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CHAPTER 1: RELATIVITY I
1 1 1 1
Ei Ef m1v1i2 m2 v2i
2
m1v1f2 m2 v2f
2
2 2 2 2
or m1 v1i v1f v1i v1f m2 v2i v2f v2i v2f . Substituting the momentum equation into
the energy equation yields a very simple and general result (true even for three-dimensional
collision if the velocities are replaced as vectors) v1i v1f v2i v2f or as Newton put it
originally, the final relative velocity is opposite to the initial relative velocity:
v1i v2i v1 ff v2
for elastic collision (and a fraction of the initial for general collisions). Now, putting in the
numerical values, the momentum equation, and this relative velocity equation gives:
m1 v1f m2 v2f 0.3v1f 0.2v2f 0.9 kg m s , and 5 3 v1f v2f . Solving the two
v1i v 20 m s 10 m s 10 m s
v2i v 0 m s 10 m s 10 m s
v2i
pi m1v1i 2 000 kg 10 m s 1 500 kg 10 m s 5 10 3 kg m s
m2 v2i
pff 2 000 kg 1 500 kg v 3 500 kg vff 10 m s , and because v 11.4 m s ,
pf 5 10 3 kg m s
1.5 Consequences of Special Relativity
L
L
6 This is a case of length contraction. in this problem the proper length L L0 ,
1 2 12 2 12
v2 L 2
L v 1 0 1 1 2
L 2
L 1 2 L0 v c 1 1
L 0 4
c L0 ; in this case 2 , L0
therefore v 0.866c .
L
L
8
12
1 L v2
1
L c 2
2 12 2 12
L 75
v c 1 c 1 0.661c
L 100
A. u 090
. c
y
+y
+x ux A
11 tt
Earth 1 2 uy
4.0 10 2 m s
2
v2
–0.90c v2
tt 1 2 1 2 t 1 3 600 s
. cc
B. u 090
2c Earth 2 3.0 108 m s 2
x
1 8.89 1013 3 600 s 3 600 3.2 10 9 s
B. at rest
tt 3.2 ns . (Moving clocks run slower.)
uX v 0.50c 0.80c
uX 0.50c
1 uX v c 2 1 0.50c 0.80c c 2
21
24
ux v 0 0.90c
ux 0.90c
1 ux v c 2
1 0 0.90c c 2
uy 0 0.90c
uy 0.392c
1 ux v c 1 0.81 1 2
2
mv
p
1 v 2 c 2
12
1
p
1.67 1027 kg 0.01c
5.01 10 21 kg m s
2 12
1 0.01c c
(a)
p
1.67 1027 kg 0.5c
2.89 10 19 kg m s
2 12
1 0.5c c
(b)
p
1.67 1027 kg 0.9c
1.03 10 18 kg m s
2 12
1 0.9c c
(c)
p
5.01 1021 kg m s 100 MeV c
9.38 MeV c
5.34 10 22 kg m s
Similarly, for (b) p 540 MeV c and for (c) p 1 930 MeV c .
2 (a) Scalar equations can be considered in this case because relativistic and classical velocities
are in the same direction.
2 12
mv 1 1
p mv 1.90mv 1.90 v 1 c
2 12 2 12
1 v c 1 v c 1.90
0.85c
1.503 10 10 J
E mc 2 4.813 1010 J 3.01 10 3 MeV
(b)
1 0.95c c 2 12
12
mc 2 mc 2 2
E mc 2
12
v c 1
1 v c 2
E
12
938.27 MeV 2
3 10 8 m s 1 2.999 5 10 8 m s
(b) 50 938.3 MeV
13 (a)
E 400 mc 2 mc 2
1 2
v2
1 2 400
c
v
4001
2 2
1 2
c
v 1 1 2
1
c 400 2
v 0.999 997 c
(b)
K E mc 2 400 1 mc 2 399 mc 2 399 938.3 MeV 3.744 10 5 MeV
14 (a) E mc 2
E 4 10 26 J
m 4.4 109 kg
c2 3.0 108 m s
2
t
2.0 10 30 kg
4.5 10 20 s 1.4 1013 years
4.4 10 9
kg s
(b)
12
Vq 2 v Vq 2
1 2 2
1 1
15 (a)
K mc 2 mc 2 Vq and so, mc and c mc 2
12
v 1
1 0.412 7
c 1 5.0 10 4 eV 0.511 MeV 2
or v 0.413c .
1
K mv 2 Vq
(b) 2
2 5.0 10 4 eV
12
12
v
2Vq
2
0.442c
m 0.511 MeV c
3
100%
(c) The error in using the classical expression is approximately 40 or about 7.5% in
speed.
17 m mRa mRn mHe (an atomic unit of mass, the u, is one-twelfth the mass of the 12
C atom or
1.660 54 10 27 kg )
K
E mc 2 0.500 0.511 MeV 1.011 MeV
2 .
pe 2 p cos pe
Conservation of momentum requires that where
is the initial momentum of
E
1.011 MeV c E2 pe2 c 2 mc 2
2
the electron and p is the gamma ray’s momentum, c . Using e
Ee Ee K mc 2
where is the electron’s total energy, , yields
pe
cos 0.703
; 45.3 .
2p
Finally,
23 In this problem, M is the mass of the initial particle, ml is the mass of the lighter fragment, vl is
the speed of the lighter fragment, mh is the mass of the heavier fragment, and vh is the speed of
the heavier fragment. Conservation of mass-energy leads to
ml c 2 mh c 2
Mc 2
1 vl2 c 2 1 vh2 c 2
obtains
3.34 10 27 kg 6.22ml 2.01mh which in turn gives
3.34 10 27 kg
m 8.84 10 28 kg
3.34 10 27 kg 6.22 0.284 ml 2.01mh or h 3.78 and
28
ml 0.284 mh 2.51 10 kg .
CHAPTER 3: THE QUANTUM THEORY OF LIGHT
2 Assume that your skin can be considered a blackbody. One can then use Wien’s displacement
law,
maxT 0.289 8 10 2 m K with T 35 0 C 308 K to find
0.289 8 10 2 m K
max 9.41 106 m 9 410 nm
308 K .
(a) for
f 5 1014 Hz , E 2.07 eV
n P P 500 10 9 s 1
3.74 10 26 J s 3 108 s1 9.45 10 44 photons s
t hfh c 6.63 10 34 J s .
hc 1 240 eV nm
K hf 2.24 eV 1.30 eV
14 (a) 350 nm
hc 1 240 eV nm
554 nm
(b) At c , K 0 and 2.24 eV
hc hc
Kmax hf Kmax
20 ;
hc
1.00 eV
First Source: .
hc 2hc
4.00 eV= 4.00 eV
2
Second Source: .
As the work function is the same for both sources (a property of the metal),
hc 2hc hc hc
100 eV 4.00 eV 3.00 eV 1.00 eV 3.00 eV 1.00 eV 2.00 eV
and .
hc 6.626 10 J s 3 10 8 m s
34
E 2.48 eV
23
5 107 m 1.6 1019 J eV
h E 2.48 eV 1.6 10 J eV
19
p 1.32 10 27 kg m s
c 3 10 m s
8
h
1 cos 0.002 43 nm 1 cos
. When 90 , 0.002 43 nm .
me c
24 (a)
hc hc 1 1
Ke hc
(b)
Conservation of energy requires that 0 K e or 0
6.625 10 34 J s 3 10 8 m s
2 10 m 1 2.024 3 10 10 m 1
10
Ke
1.6 10 19 J eV
74.4 eV
27 Conservation of energy yields hf K e hf (Equation A). Conservation of momentum yields
E hf
p
pe2 p2 p 2 2 pp cos . Using photon c c there results
hfh 2 fh2 fh f cos
pe2 2
c c c c (Equation B). If the photon transfers all of its energy,
hf 2
pe2
f 0 and Equations A and B become Ke hf and c respectively. Note that in general,
2
Pe2
hf
Ke Ee me c 2 pe2 c 2 me c 2
2 12
me c 2
. Finally, substituting K e hf and c into
Ke pe2 c 2 me c 2 hfh f me c 2
2 12 2 12
2
me c 2 me c 2
, yields
(Equation C). As Equation
C is true only if h, or f, or e , or c is zero and all are non-zero this contradiction means that f
m
cannot equal zero and conserve both relativistic energy and momentum.
29 Symmetric Scattering, . First, use the equations of conservations of momentum given by
Equations 3.30 and 3.31 for this two dimensional scattering process with :
h h
cos pe cos
(a) 0 (1)
h h
sin pe sin pe
or (2)
Substituting (2) into (1) yields 20 cos (3)
0 c 1 cos (4)
h c 0
c 0.002 43 nm cos
where me c
. Combining (3) and (4) yields c 20 . In this case,
hc
E
because E 1.02 MeV , and 0 there results
hc 1 240 eV nm
0 0.001 22 nm
E 1.20 106 eV .
0.002 43 nm 0.001 22 nm
cos 0.749 5
0.002 42 nm 0.002 44 nm
Thus, , and solving for the scattering angle,
41.5 .
pe2 c 2 h 2 ffh
2 0
2
2 2
ff 0 cos
Ee2 pe2 c 2 me c 2
2
into the relativistic energy expression yields
2me c 2 ff0
ff2 0
2
2 ff0
h
ff2 0
2
2 ff0 cos
me c 2 ff0 h 1 cos
ff0 1 cos 0
. Using f c one obtains
h me c
which reduces to ,
which is the Compton scattering or Compton shift relation.
CHAPTER 4: THE PARTICLE NATURE OF MATTER
1 1 1
R 2 2
11
nfi n . For the Balmer series, nf 2 ; ni 3, 4, 5, . The first three lines in the series
R 2 2
1 1 1
1
n where R 1.097 37 10 m .
7
have wavelengths given by 2
1
1st line:
1 1
R
4 9 5
36
R;
36
5R
656.112 nm
1 1 1
2nd line: R
4 16
3
16
R;
16
3R
486.009 nm
1 1 1
3rd line: R
4 25
21
100
R;
100
21R
433.937 nm
R 1 2 n
1 1 R R
2.99 3
n R m
1 12 12
102.6 nm ; R 102.61109
13 (a)
(b) This wavelength cannot belong to either series. Both the Paschen and Brackett series lie in
the IR region, whereas the wavelength of 102.6 nm lies in the UV region.
0
E3 13.6 eV
13.6Z 2 122.4
En 2
2
n eV n eV
E2 30.6 eV
So E1 122.4 eV
E2 30.6 eV
E3 13.6 eV , etc.
E1 122.4 eV
1 1
E 13.6 eV 2 2
20 nfi n
(a)
E 13.6 eV 251 161 0.306 eV
(b)
E 13.6 eV 361 251 0.166 eV
1
max
1 1
R 2 2 R 2
nfi n
11
2
3R
4
4 4
max 121.5 nm
3R 3 1.097 107 m 1
1
min 91.16 nm
R
CHAPTER 5: MATTER WAVES
6.63 10 34 Js
h
h
p mv 1.67 10 27
kg
10 6 m s 3.97 10 13 m
1
2 12
K 1 2 mc
K
p
relativistic expression c ? As the relativistic expression reduces to
p 2mK 1 2
for K 2mc , we can use the classical expression whenever K 1 MeV because mc for the
2 2
electron is 0.511 MeV.
h h hc
0.511c MeV 50 eV 2 0.511 MeV 50 eV 1 2
12
p 2
2
1 240 eV nm
0.173 nm
2 0.511 10 6 50 eV 2
12
(b) As 50 eV 1 MeV ,
p 2mK 1 2
hc
5.49 10 3 nm
50 10 eV
12
2 0.511 MeV 3
c2 .
As this is clearly a worse approximation than in (a) to be on the safe side use the
1 2mcK 2 12
pK
relativistic expression for p: c so
h hc 1 240 eV nm
p K 2Kmc
2 2 12
50 10 3 2 50 10 3 0.511 106 eV
2 12
5.36 10 3 nm 0.005 36 nm
3
6 From Problem 5-2, a 50 keV electron has 5.36 10 nm . A 50 keV proton has
K 50 keV 2mc 2 1 877 MeV so we use p 2mK 1 2 :
h h hc
50 keV 2 938.3 MeV 50 keV 1 2
12
p 2 938.3 MeV
c2
1 240 eV nm
1.28 10 4 nm
2 938.3 10 eV 50 10 eV
3 3 12
h h h h 1 2
12
V
p 2mK 12
2meV 12
2 me
8
6.626 10 34 Js
V 1 2
2 9.105 10 31 kg 1.602 10 19 C
1 2
9
1.226 10 kg m 1 2
12 2
V
sC 1 2
11 (a) In this problem, the electron must be treated relativistically because we must use
relativity when
pc mc 2 . (See problem 5-5). the momentum of the electron is
h 6.626 10 34 J s
p 6.626 10 20 kg m s
1014 m
and
pc 124 MeV mc 2 0.511 MeV . The energy of the electron is
E p 2 c 2 m2 c 4
12
1.99 10 11 J 1.24 108 eV
(b) The kinetic energy is too large to expect that the electron could be confined to a region
the size of the nucleus.
2 where p mv 0.05 kg 10 30 m s 1.5 10 kg m s . Therefore,
x p 3 3
18
6.626 10 34 J s
x 3.51 1032 m
2 p 4 1.5 10 3 kg m s
.
mv 2 p 2 1 10 6 eV 1.6 10 19 J eV p2
K p 2.312 10 20 kg m s
19 2 2m : 2 1.67 10 27
kg ,
h
xp
p 0.05 p 1.160 10 21 kg m s and 4 . Thus
6.63 10 34 J s
x 4.56 10 14 m
1.16 1021 kg m s 4 .
Note that non-relativistic treatment has been used, which is justified because the kinetic energy is
1.6 1013 100% 0.11%
only 1.50 10 10 of the rest energy.
22
K 1 mc 2 where
The relativistic expression for the kinetic energy is given by
K
1
2
mc 0.511 MeV for the electron. Solving this for gives mc 2 . Using the three values of
K given, we find that
1
1 v2 c 2
As we can use the above results to calculate the corresponding values of v. Solving
12
1
v c1 2
for v gives .
(a)
v 5.91 107 m s
For 1 1.02 , 1
(b)
v 2.82 108 m s
For 2 2.96 , 2
(c)
v 3.00 108 m s
For 3 197 , 3
p1 5.49 10 23 kg m s
p2 7.60 10 22 kg m s
p3 5.38 10 20 kg m s
xp
We can use the uncertainty relation, 2 with x a to determine the width of the slit.
Since it is required to resolve a 1% difference in momentum, we take p 0.01p . This gives
xp a 0.01p a
2 or 2 0.01p
. Using the calculated values of p, we find
(c)
a 9.80 10 14 nm
For p p3 , 3
n
sin
27 For a single slit with width a, minima are given by a where n 1, 2, 3, and
x x1 x2 2 x x
sin tan 2 1
L , L a and L a L a or
ax 5 Å 2.1 cm
0.525 Å
L 20 cm
1.24 104 eV Å
2
p2 h2 hc 2
E 546 eV
2m 2m 2 2mc 2 2 2 5.11 10 5 eV 0.525 Å 2
h 6.63 10 34 J s
9.93 10 7 m
mv 1.67 10 27 kg 0.4 m s
28 (a)
9.93 10 7 m
sin 4.96 10 4
2 D 2 1.0 10 3 m
(b)
y R 10 m 4.96 10 4 4.96 mm
As sin , .
(c) We cannot say the neutron passed through one slit. We can only say it passed through
the slits.
CHAPTER 6: QUANTUM MECHANICS IN ONE DIMENTION
(b) Acceptable.
(c) Acceptable.
3 (a)
A sin
2 x
A sin 5 10 x
10 2
so
5 1010 m 1
,
2
5 1010
1.26 10 10 m
.
h 6.626 10 34 Js
p 5.26 10 24 kg m s
(b) 1.26 10 10 m
p2
K m 9.11 10 31 kg
(c) 2m
5.26 1024 kg m s
2
K 1.52 10 17 J
2 9.11 1031 kg
1.52 10 17 J
K 95 eV
1.6 10 19 J eV
2 dx2
U
d2
2m .
d 2 2 4 x2
4 Ax 3 6 AxL2 4 e x
1 2
L2 U 6
x 2 2
2 2
If Ae
L
then dx
2
L , 2mL L .
3 2
U 0 0
(b) U x is a parabola centered at x 0 with mL2 :
U
3 2 x
mL2
7 Since the particle is confined to the box, x can be no larger than L, the box length. With n 0 ,
n2 h 2
En
8 mL2 is also zero. Since the energy is all kinetic, this implies px 0 .
2
the particle energy
But px 0 is expected for a particle that spends equal time moving left as right, giving
2
px px2 p x 0
. Thus, for this case px x 0 , in violation of the uncertainty principle.
n2 h 2
En
10 8 mL2
6.63 1034 Js
2
h2
6.03 10 18 J 37.7 eV
8 mL2 8 9.11 10 31 kg 10 10 m 2
(a) E1 37.7 eV
E2 37.7 2 2 151 eV
E3 37.7 32 339 eV
E4 37.7 4 2 603 eV
hc
hf Eni Enf
(b)
hc 1 240 eV nm
Eni Enfi En Enf
E Enf 603 eV 37.7 eV 565 eV 2.19 nm
For ni 4 , nf 1 , ni ,
ni 4 , nf 2 , 2.75 nm
ni 4 , nf 3 , 4.70 nm
ni 3 , nf 1 , 4.12 nm
ni 3 , nf 2 , 6.59 nm
ni 2 , nf 1 , 10.9 nm
L
11 In the present case, the box is displaced from (0, L) by 2 . Accordingly, we may obtain the
L
x
wavefunctions by replacing x with 2 in the wavefunctions of Equation 6.18. Using
sin
L x L2 sin nL x n2 sin nL x cos n2 cos nL x sin n2
n
L L
x
we get for 2 2
L2 x
x
12
cos cos 2
2
1 x P1 x
L ; L L
x P x sin
2 x 2 x
12
sin
2 2 2
2 2
L L ; L L
x P x cos
3 x 3 x
12
cos
2 2 2
3 3
L L ; L L
10
13 (a) Proton in a box of width L 0.200 nm 2 10 m
6.626 1034 J s
2
h2
E1 8.22 10 22 J
8mp L2 8 1.67 10 27 kg 2 10 10 m 2
8.22 10 22 J
5.13 10 3 eV
1.60 10 19 J eV
6.626 1034 J s
2
h2
E1 1.506 10 18 J 9.40 eV
8 me L2 8 9.11 10 31 kg 2 10 10 m 2
.
(c) The electron has a much higher energy because it is much less massive.
17 (a) The wavefunctions and probability densities are the same as those shown in the two
lower curves in Figure 6.16 of the text.
3.5 Å
2 3.5 Å
2 x
P1 dx 10 Å sin 10
2
dx
1.5 Å 1.5 Å
(b)
x
3.5
1 x 10
sin
5 2 4 5 1.5
x 1
sin axdx 2 4a sin 2 ax
2
x 1 3.5 5 sin 3.5 1.5 5 sin 1.5
3.5
1 5
P1 x sin
10 5 1.5 10 5 5
1
2.0 sin 0.3 sin 0.7 2.00 0.0 0.200
5 1
10
10