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11 CD 12 BCD 13 BC 14 1 15 0
16 8 17 6 18 5
CHEMISTRY
19 D 20 C 21 C 22 B 23 A
29 AB 30 BD 31 ABC 32 8 33 3
34 4 35 2 36 5
MATHEMATICS
37 D 38 C 39 A 40 B 41 D
47 ABC 48 AB 49 AB 50 1 51 0
52 2 53 3 54 0
Page 1
SOLUTIONS
PHYSICS
1. Considering AandB together 20 a 20 g sin 37 0.5 10 g cos 37 0.4 10 g cos 37
a 6 2 1.6 a 2.4 ms 2
Considering only A : T 10 g sin 37 0.5 10 g cos 37 10 2.4
T 60 40 24 T 4N
2. When applied force is small both A and B move together
If F kt
kt
Then a ...... 1
mA mB
After some time F becomes larger and friction fails to provide necessary acceleration to A so as to
keep pace with B , slipping starts. Acceleration of A becomes constant g and acceleration of B
keeps increasing according to
kt mA g k m
aA t A g ..... 2
mB mB mB
Obviously, slope of a vs t graph is as per equation 2 and larger than that given by 1
3.
W
For equilibrium of the block T W sin 30 0 …..(1)
2
3
And N W cos 300 W …..(2)
2
W 3 3
For equilibrium of cart + Block in horizontal direction f 0 T cos 300 . W
2 2 4
2 2
g 1 g
g 12v 2 v
12 2 3
5. The block is accelerated due to horizontal component of normal force applied by the wedge on the
block.
Page 2
horizontal component of N is N x ma 110 10 N
1 1
2
Displacement in 3s is x at 2 10 3 15m .
2 2
Wn N x .x 150 J .
6. Motion starts when
0.3 1 10
3t 2 s mg t 2 1 t 1.0s .
3
After the motion starts, friction becomes kinetic
f k k mg 2 N
dv
m 3t 2 2
dt
v 3
dv 3t 2 dt
2
0 1
v 22ms 1
7. f lim iting 0.5 2 g 10 N
(20 2)
When F1 = 2 N a 3m / s 2
6
For 2 Kg block to have this acceleration, friction on it will be 8 N towards left
Similarly, one can find friction when F1 = 8 N and 10 N. Since man is stationary, friction must be
acting on him to balance tension.
8. M 1 cannot move (immediately) after the system is released.
Let acceleration of M 2 be a . There is rubbing between M 1 and M 2 (with M 1 being stationary).
Page 3
94
a 4.7 ms 2
20
9. (A) For no acceleration, net force on the block must be zero.
f 0.4 vrel 0.4 v0 0 since speed of block 0
1
1 10 0.4 v0 0
2
v0 12.5ms 1
(B) If vrel 0 , then friction f 0 .
In this case, the block will experience an acceleration of g sin and it cannot remain at rest relative
to the belt.
(C) vr 2.5 10 12.5ms 1
As in (a), the net force on the block will be zero.
10. The force applied by the wall on the rope has a vertical component that balances the weight of the
hanging part. Horizontal component of this force must be equal to friction acting on the rope lying on
the table.
M 5
For hanging part: TA cos g TA Mg
2 8
5 3 3
T TA sin Mg . Mg
8 5 8
M 3
For equilibrium of the part on the table: N T g Mg
2 8
3 3
min
4 4
11. (a) Limiting friction at top & bottom surfaces of 4 kg block are
fT 0.2 2 10 4 N f B 0.1 6 10 6 N
Sliding will start at top surface when F = fT = 4 N.
F 4
(b) At F 4 N , 2kg will move with acceleration a m / s2
2
And 4kg will remain at rest as f1 can never exceed f B
Thus for F 2 N , both blocks will be at rest.
64
And for F 6 N , a2 kg 1m / s 2 And a4 kg 0
2
12. When the bicycle is accelerating, friction is up the plane and greater than Mg sinθ.
Page 4
It is possible that friction is up the plane but is less than Mg sinθ. In this case, the bicycle will retard
even if the friction is up plane.
mg sin
13. Acceleration of the chain is given by a
M
Where M mass of complete chain m mass of chain on the incline.
As chain slides, m increases and hence acceleration increases.
Considering motion of lower half of the chain
M M M M
g sin T a T g sin a
2 2 2 2
Since a is increasing, T will decrease till a part of chain is there on the horizontal surface. By using
1 L M b
Mv 2 M ( g sin ) b( g sin )
2 2 L 2
energy conservation,
g sin 2 2
v
L
L b
1 2 1 2 k 100
14. mv kx v .x 0.05
2 2 m 0.1
0.5 10 ms 1
2h 2 2
Range of projectile after it leaves the horizontal surface is R v 0.5 10 1m
g 10
F 30
15. Retardation produced a 2ms 2 .
M 15
Velocity of particle becomes zero at t 2.5s .
Page 5
mg g
48m a 12n 336 a n 28
5 20
g g
n 28 4 n 28 n 32
5 20
Note: The question does not tell which way the chain is moving. But it is easy to guess that the part
on the incline cannot move down the incline even if the entire chain lies on the incline. This is
because m tan 37 .
17. Block is moving hence friction is kinetic N F sin 60 Mg cos 30
For no acceleration
f1l mg
(i) Maximum allowed acceleration of A is: a1max
M M
The cloth must not be pulled with an acceleration greater than a1max .
Friction f 2 can easily provide this acceleration to block B .
When A is moving with a1max , the acceleration of B will also be a1max . Friction f 2 will be
m2 g
f 2 ma1max
M
m2 g m
Using 1 F f1 f 2 mg mg 1
M M
m
F mg 1 45 N
M
Page 6
CHEMISTRY
19. If ‘x’ value 0,3,5 then the molecule PF5 , PCl3 F2 , PCl5 are nonpolar
If ‘x’ value 2,1,4 then the molecules PCl2 F3 , PClF4 , PCl4 F are polar molecules.
20. XeF4 is nonpolar
21.
CH 3
Br
CH 3
Br
O O
CF3 S OH C6 H 5 S OH CH 3COOH
O O
1
23. Na H 2O NaOH H2
2
‘Zn’ is amphoteric metal so it liberates H 2 with both acid and base.
24. In trans isomer symmetry is absent. So it is optically active.
25. Conceptual
26. A. number of stereogenic centers 3. So isomers 23 8
B. Having plane of symmetry so optically inactive
C. Benzaldehyde has No ' ' hydrogen. So does not show tautomerism
27. Structure I is 2 S , 3 R 3 Bromo 2 Butanol
Structure II is 2 R ,3S tartaric acid
Structure III is 2 S ,3S 3 Bromo 2 Butanol
Structure IV is 2 R ,3S 3 Bromo 2 Butanol
28. Amides are weak bases than any amine.
29. Rate of SN 1 reaction stability of carbocation
30. In Aryl halides halogen is linked to sp 2 carbon of aromatic ring. (Resonance) sp 2 carbon has more
E.N. value then sp 3
31. A- I 1 is better leaving group than Cl .
D- CH 3Cl is more reactive than C2 H 5Cl towards SN 2 reaction
32. C5 H12O formula stands eight alcohols. All alcohols gives CH 4 gas with CH 3 MgBr
C C C C OH
C C C C C OH C
OH
C C C C C C C C C
OH C
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OH
OH C C C C C C C C
C C
C
C C C OH C C C C C
C OH
33.
VIII-A VII-A VI-A V-A IV-A III-A
10 9 8 7 6 5
18 17 16 15 14 13
36 35 34 33 32 31
54 53 52 51 50 49
86 85 84 83 82 81
118 117 116 114 113 112
Atomic numbers of ‘p’ block elements
34. Before rearrangement of carbocation one alkene.
After rearrangement 3 alkenes.
35.
I
x6
36. 2-reducing properties of solution is due to “electrons”
3- NaHCO3 having acidic hydrogen.
7- CsBr3 contains Cs , Br3 ions
Page 8
MATHS
37. Let ln x – 3 = t
tn 0
lim m form = –1
t 0 ln(cos t) 0
nt n 1
lim = –1
t 0 m tan t
n
n – 1 = 1 & 1 n = m = 2.
m
38. g n f n f n 1
If n is even, n+1 is odd.
g n 2n 1 2 n 1 2 4n 3
If n is odd, n+1 is even.
g n 2n 2 2 n 1 1 4n 3 .
39. [ 117] 10; If r [ n 2 ,(n 1)2 ) : n then [ r ] n
The interval [n 2 ,(n 1)2 ) has 2n + 1 integers
1 1 1 1
S .3 .5 .... .19 .18
2.1 1 2.2 1 2.9 1 2.10 1
18 69
9 .
21 7
40. f(– 2) = 1 f(2) = 3
1
– 2m + c = 1 2m + c = 3 c=2 m
2
1
f x x 2 sub f(x) rationalise and evaluate f(x)
2
41. cos sin x 0 true for all x R; log x x 0 for x 0, 1
42. Let a = [x] + [y] = [x]. [y].
Then from the given equation, we have a + b = a. b ab – a – b = 0
ab – a – b + 1 = 1 (a – 1)(b – 1) = 1.
This is possible if (i) a – 1 = 1, b – 1 = 1 or (ii) a – 1 = - 1, b – 1 = - 1.
Now, for (i), a – 1 = 1 a = 2 and b – 1 = 1 b = 2
And for (ii) a – 1 = - 1 a = 0 and b – 1 = - 1 b = 0.
Thus (a = 2 and b = 2) or (a = 0, b = 0)
i.e., ([x] = 2 and [y] = 2) or ([x] = 0, [y] = 0).
But x 2 2 x 3 and y 2 2 y 3 .
Again x 0 0 x 1 and y 0 0 y 1 .
Thus, the solution sets are (i) 0 x 1 and 0 y 1 (ii) 2 x 3 and 2 y 3 .
43. Let f(x) = ax3 + bx2 + cx + d
sin 2 x 1
lim 3
x 0 ax bx cx d
2
3
For the limit to exist d = 0, c = 0, b = 3 and a can be any real number but a ≠ 0
So f(1) = a + b + c + d which can be any real number except 3.
44. Giving limit
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x3 x 5
a x .... bx cx 2 x3
3! 5!
= lim
x 0 x 2 x3
2x2 x ... 2 x3 x 4
2 3
a ax5
( a b) x cx 2 1 x3 ....
= lim 6 120
x 0 x5 x 6
2 ...
3 2
For this limit to exist, we must have
a b, c 0, a 6
a 3 63 3
and given limit =
120 2 120 2 40
sin sin x sin x 1
45. lim
ax bx c
5 3
x 0 12
sin x x sin x x
2sin cos sin x x
lim 2 2
x 0
sin x x 2 ax 5 bx3
2
sin x x sin x x
sin cos sin x x
lim 2 2 1
2
x 0
sin x x x
3
ax b
2
1 1
b2
6b 12
a R, b 2, c 0
h2 1
46. lim f x lim cos 0
x 1 h 0 h h
h 2 h 1
lim f x lim cos does not exist
x 1 h 0 h h
x 15
47. f x ; x 0,90
15 x
0 x 15 f x 0 75 x 90 ; f x 5
15 x 30 f x 1 Total Integers
30 x 45 f x 2 f x 0, 1, 2, 3, 4, 5
45 x 60 f x 3
60 x 75 f x 4
48. 3x 5 x 2.......(1)
3 x x 5 x 2
3 x 2 x 2....... 2
But 0 x 1 0 3 x 3 0 2 x 2 3
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x 1, 2 Now x 1 x 1
x 2 x 8 / 3
49. x 1 f x x is a polynomial of degree n 1 .
x 1 f x x k. x x 1 x 2 ... x n
Put x n 1
n 1
1
n 2 f n 1 n 1 k n 1! k
n 1!
Hence f n 1 1 , n is odd
n
, n is even
n2
4 x2
50. f(x) exits if
x 2
Case (i) : 4 x2 0 and x 2 0
x 2 4 0 and x 2
x 2, 2 and x 1,
x 1, 2
Case (ii): 4 x2 0 and x 2 0
x 2 4 0 and x 2
x , 2 2, and x , 2
x , 2
Domain of f is , 2 1, 2
tan 5 x
3
51. lim tan x
x
10
10
tan 5 h
2 2
lim tan h
h 0
5
0 lim a
x
x
0, a 1
1 cos x
52. f x cos x
1 cos x 1 cos x 2
cos x
1 cos x
2
1
x 0
lim 1 cos x f x
2
cos x 1
cos x 1 cos x 1
1
1
lim cos x cos x 1
e 2
x 0
x2 x2
1 ...
1 x ...
53. lim
1 cos x 2! 2!
2 n 2
x 0 x x
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1
lim
x x ...
2
2 x0 x n2
n 2 1
n3
54. sin x 2 cos 2 x 4 x 2 37 x 22 4 p 1
0 2 4 x 2 37 x 22 4 p 1
2 4 x 2 37 x 88 4 p 1
86 4 x 2 37 x 4 p 1
85 4 x 2 37 x 4 p
As 85 is not an integral multiple of 4, hence no integral value of p is possible
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