = x – 3x2 + 4x – 2)
2
1
I2  3  ucos u3  u  du = 0 (where u = x – 1)
1

50. 7.63
Sol. If each of two positive real number x, y is not integer but x + y is an integer,
then [x] + [y] = x + y – 1

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AITS-PT-I (Paper-1)-PCM(Sol.)-JEE(Advanced)/2023 14

 x  y  1
305k 305  503  k 
Since,   305 for 1  k  502
503 503
 305   305  2   305  502 
 S     .....   = 304.251 = 76304
 503   503   503 

51. 4044.00
1
1010
Sol. I2   x1010 1  x 2022  dx let x1011  t
0
1 1 1
1
1  t 2  dt = 1  1  1  t 2   dt = 1  t1010  2  t 1010 dt
1010 1010
 I2  
1011 0 1011 0 1011 0
Put t = 2y
1/2 1 1/2
22021 1010 1010 1010 1010 1010
I2   y 1  y  dy and I1   x  1  x  dx = 2  x1010 1  x  dx
1011 0 0 0

I1
 I  22022  4044
I2

52. 199.00
1 1
Sol. f  x   ln x   f  e200   200  200
x e

53. 16.00
 /4
A
Sol. A 1  4   cos x  sin x  dx  4  2  1 also A1  A 2 
0 2

54. 4.75
 /2
1
Sol. I   sin x  ln  sin2 x   dx , put cos x = t
2 0
2 3
1  2  t 2   t 2  
1 1
1 1 1 1 1 
I   ln 1  t  dt =    t 
2
  .....  dt =      .....
20 2 0 2 3  2  3 10 21 
1 1 1   1 1   1 1  
=     .....           ..... = loge 2  1
 6 20 42   2 3   4 5  
15
and A   ln 2
4

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