SRI CHAITANYA IIT ACADEMY, INDIA 09-12-2023_Sr.

Elite&Target_Jee Main_RPTM-16_Key & Sol's

Sri ChaitanyaIIT Academy.,India.

A.PT.S KARNATAKA TAMILNADU MAHARASTRA DELHI RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr. Elite & Target(C-120, C-IPL&IPL-IC) JEE-MAIN Date: 09-12-2023
Time: 09.30AM to 12.30PM RPTM-16 Max. Marks: 300
KEY SHEET
PHYSICS
1) 4 2) 4 3) 3 4) 4 5) 3
6) 1 7) 3 8) 2 9) 3 10) 2
11) 3 12) 2 13) 1 14) 2 15) 3
16) 2 17) 1 18) 1 19) 1 20) 4
21) 0 22) 5 23) 64 24) 200 25) 2
26) 5 27) 3 28) 25 29) 5 30) 5

CHEMISTRY
31) 1 32) 3 33) 3 34) 3 35) 2
36) 3 37) 2 38) 2 39) 2 40) 2
41) 3 42) 3 43) 2 44) 2 45) 3
46) 3 47) 2 48) 4 49) 2 50) 2
51) 4 52) 6 53) 6 54) 0 55) 20
56) 6 57) 3 58) 3 59) 3 60) 4

MATHEMATICS
61) 4 62) 1 63) 4 64) 4 65) 4
66) 3 67) 2 68) 2 69) 2 70) 2
71) 2 72) 1 73) 1 74) 2 75) 2
76) 2 77) 3 78) 3 79) 2 80) 2
81) 2 82) 2 83) 1 84) 3 85) 9
86) 3 87) 9 88) 785 89) 4 90) 3

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 SRI CHAITANYA IIT ACADEMY, INDIA 09-12-2023_Sr.Elite&Target_Jee Main_RPTM-16_Key & Sol's

SOLUTIONS
PHYSICS
1. Conceptual.
2. Conceptual.
3. Conceptual.
4. Conceptual.
5. Conceptual.
6. Truth table for given circuit is

A B Y1 Y2 Y3 Y
0 0 1 1 1 0
1 0 1 1 0 1
0 1 1 1 1 0
1 1 0 1 1 0
This is the same output produced by A.B gate or

So, given circuit is equivalent to Boolean expression A.B .

7. Because N  side is more positive as compared to P  side.
8. For the positive half cycle of input the resulting network is shown below

1 1
 V0 max  Vi max   10  5V
2 2
9. Conceptual.
10. Conceptual.
1
11. Wo 
LC

L  2 L, C  18C

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 SRI CHAITANYA IIT ACADEMY, INDIA 09-12-2023_Sr.Elite&Target_Jee Main_RPTM-16_Key & Sol's
1 1 1
W01   
2 L  18C 36 LC 6 LC

1
10  
6

12. Conceptual

13. Conceptual.

WL
14. tan  
R
A


B R C

1 1
Power factor= 
1  tan 2   L 
2
1  
 R 

R
cos  
R 2   2 L2


Vm 2Vm
15. Vav 
  sin  .d  
0


2 Vm2 2 Vm2
Veff 
 
sin  d 
2
0

V
Veff  m
2

16. Conceptual

17. Conceptual

1 1
18. XC  
2 fc 2  3.14  200  0.4  10 6
1
XC   106  0.001990  106
502.4

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 SRI CHAITANYA IIT ACADEMY, INDIA 09-12-2023_Sr.Elite&Target_Jee Main_RPTM-16_Key & Sol's
X C  1990
19. Conceptual

v v 4
20. I  
 
z 2 2
R  L 2 2
 4 2  1000 2  3  103

4 4 4 4
I     0.8 A
16  106  9  106 16  9 25 5

21. A  1, B  1 Y  A.B  B. A
Y  1.0  1.0  0  0  0
V 5
22. i  3  5  103 A  5mA
R 10
23. Conceptual.
24. Conceptual.
25. Given X L  X C  5 this is the condition of resonance So VL  VC , so net voltage across
L and C combination will be zero
26. As current is in phase with emf, so the circuit is in resonance, and frequency of
source=frequency of resonance
1 1
   0.5  103  5  102 Hz
2 LC 2    0.5  10  200  10
 3  6

27. Given, Inductance, L  30 mH Resistance, R  1

Angular frequency,   300rad / s We know that in L-C-R circuit,
X  XL
tan   C
R
Where,   phase angle  450
1
X C  capacitive reactance 
C
X L  inductive reactance   L
XC  X L
 tan 450   X C  X L  R  tan 450  1
R
1 1
  L  R   300  30  10 3  1
C C
1 1 1 1 1 1
  10  C   C  C   C   103 F   103
C 10 10 10  300 3 x
Hence, x  3

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 SRI CHAITANYA IIT ACADEMY, INDIA 09-12-2023_Sr.Elite&Target_Jee Main_RPTM-16_Key & Sol's
V0 V0
28. I0  
Z R2   X L  X C 
2

2500 2500 2500

I0   
80 2  100  40 2 80 2   60 2 100

I 0  25 A
R2 5
z  R   X L  XC 
2 2 2
29.  R   .R
4 2
VR2  VL2  100 
2
30.
130  VR2  VL  VC 
2

16900  VR2  1400

VR  2500  50V
VR 50 5
cos    
V 130 13

CHEMISTRY
31. d3 type of ions- number of unpaired electrons in octahedral complexes is same for weak
or strong field ligand and in the free ion.

32.  K 4  Fe(CN )6   K 2 SO4

FeSO4  6 KCN 

CN- is a strong field ligand . So, no unpaired electrons present.

1 1
33. Ks    1  1044
Kd 1  10  44

Which complex has the highest stability constant that complex is most stable.

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4
34. t   o
9

4
t   18000
9

t  8000

35. Organometallic Compounds are chemical compounds which contain at least one bond
between a metallic element and a carbon atom belonging to an organic molecule.

All carbonyls are and bonded in nature because the metal - carbon bond in metal
carbonyls possesses both σ and π character. The M−C bond is formed by the donation of
ion pair of electrons on the carbonyl carbon into a vacant orbital of the metal.

36. Cisplatin, cisplatinum or cis-diamminedichloroplatinum(II) (CDDP) is a platinum-based

chemotherapy drug used to treat various types of cancers, including sarcomas, some
carcinomas (e.g. small cell lung cancer, and ovarian cancer), lymphomas and germ cell
tumors.

37. II and III are geometrical isomers

38.

39. The larger the ligand strength, larger the splitting of d orbitals. Hence, d-d transition has
larger energy or lesser wavelength. Since the energy of absorbed light follows the order

Blue > Green > Yellow > Red

Thus, the ligand strength will follow the order. L1  L3  L2  L4

40. All pairs of isomers and types of isomerism are correctly matched.

41. Al  OH 3 is soluble in excess of NaOH so, to separate Fe  OH 3 and

Al  OH 3 , aqNaOH solution is added. Al  OH 3 will dissolve in it. Where as Fe  OH 3
will remain insoluble.

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 SRI CHAITANYA IIT ACADEMY, INDIA 09-12-2023_Sr.Elite&Target_Jee Main_RPTM-16_Key & Sol's
42. Chloride liberates deep red vapours of chromyl chloride  CrO2Cl2  when heated with
solid K 2Cr2O7 and con. H 2 SO4

K 2Cr2O7  4 NaCl  6 H 2 SO4 

 2CrO2Cl2  2 KHSO4  4 NaHSO4

But Chlorine is not evolved when chloride is treated with conc. H2SO4.

2 NaCl  H 2 SO4  2HCl  Na2 SO4

43. BaSO4 is formed as insoluble precipitate but MgSO4 is water soluble

44. NH 4Cl  aq   NaOH  aq   NH 3  aq   H 2O l   NaCl  aq 

45. 2 AgNO3  H 2 SO4 

 Ag 2 SO4  2 NO2  H 2O  1 O2
2
Brown vapours

 Cu  NO3 2  2 Ag
2 AgNO3  Cu 
blue

AgNO3  HCl  AgCl  HNO3

46. group- II reagent is HCl  H 2S

Cd2+ (from group II of analytical chemistry) gives yellow ppt. of CdS in slightly acidic
medium. Ni2+,Zn2+ and Mn2+ (from group IV of analytical chemistry) gives ppt. only in
alkaline medium.

47. Fe3 cation gives blood red colour with SCN 1 and blue colour with K 4  Fe  CN 6 

Fe3 ( aq ) SCN  


 [ FeSCN ]2 
pale yellow Blood red

Fe3 ( aq )  K 4 [ Fe(CN )6 ] 
 Fe4 [ Fe(CN )6 ]3
pale yellow Blue

Cl  anion undergoes chromyl chloride test. Hence, the salt ' X ' is FeCl3

48. In V group. Barium ions are precipitated as their carbonates by adding ammonium
carbonate to their solution.

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 SRI CHAITANYA IIT ACADEMY, INDIA 09-12-2023_Sr.Elite&Target_Jee Main_RPTM-16_Key & Sol's
49.

SO 2 
3  BaSO   HCl
50. BaCl2  3  SO2 
white ppt characteristic smell

SO32  ion is present in the inorganic salt.

51. SCN  is a weak ligand while CN  is a strong ligand

Fe 3   Ar  3d 5

For weak ligand, t2g 3eg 2 i.e., n=5,   5  5  2   35BM

For strong ligand, t25eg o i.e., n  1 ,   11  2   3BM

Difference  35  3  4

2 AgNO
52. Cr  H 2O  Cl  Cl2 
 5 
 Cr  H 2O 5 Cl   2Cl  
3  2 AgCl

Millimoles required for complete ppt ion  M Vml  2  30  0.01 2  0.6

0.1 V  0.6  6mL

53. M ( aa ) 2 b2 , Ma4b2 , M  aa 2 bc, Ma4bc are exhibit geometrical isomerism.

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2
54.  Ru  H 2O   o  P
 6

Ru  44  :  kr  4d 7 5s1

Ru 2 5s 0 4d 6 t26g eg 0

number of unpaired e s  n  0,   0 B.M

55.

L L L L
L
M L M
L L
L
L

Sum of all L  M  L angles in two complexes is  2  8  1  6  3  20

56. PbS, CuS, HgS, Ag2S, NiS and CoS are black coloured.

57. All chlorides are soluble except PbCl2, AgCl.HgCl2

58. The sulfides of As3+, As5+, Sb3+, Sb5+, Sn2+, Sn4+are soluble in yellow ammonium sulfide
where they form polysulphide complexes.

59. Mg 2 , Be 2 , Zn 2 do not give flame color.

2 2 3
60.  NiCl4 2 ,  Fe  H 2O 6  , Cu  NH 3 4  ,  Fe  CN 6 

MATHEMATICS
1 2  3  4  5  6 7
61. Mean = 
6 2
2 49 12  22  32  42  52  62
c  
4 6
91 49 35
2   
6 4 12

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3  4  7  9  9  10  14 56
62. Mean  k    8
7 7
The deviations about mean are given by 5, 4, 1, 1, 1, 2, 6
Sum = 20
1
Mean deviation from mean   20   2.857
7
3 1
63. (d) We have, sin1  sin 2  2cos ,sin  0
2 2

 sin1  sin 2
Similarly sin1  sin 3   2cos 2sin1  0
sin1  sin 3
From Eqs, (i) and (ii), we get sin 3  sin1  sin 2
23 5
64. Median = 
2 2
5 5 5 5 3 1 1 3
1  2   3   4    
2 2 2 2 2 2 2 2
M.D about median =  1
3 4
2
65. cos ec 2 x  25sec2 x  26  cot 2 x  25tan 2 x  26  10   cot x  5tan x   36
 2 
66. S  cos 2  cos2  ......  cos 2  n  1
n n n
1 2 4 6 
1  cos  1  cos  1  cos  ...  1  cos 2  n  1 
2 n n n n
n 1
1 2 k  1 1
  n  1   cos    n  1  1   n  2 
2 n  2 2
 k 1 
 5 7
67. a  sin sin sin  sin100 sin 500 sin 700
18 18 18
1 1
  2sin 700 sin100  sin 500  cos600  cos800  sin 500
2  2 
1
4
1
4
  1
4
1
 sin500  2cos800 sin 500  sin 500  sin1300  sin 300
4
 
1 1 1 1 1
 sin 500  sin 500  . 
4 4 4 2 8
y  2  x   2 and y  3 x  2  2  x   2  3 x  2  3 x   3 2   x   8

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1
 a
 x
68. Given series
 2 2   2 4   6 6   20 20 
  sin  cos    sin  cos    sin  cos   ....   sin  cos 
 11 11   11 11   11 11   11 11 
 2 4 20   2 4 20 
  sin  sin  .....  sin    cos  cos  ....  cos 
 11 11 11   11 11 11 
10 10  
sin  .sin cos  .sin sin    
11  11  0   11 
 1
  
sin sin sin
11 11 11
69. Clearly, 1  sin 2 1100 .sec1100  cos1100 sec1100   cos1100 sec1100  1

70. a  cos  2012   1

b  sec  2013   1
c  tan  2014   0
b  c  a
71.  cos 3 A  cos3 B  cos 3C  1  cos3 A  cos3B  cos3C  1  0
 cos3 A  cos3B  cos3C  cos3  0
 3 A  3 B   3 A  3B   3  3C   3  3C 
 2cos   cos    2cos   cos  0
 2   2   2   2 
 3  3C    3 A  3B   3  3C  
 2cos   cos    cos    0
 2   2   2 
 3 3C   3  3C  3 A  3B   3  3C  3 A  3B 
 2cos    .2cos   cos  0
 2 2   4   4 
 3 3C   3 3B   3 3 A 
 2cos    .2cos    .cos   0
 2 2   2 2   2 2 
 3 A   3B   3C   3 A   3B   3C 
  4sin   sin   sin    0  sin   sin   sin  0
 2   2   2   2   2   2 
3A 3B 3C
   or   or 
2 2 2
2 2 2
 A or B  or C 
3 3 3

72. Let
 cos    sin    k , So that cos  ak and sin   bk . Then
a b

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 
a cos 2  b sin 2  a 1  2sin 2   2b sin  cos  a  2ab2k 2  2b.bk .ak

 a  2ab2k 2  2ab 2k 2  a
73. 8  x 2  x   4  x   13  12  sin x 
 
LHS is always even and RHS is always odd. Hence, no solution
74. Conceptual.
75. Conceptual.
76. Consider
1   k  1  k  
5  5
1
  tan      tan  k  1  tan 1 k
k 1  1  k  k  1   k 1
Now, T1  tan 1  2   tan 1 1 ; T2  tan 1  3   tan 1  2  and so on
5
 cot 1  k 2  k  1  tan 1  6   tan 1 1  tan 1  7   cot 1  5 
5 7
Hence,
k 1
 7
 5cot  cot 1   7
 5

1 2 x
4
x6  
1 4 x
8
x12  
77. sin  x   .......   cos  x   ......  
 3 9   3 9  2
  
x y

x2 x4 3 3x 2
 X Y      9  3x4  9 x 2  3x4  x 2  1
x2 x4 3  x2 3  x4
1 1
3 3
Thus, x  0, 1 or -1
Hence, number of values is equal to 3.
78. sin 1  sin 5   x 2  4 x
 sin 1  sin(5  2   x 2  4 x
 5  2  x 2  4 x
2
 9  2x   x  2
2
  x  2   9  2
  9  2  x  2  9  2
 2  9  2  x  2  9  2
79. The graphs of y  sin x and y  x is

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sin x  x Has only one solution x  0 , but statement II is not the only explanation of
Statement I.
1 sin  cos 
80. In statement, 1 cos  sin   0
1 sin   cos 
 Either sin   0 or tan   1     / 4  as 0     
And Statement II,  sin x  2cos x 
1 cos x cos 
1 sin x cos x  0
1 cos x sin x
2
  sin x  2cos x  cos x  sin x   0
2
  sin x  2cos x  cos x  sin x   0
Which does not hold for any value of x as  / 4  x   / 4

81. tan  cos   tan  / 2   sin     cos   n   / 2   sin   n  I 

 2n  1
   sin   cos    2n  1  sin   cos 
2 2
2n  1
 cos  / 4    
2 2
2n  1
Since 1  cos  / 4     1   1  1
2 2

 n  0 or -1 is an integer  cos  / 4      1 / 2 2 
 
 8cos 2  / 4     1  16cos 2      2
4 
82. Conceptual.

83. Conceptual.

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84.
tan 460  tan140
1  tan 460 tan140

 tan 460  140  3 
tan 740  tan140
1  tan 740 tan140

 tan 740  140 
 3
tan 740  tan 460
1  tan 740 tan 460

 tan 740  460 
 3
From Eqs. (i), (ii) and (iii)
tan 460  tan140
tan 460 tan140  1 
3
0 tan 740  tan140
0
tan 74 tan14  1
3
tan 740  tan 460
tan 740 tan140  1 
 3
 tan 460 tan140  tan 740 tan140  tan 740 tan 460  3
3 3
85.  24sin x  2  24cos x  24  sin x  2  cos x
 24sin 3 x  cos 2 x  1  sin 2 x
Put sin x  t , we get

 
24t 3  t 2  1  0   3t  1 8t 2  3t  1  0 .  t 

1
3
0
1 1
 t  i.e.sin x   cos ecx  3  cos ec 2 x  9
3 3
86. We have, 6cot   cot      cot    
6cos sin 2 6cos 2sin  cos
   
sin  sin     sin     sin  sin 2   sin 2 
2sin 2 
 2 2
 3 sin   sin   sin   2 2 2
Or 2sin   3sin  
2
sin 
3

87. 2a  4sin 2 x  cos ec 2 x  sin 2 y  4cos ec 2 y

2 2
  2sin x  cos ecx   4   sin y  cos ec y   3cos ec 2 y  2

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2 2
 6   2sin x  cos ec x    sin y  cos ec y   3cos ec 2 y
 or Minimum value of 2a  6  3  9,
When 2sin x  cos ec x and sin y  cos ecy
88.   
Here, cos 2900  cos 2700  200  sin 200 and sin 2500  sin 2700  200   cos 200 
1 1
The given expression   
sin 200 3 cos1200
1 cos 600
  
sin 200 sin 600 cos 200


sin 600 cos 200  cos 600 sin 200
 

sin 600  200  
sin 200 cos 200 sin 600 sin 400 3

2 2
4 16
  2 
3 3
256 16
Then, 9 4  81 2  97  9   81   97  256  432  97  785
9 3
 sin 2 x  sin 2 x 1 1
89. Given, log10    1 Or  Or sin 2 x 
 2  2 10 5
 n
log10  
Also log10  sin x  cos x    10  Or log sin x  cos x 2  log  n 
10   10  
2  10 
n 1 n 6 n n
Or 1  sin 2 x  Or 1   or  Or  4
10 5 10 5 10 3
90. tan x  2t , tan y  3t , tan z  5t
Also x  y  z  
1
 tan x  tan y  tan z  tan x tan y tan z  t 2 
3
 tan 2 x  tan 2 y  tan 2 z  t 2  4  9  25   38t 2 ,

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