Narayana IIT Academy 10-05-20_Incoming.Sr.

IIT_*CO SC_JEE-Adv_WAT-43_KEY&SOL

Sec: Incoming.SR_*COSC WTA-43 Date: 10-05-20

Time: 3hrs 2017-P2 Max.Marks:183
KEY SHEET

PHYSICS
1 C 2 A 3 D 4 B 5 A

6 A 7 A 8 B 9 C 10 AC

11 AD 12 ABC 13 ABCD 14 AC 15 C

16 B 17 D 18 B

CHEMISTRY
19 B 20 C 21 B 22 A 23 D

24 D 25 B 26 ABCD 27 BCD 28 ABC

29 ABCD 30 AB 31 ABC 32 AB 33 B

34 C 35 B 36 A

MATHS
37 C 38 A 39 A 40 A 41 D

42 D 43 A 44 AC 45 AB 46 ABD

47 AC 48 ABD 49 ABCD 50 ABC 51 D

52 A 53 B 54 A

Sr-IIT_*COSC Page 1
Narayana IIT Academy 10-05-20_Incoming.Sr.IIT_*CO SC_JEE-Adv_WAT-43_KEY&SOL
SOLUTIONS
PHYSICS
1. j  i  k

2. B  0
 qv 
 0  2 
l 
 v  l2
 02 . 0 .v
l d
 
3. B  0 3 .  ava  2qva  qva 
4a
 qv
 02
a
4. dq   2 .2rdr
di  3 .dr
0r 2dr
dB 
2
 R 3
B 0
6
 0i
5. 3.
2R
 di  i d
6. dB  0 2  0 2
2 R 4 R
 i
dBy  02 cos d
4 R
 i
By  02  Bn
4 R

0 i
 1 
7. B . 1  

4 R / 2  2
 i

4R

0
2  1
8.

Sr-IIT_*COSC Page 2
Narayana IIT Academy 10-05-20_Incoming.Sr.IIT_*CO SC_JEE-Adv_WAT-43_KEY&SOL

9. In A, B dye to top & bottom squares cancel.

10.
FBC
C

B

 
O O


FAD

11. 0  r  R B  0 ni k
  ni
R  r  2R B   0 ni k  0 
2r
  i
2R  r B  0 
2r

qvb
14.   2. .y
m
w m  qvB.L   quBvdt
 qvB.L   qvB  .L
=0
w N  qvBL

Sr-IIT_*COSC Page 3
Narayana IIT Academy 10-05-20_Incoming.Sr.IIT_*CO SC_JEE-Adv_WAT-43_KEY&SOL

15. 2Bw sin   Br

0 i sin 2  0 i a 2
 
2 a 3


2 a2  h2  2

 
 4 a 2  h 2  2 a 2
 2 
 h 2    1 a 2
 4 
 h  3 / 2a
  
16. z  MB
i
 i.a 2 .2. 0 .sin 300
2d
ia 2 2
 0
2d

CHEMISTRY
19. It is a  -maltose
20.

Sr-IIT_*COSC Page 4
Narayana IIT Academy 10-05-20_Incoming.Sr.IIT_*CO SC_JEE-Adv_WAT-43_KEY&SOL
21.

22.

pK a1 and pK a2 are greater than pH of the solution.

pK a3 is less than pH of the solution.

23. This amide does not formed from natural amino acids

24. E and Y have pI > 7.7 will be anionic and will move towards positive electrode
While K having pI < 7.7 will be cationic will move towards positive electrode

Sr-IIT_*COSC Page 5
Narayana IIT Academy 10-05-20_Incoming.Sr.IIT_*CO SC_JEE-Adv_WAT-43_KEY&SOL
25.

26. In pair (a)  is soluble in both NaOH and NaHCO3 but can not

In pair (b)  is soluble in both NaOH and NaHCO3 but can not

Sr-IIT_*COSC Page 6
Narayana IIT Academy 10-05-20_Incoming.Sr.IIT_*CO SC_JEE-Adv_WAT-43_KEY&SOL

In pair (c)  is soluble in both NaOH and NaHCO3 but can not

In pair (d)  is soluble in both NaOH and NaHCO3 but can not

27. Glucose decolourises the Br2 -water but fructose cannot decolourise Br2 -water.
Glucose and fructose can be differentiate by Br2 -water.
HNO
28. Glucose 
3
 Dicarboxylic acid
NaBH
Fructucose 
4


29. Cellulose trinitrate is a guncotton

Cellulose on partial nitration gives pyroxylin
30. Conceptual
31. Glycine does not contain chiral carbon. So it does not belong to L – configuration.
32. Isoleucine and Triptopan are essential amino acids

33 & 34.

Sr-IIT_*COSC Page 7
Narayana IIT Academy 10-05-20_Incoming.Sr.IIT_*CO SC_JEE-Adv_WAT-43_KEY&SOL

pK a1  pK a2
35. IEP 
2

36. Carboxylic Acid is more acidic when compared to  N H 3
a  b  c

Sr-IIT_*COSC Page 8
Narayana IIT Academy 10-05-20_Incoming.Sr.IIT_*CO SC_JEE-Adv_WAT-43_KEY&SOL
MATHS
37. Let population = x at time ‘t’ years.
dx
Given, x
dt
dx
  kx
dt
dx

x 
 k dt  ln x  kt  ln c

 x  ce kt
If t  0, x  x0 ; c  x0 ; x  x0 e kt , given x  2 x0 at t  30 .
2 x0  x0 e30 k
 2  e30 k
 ln 2  30k -- (i)
x  3 x0 at ‘t’
3 x0  x0 e kt  3  e kt
kt  ln 3 -- (ii)
t ln 3
Dividing equation (ii) by (i); then  or t  48 years.
30 ln 2
dy 1 dx
38.    xy  x 2 sin y 2  1
dx xy  x sin y  1
2 2
dy
1 dx 1
 3  2 y  y sin y 2 -- (1)
x dy x
1
Putting  2  u; eq. (1) can be written as
x
du
  2uy  2 y sin y 2
dy
So, I.F.  e y .
2

So, solution of D.E. is

 ue y   2 y sin  y 2  e y dy    sin t  et dt
2 2

e y  sin y 2  cos y 2 
2

 c
2
 2u   sin y 2  cos y 2   2ce  y
2

 2  x 2 cos y 2  sin y 2  2ce  y  .

2

 
dy dy  y  1
39. Slope   
dx dx  x 2  x 
dy dx 1 1 
    
 y  1 x  x  1  x x  1 
dx


 y  1 x  1  k , Putting x  1 ; y  0 , we get k  2 , the equation is
x
 y  1 x  1  2 x  0 .

Sr-IIT_*COSC Page 9
Narayana IIT Academy 10-05-20_Incoming.Sr.IIT_*CO SC_JEE-Adv_WAT-43_KEY&SOL
dy
40. sin x  y cos x  1
dx
dy
   cot x  y  cos ec x
dx

 cot x dx
I .F  e  eloge sin x   sin x

 y sin x   cos ec x sin x dx  x  c

If x  0, y is finite  c  0
 /2
x x x
y
sin x
,I   sin x dx
0
as 1 
sin x
 /2

 dx  I ; So,
0
2
 1.

41.  y cos y  sin y  dy   2 x log x  x  dx

x2 x2
Integrating, y sin y   sin y dy   sin y dy   log x  x    c 2

2 2
y sin y  x 2  log x   c .
42. e  x  y  1 dy   cos 2 x  sin 2 x  y dx  0
 1
 1  y  dy   e  cos x  sin 2 x  dx  0
x 2

y  lny  e x cos 2 x  C
At x  0; y  1 so C  2
y  ln y  e x cos 2 x  2 .
43. f  x 2 y   x 2 f  y   yf  x 2 
Keeping ‘y’ as constant and differentiate w.r.to ‘x’
f 1  x 2 y  2 xy  2 xf  y   yf 1  x 2  2 x
Put, x  1
f 1  y  2 y  2 f  y   2 y f 1 1
yf 1  y   f  y   y  f 1 1  1
df  y 
y  f  y  y
dy
Differentiate w.r.to ‘y’ again
df  y  d 2 f  y  df  y 
y  1
dy dy 2 dy
1
f 11  y  
y

Sr-IIT_*COSC Page 10
Narayana IIT Academy 10-05-20_Incoming.Sr.IIT_*CO SC_JEE-Adv_WAT-43_KEY&SOL
1
f 11    7 .
7
dy  
44. Given,  3 y cot x  sin 2 x, y    2 ( Linear differential equation)
dx 2

 3cot x dx
1
 I.F.  e  e 3ln sin x  
sin 3 x
 1  2sin x  cos x
 General solution si y  3    dx  C  2 cos ec x cot x dx  C
 sin x  sin 3 x
y
  2 cos ec x  C
sin 3 x
  2
As, y  x    2  3  2  C  C  4
 2 1
 y   4sin 3 x  2sin 2 x 

 
3 2
1 1 1 1
(A) y    4    2      0
6 2 2 2 2
(B) y  x   12sin x cos x  4sin x cos x 
1 2

    12  3 1 3 1 9 2 3 92 3 
So, y1       4      
3  4 2 2 2  2 2  2 
(C) As, y1  x   4sin x cos x  3sin x  1  2sin 2 x  3sin x  1
  
 y  x  increases in  , 
6 3
 /2  /2
(D)   4sin 3 x  2sin 2 x  dx  0  4  sin 2 x dx  4  4    .
 /2 0

dy
45. 2 xy  x2  y 2  1
dx
Put y 2  t
dt
x  x2  t  1
dx
dt t x 2  1
 
dx x x
1
I.F. 
x
t x2  1 1
Hence,   2 dx  x   C
x x x
 y 2  x 2  1, C  0 as y 1  0
Now, y  x0   3  3  x02  1  x02  4
 x0  2 .
1
1
dy dy e x
46. x2  y 2 e x  2  2 dx
dx y x
Integrating both sides,

Sr-IIT_*COSC Page 11
Narayana IIT Academy 10-05-20_Incoming.Sr.IIT_*CO SC_JEE-Adv_WAT-43_KEY&SOL
1 ex 1 1 1
  2 dx  C  Putting  t  2 dx  dt      et dt  C
y x x x y
1  t 1 1
  e C   e x  C
y y
 lim f  x   1  1  0  C  C  1
x 0

1 1
1 dy 1 1/ x  1  e1/ x
 e x  1  y    e  2 
y 1  e1/ x dx 1  e1/ x 2  x  x 2 1  e1/ x 
2

dy
  0x  R  0
dx
1 1 1
lim  and lim 0
x  1  e1/ x 2 x  0 1  e1/ x
 Graph of the function is

From the graph options (A), (B) and (D) are correct.

dy 4y dy
47. Given that y  at  2,1   2 at (2,1)
dx dy dx
dx
 Equation of tangent having positive slope is y  2 x  3.
Now verify alternatives.
dy
48.  y  f  x
dx
I.F = e x

ye x   e x f  x  dx  C

Now if 0  x  2 then ye x   e x e  x dx  C  ye x  x  C

x  0, y  0   1, C  1
 ye x  x  1
x 1 2
y  x ; y 1 
e e
e   x  1 e x
x

y1 
e2 x
e  2e  e 1
y1 1  2  2  
e e e
If x  2

ye x   e x  2 dx

ye x  e x  2  C
y  e 2  Ce  x
Sr-IIT_*COSC Page 12
Narayana IIT Academy 10-05-20_Incoming.Sr.IIT_*CO SC_JEE-Adv_WAT-43_KEY&SOL
As ‘y’ is continuous
x 1
 lim x  lim e 2  Ce  x
x2 e x2
 
3e  e  Ce 2  C  2
2 2

 For x  2
y  e 2  2e  x ; Hence y  3  2e 3  e 2  e 2 2e 1  1  
x
y  2e
1

y1  3  2e 3 .
dy dy 16 x
49. 32 x  2 y 0  m1   and
dx dx y
dy dy k
16 y15 k  m2  .
dx dx 16 y15
sin x
50. f  x 
x
a 1
51.  f  x  dx   f  x  dx  2 f  a   3a  b
0 a
Differentiating w.r.t ‘a’ by Leibnitz rule,
3
2 f  a   2 f 1  a   3 (or) f 1  a   f  a    ,
2
Which is a linear d.e. with integrating factor, e  a .
3 3
 f  a   e  a    e  a da  e  a  A
2 2
3 3 3
 f  a    Ae a , f 1  0   Ae  0  A   e 1
2 2 2
 f  a   1  e a 1  , f  x   1  e x 1  .
3 3
2 2
a 1
52. b   f  x  dx   f  x  dx  2 f  a   3a
0 a
a 1

3
20 1  e x 1  dx   1  e x 1  dx  3 1  e a 1   3a
3
2a
3a 3 3
  1  a   3  3a  3e a 1  e x 1 / 0a e x 1 /1a 
2 2 2
9 3  1  3
   3e a 1  e a 1    1  e a 1 
2 2 e 2
9 3 3 3
    3.
2 2e 2 2 e
53. Differentiating the given equation,
3 y 2 y1  3 y 1  1  0 -- (1)
6 y  y1   3 y 2 y11  3 y11  0
2
-- (2)
1 1
1  y1 
3  y  1
2 
, y1 10 2 
3  8  1

1
21

2 y  y1 
2
4 2  1  4 2
2

 2  y  11

1 y2

, y11 10 2      2 3
1  8  21  3 7
Sr-IIT_*COSC Page 13
Narayana IIT Academy 10-05-20_Incoming.Sr.IIT_*CO SC_JEE-Adv_WAT-43_KEY&SOL

b b
xdy
54. Area   y dx  xy /   b
a dx
a a
dx
b
 bf  b   af  a    xy1dx
a

xdx
 bf  b   af  a   
3  f  x  1
2

Since y  f  x  .

Sr-IIT_*COSC Page 14