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Sri Chaitanya IIT Academy, India

A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI


A right Choice for the Real Aspirant
ICON CENTRAL OFFICE, MADHAPUR-HYD
Sec: Sr-ICON-B-1 JEE-ADVANCE-2019-P1 Date: 02-05-21
Time: 09:00 AM to 12:00 PM GTA-02 Max.Marks:186

KEY SHEET
PHYSICS
1) D 2) B 3) A 4) A 5) B,D 6) A,C,D 7) A,B,C 8) A,B,C

9) A,B 10) A,B 11) B,C,D 12) B,C 13) 1.5 14) 2.0 15) 3.3 16) 3.0

17) 2.6 18) 25.0

CHEMISTRY
19) A 20) C 21) B 22) B 23) A,B,C 24) A,D 25) A,B,C 26) A,B

27) A,C,D 28) A,B,C 29) A,B,C 30) A,B,C,D 31) 2.5 32) 2.0 33) 10.0 34) 12.0

35) 6.0 36) 8.0

MATHEMATICS
37) A 38) D 39) D 40) A 41) A,B,C,D42) B,D 43) A,B,C 44) A,B,C,D

45) B,C 46) A,B 47) A,B,C 48) A,B,C,D49) 0.2 50) 24.0 51) 11.0 52) 50.0

53) 0.0 54) 2.0


SRI CHAITANYA IIT ACADEMY, INDIA 02-05-21_Sr.ICON-BT-I_Jee-Adv(2019-p1)_GTA-2_Key&Sol’s

SOLUTIONS
PHYSICS
1)

mu02
u0  2 gR sin  N  mg sin  
R
1
N  3mg sin  N  mg  3mg sin   sin  
3
2) 6  30 2  1.5
VAB   3.6V . Terminal voltage of cell=  1.5V
50 2
3.6
Using V  kl  1.5  l or l  125cm
300
3) Given The equation of stationary wave is

….(1)
General stationary wave equation is
…..(2)
From equations (1)&(2),we have

A=4 , ,

k=propagation const=

Gap between antinodes is,

Second antinode position=

Third antinode position=


4) Given
The ratio of cube of circumference of the orbit of a satellite to the volume of the
earth is  6 1010 g / R We know
2K 3
3 R
2π r K r K K 3 2 K 3R
Time period T   , if K  2πr =  
R g R g R 2πg 4 3 3 Vg
 πR  g
3 
K 3 6 1010 g 2  6  1010
Given,  So, T   2  105 sec
V R 3
5) Magnetic field is clearly in z axis.
6) Ans: ACD
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SRI CHAITANYA IIT ACADEMY, INDIA 02-05-21_Sr.ICON-BT-I_Jee-Adv(2019-p1)_GTA-2_Key&Sol’s

a
1
dI = JdA  dI  kr 2  2 r dr   I  2 k r 3dr  I   ka 4
0
2
  kr 4 
 0  2 
0 I 0ka 4   1  kr 3
Further, field for r > a is B   , And field for r < a is B   0
2 r 4r 2 r 4
7) 1242eVnm
Energy of K absorption edge EK   72.21 103 eV  72.21KeV
0.0172nm
he 1242eVnm
Energy of K line  K k   59.14 KeV
e 0.021nm
Energy of K shell   K K  EK    59.14  72.21 KeV  13.04keV

Energy of L shell Ek  72.21keV  64.69keV  72.21keV  7.52keV


1242Vnm
Energy of M shell Ek  Ek   72.21keV  69keV  72.21keV  3.21keV

0.018nm
8) n for liquid= n for Glass/ yellow light.
But n for liquid  n for glass (red light), so it will deviated towards base, for blue light n
(liquid) > n (glass) so it will deviate towards vertex.
9) Process A  B is isothermal. Hence
4V  
 U  AB  0 and WA B  nRT01n  0   nRT01n  4   PV
0 0 1n  4 
 V0 
 VA  P0
Hence choices (a) and (b) are correct. Also PAVA  PBVB or PB  PA  
 VB  4
If the line BC passes through the origin of the V – T graph, then V  T . So process
P0 V V T
B  C is isobaric. Hence PC  PB  . Also C  B  TC  0
4 TC TB 4
If the line BC does not pass through the origin, then the correct choices are (a) and (b). If
the line BC passes through the origin, then all the four choices are correct.
10) R  2 h  H  h
11)

I 2v1  4v2  v1  2v2 , v1 and v2 are velocities of A and B along


1 3 3 1 2
the line of impact after collision  4   2   v1  v2  v2  m / s and v1  m/s,
3 2 2  3 3

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SRI CHAITANYA IIT ACADEMY, INDIA 02-05-21_Sr.ICON-BT-I_Jee-Adv(2019-p1)_GTA-2_Key&Sol’s
Magnitude of impulse during deformation = 4 3 N .S , Magnitude of impulse during
4 1 4 2
reformation =
3 2 3
 
N .S , Loss in K.E =   3 3  1  e2  , 3 3m / s is vrel along line of

impact = 16T.
12) Conceptual
13) By conservation of angular momentum about pivot
2
mvd  Md 2 d    md 2 md 2  3 2 2v
  m         md   
2  12  2    2 4  4 3d
14)

3 2 (200  106 ) 2 2 4  108 2 4  108  109


2  10 i  i  i 
5  106 2  10 3  5  106 10
15) As V(t)= 220sin100 t
220
So, I(t)= sin 100 t i.e; I= I m  sin(100 t )
50
 1 1 I I
For I= I m t1    sec And for I= m  m  I m sin(100 t2 )
2 100 200 2 2
1
 t2  s
 600
  100 t2
6 1 1 2 1
 treq     s  3.3ms
200 600 3 300
t
16) N  1 T 12
 
N 0  2 
18
N1 2 9 22 1 1 dN
 18  6  4  R  N
N2 2 2 16 dt
23
R1 T2 N1 9 1 3
    
R2 T1 N 2 3 16 16
17) s  2  r  l
18) RB
TJ  100  0
RA  RB
1 100
  100   250 C
RA 3 1
1
RB

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SRI CHAITANYA IIT ACADEMY, INDIA 02-05-21_Sr.ICON-BT-I_Jee-Adv(2019-p1)_GTA-2_Key&Sol’s

CHEMISTRY
2 2
19) SO3  H 2 SO4  SO4  H 2O  SO2
K 2Cr2O7  H 2 SO4  3SO2  K 2 SO4  Cr2  SO4 3  H 2O
green

20) For zero order reaction change in concentration is same in equal interval of time
21) Conceptual
22) conceptual
23) CONCEPTUAL
24) If a univalent ion is used for coagulating a hydrophilic sol, the coagulating power
increases with increasing dilution of the sol bat if a polyvalent ion is used, the coagulating
power decreases with increasing dilution of the sol.
25) CONCEPTUAL
26)

27) From mechanism


28) Same s  character means same hybridization.
CH 4 ,[ Ni (CO) 4 ] and XeO3 have sp 3 hybridization whereas [ Ni(CN )4 ]2  has dsp 2 hybridization.
29)

C is silicic acid and D ishydrofluorosilicic acid


Hence (a), (b) and (c) are correct while (d) is wrong.
30)

31)  w  w
P  V  b   RT
 M  M
P  M  db   dRT
P  80  8  0.4   8  0.08  300
P=2.5 atm
32) PT  P10 X1  P20 X 2 , PT  P10 (1  X 2 )  P20 X 2

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SRI CHAITANYA IIT ACADEMY, INDIA 02-05-21_Sr.ICON-BT-I_Jee-Adv(2019-p1)_GTA-2_Key&Sol’s
33) Mg 
 Mg 2
 2e
Cu 2   2e   Cu
Mg  Cu 2  Mg   Mg 2   Cu
RT x
E  2.67  2.7  n
nF 1
300
0.03  nx
2  11500
2.3  nx
X  10
34) H 3C  C  H  H 3C  CH 2  C  H

O O

dil NaOH

O CH 3
* *
H3C  CH  CH 2  C  H 3C  CH  CH  C  H 
*
OH H OH O

2 22  4

CH 3
* *
H 3C  CH 2  CH  CH  C  H  H 3C  CH 2  CH  CH 2  C  H
*
OH OH
O O
2
2 4
2
Total=12
35) NH 2 NH 2
CH 3 CH 3 CH 3
,
are less basic than aniline
36) Magnesite, Dolamite, limestone, calamine, Malachite, Azurite and cerrucite are carbonate
ores Bauxite is hydrated oxide ore. These are calcinated to remove CO2and H2O.

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SRI CHAITANYA IIT ACADEMY, INDIA 02-05-21_Sr.ICON-BT-I_Jee-Adv(2019-p1)_GTA-2_Key&Sol’s

MATHEMATICS
37)  0 1 0  0 1 0  0 0 1 
A  AA   0 0 1    0 0 1 
2
  p q r 
 p q r   p q r   pr p  qr q  r 2 
Again
0 0 1   0 1 0
A  A A   p
3 2
q r    0 0 1 
 pr pr q  r   p q r 
 p q r 

  pr p  qr qr 2 

 pq  r 2 p pr  q 2  qr 2 p  2qr  r 3 
 p 0 0  0 q 0   0 0 r 
  
  0 p 0    0 0 q    pr   qr r 
2

2 2
 0 0 p   pq q qr   pr pr  qr 2 pr  r 3 
1 0 0  0 1 0 0 0 1 
  0 1 0   q  0 0 1   r  p q r 
 0 0 1   p q r   pr p  qr pq  r 2 
 pI  qA  rA2 .  A3  rA2  qA  pI
38)

2
area  of  circle  x 
Required  area  :   4  x 2  2 sin  dx
4 0  2 2
39) Given, z 2  z  0
Let z  x  iy
2
  x  iy   x  iy  0
 x 2  y 2  2ixy  x  iy  0
 x 2
 x  y 2   i  2 xy  y   0
On equation real and imaginary part, we get
 x2  x  y 2  0 ....  i 
1
and 2 xy  y  0  y  or x 
2
2
if y  0, then Eq.(i) gives x  x  0
 x  0 or  1
1 1 1
If x  , then Eq. (i) gives   y 2  0
2 4 2
3 3
 y2   y
4 2
Hence, there are four solutions of given equation.
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40) 
We have  
3

   1  
i.e.   i.e.  sin    1
6 2 2 2 2
1 1   1 
i.e.   1  sin     see fig 
2 a  2 a 
i.e. 1  a  2
There can be symmetrical points on the negative x  axis too.
Hence, we have a   2,  1  1, 2  .
41) f  x   0, x  R, a  0 and b 2  4ac  0
We have f '  x   2ax  b and f ''  x   2a
Thus, g  x   ax2  bx  c  2ax  b  2a  ax 2   2a  b  x   2a  b  c 
2
We have a  0 and D   2a  b   4a  2a  b  c 
 b 2  4ac  4a 2  0, since b 2  4ac  0 thus, g  x   0, x  R. Therefore, g  x   0 has non-real
complex roots.
42) If min {b,c} = b
A,b,c are in A.P ; 2b = a + c
2 2 2
b 2  c 2  a 2 b  c   2b  c  4c  3b
cos A   
2bc 2bc 2c
Min {b,c} = c ; a,c,b are in AP
2c = a + b
4b  3c
cos A 
2b
43) d  yy ' x2
 x  yy '   C
dx 2
f ' x
Also, y 2  f  x   yy '  and f  0   f 1  1
2
x3  x  3
 f  x 
3
44) If A and B are invertible square matrices of the same order, then
adj  AB    adjB  adjA
'
 adjA   adjA
n 1
adjA  A , where n is the order of matrix A and
n 2
adj  adjB   B B , where n is the order of matrix B
 (a), (b), (c), (d) are the properties of adjoint.

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45) b b b
tan   tan  1 1
tan   a  a  a  a b
b b
1  tan 2  cot   tan  2 b 2 ab
a a a

b b 2b
tan   cot 
 2ab 
tan   a a
2
 a 2  2 2 
b b a b 
1 2 1 2 
a a
46) f  x   cos x sin 2 x  2sin x  2sin 3 x, min f  x   min g  t  where
g  t   2t  2t 3 , x    ,   , t   1,1.
g   t   2  6t 2  0  t  1/ 3

  
g   t   12t , so g  1/ 3 0and g  1/ 3 0 
4 7 9
Hence min g  t   g  1 3      s
3 3 9 7
 ˆ ˆ  ˆ ˆ  ˆ ˆ
47)      
a) r  r .i i  r . j j  r .k k
  
 
Put r  a  b  (a) is correct
   
b) Put r a and r  b

Take a.b   b  is correct.


c) u  bˆ  aˆ  bˆ 
   
u  a  b  V   c  is correct.
d) is obviously wrong.
48) i ) P  E1   1  P  RRR 
1 2 3
 1   . .   0.9
3 4 5
ii ) P  E2   P  BRR   P  RBR   P  RRB 
2 1 2
 3P  BRR   3. . .  0.2
3 4 5
P  RRR 
iii ) P  E3  
P  RRR   P  BBB 
2 3 4 8 0.1
but P  BBB   . .   P  E3    0.2
3 4 5 20 0.1  0.4
2
iv ) P  E4   1  P  BBB   1   0.6
5
49) P( A)  0.5, P( B)  0.3, A  B  
P( A  B)  P( A)  P( B)
 0.5  0.3  0.8

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SRI CHAITANYA IIT ACADEMY, INDIA 02-05-21_Sr.ICON-BT-I_Jee-Adv(2019-p1)_GTA-2_Key&Sol’s
P ( A  B )  1  0.8  0.2
 The probability of neither A nor B occurring is 0.2
50) Variable plane is lx  my  nz  p  (1)
1 P3 P3
4  24
6 lmn lmn
r x1 y1 z1
If f  x1 , y1 , z1  is foot of  of (0, 0, 0) to ---(1), Then  
l m n
x12 y2 z 2 x 2  y12  z12
  1  1  1
lx1 my1 nz1 P
p x12  y12  z12 p x12  y12  z12 p x12  y12  z12
  ,  , 
l x1 m y1 n z1
3

multiplying,
x 1
2
 y12  z12 

p3
 24
x1 y1 z1 lmn
51)  3 1  3 1
sin  ,cos 
12 2 2 12 2 2
sin15 cos15
 2
sin x cos x
11
sin 15 x  sin 2 x  sin 180  2 x  x  55     11
36
52) (1,  4) lies on common chord of the circles 6 x  14 y  c  d  0  c  d  50
53) n( A)  m  3, n(B)  n  4
For onto, n( A)  n(B)
Here n( A)  n(B)
 Number of onto = 0
1
54)
  f  x x
3
Lt  1  x  1  2  e
x 0
  kx 
f  x
1
kx 2
e  e3
f  x f  x
1 2
3 2 f  x   2kx 2
kx kx 2
2
f  4   2k  4  64  2k.16 k  2.

Sec: Sr.ICON-B-1 Page 10

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