ISR_*CO-SC(MODEL-B) Date: 07-04-24

Time: 3 Hrs WAT-40 Max. Marks: 186

KEY SHEET
MATHEMATICS
MATHS
1 A 2 C 3 C 4 D 5 ABCD

6 AD 7 AC 8 AB 9 ABC 10 AC

11 ABC 12 ABCD 13 7.9372 14 0.50 15 0.125

16 3.20 17 0.25 18 1.50

PHYSICS
6 ABCD
1 D 2 B 3 B 4 C 5 ACD

12 ABC
7 CD 8 AD 9 ACD 10 AD 11 AC

18 7
13 1 14 3 15 0.05 16 5 17 5

CHEMISTRY
37 C 38 D 39 C 40 B 41 ABC

42 BCD 43 C 44 AD 45 ABCD 46 D

47 B 48 ABD 49 60 50 2 51 48

52 50 53 5 54 2
Narayana IIT Academy 04-04-24_ISR.IIT_*CO SC(MODEL-B)_JEE-ADV_WAT-40_KEY&SOL
SOLUTIONS
MATHS
1. Let the centres of the three circles be A, B and C respectively and left their radii R1 , R2 and R3
respectively

2. Any point on the given parabola is  t 2 , 2t 

3 We know that two diameters y  m1 x ,

4. Equation of the tangent for the curve y 2  8 x is y  mx  alm

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 y  mx  2lm  a  2 
Since the above equation is also tangent on curve xy=-1, thus solving together is quadratic obtained
 2
has equal roots x  mx    1
 m

2 2
5. The circle are S1 :  x  1   y  2   52

6.

7.

8.

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9.

10

11.

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12.

13.

14.

15.

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16.

17.

18.

PHYSICS
 RT
19. c
M
Both the gases are diatomic, so their  is some. So the speeds are dependent on
temperature and molecular weight.
20. At time t
l   l  t    4
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C
 Fundamental frequency f 0 
4l
C
f0 
4  l  t 
df C CV
   V  
dt 4  l  t 2 4l 2
21. Let us consider a small element of mass ‘dm’
 dm    dx 
 Total energy of element is
1
dE   dm  2 A2
2
1 2 2
 A  dx 
2
The rate at which energy is supplied is given by
dE 1 2 2
P   A  dx 
dt 2
1
 P  2 A 2 v
2
 RT k k
22. f   , fA 
2L M L M L 2
2k 3k
fB  , fC
L 32 2l 28
3k
fD  ,  fC f D  11 28
L 44
23. y  f  x  vt 
Particle velocity.
dy
vp    vf   x  vt 
dt
To find velocity of wave
d dx
 x  vt   0 v
dt dt
24. As the motions of particles are simple harmonic, amplitude = 2cm.
 (Angular frequency) = 3 rad/sec.
As the phase difference of particles separated by 1cm is  8
8
   2  16cm


Hence, wave velocity     24 cm s
2
 2 
y   2  sin   24t  x   cm
 16 
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25. y  a0 sin  kx  sin  t   
kL kL  1
 n and   n  
3 2  2
3
 n  1, k 
L
 3 5L 
Also, a  a0 sin     a0
 L 6 

26. When reservoir is lowered by x, let the level of water fall by y

ga
27. acceleration of wave-1 w.r.t string   g 
2
ga
acceleration of wave-2w.r.t string   g 
2
Time for same horizontal level:

t
2 g
arel  0
1  
Height raised by the lift  g  
2 2g 4
28. ABC has negative slope hence, represent compression, while CDE has positive slope
hence represents rarefaction.
V 5V 15
29. f  5     m
4 4 f 16
The open end is position of node of pressure. So it means that there is no pressure
variation at these points.
30.

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From v  f 
 340  340      1m

For first resonance, l1 
4
 l1  25cm , so length of water column is 95cm.
3
For 2nd resonance, l2   75cm so length of water column is (120- 75) cm = 45cm
4
3rd resonance won’t be established as for that length of air column required is,
5
l  125cm > length of tube
4

Separation between consecutive nodes is,  50cm
2
1
31. P   2 A2 sV
2
 1 f  2
since 1  , 1  1 
2 2 f 2 2 1
since P1  P2 , 1 A1  2 A2
pressure amplitude, P0  B0 Ak
 A1  k1 
 P0 1  P0 2    
 A2  k2 
 A     1  2 
  1  2       1
 A2  1   2  1 
32. y = 2A sin kx cos t
P  2 BAk cos kx cos t
P A 1 2
  ;n  3
P B  3
cos
2n
 2  3 1
33. Let l be the end correction.  
2
Given that, fundamental tone for a length 0.1m = first overtone for the length 0.35m
34. The string has same shape in figures first and last. The distance travelled by the pulse
(between these two situations) = 2  0.3  0.6m

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T 1.2
v  2
 6ms 1
 10 0.3
0.6 1
 t   0.1  s
6 25
 k=5
35. A  0.5  10 m, f  100Hz , T  100 N , v  100ms 1 (given)
3

T 100
 2 0.01kgm 1
v 100  100
1 1 2 2

Now, P   2 A2v   0.01 2  100  0.5  103  100
2 2

0.049W   0.007   7W
  7
0.06 1
36.  AB  1  kgm 1  kgm 1
4.8 80
0.2 20 10
 BC   2  kgm 1  kgm 1  kgm 1
2.56 256 128
T 80
v1    80ms 1
1 1 80
.8 4.8
 t1    0.06s
v1 80
T 80
v2    128  8  2  64  32ms 1
2 10
2.56
 t2   0.08s
32
 Required time is t  t1  t2  0.06  0.08  0.14s
14 2
or t  7
100 100
  7

CHEMISTRY
37. (C)
G   ve
38. (D)

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1
Flocculation value 
Charge an ion
39. (C)
Adsorption isotherm
40. (B)
Number of N 2 molecules adsorbed per gram of silica gel
6.023 1023 1.30
=  3.48  1019
22400
Area of cross-section of N 2 molecule
= 0.16 nm 2 = 1.6 1019 m 2
 Surface area covered per gram of silica gel
= 1.6 1019  3.48 1019  5.568 m 2 ,
41. (ABC)
Lyophobic colloids
42. (BCD)
Brownian motion and Tyndall effect shown by colloids
43. (C)
Above the CMC and above the Kraft temperature.
44. (AD)
On a body diagonal, two corner Cl  ions and one Na  ion in OV (at body center) are present
45. (ABCD)
Non-stoichiometric NaCl has F-centres due to anion vacancy defect
46. (D)
47. (B)
For per oxide ion in unit cell
Number of tetrahedral voids per ion in lattice = 2
Number of divalent cation (A)
Number of octahedral voids per ion in lattice = 1
Number of trivalent cations (B)
Formula = A1/ 4 B1/ 2 O  AB2 O4 .
48. (ABD)
CaCl2 absorb H2O
49. (60)
Number of detergent molecules present in one litre solution
= 103  6 1023  6 1020
i.e., 1000 ml  6 1020 detergent molecule

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1mm  ?3
= 6 1014

No. of colloidal particles per mm3  1013

No. of molecules per colloidal particles
6 1014
=  60 .
1013
50. (2)
Weight of wood charcoal = 0.6 g
Mass of CH3COOH adsorbed
M1V1  M 2 V2
=  60
1000
0.2  200  0.1 200
=  60 = 1.2 g
1000
Mass of acetic acid adsorbed per gram of carbon
1.2
= 2
0.6
51. (48)
From Freundlich adsorption isotherm equation,
x 1
log  log K  log p
m n

x
When we plot log vs log p, we get a straight line of
m
1 1
(i) slope = 2  n
n 2
(ii) intercept = log K = 0.4771
 log K = log 3  K = 3
x
So,  Kp1/ n  3  42  48 ( p = 4 atm)
m
52. (50)
20 mL of 0.5 M NaCl contains = 20  0.5  10 m mol

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200 mL of As2S3 required NaCl for coagulation = 10 m mol

Therefore, 1000 mL of As2S3 required NaCl for coagulation

1000
= 10   50 m mol .
200
53. (5)
Colloidal Dispersed Dispersion
system phase medium
Gem stone Solid Solid
Paints Solid Liquid
Smoke Solid Gas
Cheese Liquid Solid
Milk Liquid Liquid
Hair cream Liquid Liquid
Insecticide Liquid Gas
sprays
Froth Gas Liquid
Soap lather Gas Liquid
So, among the given colloidal systems, 5 have liquid dispersion medium
54. (2)
Statements given in C and E are characteristics of physisorption
It is non-specific in nature
Its enthalpy of adsorption is low
In this, extent of adsorption decreases with increase in temperature
It results into multimolecular layer
In physisorption, no activation energy in needed

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