Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur – Hyderabad
Sec:Jr.C-120 2021_P2 Date:03-12-2023
Time: 09.30 AM to 12.30 PM WTA-22 Max. Marks:180

KEY SHEET
PHYSICS
1 ABCD 2 BC 3 BD 4 C 5 BD 6 AD

7 217 8 8 9 9 10 5 11 7 12 5

13 A 14 A 15 A 16 A 17 2 18 3

19 5

CHEMISTRY
20 BCD 21 AC 22 BCD 23 AB 24 AB 25 BD

26 2 27 4 28 4 29 6 30 1 31 30

32 B 33 D 34 B 35 C 36 4 37 4

38 9

MATHEMATICS
39 BC 40 AD 41 BC 42 ABC 43 BCD 44 ABC

45 18 46 3 47 7 48 41 49 1 50 5

51 B 52 A 53 C 54 C 55 9 56 6

57 3
 Sri Chaitanya IIT Academy 03-12-2023_Jr.C-120_Jee-Adv(2021-P2)_WTA-22_Key & Sol’s

SOLUTIONS
PHYSICS
1. In isotropic material distance between any two molecules will increase in all directions.
l l   l0  0
2. T  2  2 0
g g

 1 
 T0  1   
 2 
T300  T200
At 300 C fraction loss of time 
T200

 5  5 19 106
Time lost in 24 hours  86400  95 106  8.2 s
On a cold day at 100 C fraction gain of time
T100  T200
  5
T200

Time gained in 24 hours = 8.2 s

3.
Let L0 be the original length of the strip.
Co-efficient of linear expansion of brass is greater than that of copper i.e.  B   C .
LB  L0 1   B T  R  d 

 L0 1   B T 

Again LC  L0 1   C T   R


 R  d  
1   B T
R 1   C T

Rd
Or  1   B T 1   C T  ,
R
[By binomial expansion]
d 2
Or 1   1   B   C  T   B C  T 
R

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 Sri Chaitanya IIT Academy 03-12-2023_Jr.C-120_Jee-Adv(2021-P2)_WTA-22_Key & Sol’s
d d
Or   B   C  T or R 
R  B   C  T
1 1
 R and R
T  B  C
4. Due to volume expansion of both mercury and flask the change in volume of mercury
relative to flask is given by
V  V0  L   g  

 V  m  3 g  

 50 180  106  3  9  106   38  18   0.153cc

5. Thermal stress (F/A) = YαΔT

Thermal force (F) = YAαΔT FαA
Strain = Δl/l
Thermal energy due to elasticity = ½ (YαΔT)x(αΔT)x(Al)
6. VV  VL  Constant
So VV  VL
 V VV T   L VL T
 V VV   L VL
 V VL

 L VV
We know
VV  VL
 L  V
 Option A and D are correct
7. l1  l0 1   t 

2  6
 l0 1   t 
2
2  5.98
 l0 1  20 
2

6

1 t

1  17  106 t 
5.98 1  20 1  20  17  106
 t  216.80 C  2170 C

8. Tensile stress  Y

 11 1010  17  106   217  20 

 3.68 108 N / m 2

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 Sri Chaitanya IIT Academy 03-12-2023_Jr.C-120_Jee-Adv(2021-P2)_WTA-22_Key & Sol’s
9. Fully prevented to expands stress = Y   
2  1011  15  106  30   15  60 105  900 105  9  107
10. Permitted to expand partially
enet  emax  eallowed emax  L0     0.9mm ; eallowed  0.4 mm
'
 
enet  not allowed   0.5 mm  e '  stress  Y  e 7
  5  10 Nm
2

L
 0
mg 4mg 4 7 
11. p0  ......... 1 p1  .........  2  p2  p1  p0  p0  p0  p0  
A 3  A 3 3
7p 6 V 6 1
Solving the above equations 2 p0 Vinitial   0 V final V final  Vinitial final  1   1 
3 7 Vinitial 7 7
Gas gets compressed
mg mg  g  2 mg 2
12. p0  ........ 1 p1 
g   p0 ........  2 
A A  3 3 A 3
2 5
p2  p1  p0  p0  p0  p0 ........  3
3 3
5
Solving the above equations 2 p0 Vinitial   p0V final
3
6 V final 6  V final  6 1
V final  Vinitial    1   1 
5 Vinitial 5 Vinitial  5 5
Gas gets expand

13. l11T  l2 2T  T  l11  l2 2 

Fl1
Decrease in length of first rod 
Y1 A
Fl2
Decrease in length of second rod 
Y2 A
F  l1 l2 
Decrease in length due to F    
A  Y1 Y2 
 
l l   A 1   2  t y1 y2
F  AT  1 1 2 2  
 l1  l2  y1  y2
 Y Y 
 1 2 
14. Length of the rod = original length +(increase in length due to temperature) – decrease in
Fl2
length due to force = l 1   2t  
Ay2
l 0.1 l 0.08
15. 1   1  2  105 / 0C  2    2  1 105 / 0C 1 :  2  2 :1
l t 50  100 l t 80  100
16. x  10 cm
1 2
x y

Case(iii) For composite rod x  y 3  50cm ....1

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 Sri Chaitanya IIT Academy 03-12-2023_Jr.C-120_Jee-Adv(2021-P2)_WTA-22_Key & Sol’s
Also ez  ex  ey .... 2a   0.03   x 1   y  2  50 ..... 2b 
Solving (1) and (2) x  10 cm; y  40 cm
l
17. Stress  Y  strain  Y 
l
lT
Y   YT l  lT 
l
Compressive Tension = Stress  Area of cross section
 YAT  2  1011 10 5  100  0   2  104 N
1 100
R a  a  a  R
100 101
 R   a  3
18. 100
R   R  3
101

 R
303
19. Let T be the temperature at which the clock is correct. Time lost per day = ½  (rise in
temperature)  86400

 12  1/ 2   40  T   86400 ………….(i)

Time gained per day  1/ 2  (drop in temperature) 86400

 4  1/ 2 T  20   86400 …………..(ii)
equation 1 12 40  T
 
equation  2  4 T  20

T  250 C

CHEMISTRY
20.

21. -CH3 group is a ring activating and ortho and para director.
22. AROMATIC compound should have cyclic planar and (4n+2)π electron system.
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 Sri Chaitanya IIT Academy 03-12-2023_Jr.C-120_Jee-Adv(2021-P2)_WTA-22_Key & Sol’s
23. Na+O2→Na2O2 and Na2O
24. Aluminium and Zinc are amphoteric metals

25. Cl2→NaOClCl2→NaClO3
26. X = +3;Y = +5
27. 2 mole of hydrogen is liberated
28. 2LIHCO3  
 Li2CO3+CO2+H2O
29. CS [RN]7S1 Y=7X=1
30. CONCEPTUAL
31. X = 12 Y = 18
32. HNO3 IS PROTONATED AND IS BRONSTED BASE
33. STABILITY ORDER : M-XYLENE > P-XYLENE > O- XYLENE
Δ
(A) Li  O 2  N 2  Li3 N B
H2 O
34. Li3 N  C LiOH  NH 3 GaS d 
NH 3  
Nessler 's reagent
 (Brown ppt)
(A) Li  O 2  N 2  H 2O   (B)
Air (heat )

35. Li3 N H

O 2
C LiOH  d GaS 
NH 3  
Nessler 's reagent
 (Brown ppt)
36.
BENZENE MOLECULE IS HAVING TWO DEGENERATE ORBITALS. EACH ORBITAL OCCUPIES TWO ELECTRONS.
37. Non metals P4 , S , Cl2 and Br2 ‘F’ exhibits only one OS
38.

MATHEMATICS
39. AC  a  b
AC  a  b
2 2
AC  a  b
2 2
 a  b  2a.b
D
C

b
A B
a

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 Sri Chaitanya IIT Academy 03-12-2023_Jr.C-120_Jee-Adv(2021-P2)_WTA-22_Key & Sol’s
| a  b || a  2b |
S.O.B.S
| a |  | b | 2(a  b ) | a |2 4 | b |2 4(a  b )
2 2

6(a  b )  3 | b |2
| b |2
a b 
40. 2
1
Also a  b 
| b |2 2
| b |2 2 1
  1
2 | b |2 2
 2 1
 either b  a  o  or  1  a.b  1

Either b  a  or  a.b  0  either     or   
2
4
41. Let b  xi  y j, sin a a is perpendicular to b so 4 x  3 y  0 thus b  x  i  J 
 3 
Let c  4i  v j be the required vector
c.a
But  1  4u  3V  5
a
c.a
 2  3u  4V  10
b
Solving these two equation we have
2 11
u  2 and v  1  or  u  and v 
5 5
42. Let a  a1i  a2 j  a3 k , b  b1i  b2 j  b3 k a  b  i  3 j  4k
i j k
 
a  a  b  a1 a2 a3   4a2  3a3  i   a3  4a1  j   3a1  a2  k
1 3 4
So 4a2  3a3  2, a3  4a1  2,  3a1  a2  1
3 2 2k
Solving there equations a3  k1 a2  , a1  K R
4 k
b1  1  a1  2  k , b2  3  a2  10  3k , b3  4a3  4  k
4 4
 2 k  3 2 2  k 10  3k
a i   k k; b  i j  4  k k
 4  4 4 4
 0 c3 c2   1   3  c1 
43. c 0  c1  b2    1  c2 
 3    
 c2 c1 0   b3   1  c3 
b2c3  b3c2  3  c1 ........1
c  c1b3  1  c2 ............. 2
3

c  c1b2  1  c3 ............. 3
2

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 Sri Chaitanya IIT Academy 03-12-2023_Jr.C-120_Jee-Adv(2021-P2)_WTA-22_Key & Sol’s
Applying 1 i   2  j   3 k , we get
 b c  c  a
 
b b  c  b. c  a   0  b.c  b.a
.

b.c  0  a  c  0 

 c. b  c  c. c  a
.   
2 2
0  c  c.a  c.a  c
2 2
b  c  c  a 
2 2 2 2
b c  c  a  2c.a
2 2 2 2
b c  c  11  2 c
2 11
c  2
 c  11
b 1
Given that a.b  0 b2  b3  3  0  b3  b2  3
Also b2b3  0
2 2
Now b  1  b22  b32  1   b3  b2   2b2b3  10  2b2b3
2
 b  10  b  10
1 
44. OB  OC 
2
OB  OB   OA  OA  OB
2
   
Since OA . OB  0  OA  OB
  
 OB  OC 
2
OA  OB 
2
OA OB sin
2
 
9 
  .3.3.1    1    0 
2 2
OB  OA 1
OC 
2
 i  4 j  k
2
 
OC.OA 3
a) Projection of OC on OA  
OA 2
1 9
b) Area of all OAB  OA  OB 
2 2
1 9
c) Area of all ABC  AB  AC 
2 2

d) cos 
 OA  OC  .OA  OC   18
 

OA  OC OA  OC 3 2 90 3

45-46. Let r  xi  y j  x 2  y 2  8 x  10 y  40  0
c   4,5  , r  1
p1  max  x  2 2   y  32 ;  2
p2  min  x  2    y  3
2

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 Sri Chaitanya IIT Academy 03-12-2023_Jr.C-120_Jee-Adv(2021-P2)_WTA-22_Key & Sol’s
Let P be (-2 3)
2 2
Then cp  2, r  1,  p2   2 2  1 , p1   2 2  1
p1  p2  18
 a.b  b  41 2i  3 j  6k
47-48. a1  2
49
 
b

 a .c  c 
1 943
a2  2
 49 
2  2i  3 j  6k 
c
2
 49 a2  7
943
41
a1.b  .49  41
40
49-50. a  2, a  2 & c  a  b  c a sin   b
3 2 2 2
 c  cos ce Consider c  a  c  a  2  a  c 
2
 9 cos ce2  4  2.2. 3 cos ce cos  25  9 cot 2   6cot 
4 2 4 4
2

 25   3 cot   2  9 3
c  a  and least possible when
4
4 2  4 2
 c a  1 3 3  3 3 3 3
cot   2 tan      tan 1   c  cos ce 2 c   5
  2 4  4 2 sin  3
5
51-52. The angle between the line and the plane is
 11  11  11  1 1
 cos 1   cos 1    sin 1  
2 3. 3 2 3  3
Solving two equation we get r  i
3
53-54. ADCB is rhombus ABC  ADC 
5
OA  AE  1, & DC  CD  1, DCD, EAD all isosceles
In triangle OCD

1  2cos
OC OD 1 1 5  AD
  OD   OE AD  OA  OD  1  
2   2cos  BC
sin sin 2cos 2cos
5 5 5 5

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 Sri Chaitanya IIT Academy 03-12-2023_Jr.C-120_Jee-Adv(2021-P2)_WTA-22_Key & Sol’s
A
B

2
O
E 5
2 C
2 5
5

EC 1 D
And 
AD 2cos 
5
55.  
r b  c b  r  c b  o  r  c  b .1
 
 c.a  c.a 
r.a  0  c   b  .a  0  c.a. b.a   0 .  Sub in (1) r  c  
 b.a 
b
 b.a   

r.b  c.b  c.a b r.b  c.b  c.a b

2 2

b.a b.a
9  r.b   81
56. Given a  b  1 a.b  0 and c  2


c  xa  yb  a  b 
c.a  x a cos   2cos   x  2cos 
c.v  2cos   y  2 cos 
2 2
c  c.c   2 cos   a   2cos   b  a  b  
2
4  4cos 2   4cos 2   a  b
4  8cos 2   1  8cos 2   3
16cos2   6
57. The unit vectors in the diction of the given vector an
6i  2 j  3k 6i  2 j  3k 3i  2 j  6k 2i  3 j  6k
 , ,
2
b 2 32 2 7 7 7
Since forces F1 , F2 & F3 of magnitudes 53 units

F1 

5 6i  2 j  3k  , 33i  2 j  6k  , 1 2i  3 j  6k 
7 7 7
 Work done   F1  F2  F2  . AB  33 units

Sec : Jr.C-120 Page 10