Sri Chaitanya IIT Academy., India.

AP, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI

A right Choice for the Real Aspirant
ICON Central Office , Madhapur – Hyderabad
Sec: Sr.Super60 & All GTA-19 Date: 12-08-2021
Time: 02.30Pm to 05.30Pm 2019_P2 Max.Marks:180

KEY SHEET

PHYSICS
1 AC 2 ABCD 3 AB 4 BC 5 AB
6 AC 7 BD 8 ABC 9 25.2 10 3.87
11 9 12 27 13 10 14 1.25 15 B
16 A 17 C 18 A

CHEMISTRY
19 AC 20 ABC 21 D 22 ABD 23 ABC
24 ABC 25 AD 26 BCD 27 6 28 3
29 4 30 5 31 9 32 6 33 C
34 D 35 A 36 C

MATHEMATICS
37 BD 38 CD 39 AD 40 BCD 41 BC
42 ABC 43 AC 44 ABCD 45 2.00 46 1.00
47 5.0 48 6.0 49 3.0 50 4.0 51 A
52 D 53 B 54 C
Sri Chaitanya IIT Academy 12-08-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-19_Key & Sol’s
SOLUTIONS
PHYSICS

1. 
Y  A sin t  k.r 

r  xi yj  zk

k .r  3 x  2 y  z  


k  3i  2j   k  

k   9  4  1   14
 2 2 2 2
k      m
 k  14 7

3i  2j  
k
unit vector in the direction of wave propagation =
14
2.
FAB   B0il / 2k
y

A B

x
D C

FBC   B0 il / 2k
F   B il / 2k
CD 0

FOA   B0il / 2k

R
3. Due to  E1  parallel to C1 C2
6 0
2 R  R
Due to 2  , E2   parallel to C2 C3
3 0 4 6 0
4 R  R
Due to 3 , E3   parallel to C3A
3 0 8 6 0
2 5 R
E A  E12   E2  E3  
6 0
 1 1 1
4. E 0 z 2 1    E 0 z 2     3E 0
 9  4 9
z=2
1
3
2
 1
KE1  E 0 1    
 9
 1
KE 2  E 0 z 2 1    
 4

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Sri Chaitanya IIT Academy 12-08-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-19_Key & Sol’s
1
KE 
2
= 8.5 eV.
5.

6.

 
dw  f . ds.
Since body is hauled slowly, so
f  mg sin    mg cos 
W   mg sin    mg cos 

  mgds sin     mgds cos 

  mgdy    mgdx
 mgh   mgL
7. For rotation equilibrium, taking torque about the point from where normal force
passes.
a a
 laB0  laB0  mgx  0
2 2

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Sri Chaitanya IIT Academy 12-08-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-19_Key & Sol’s
2
la B0
x
mg
a mg
For the block not to topple x   l 
2 2aB0
8.

W dy
 de  
A  y0  Ky 
y L
w  ln  y0  Ky  
e  
A K  y0

w  y0  Kl 
ln  
AK  y 0 
 
2
9. H  i R t  m S  .

302  t  A  d  S  300
A

10.
11. If intensity of light incident on slits S1 and S2 is I0.
The intensity through S4 will be I1 = 4I0
The intensity through S3 will be I2 = 4I0 cos2(/2) = I0
2
2
Imax  4I0  I0   3  9
k=     
Imin  4I0  I0   1  1

12. (R = 1.1 × 10 7 m –1 , b = 1 and 5 / 33 = 0.39)

Ans 7
1 3R
(A)  (Z  1)2
 4
4 4
 (Z – 1) = =
3R 3 1.110 1.8 10 10
7

200 5 78
= = = 26. Z = 27
3 33 3
13.

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Sri Chaitanya IIT Academy 12-08-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-19_Key & Sol’s
From the given inform after, the screw gauge has negative zero error of 4 circular
scale divisions. To allow 4.68mm thick plate, the screw gauge to be conscred by 9.5
rotation
1
i.e. thickness of plate nearly ( 9.5  m  4.75mm )
2
14.
dy x dx 3
y  v 2  x2  . vy   m / s
dt v 2  x 2 dt 2
d x
Vcom  x     1
dt  2 
d y 3
Vcom  y    
dt  2  4
2
3 5
Vcom  12    
4 4
15 & 16.

2T


T T

p
k m

From the equilibrium position if upper spring elongates by x , elongation in the lower
x x 5
spring is  net displacement of block in the down ward defection is  2 x  x and
2 2 2
kx
incase in tension in the string connected to mass m is , it is the restoring force on
2
5x x
blocks m 2  k
2 2
k 5m
2  or T  2
5m k
B) In this case if pulley moves down by ' x ' from equilibrium, block displaced drum by
kx kx
2x and incase in spring force in each spring is incase in tension an the block is
2 4
kx k
So  m 2 2 x or  2 
4 8m
8m
T  2
k
C) If pulley moves dawn by ' x ' elongation of each spring dues the equilibrium is x .
m
And incase in tension an the block is 2kx so 2km  m 2 x or T  25
2k

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Sri Chaitanya IIT Academy 12-08-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-19_Key & Sol’s
D) If x is the additional elongation in the upper spring, lower spring elongates by 2x
x 5x
and set displacement of block is 2 x   change in tension an the block is 2kx so
2 2
4k
2kx =  2 
5m
17 & 18.
GM
Velocity at A in a circular orbit VA   GM  gR 2
r1
gR 2 g
R
r1 r1
1 1 
Velocity in elliptical orbit is given by the expression, v 2  2 gR 2   
r 2a 
r1  r2
Where a 
2
1 1 
Velocity at Perihelion of the transfer orbit, v AP
2
 2 gR 2   
r 2a  1 
1 1  2 gr2
v   R
'
AP 2g   R
r1  r1  r2 
 r1 r1  r2 
r1vAP  r2 vBa
Velocity at aphelion of the transfer orbit
2 gr1
 vBa   R
r2  r1  r2 

g  2r1 
Velocity increment, va  R 1  
r2  r1  r2 

CHEMISTRY
3
19. SF4 sp d hybridized with one lonepair. Sea-saw structure
XeO2 F2 , sp 3d hybridized with one lone pair-structure same as in SF4
CO2  sp hybridized linear
I3  sp 3d hybridized linear shape
20.  Br is better leaving group than Cl
Dielectric constant of H 2O is greater than CH 2OH . As conc. Of substrate increase rate
of S N increases.
1

21. Bakelite is formed by the reaction of formaldehyde (HCHO) and phenol

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Sri Chaitanya IIT Academy 12-08-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-19_Key & Sol’s
OH


OH
n n HCHO  

OH OH OH

CH 2 CH 2

CH 2 CH 2

CH 2 CH 2

OH OH OH
Bakelite

22.

CH 3 CH 3 CH 3
H H
CH 3  CH 2  CH  CH 2 CH 3  CH 2  C  CH 2 CH 3  CH 2  C  CH 3 CH3  CH  C  CH3   CH 3
  H 2O
H
23. OH

CH 3 CH 3
CH 3
H H
CH 3  CH  CH 2  CH 2 CH 3  CH  CH  CH 2 CH 3  CH  CH  CH 3 CH 3  C  CH 3   CH  CH 3
  H 2O
H H
OH

CH 3 CH 3
CH 3 H
H CH 3  C  CH 3   CH  CH3
CH 3  C  CH 2 CH 3  C  CH 2 CH 3  C  CH 2  CH 3

  H 2O
CH 3 OH CH 3

24. Conceptual
25.

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Sri Chaitanya IIT Academy 12-08-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-19_Key & Sol’s
26.

27. Complexes No. of geometrical isomers

(i)  Pt  NH 3 2  SCN 2  2
(ii) Co  NH 3 3  NO2 3  2
(iii)  Pt  en  Cl2  0

(iv) Cr  en 2 Br2  2
3
(v)  Rh  en 3  0
2
(vi) CoCl2 Br2  0
Hence, sum of total number of geometrical isomers = 6.
28. X=1 Y=2
29. Kb of X   1010
Ka of HX IS 104
For an acidic buffer
 acid 
 H    Ka    Ka  104
 salt 
H
P 4
30. H 3 PO3  2 H   HPO3 ; H r  ?
 
2H  2OH  2H 2O H r  55.84  2 = -111.68
Heat of neutralization of H3 PO3 is 10x10.668
-106.68 = Hion 111.68
Hion  5 KJ / mole .
31.

32. M eq of I 2  m eq of Na 2S2O3  60  0.2 1  12

Milli moles of I2 liberated  12 / 2  6
2I   aq   I2  aq   2e
I 193
Moles of I 2  6  10 3 , moles of e liberated at anode  12 103  , I  6A
96500

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Sri Chaitanya IIT Academy 12-08-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-19_Key & Sol’s
 n2  2
33 & 34. rn  0.529   A  rn  n
 Z
nh 
Angular momentum  l    ln
1

2
 
2
1 1  Z
K.E.  mv 2  m  2.18  106 
2 2  n
2
Z
 K.E.  2  K.E.  n 2
n
Z2
P.E.  2K.E.  P.E.  2
n
 P.E.  n 2
35 & 36

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Sri Chaitanya IIT Academy 12-08-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-19_Key & Sol’s
MATHEMATICS
37. by IMVT in 1, 3
ex  x  1 1
38. lim 2

x  a  x 2
39. x  22x 5  6x 3  3x 2  55  0
8

x  even
Even - Even - Even + Even + odd  0
X = Odd
Odd – Even – Even + Odd + Odd  0
Number of solution = 0
a
40. Let terms are a ar
r
8
a  8   1.5,8r  9  A.P
r
8 1
10   1  8r  9  r  2,
r 2
 r  2  481632....GP
Now check options
 1 
41. f  x    x 2  4  x   , 3
3 

 x 2  4   4, 5
Discontinuous at 9 points
g  x    x 2  4   x  2  3x  5 
g  x  is non differentiable at 10 points
1
42. L1  y   x  1  x  y  2
1
 1 1
L 2  y  1 x    x  y 
 2 2

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Sri Chaitanya IIT Academy 12-08-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-19_Key & Sol’s
1
Slope of L1 
2
1
Initial ordinate of L2 
2
1 5 5 25
Area of triangle  . . 
2 2 4 16
1  By2
43. Ax 2  By 2  1A 
x2
Diffrentiat both sides
0  x 2  2Byy '  1  By 2  2x
1
1  By2  Byxy '  B  2
y  yxy '
1 2
 y2  yxy '  2yy ' yxy '' xy ' x  y '  0
B
2
x  y '   yy ' yxy ''  0
2
xyy '' x  y '   yy
 P  xy, Q  x
44. 2 f x  f  y  x  y
f  x   f  y 1
 
xy 2
f  x   f  y 1
lim 
xy xy 2
1
f '  y 
2
1 1 1
 f ' x  , and f '  x  
2 2 2
1
From both we can say that f '  x  
2
x
 f x  C
2
x
A) y   c and y  x is one
2

x
B) y   C and y   x 2 is one
2
x x
C) y  and y   C can be one, infinite or zero
2 2

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Sri Chaitanya IIT Academy 12-08-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-19_Key & Sol’s

D) y2  x may be more than one

 1 cos x 
45. f  x   cos x   
 1  cos x 1  cos x 2 
 
cos x
 2
1  cos x 
1
 2 
lim 1  cos x  f  x  cos x 1 
x 0
 
1
 1
  cos x 1 
 lim  cos x  cos x 1  e cos x 1 2
x 0
  
x
46. l1   x cos x   00  l1  e0  0
ln x cos x 1/ x
log l1  lim  l2  lim  x sin x   0   0
x 0 1/ x x  0

l1  l2  1
47. D0
4P2  4  3P  4   0
P 2  3P  4  0
 P  4  P  1  0
P   ,1   4,  
1
48.  dx
1  x 
x  t2
2tdt
 1  t  8

t 11 1 1
 2 8
 2  2 8
1  t  1  t  7 1  t 
1 2
 6
 7
c
3 1  t  7 1  t 
1 2
 6
 7
3 1  t  
7 1 x 
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Sri Chaitanya IIT Academy 12-08-2021_Sr.Super60 & All_Jee-Adv(2019-P2)_GTA-19_Key & Sol’s
a  6, b  7
1/n
2
x  a 2 1
49. lim n  x dx
n 
0
1
x  a 2 1
x
0
dx
lim 2
n 
t
Apply L- Hospital rule
2
t t  t21
1
lim 2  2
1 2
 lim
 2
n  0 a .t n 0  
1
lim t t  1  f     2
n  0 
1
f x 
25
a l m
50. A l b n
m n c
bc  n 2 mn  lc ln  bm
2
adjA  mn  lc ac  m ml  an
ln  bm lm  an ab  l2
3
A . adjA  A  64  A  4
2a  3l 3l  5m 5m  4a
2l  3b 3b  5n 5n  4l
2m  3n 3n  5c 5c  4m
a l m 2 0 4
l b n 3 3 0
m n c 0 5 5
  360
51. conceptual
52. conceptual
53. conceptual
54. conceptual

Sec: Sr.Super60 & All Page 13