Sec: SR.

IIT_*CO-SC GTA-2(P1) Date: 24-04-22

Time: 3HRS 2019_P1 Max. Marks: 186
KEY SHEET
PHYSICS
1 C 2 B 3 D 4 A 5 ABD
6 AD 7 AD 8 BD 9 ABCD 10 AD
11 AB 12 ACD 13 9 14 6.82 15 1.10
16 3 17 0.6 18 5

CHEMISTRY
19 C 20 A 21 B 22 A 23 ABC

24 ABC 25 BCD 26 C 27 AB 28 AD

29 ABCD 30 ABD 31 6 32 2 33 9
12 to
34 35 6 36 5
13

MATHEMATICS
37 C 38 C 39 C 40 B 41 BC

42 ABD 43 BC 44 AB 45 BD 46 ABC
0.70 2.71
47 BD 48 AD 49 83 50 TO 51 TO
0.71 2.72
52 2 53 5 54 –3
Narayana IIT Academy 24-04-22_SR.IIT_*CO-SC_JEE-ADV_GTA-2(P1)_KEY&SOL
SOLUTIONS
PHYSICS
1.

2. B due to entire long solenoid   0 n

 n
B due to half solenoid  0
2
 M  M2 R
3. Td    Rd   2  R  T 
 2R  2
M R 2 2
L  
 yA  YA
 
 2R 
A 2h R 2 2  H  R 2 H
4. t  2   
a g r g  2  r2 g
5. As the photoelectrons get ejected, the conductor acquires positive potential and gradually increases
to stopping potential.
6.

7. Both move together

20  0.25  5 10
 a sys   1.5m / s 2
5
 f block  1.5N

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8.

9.

10.

11.

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12.

13.

14.

15.

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Narayana IIT Academy 24-04-22_SR.IIT_*CO-SC_JEE-ADV_GTA-2(P1)_KEY&SOL
16. T = 2T
T0
aA  aB  g
17.

18.

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Narayana IIT Academy 24-04-22_SR.IIT_*CO-SC_JEE-ADV_GTA-2(P1)_KEY&SOL
CHEMISTRY
+4
18. Pb is oxidising and I- is reducing agent.
19. Trans 1,2-dimethylcyclohexane.
21. At equilibrium
R1  OH  CH 3COOH  CH 3COOR1  H 2O  KC1 
1 x 1 x  y x  x y 
R2  OH  CH 3COOH  CH 3COOR2  H 2O  KC2 
1 y 1 x  y y  x y 
x 3
 x  y  0.8
y 2
3y
2x  3y  y  0.8
2
y  0.32
x  0.48
x. x  y  0.48  0.8
K C1    3.69
1  x 1  x  y  0.52  0.2
3
22. Hydrolysis of PO 4 will take place
 k 
PO 43  H 2O  HPO 42  OH   k h1  w 
 x  y z 
 c x   xy  k3 
 k 
HPO 42  H 2O  H 2 PO 4  OH   k h 2  w 
 x  y z 
 xy  yz   k2 
 k 
HPO 4  H 2O  H 3PO 4  OH   k h3  w 
 x  y z 
 yz  z  k1 
 OH    x  y  z
 OH    x
x  y  z

k h1 
 x  y  z  x  y 
c  x 
kw x.x.

k3 c  x 
x2
2.2  102 
 0.1  x 
on solving x  3.73  102 molar
23. The given ionic radius order is correct.
24. Conceptual
25. No vacant orbitals for boron.
26. Conceptual
27. Acylsubstitution followed by decomposition of azide into isocyanate.
28. Cu and Pb
29. Conceptual

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Narayana IIT Academy 24-04-22_SR.IIT_*CO-SC_JEE-ADV_GTA-2(P1)_KEY&SOL
1 2
30. A) mv  q.V
2
v  4  106 m/sec
2 KZe 2
B) v
nh
v  4.38  106 m/sec
h
C) 
mv
v  1.09  106 m/sec
hc  c
D)  K.E max  
 0
1
 K.E max  mv 2
2
v  1.55  106 m/sec
31. Octahedral structure
32. Two lone pairs and four bond pairs.
33. Conceptual
RTf2 M
34. Kf 
H fusion
8.314   273  18
2

Kf 
1000  6  103
 K f  1.86K. Kg mol-1
Now Tf  K f  m
T  273  271
m  f   1.07 moles/Kg
Kf 1.86
moles of solutes
But m 
weight of solvent (in Kg)
 0.9  18  2
moles of solute  1.07     1.74  10
 1000 
760  700
Also X solute   0.079
760
mole of solute
X solute 
total moles
1.74  102
 Total moles   0.22
0.079
Moles of solvent  H 2 O   0.2026
 Mass of ice separated out   0.9  0.2026   18  12.55 gm
1 1 8RT P
35. Z  u aV  N*    Constant
4 4 M kT
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Narayana IIT Academy 24-04-22_SR.IIT_*CO-SC_JEE-ADV_GTA-2(P1)_KEY&SOL
P
or,  Constant  P  V 1  Constant
T
R 5 R
 C m  C V1m   R  3R
1 x 2 1   1
 6 cal/K mol
36. 2NH 3  g   N 2  g   3H 2  g 
3 0 0-initially
3  2x  x 3x -after time  t 
1 d  NH 3 
Rate of Reaction    0.1
2 dt
 d  NH 3 
  0.2  k
dt
For Zero Order Reaction P  P 0  Kt
3  2 x  3  0.2 10
3  2x  1
x 1
Ptotal   3  2x 
 5 atm

MATHS
37. Matrix A can be formed in 6 ways
Matrix A can be formed in 8 ways
So, A and B both can be formed in 48 ways
In only 4 of these combination A  B possible.
4 1
 Required probability  
48 12
38. 2 xy 4 e y dx  x 2 y 4 e y dy  2 xy 3d  x 2 y 2 dy  ydx  3dy  0
2 xy 3dx  x 2 y 2 dy y 3dx  3xy 2 dy

Divide whole equation with y 4 , d x 2 e y   y4

y6
0

 x2   x 
d  x 2e y   d    d  3   0
 y y 
41.

Area of parallelogram ACBD is least

= Area of ABC is least
In ABC , h  2 when base is AC

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Ac = 2  cot   tan   is least when   45 0

42. Conceptual
43. Conceptual
44. Conceptual
45. a) Lt g  f  x  Lt g  x  does not exists
x1 x0
b) Lt g  f  g  x   Lt g  f  x   Lt g  x   0
 x 0 x 2
x
2
f  g  x 
c) Lt 0
x 2 f  x  2
g 2  x 1  cos x 1
d) Lt 2
 Lt 
x 0  2  x  2 x O x2 2
1
 2
3
46. tan   2 
1 2 4

1 20
 PC  PB sin   2  BD 
2 3
Which rule APB
2
AB  58
3
dPB which rule
2
BC  10
3
47. Conceptual
49.  ,  2 are the roots of the equation  2  px  1  0
 2  1   i 
Again  2 ,  are the roots of the equation  2  px  1  0
 2   8   ii 
From (i) and (ii)
 3  3  8    2   iii 
1
From (i) and (iii) 
2
From (ii) and (iii)  4
1 17
Now p     2  4  
4 4
1 33
q   2    16  
2 2
r
 is A.M of p and q
8
r pq  17 33 
  r  4     83
8 2  4 2 

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
50.  a.x  0   i 
   
 
Again x  b x  a   ii 
      
 
 x a  b a  x a  a
       
   
 x  a  b  a  x.a a  a.a .x
   
 x  b  b  a  x [from (ii) and (i)
   
 2x  b  b  a
 1
x 
2
51. Conceptual
z2  z  1
52. z
z2  z  1
z2  1 z  1
   z  1
2 z 2 z  1 
1
 z  must be purely real
z
 e i  
 In  rei   0
 r 
sin 
 r sin    0    0 as r  1
r
x2  x 1
 2  x  for x  0 1 solution
x  x 1
for x < 0 no solution
sin 60 sin 60
53. tan12  tan 48  tan 84  tan120  tan156    tan120
cos12 cos 48 cos 24 cos 84
2sin 60 2sin 60
   35 3
cos 60  cos 36 cos108  cos 60
 x
1 cos 2sin 2 
 4
54. Lt 1
x0 2m x n
4sin 4 x 4
Lt 2
x0 2m x n
2
 n  4, 8m
 1  m  7
2
 m  n  3

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