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1.(B)
V 1
V ; 3 X 1 3
3 3 3 3 2 2
2
3.(D) If n is the number of electrons per unit volume, then total number of electrons = nLA
Hence total mass of the electrons nLAme
Total momentum of electrons nLAme vd
1 9.1 1031 16
19
91 10 12 kg m sec1
1.6 10
4.(B) According to Avogadro’s hypothesis
N m N m N
; n NA A d (d = density)
NA M V VM M
6 10 23 5 103
Number of atoms per unit volume n
60 103
5 1028 / m3
As I neA vd
I
Hence drift velocity vd
neA
16
vd 28 19 6
2 10 3 m / s
5 10 1.6 10 10
5.(B) When S 2 is open
Let potential gradient be x
L
x 6; xL 12V
2
When S 2 is closed
5L 60 5 60
x ; xL
12 10 r 12 (10 r )
60
5 10 r 12 r 2
10 r
E
xL 12V ; x
L
E
L 12V E 12V
L
dq V
6.(B) I
dt R
dq dR V dR
; dq 12V
dR dt R R
40
dR
q 12 V 12V (log e 40 log e 20) ; 120 log e 2
20
R
10
8.(A) 10 ; r 5
i 2
p cos
9.(A) using V r ,
4 0 r 2
r 3r p cos 30 p cos 60
net potential at ,
, 0 is
2 2 4 0 r 2 4 0 r 3
3p
p cos 60
p 3 1
2 4 0 r 2
4 0 r 2
8 0 r 2
11.(D)
Ammeter I g 1mA
12.(A) R R1 R2
(1 2 ) 11 2 2 2 2
or 1 1
A A A 1 2
13.(C) If we connect a resistor in parallel, effective resistance of the circuit will decrease, hence increasing the
current.
V 2
14.(D) 2.2 V . Also i 0.5 A
R 4
Using V ir
2 2.2 0.5r r 0.4
15.(A) R eq 14
V 28
I 2A
Req 14
Current in 5 2 A
VC 28 5 2 18V
V A VC 3 1 15V
VB 18 10 1 8V ; VA VB 7V
18.(D) Due to charge +q negative charge will be induced on the surface near to the external charge. Positive
charge will shift on the other side of the cube
Being metal conductor, the interior will remain charge free
19.(D) v u at
Considering along the line AC
v
0 v g sin t t
g sin
Now, consider along the line CB
v
v ' 0 g cos v cot
g sin
SECTION - 2
21.(2) For particle ‘A’ For particle ‘B’
X A 3t 2 8t 10 YB 5 8t 3
V A (8 6t ) iˆ VB 24t 2 ˆj
a A 6 iˆ aB 48tjˆ
At t 1sec
VA (8 6t )iˆ 2iˆ & VB 24 ˆj
VB / A v A vB 2iˆ 24 ˆj
2h 5
22.(10) S u 10 u 2 u 10 m / s
g 10
23.(8) Given, 2 rad s 1 , r 2m, t s
2
Angular displacement, t 2 rad
2
Linear velocity, v r 2 2 4 ms 1
change in velocity v 2v 2 4 8 ms 1
8 12 320
24.(16) or , x 16 cm
x 40 x 20
25.(5) At equilibrium
T (3 104 )2 (4 10 4 )2 5 10 4 N
CHEMISTRY
SECTION-1
1.(C)
2.(B)
3.(D)
5.(C)
6.(C) Formation of P1 takes place by E2 mechanism and formation of P2 takes place by SN 1 mechanism.
8.(C) Attack of electrophile will take place at position C due to meta directing nature of –NO 2 group and
COOH group.
10.(A) Methyl and Methoxy are activating group for electrophilic reactions while Cl is deactivating for
electrophilic substitution reaction.
11.(D)
12.(B)
13.(C) The given conversion clearly shows that the reaction follows SN 2 path
Θ
Now, S H replaces IΘ which means X should be NaSH
Also, SN 2 path is favored in polar aprotic solvents
Hence, NaSH in acetone is the most appropriate combination.
14.(C) Activating group increases reactivity towards electrophilic substitution reaction.
15.(D)
16.(C) Conjugated product is more stable than Saytzeff product. Me3COK favours less substituted
conjugated product.
17.(C)
h
18.(B)
mv
1
with same ‘v’,
m
will be the shortest
19.(A) V 4 [Ar]3d1
n 3, 2 (d subshell)
m l can be any value from – 2 to +2
1 1
s can be or
2 2
Z
20.(D) V 2.18 106 m/s
n
For 1st orbit of H
1
V 2.18 106
1
V 2.18 106 m / s
For 2nd orbit of Li 2
3
V2 2.18 106 m / s
2
V2 3 3
V2 V
V 2 2
SECTION - 2
21.(8)
II.
III.
IV.
23.(2)
25.(3) p z ,d zx ,d yz
These 3 will have one of the nodal planes as xy plane.
MATHEMATICS
SECTION-1
1.(C) Since, & are the roots of the equation
5x 2 6 x 2 0
Then, 5 2 6 2 0, 5 2 6 2 0
5 2 6 2
5S6 6S5 5(6 6 ) 6(5 5 ) (5 6 6 5 ) (56 65 )
4 (5 2 6 ) 4 (5 2 6) 2( 4 4 ) 2 S4
1/ x
4.(C) lim 1 a x x
x
1
lim 1 a x x 1
e x x e
a
1
5.(C) Put x ;
t
(1 2t )1/2 (1 3t )1/3
lim
t 0 t2
11 2 11 2
1 (4t ) 1 (9t )
1 t 2 2 3 3
........... 1 t ...........
2! 2!
1
lim
2 2
t 0 t
x
6.(D) Lt
tan x Lt
cos x 1/ x
x 0 x 0
log e
tan x
0
Lt
1 e 1,
x 0
e x
cos x 1
Lt
1/ x x 0 x
Lt cos x e e0 1 as 0 cos x 1
x 0
7.(B) a (sin x cos cos x sin ) (sin x cos x) 2 8
4 4
Let sin x cos x t where t 2, 2
a
t2 t 8 0 must have at least one root in 2, 2
2
1 9
Lt f (n 1) Lt f (n )
n n 2 f ( n)
1 9
k k k 3
2 k
Lt f ( n ) 3
n
cos x 1 x x
9.(B) tan 1 tan tan 4 2
1 sin x 4 2
10.(B) cot 1 x cot 1 y cot 1 z
2
tan 1 x tan 1 x
2 2
tan tan 1 x 0
tan tan 1 x tan tan 1 x
x y z xyz
17 1 5 1 5 5
11.(C) cos 1 cos cos cos 2 cos cos 6 6
6 6
9 6 a a 2 a 3 0 a 2 5a 6 0
(a 2)(a 3) 0 either a 2 or a 3
Hence a 2 satisfy all.
ax 2 bx c ax b (c / x) a b
16.(C) lim lim lim x
x dx e x d (e / x ) x d d
a
if is positive.
d
a
if is negative.
d
3
17.(D) f ( x) (sin 2 x cos2 x)3 3sin 2 x cos2 x(sin 2 x cos 2 x) 1 sin 2 2 x
4
Range of sin 2 2x is [0,1]
1
Range of f ( x ) is ,1
4
18.(D) 5 5 3
5 5 3
b
p5 5( ) 6 5 6 [ from x 2 x 1 0, 1]
a
2 2
p5 11& p2 1 1 3
p3 3 3 2 1 2 1
2(1) 2 4
p2 p3 12 & p5 1 p5 p2 p3
20.(A) lim [5 2 x] 0
x 2
lim [| x 2 | a 2 6a 9] 0 ( a 3) 2 1
x 2
SECTION - 2
21.(5) sin 1 x . Hence, from the question, sin 1 xi for all i.
2 2 2
xi 1 for all i
3 1 3 1
23.(0) sin 1 cot sin 1 cos 1 cos 1
2 2 2 2
1
sin {cot(15 30 45)}
sin 1[cot 90] 0