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Solutions to JEE Main - 2 | JEE - 2023


PHYSICS
SECTION-1


1.(B)
V 1 
 V  ; 3  X  1  3   
 
 3 3  3 3 2  2
2

2.(A) The current through ammeter


i  5A

3.(D) If n is the number of electrons per unit volume, then total number of electrons = nLA
Hence total mass of the electrons  nLAme
Total momentum of electrons  nLAme  vd

1  9.1  1031  16
 19
 91  10 12 kg m sec1
1.6  10
4.(B) According to Avogadro’s hypothesis
N m N m N
 ; n  NA  A  d (d = density)
NA M V VM M
6  10 23  5  103
Number of atoms per unit volume n 
60  103
 5  1028 / m3
As I  neA vd
I
Hence drift velocity vd 
neA
16
vd  28 19 6
 2  10 3 m / s
5  10  1.6  10  10
5.(B) When S 2 is open
Let potential gradient be x
L
x   6; xL  12V
2
When S 2 is closed
5L 60  5 60
x  ; xL   
12 10  r  12  (10  r )

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60
5  10  r  12  r  2
10  r
E
xL  12V ; x
L
E
  L  12V  E  12V
L
dq V
6.(B) I 
dt R
dq dR V dR
  ; dq  12V
dR dt R R
40
dR
q  12 V   12V (log e 40  log e 20) ;  120  log e 2
20
R

7.(B) Current through battery


80
I  10 amp  10 amp
8
Current through 6 ohm resistance will be 20/3 amp. And current through 12 ohm resistance will be
10/3 amp. Hence, current through wire AB will be 20/3 – 10/3 = 10/3 amp.

 10
8.(A)   10 ; r   5
i 2

 p cos  
9.(A)  using V  r ,    
 4  0 r 2 
r 3r  p cos 30 p cos 60
 net potential at  ,
 , 0  is 
2 2  4 0 r 2 4 0 r 3


3p

p cos 60

p  3 1 

2 4 0 r 2
 4 0 r 2
8 0 r 2

10.(D) The effective circuit is shown in figure


 RR 
RAB   1 4 
 R1  R4 

11.(D)

Ammeter I g  1mA

 In ammeter case shunt Resistance has min. value


In voltmeter case we connect in series higher value of Resistance.
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12.(A) R  R1  R2
(1   2 ) 11 2 2     2  2 
or     1 1 
A A A  1   2 
13.(C) If we connect a resistor in parallel, effective resistance of the circuit will decrease, hence increasing the
current.

V 2
14.(D)   2.2 V . Also i    0.5 A
R 4
Using V    ir
2  2.2  0.5r  r  0.4 

15.(A) R eq  14 

V 28
I   2A
Req 14
Current in 5   2 A
VC  28  5  2  18V
V A  VC  3  1  15V
VB  18  10  1  8V ; VA  VB  7V

16.(B) For earthed conductor [the inner shell], V = 0


1  q q '
Here V   where q is charge that would appear on inner shell as it is grounded
4 0  3r r 
 q   q / 3
Hence, the charge flown to earth  0  (q / 3)  q / 3

17.(B) Charge distribution is as shown :


Q1 Q1  Q2 Q1  Q2  Q3
1 =  2 = 3  2
= 2
= 2
4R 4  2 R  4   3R 
On solving we get ; Q1 : Q 2 : Q 3  1: 3 : 5

18.(D) Due to charge +q negative charge will be induced on the surface near to the external charge. Positive
charge will shift on the other side of the cube
Being metal conductor, the interior will remain charge free
  
19.(D) v  u  at
Considering along the line AC
v
0  v  g sin t  t 
g sin 
Now, consider along the line CB
v
v '  0  g cos   v cot 
g sin 

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 
20.(C) Since, g  v
v02
Radial acceleration ar  g   g where r is the radius of curvature
r
2gH
  g ( v  2 gH )  r  2H
r

SECTION - 2
21.(2) For particle ‘A’ For particle ‘B’
X A  3t 2  8t  10 YB  5  8t 3
 
V A  (8  6t ) iˆ VB  24t 2 ˆj
 
a A  6 iˆ aB  48tjˆ
At t  1sec
 
VA  (8  6t )iˆ  2iˆ & VB  24 ˆj
  
 VB / A  v A  vB  2iˆ  24 ˆj

 Speed of B w.r.t. A,  2 2  242  4  576  580


 v  290  580 ; v2

2h 5
22.(10) S  u   10  u 2   u  10 m / s
g 10


23.(8) Given,   2 rad s 1 , r  2m, t  s
2

Angular displacement,   t  2    rad
2
Linear velocity, v  r    2  2  4 ms 1

 change in velocity v  2v  2  4  8 ms 1

8 12 320
24.(16)  or , x   16 cm
x 40  x 20
25.(5) At equilibrium

T cos   mg & T sin   qE


mg  30 106 10  3 104 N
qE  2  108  20,000  4  104 N

 T  (3  104 )2  (4  10 4 )2  5  10 4 N

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CHEMISTRY

SECTION-1

1.(C)

2.(B)

3.(D)

Size of substituent decreases SN 2 reactivity.

4.(C) Rate of dehydration  stability of carbocation

5.(C)

Formation of P1 is free radical substitution reaction while formation of P2 is electrophilic substitution


reaction.

6.(C) Formation of P1 takes place by E2 mechanism and formation of P2 takes place by SN 1 mechanism.

7.(D) A is formed by SN 2 mechanism but B and C can be formed by E2 mechanism.

8.(C) Attack of electrophile will take place at position C due to meta directing nature of –NO 2 group and
COOH group.

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9.(C) SN 2 path is not possible due to steric hindrance

10.(A) Methyl and Methoxy are activating group for electrophilic reactions while Cl is deactivating for
electrophilic substitution reaction.

11.(D)

12.(B)

13.(C) The given conversion clearly shows that the reaction follows SN 2 path
Θ
Now, S H replaces IΘ which means X should be NaSH
Also, SN 2 path is favored in polar aprotic solvents
Hence, NaSH in acetone is the most appropriate combination.
14.(C) Activating group increases reactivity towards electrophilic substitution reaction.

15.(D)

16.(C) Conjugated product is more stable than Saytzeff product. Me3COK favours less substituted
conjugated product.

17.(C)

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h
18.(B) 
mv
1
with same ‘v’,  
m
   will be the shortest

19.(A) V 4   [Ar]3d1
n  3,   2 (d subshell)
m l can be any value from – 2 to +2
1 1
s can be  or
2 2

Z
20.(D) V  2.18  106 m/s
n
For 1st orbit of H
1
V  2.18  106 
1
V  2.18  106 m / s
For 2nd orbit of Li 2 
3
V2  2.18  106  m / s
2
V2 3 3
  V2  V
V 2 2
SECTION - 2

21.(8)

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22.(4) I. in an optically active molecule so it rotates plane polarized light

II.

III.

IV.

23.(2)

Number of acyclic C-atoms = 2

24.(4) Fe3 , Mn 2  , Fe 2  ,Cu 2   paramagnetic [refer electronic configuration]

25.(3) p z ,d zx ,d yz
These 3 will have one of the nodal planes as xy plane.

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MATHEMATICS
SECTION-1
1.(C) Since,  &  are the roots of the equation

5x 2  6 x  2  0
Then, 5 2  6  2  0, 5 2  6  2  0

5 2  6  2
5S6  6S5  5(6  6 )  6(5  5 )  (5 6  6 5 )  (56  65 )
  4 (5 2  6 )   4 (5 2  6)  2( 4  4 )  2 S4

2.(D) lim sin 1 (sec x )


x0
sec x  1, when x is near 0
sin 1 (sec x) is undefined
lim sin 1 (sec x) does not exist
x0

3.(B) lim [cos x ]  0 and lim [cos x ]  0


x 0 x 0

lim | x |[cos x ]  lim | x |0  1


x0 x0

1/  x  
4.(C) lim 1  a  x    x    
x 
1
lim 1 a  x   x   1 
e x   x   e  
a 

1
5.(C) Put x  ;
t
(1  2t )1/2  (1  3t )1/3
lim
t 0 t2
 11  2   11  2 
   1  (4t )     1  (9t ) 
1  t  2  2  3 3 
...........   1  t   ........... 
 2!   2! 
    1
lim     
 2 2
t 0 t

x
6.(D) Lt

 tan x   Lt

 cos x 1/ x
x 0 x 0
log e  
tan x   
0
Lt
1    e 1,
x  0   
e x

cos x 1
Lt
1/ x x 0  x
Lt  cos x  e  e0  1 as 0  cos x  1

x 0

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 
7.(B) a (sin x cos  cos x sin )  (sin x  cos x) 2  8
4 4
Let sin x  cos x  t where t    2, 2 

a
 t2  t  8  0 must have at least one root in   2, 2 
2  

Clearly product of roots = 8 so both roots can not lie in   2, 2 


 
For exactly one root to lie in   2, 2 
 
f  2  f   2   0  (2  a  8)(2  a  8)  0
 (a  10)(a  10)  0  | a |  10

8.(A) Lt f (n)  Lt f (n  1)  k (say)


n  n

1 9 
Lt f (n  1)  Lt  f (n )  
n  n  2  f ( n) 
1 9
k  k    k  3
2 k
Lt f ( n )  3
n 

 cos x  1    x   x
9.(B) tan 1    tan  tan      4  2
 1  sin x    4 2 


10.(B) cot 1 x  cot 1 y  cot 1 z 
2
  
    tan 1 x     tan 1 x  
2  2
  
tan  tan 1 x  0    
 tan tan 1 x   tan tan 1 x 
 x  y  z  xyz

 17   1    5    1  5  5
11.(C) cos 1  cos   cos  cos  2       cos  cos 6   6
 6     6   

12.(A) Given equation is x 2  2 ax  a 2  a  3  0


If roots are real, then D  0
 4a 2  4( a 2  a  3)  0   a  3  0
 a30  a 3
As roots are less than 3, hence f (3)  0

9  6 a  a 2  a  3  0  a 2  5a  6  0
 (a  2)(a  3)  0  either a  2 or a  3
Hence a  2 satisfy all.

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13.(A) L.H.S. and R.H.S. of the given equation are defined if


ax x b
0& 0
a b ab
 either a > x > b or a < x < b
     
14.(B)   cos 1 x   cos 1 x  and 2 cos 1 x   
2  6 2 6 3
 3
or cos 1 x  x 
6 2
2sin 6 x
15.(C)  0  sin 6 x  0  6 x  (0, )  (2,3)
1  sin x
   
 x   0,    ,  …(i)
 6 3 2
tan 2 x  2 2 tan x  1  0  (tan x  2) 2  1
 
 2  1  tan x  2  1   x  …(ii)
8 8
   3 
   3 cd   
  
From (i) and (ii) we set x   ,    ,

   3  8   6
 8 6   3 8 
 ab     
  
 8  6 

ax 2  bx  c ax  b  (c / x) a b
16.(C) lim  lim  lim  x  
x  dx  e x  d  (e / x ) x   d d
a
  if   is positive.
d 
a
  if   is negative.
d 
3
17.(D) f ( x)  (sin 2 x  cos2 x)3  3sin 2 x cos2 x(sin 2 x  cos 2 x)  1  sin 2 2 x
4
Range of sin 2 2x is [0,1]
1 
Range of f ( x ) is  ,1
4 

18.(D)  5  5  3
5  5  3
b
p5  5(  )  6  5  6 [ from x 2  x  1  0,      1]
a
2 2
p5  11& p2        1    1  3
p3  3  3  2  1  2  1
 2(1)  2  4
p2  p3  12 & p5  1  p5  p2  p3

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19.(C) 1  sin 1 x  1  x    sin1,sin1

20.(A) lim [5  2 x]  0
x 2

lim [| x  2 |  a 2  6a  9]  0  ( a  3) 2  1
x 2

SECTION - 2
  
21.(5)   sin 1 x  . Hence, from the question, sin 1 xi  for all i.
2 2 2
 xi  1 for all i

22.(1) Put x  cos y 0  y   | x |  1


Thus, required equation becomes.
2cos 1  cos y   sin 1 sin 2 y  (1)
 
So sin 1 (sin 2 y)  2 y   y
4 4
And 2cos 1(cos y)  2 y 0  y  
Equation 1 holds only when
   2 
y  0,  ; x ,1
 4  2 
Integral x = 1

  3 1 3 1  
23.(0) sin 1 cot  sin 1  cos 1  cos 1 
 2 2 2 2  
 
1
 sin {cot(15  30  45)}
 sin 1[cot 90]  0

24.(2) As one map is increasing, and another map is decreasing

25.(7) Put 3 x  t . Then 3x  0 as x   and 3x  3 as x  1


2
 1 3
x   ,1  t   0,3 g t   t 2  t  1   t   
 2 4
3
0t 3  g t   7
4
No of elements in the range of  g  t   is 7

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