01-12-19 - Sri Chaitanya-Sr - Chaina-I - L-I & II - Jee-Adv - 2018-P2 - CTA-6 - Key & Sol's

Sri Chaitanya IIT Academy., India.
AP, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI

A right Choice for the Real Aspirant
ICON Central Office , Madhapur – Hyderabad
Sec: Sri Chaitanya-Sr.Chaina-I(L-I&II) CTA-6 Date: 01-12-19
Time: 02:00 PM to 05:00 PM 2018_P2 Max.Marks: 180
KEY SHEET
PHYSICS
1 BC 2 CD 3 ACD 4 AD 5 BD
6 ABCD 7 0.41 8 8.00 9 3.00 10 4
11 4 12 34.00 13 7 14 60.90 15 A
16 A 17 B 18 A
CHEMISTRY
19 ABCD 20 BC 21 AC 22 ABCD 23 BCD
24 CD 25 4.00 26 4.00 27 9 28 4
29 2 30 70 31 9 32 292 33 C
34 B 35 A 36 A
MATHS
37 BCD 38 ABD 39 BC 40 ABCD 41 BC
42 AB 43 5.00 44 1.50 45 33.00 46 9.00
47 10.22 48 5.00 49 3.00 50 2.00 51 A
52 B 53 D 54 A
Sri Chaitanya IIT Academy 01-12-19_Sri Chaitanya-Sr.Chaina-I_L-I&II_JEE-Adv_2018-P2_CTA-6_Key&Sol’s
SOLUTIONS
PHYSICS
1.  Acceleration is parallel to relative velocity
 Straight line path
1 2 
 3i  4.5 j1   4 i  6 j1 S
2 
 3i  4.5 j  2i  3 j  S

 5i  7.5 j  S
2. Normal reaction in more in 2nd case
2
 
3. 2
2
k 
2
Moving in negative x- direction


With initial phase angle 
4
4. h1 cot 2  h 2 cot 2  h 2 cot   h1 cot 
h 2  cot   cot 2   h1  cot   cot 2 
h 2 cot   cot 2
 and 1 sin  90      sin  90  3 
h1 cot  cot 2
cos   cos3
5. Piston A will go totally down and Area of piston A is half of Piston B
 a3 
6. a)2048  10 3  10     103  10
2
a
b)  600  a 2   V   600  a 2  a  600x  V  10.24L
2
3
c)2048  103  10  10  F  16   106  103  10
6400
d) k 
39
Then F  kx
x  12.48cm
dF
dθ
C θ
 θ
dF
7.
Sec: Sr. Chaina-I Page 2
2κλ . Rdθ
d = dF.2Rsin = 2R sinθ
r  R cosθ
τ  4κλ 2 R
π 2
R sin θ d θ
0 r + R cos θ
π 2  r 
 4κλ 2 R  nr  R cosθ 0  4κλ 2 R n
 r  R 
 r 
τ  4κλ 2 R n  
rR
λ2R  R + r 
τ  4κ n
 0  r 
8. ωc  100  100  10  6
 102
1
 100
ωc
16
I1  sin 100t  tan 1  2  
50 5
16  50
VA  sin 100t  tan 1  2  
50 5
16
VA  sin 100t  tan 1  2  
5
VB  8sin 100t 
2
16 16 1
 VAB max     8   2  8 
2
 5 5 5
256 256
  64 
5 5
 8volt
9. kr 4  2 r   0  c r n  2 r d r
  C  2  n+2
2 k r 5   0 r
 r2 
n25
n 3
P0 v 0
10. Wnet  2P0 v 0   P0 v 0  
4
P0 v 0 Pv
Wnet  P0 v 0   4   0 0 ; Put  = 3.14
4 4
0.86
Wnet  P0 v 0  0.22  P0 v 0 
4
Now,

P0 v 0  3R
T1   U12  1  T2  T1 
R 2

4P0 v 0  3R
T2   Thus, U 23  1  T3  T2 
R  2
2P v  3R
T3  0 0  U 31  1  T1  T3 
R  2
Q 1 2  4.5P0 v 0   1.22P0 v 0   5.72 P0 v 0 
Q 2 3  3P0 v 0  0  3P0 v 0 
Q 3 1  1.5 P0 v 0   P0 v 0   2.5 P0 v 0 
Wnet
Thus efficiency  
 ve heat
0.22 P0 v 0 
  0.04
5.72 P0 v 0 
Thus efficiency is 4%
11. Use KCL and KVL

Xc
12. tan 370 
R
3 Xc

4 R
3R
  Xc
4
XL
 tan 450 
R
 XL  R
V 1
I 0
V2 R
2
2
R  
4
V  L1 4V0
 0 
2 17 34
13. Let N 0 initial number of nuclei at time t  0 . The number of undercayed nuclei in time
t is N  N 0et . The number of nuclei decayed in time t is
n  N 0  N  N 0  N 0 e t ----------- (i)
The number of undecayed nuclei in next time t,
N '  Ne t   N 0e t  e   N 0e 2 t --------- (ii)
Number of decayed nuelci in next time t,
0.75n  N  N ''  N 0et  N 0 2 t
 N 0et 1  et 
4
Dividing Eq. (ii) by Eq. (i) , we get 0.75  et     et
3
4
In
4 3
Taking natural logarithm , in  t   
3 t
Given t  2 s,
in 4  in 3 2 in 2  in 3 2  0.6931  1.0986
  
2 2 2
1
 0.1438s
1 1
Mean life,     7 s  whole number 
 0.1438
14. E1  200  10  190eV
13.6  4
E2   13.6eV
31
15. A  X cm will be  ve , Ycm will be  ve
B  Ycm is  ve X cm will be zero
C  X cm is zero Ycm is  ve
D  X cm is zero Ycm is  ve
16. a) mg  Vin dg
d should remain constant
m m
b) V0 1  3 T  - 1  T  =V0 
d d
m
V0 3T  T
d
m m
3  
 d
m
C) V0 1  3T   1  T   HA0 1  2T 
d
AH 1  2T 
d) mg  g  1  T  1  2T
1  T 
x  d  vt   2Q  x 
17. a)   d  vt 
 0 A  0 A
x  d  ut  d  ut   2Q  d  ut 
2 xd  2Q  d  ut 
b) Charge on B  2Q  x
d
c) Current   x 
dt
 C1V 2   d  vt 
d) Ratio   2 
 
 2   d  vt 
C V
18. In all cases kinetic energy will increase and potential energy will decrease but
separation depends on attraction or repulsion .


CHEMISTRY
19. Aromatic Products are:
OH
N
N N
N OH
A) B)
NO
OH
OH
C) D)
20.
O O
C C
O LiAlH 4 HO OH cold.KMnO4
O  HO OH
C C
O O
O
OH
HO OH HO OH
OH +
 3-mol  HO HO OH
Acetal formation
OH
Meso
OO O
O
O O O
O
+
O O O O
21.

HO OH : OH O Ts O
TsCl py
C   X
1, 2 CH3
H
H H
HO OH :OH O
H
H Δ H Δ
 C  CH 3  Y 
1,2 H
H H
H OH O
Hg H +2 tauto
 C  C  CH3  CH 2  C  CH3
H OH O
H.B.O.
  C  C  CH3  CH 2  C  CH3
22. Solids does not participate in equilibrium
23. Zn  I.P  9.35eV Cu  I.P  7.69 eV
Cd  I.P  8.95 eV Ag  I.P  7.54 eV
Hg  I.P  2 eV Au  I.P  9.19 eV
Kw
24. h
Kb  c
25.
Br Br Br
1 1 1 1
3 2 Br 2
Br
3 3 2 2
4 Br 3
4 4 4
6 5 6 5
6 5 6 5
Br Br
26.
HOCH 2 O OH
OH OH
H CH 2 OH
* *
H H 22  4

27.
O O CH 3
C  OH H  O  Et HΔ
C  O  Et HO  C  CH3
 i  4CH3 -MgBr
+  By Esterification 
    ii H3O 
C  OH H  O  Et C  O  Et HO  C  CH 3
 2 mol 
O O  A  B  CH 3
O O
 2 i 3CH KOH HΔ
CHCl3  HO  C   CH3 3  
 ii H  CH3  C  C  CH3 3 By Pinacole-
Pinacolone
rearangment
28. A, B, E, F are correct

29. n- factor of Cu 2S is 10
n- factor of KM n O4 is 5
Al Al
30.
12  4+11 2 = 70
l 2 l 1
31.  ;R   .  100  ρ. or ρ  200  cm
A 4 A 2
1 1 1
  cm
200
1 1000
   50
200 0.1
  300  100  400
 50 1
  
 400 8
Tb  i  K b  m
 1
 1    0.5  0.1  0.05625
 8
 0.05625  160  9
32. XeF4  Xe  4F H  34  4  136
Xe  Xe  e H  279
 
Fe F H  85
F2  2F H  38
 
XeF4  Xe  F  F2  F
H  136  279  85  38  292 kcal mole
O
O O
O
Active
Active
Enatiomer
33. A)
C3
CH3
+ CH3  Carbocation  & molecular POS
CH 3
B)
Me Me
R S
R 2 real cc = Enantiomers(1pair)
S
Me Me
Enantiomers
C)
Me Me
*R R
*R S
POS 2 real + 1 presseudo cc = Diastereomers = Meso (2)
*S
S
Me Me
C C3 + POS
H H
D) H

2 enentiomer
34. P)
Q) CD3  CHO
CH 3
OH OH
  2  4
 2
R)

Cl
5
S)
35. All the molecules involving d 2z orbital
36. E – cell  ve cell reaction spontaneous


MATHS:
f     sin    cos 2  1
2 2
37.
  2  2 sin 2   1 
at sin 2   0  f    1  
at sin   1 f        1
2 2
 2    1  1       2  0
for   0
range of f    1   , 2    1
 
   0,1 f   |max  3
2  2 2  2
f      2 sin   1   
2 2
2 2
n  r
3 3r1  3n
38. Sn     
  3
2  r  r  1  n
(A) (B) S9  3  3  327 1  3.26.28
7 2
310
(C) S10   3 10S10  30  310
10
(D) n  Sn  3  3
n
39. x 2
1 x2 x3   x1  x1 x2 x3  4 x1 x2 x3 x4
 ac  4d
x 2
1 x22 x3   x1 x2  x1 x2 x3  3 x12 x2 x3 x4
 bc  3ad
40. Let C   1  1, 21  2,31  3 and
D    2  1, 2 2  2, 3 2  3
CD  14
2 2 2
  1   2   4  1   2   9  1   2   14
  2  1  1   2  1   1
Let G   , ,  
4  5  21
4  10  41
4  9  61

4 x  5 4 y  10 4 z  9
Locus of G is  
2 4 6
5 5 9
2x  y z
2 2 4
1 1 3
2
2 x2 1  1 2 x2
 ln  x 2 x
2
2x 1
41. x dx  x
  2
42. Let f  x    x  1  x  2 ...... x  2020 
f 0  f 1
 1.2 ......2020  1 1 1  2 .....1 2020 
 1 .2 .......2020  1 1  1 .2 1  2 ......2020 1  2020 
2 2 2
Apply A.M.  G.M. in 1 and 1  1

1  1  1 1
 1 1  1 2
2
1
1
 1 1  1 2 
2
 1 2020 1
 1 1  1 2 1  2 .......2020 1  2020     2
 2
1
 Product of roots 
2 2020
Eight numerical value
43. Take x  r cos , y  r sin 
x 2  y 2  xy  1  r 2 1  sin  cos    1
1
 r2 
1  sin  cos 
3 3
x 3 y  xy 3  7   r cos   r sin    r sin  r cos   7
 r 4 cos3 sin   r 4 cos  sin 2   7

 r 4 cos  sin  cos 2   sin 2   7 
2
 1  2sin 2
 cos  sin   7  7
 1  sin  cos    2  sin 2 2
2sin 2
f    2  f   at    / 2
 2  sin 2   max
min at    / 2

 x y  xy
3 3
7  min
 2  7  5
44. s  ax 2  2hxy  by 2  2 gx  2 fy  c  0
s '  a ' x 2  2hxy   a ' a  b y 2  2 g ' x  2 f ' y  c  0
s  s '  0
 a  a ' x 2  2hxy 1     y 2  b    a ' a  b   2 x  g  g '  2 y  f  f '   c  c  0
To represent a circle
Coefficient of xy =0 & Coefficient of x 2  coefficient of y 2
1     0, a  a '  b    a ' a  b
 1
 a  a ' x 2   a  a ' y 2  2 x  g  g '  2 y  f  f '  2c  0
 g  g ' f  f '
Centre is  ,
 a  a ' a  a ' 
P is centre
PA2  2 PB 2  3PC 2
A, B, C, D are points on circele 
4 PD 2
R 2  2 R 2  3R 2 6 R 2 3
   =1.50
4R2 4R2 2
2 x2 y 2
45.  
x  r  y 2
 r 2
 1
a 2 b2
2 2
P  a cos , b sin    a cos   r    b sin   r 2 ..........1
P
 0,b
 a,0  r,0  r ,0  a,0
Normal passes through  r ,0

a.r b.0 r
  a 2  b 2  cos   2
cos  sin  ae
r2 r
Put in (1) b 2  2  b 
e e
2
b r 2
Area = ab   2 Differentiable w.r.t .e e  2 / 3
2 2
1 e e 1 e

46. zk  R, K  1, 2,3
Z1
Z3
Z2
Represent Z1 , Z 2 , Z 3 by three vertices of le ABC
 AB  BC    AC  BC    AC  AB
R2

 ABiˆ  ACjˆ  BCkˆ  . BCiˆ  ABjˆ  ACkˆ 
R2
AB 2  AC 2  BC 2

R2
Largest when AB=AC=BC
3a 2 a
 2 R for equilateral triangle
R 3
2

3  3R  9
R2
10 log e
 log7 loga5 
  log 
 r log 2e
47. 7 log5 a  log 7 log 5a  t
r 1
log et
 t  r log 2e
  t 
 r log e2 .logte
 2 r
10
 1   1 
  1    
10
1 1 1r 1 2  2  210  1

r 1
2     .............  10 
2 4 8 2  1
 10
2
1  
2

10
2m  n 2 2  1  2
10


210  2 1024  2
  10.22

100 100 100 100
48. f (10  x)  f ( x )
1 1
  1  1/ n 2
49. lim n
x 
2  n
 11.2 2..........n n 
1 2
  n 1 n 1/ n
 lim n
x
2n
1.2 ..........n 
1 2

n n 1 2

n 1/ n
 lim n
x 
2n2
1 .2 ..........n 
1 2
1/ n 2
 1 2 
1.2 ..........n n
 lim  n n 1

x   
 n 2
1/ n 2
 11  2 2 n
 n 
 lim      ..........  
x   n   n   n 

1/ n 2
  11  2 2 n
 n 
s  lim      ..........  
x  n   n   n 

1   1  2  n 
log s  lim 2 1log    2log    ........  n log   
x n
  n  n  n 
1 1  1 2  2 n  n 
lim  log    log    ........  log   
x n n
  n n  n n  n 
1 x2 x2 1
  x log x dx  log x  !
2 4
1
1 
 se 4
4
50. lim x p
x 
 3

x  1  3 x  1  2 3 x  Non zero real numbers
p
  1  1/3  1  1/3 
1/3
lim x .x  1    1    2
x
 x  x 
  1  1 
 1  x   3   3  1  1  2
 1
1
1
3
 lim x 1     
x 
 3 2! x

 1  1   1 
    1   2 1 3
3 3 3  
   ............. 
3! x
 1   1  1   1  
        1 1 2 
3 x 3 3  
1     ..........2 
1! 2! x 

2 4
p   2  1  
1
3
160  1 
 lim x       ........
 9  x   81 24  x 
x


 1 
 p   2  0  p  5 / 3  1.666....
3
P=1.67 (after winding to two decimals)
2 2
 1  1
51. (A) a  b  1,  a 2  2    b 2  2  minimum value at
 a   b 
2 2
1 1  1 289 289
a  b  4   4    2  
2 4  4 16 8
(B) Image  3, 4,12
Point on Z-axis for perpendicualar distance  0,0,12
d  32  42  5
B
C A1,0
B  0,1
 1 3 
A C , 
D  2 2 
  3 1
D , 
 2 2
(C)
1 3
 0
1 2 2
Area of Quadrilateral 
2 3 1
1
2 2
1 1 1 3 1
 1   
2 2 4 4 2
3
 sq units
2
3
 
D) 1  cos ec 2 2 x min  1  1  23  8
3

 
52. f  x   tan 1 

 12  2  M , m0

 x 2  2  32  12
 x 
53. a)Assume sphere as x 2  y 2  z 2  2ux  2vy  2wz  0 .
Now P, Q, R are  2u,0,0  ,  0, 2v,0  ,  0,0, 2 w 
x y z
So, equation P,Q,R are   1
2u 2v 2 w
1 2 3
Since it passes through 1,2,3  :   1
2u 2v 2 w
If centre is  x, y, z    u, v,  w 
1 2 3
 locus is   2
x y z
b)Assume equation of sphere as x 2  y 2  z 2  2ux  2vy  2wz  0
If passes through  ,0,0  ,  0,  ,0  ,  0,0 
  r
 u   , v   ,  
2 2 2`
2 2 2
      
Radius  1           1
 2  2  2
 2   2   2  4 if  x, y , z  are coordinates of centroid
   4
x , y  , z   x2  y 2  z 2 
3 3 3 9
c) P   ,0,0  , Q   0,  , O  , OPQ  150

 tan150 

Now if sphere is made with PQ as diameter  x    x   y    y  z 2  0
 x 2  y 2  z 2  ax  by
A plane through PQ parallel to z-axis is
x y
 1
 
x y
Using (1), (2), (3) we get x 2  y 2  z 2   x   y    
  
z2
 z  xy  tan 15  cot15   2 xy   0
2 0 0
2
d)Using family of planes any plane through line of intersection is
x  y  6    z  2 z  3  0
6  3 1
Now, its distance from centre of sphere is radius  3,   1, 
1   
2
 1  4 2 2
 Equation is x  2 y  2 z  9,2 x  y  2 z  9
xdy  ydx x
54. a) x dy  y dx  y 2 dy  2
 dy  d    dy
y  y
x
  y  c put x  1, y  1 c  2
y
x x
  y  2   5
y 3
t 11
dy t 1 f dt
b)   I.f I . f  e t 1   t  1 e 1
dt t  1 t  1
Solution is  t  1 e 1 y  e 1  c put t  0 and y  1  c  0
1 1
 2e1 y  e y
2
x y dx
c)  x 2  2  dy  xy dx  
y x dy
x dx dt
 t  x  yt  y t
y dy dy
dt 1 dy
y tt tdt 
dy t y
2
t2 1  x
 1xy  1xc  1n  cy 
2 2  y 
1
x  y  1  ln c  c  e1/2
2
2
1  x
2  y 
 1n  e y
y  x   ve
2
1 x 
    1n  ve  ve  x 2  2e  x  2e
2 e
dy y 1
 2  0 x 2 y  C put x  1, y  1 and we get C=1Put x  2  y 
d) dx x 4

01-12-19 - Sri Chaitanya-Sr - Chaina-I - L-I & II - Jee-Adv - 2018-P2 - CTA-6 - Key & Sol's

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Sri Chaitanya IIT Academy., India.

AP, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI

6 ABCD 7 0.41 8 8.00 9 3.00 10 4

42 AB 43 5.00 44 1.50 45 33.00 46 9.00

47 10.22 48 5.00 49 3.00 50 2.00 51 A

Moving in negative x- direction

Sec: Sr. Chaina-I Page 3

11. Use KCL and KVL

Sec: Sr. Chaina-I Page 5

Sec: Sr. Chaina-I Page 6

Sec: Sr. Chaina-I Page 7

Sec: Sr. Chaina-I Page 8

28. A, B, E, F are correct

Sec: Sr. Chaina-I Page 10

Sec: Sr. Chaina-I Page 11

Sec: Sr. Chaina-I Page 12

Sec: Sr. Chaina-I Page 13

Apply A.M.  G.M. in 1 and 1  1

Sec: Sr. Chaina-I Page 14

 a,0  r,0  r ,0  a,0

Normal passes through  r ,0

Sec: Sr. Chaina-I Page 15

Sec: Sr. Chaina-I Page 16

Sec: Sr. Chaina-I Page 17

(B) Image  3, 4,12

Point on Z-axis for perpendicualar distance  0,0,12

Sec: Sr. Chaina-I Page 18

Sec: Sr. Chaina-I Page 20

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