Narayana IIT Academy 30-08-15_Sr.

IIT-IZ-CO-SPARK_JEE-ADV_(2012_P1)_CTA-1_Key&Sol’s

NARAYANA IIT ACADEMY

INDIA
Sec: Sr. IIT-IZ-CO-SPARK JEE–ADVANCE Date: 30-08-15
Time: 3 Hours 2012-P1-Model Max Marks: 210
PAPER-I
KEY & SOLUTIONS

PHYSICS
1 C 2 C 3 C 4 B 5 D 6 C

7 C 8 D 9 D 10 C 11 BC 12 AC

13 ABCD 14 ABCD 15 AC 16 8 17 2 18 4

19 2 20 5

CHEMISTRY
21 D 22 D 23 B 24 C 25 B 26 D

27 C 28 C 29 A 30 B 31 A 32 ABD

33 B 34 BC 35 ABC 36 8 37 8 38 5

39 5 40 3

MATHS
41 D 42 A 43 C 44 A 45 A 46 D

47 A 48 B 49 D 50 B 51 ABC 52 ABCD

53 AB 54 ABC 55 BC 56 5 57 4 58 2

59 1 60 7

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PHYSICS
1.
Solution tension in both springs becoems zero and A,B,C,D,E all are in free fall under
gravity.
2. For every set of collisions, two blocks will fly off hence number of collisions = n + n –
1 + ……….. = (n)(n+1)/2
3. sol. (c)
Pitch 1 mm
Least count = =  0.01 mm  0.001 cm
Number of divisions on circular scale 100
Zero error = – 0.03 mm
Measurement = 3.76 – (– 0.03) = 3.79 mm

4. sol. (b)
9
Least court (LC) =1 MSD – 1VSD = 0.05mm – (0.05) mm = 0.005 cm
10
Reading of scale = Diameter = MSR + n ( Least count) – zero error
= [ 1.8 + 6 × (0.005) – 4×(0.005)] cm
D = 1.81 cm
5. Sol. (D)

T  mg sin 37 0  mg cos 37 0

3 4
 20   0.2  20 
5 5
 12  3.2  15.2 N
F  T    2  4 g
 15.2  12  27.2 N

6. Initially ball will be in contact to inner and finally it will be in contact to outer surface
2
after covering cos   .
3

7. Sol. (c)

R v
u


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Narayana IIT Academy 30-08-15_Sr.IIT-IZ-CO-SPARK_JEE-ADV_(2012_P1)_CTA-1_Key&Sol’s
u sin   v
The horizontal acceleration of the small mass and the block is zero, when they lose
mu 2 cos 
contact  mg cos  sin 


mu 2
 mg cos 

 u  g sin 
v  sin  g sin 
8.
Sol. (D)

d 4
 sin 53 
7.5 5
4 75
d   6m
5 10
9.
 

v dt  (u  at ) dt u v
0 0
Sol.  v  
 
 2
 dt
0
v u
Where  
a

1 2
 2 · (u  at ) dt
1
 KE   0

 (u 2  v 2  uv )
6
 dt
0
 (A, D)
10. Ans C
Speed of m just before string become light = 2g  2h
Let IT be the impulse due to tension on both block
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Narayana IIT Academy 30-08-15_Sr.IIT-IZ-CO-SPARK_JEE-ADV_(2012_P1)_CTA-1_Key&Sol’s
IT  m  4gh  v 
I T  MV

m2 gh
 v
mM
11. B,C
Sol. 200 – kx = 20a1
and kx = 10(12) = 120
 200 – 120 = 20a1
80
 a   4 m/s2
1
20
12.
13. sol. ABCD
Particle will change its direction at t = T. Slope is constant so, acceleration will be
constant.
Total area of graph is zero
v

T
O
2T t

14. Ans ABCD

u
u cm 
3
 No external force working on system so u cm will be constant .

No external impulsive force acts for system of A&P, hence their combined velocity
just after collision,
u
u'
2
mu mu
Final linear momentum =   m B u 'B  mu
2 2
u 'B  0

15. Sol. (A, C)

Here the component of momentum along the surface remains constant, it means these
is no component of impulse along the surface. So impulse is acting along the  ve y-
 
axis j  P t  P i  50 N  S along  ve y-axis
15cos 53 9
e 

20cos 37 16
16. Main scale reading is 7 vernier constant = mSD – vSD = 0.06 mm
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0.62  n1 V .C  n2 mSD , where n2 can be 0, 1 or 2
0.62  n1  0.06  n2
Solution of above equation is n2  1,n1  27
The corresponding main scale readings will be, m  n1  n2  33
17. sol. 2
d va


h
d va


V2  2ad
mv 2
 dm  gh 
2
m m
dgh  2ad
 2
g4R 2g
 a  gh /   
2 R 
18. Ans 4
SOL (1) a=gtan
N= mgcos +masin  = mg sec
(11) a=0, N= mgcos
ratio= sec2  =4
19. Ans. 2
Sol. The situation is shown clearly in figure.
From constraint equation
x  y  x 2  (  )2 = constant
dx dy 1 dx
   2x 0
dt dt 2 x  
2 2 dt

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Narayana IIT Academy 30-08-15_Sr.IIT-IZ-CO-SPARK_JEE-ADV_(2012_P1)_CTA-1_Key&Sol’s

y l
m1
x

dx
is the velocity of m2 towards left and is –ve as x is decreasing with
dt

time
dy
is the velocity of m2 in vertical downward direction and is +ve as y is
dt

increasing with time.

v
v+3+ =0
2

 v = –2 m/s.

20. sol. (5)

u
ux 
2
vx  v sin 45
v y  v cos 45 
u qE
 v sin 45   t
2 m
u
v cos 45   gt
2
q
10  E
m
E = 5N/C

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CHEMISTRY
21.
+
N2 OH
HO OH
NaOH
+ N
N
OH
SO3H SO3Na
22.

Figure 1

Figure 2
Fluorine tdisplays very little selectivity because the transition states for the two
competing processes are reached very early, their energies and structures are
similar to each other, as well as similar to those of the starting material (Figure
1).Conversely, bromination of the same compound is highly selective, giving the
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tertiary bromide almost exclusively. Hydrogen abstractions by bromine have late
transition states in which extensive C – H bond breaking and H – Br bond
making have occurred. Thus, their respective structures and energies resemble
those of the corresponding radical products. As a result, the activation barriers
for the reaction of bromine with primary and tertiary hydrogens, respectively,
will differ by almost as much as the difference in stability between the radicals.
(Figure 2)

23.
CH 3 H 3C H H CH 3

H2/Ni

H 2C CH3 H 3C CH 3 H 3C CH 3
(R)-limonene achiral and are d iastereom ers

H 2 (1 equiv)/Ni

CH 3

H 3C CH3
chiral but only one isomer results

24.
COOPh
1
2 COCH3
5
3 4
phenyl 2-acetylcyclopent-3-ene-1-carboxylate
25. (B) is the least significant contributing structure, as it is against the +R effect of
OCH3 group.
26. There is no reaction as OH group is poor leaving group.

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Narayana IIT Academy 30-08-15_Sr.IIT-IZ-CO-SPARK_JEE-ADV_(2012_P1)_CTA-1_Key&Sol’s
27.
CH3 CH3
CH3
+

+
O MeO
BF3 MeO
MeO H

CH3
CH3

+
+

MeO
MeO
CH3

etc

MeO
28. Potassium phenoxide is carboxylated regioselectively in the para position by
CO2.
OH OH OCOCH 3

(i) CO2/KOH Ac2O

+
(ii) H3O

COOH COOH
29. Both [A] & [B] are formed in reaction 1 as both the carbon atoms are secondary.
In reaction 2, ONLY Markownikov’s product is formed.
30. Overall stereochemistry of HBO is Syn which leads to the formation [Q].
31. A is the only one which satisfies all the conditions given in the question. B
decolourizes acidified dichromate. (C) gives two moles of iodoform and (D)
gives two products in ozonolysis of one of the exocyclic alkenes formed and
does not give idoform with the endo cyclic alkene (considering both possible
alkene as there may not be much difference in stabilities of them)
32. (A), (B) & (D) involve SNAr. Replacement of second F in (D) also takes place
by the same mechanism which is aided by many –I groups in the ring. (C)
follows benzyne mechanism which should give meta product as the major
product.

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Narayana IIT Academy 30-08-15_Sr.IIT-IZ-CO-SPARK_JEE-ADV_(2012_P1)_CTA-1_Key&Sol’s
Cl NEt2

NEt2
LiNEt2
+
Et2NH

CH3 CH3 CH3

major
33. As both are secondary alcohols, only iodoform test can distinguish them. Pentan-
2-ol gives iodoform while pentan-3-ol doesn’t.
34. There is an equilibrium between various secondary carbocations which leads to
the formation of a mixture of different Linear Alkylated Benzenes (LAB), 2-, 3-,
4-, 5- &6-phenyl dodecane.
HF +
H3C H3C
CH2 CH3

H3C
CH 3
+

+
H3C
CH3

H3C
CH3
+

+
H3C
CH3

35. (A) undergoes E2 as the main reaction.

(B) can notundergoe SN
(C) is unreactive towards SN2 and undergoes E1.
36. Fullerene, C60 has 12 pentagonal faces and 20 hexagonal faces.
37.
CH 3
H 3C CH 3 CH 3 CH 3 CH 3
CH 3

CH 3
CH 3
cis & trans cis & trans cis & trans
38.
NO 2 Cl CCl3 CN

39. (a), (c), (f), (g) and (h). Rest four reactions give substitution products as the main
products.
40. Cellulose is a polymer of β-D-glucose. Only three OH group will be present per
unit of glucose in the polymer. This leads to the formation of triacetate.
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MATHS
41. As line passes through the point of intersection of x  2y  2  0 and 2x  by  6  0
It can be represented as   x  2y  2    2x  by  6   0
As it passes through the origin
2   6  0

  3

 equation of the line is  x   6  b  y  0

1
Its slope is
6b

As its angle with y = 0 is less than
4
1
1  1
6b
 6  b  1 or  1  b  5 or b  7

But b4 (as the lines intersect)

 b   , 4    4,5    7,  

42. Clearly circumcentre of triangle ABQ will lie on perpendicular bisector of line
AB , which is 6 x  8 y  7  0

43. Q is (-1, 0)
The circle with centre at Q and variable radius r has the equation
 x  12  y 2  r 2
This circle meets the line segment QP at S where QS = r
 r2  2 r 
It meets the circle x 2  y2  1 at R  , 4  r 2  found by solving the equations
 2 2 

of the two circles simultaneously.

A = area of the triangle QSR

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1
 QS  RT
2
1 r 
 r 4  r2  since RT is the y coordinate of R
2 2 

dA 1  2
  2r 4  r   
 
2
r 2   r   2r 4  r  4
3


 
8r  3r 3
dr 4  4  r 2  4 4  r2 4 4  r2

dA 8
0 when r 8  3r 2   0 giving r 
dr 3

  r 4
d 2A
4 4r 2
8  9r   8r  3r 
2 3

4  r2 , 8 d 2A
 where, r  , 0
dr 2 16  4  r 
2 3 dr 2

8
Hence A is maximum when r = and the maximum area =
3

8 8 16 4 4 3
4   
43 3 12 3 3 3 9

44.  6  rcos ,8  r sin  lies on 2x 2  y2  2

  2cos2   sin 2   r 2  2 12cos   8sin  r  134  0

AB, AP, AC are in H.P  

2 AB  AC 1
 
 6cos   4sin    6x  4y  1  0
r AB.AC r 67
1
Minimum distance from 'O' 
52

45. Line of shortest distance is normal for both parabola and circle
Centre of circle is  2,1
Equation of normal to circle is y  1  m  x  2   y  mx  1  2m  1

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Equation of normal for a parabola is y  mx  2am  am3  3
Comparing (A) and (B)
am3  1  m3  1  m  1  a  1
Equation is y 1  x  2  x  y  3

46. x 2  y 2  1; x 2  2 y 2  4

Let R ( x1 , y1 ) is pt of intersection of tangents drawn at P,Q to ellipse

 PQ is chord of contact of R ( x1 , y1 )

 xx1  2 yy1  4  0

This touches circle  r 2 ( 2  m 2 )  n 2

 1( x12  4 y12 )  16

3
 x 2  4 y 2  16 is ellipse e ; LL1  2
2

47. r  S
S

1 ae  b  a 2e 2  b 2
 ae  b 
2 2
5
ae  6  6b  6  b  36  b 2  b 
2
25 25 13
 a 2 1  e 2    a 2  36  a 
4 4 2

48. OMPN is rectangle.

Y
P
N

O M x

 c
P   Ct , 
 t

 ct c  c2
Mid point =  ,    x, y   xy  e  2
 2 2t  4

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49. z2  iz1  z1  z 2  z 2 , iz1 , 0 are collinear.
 arg  iz1  arg z2 

 arg i  arg z1  arg z2


 arg z 2  arg z1 
2
z2  iz1
z3 
l i

l  i  z3  z2  iz1
z3  z2  i  z3  z1 

z3  z2 z z  
 i  arg  3 2   and z3  z 2  z3  z1
z3  z1  z3  z1  2
2 2 2
 AB=BC,  AB  AC  BC

25  2AC 2
5
 AC 
2
1 5 5 25
Required area=    sq. units
2 2 2 4

50.
P  2cos  , 2sin   , Q  2 cos  ,  2sin  
2 cos   2sin   1 2cos   2sin   1
 
2
2
4  cos   sin    1 7
 
2 2

51. Radius = 16  81  93  2
CP  20; AP  20  2; BP  20  2

AP  BP
 CP   A is correct
2

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2 2 1
Now, let L  PR   PC   r 2  20  4  4  PQ; tan   
4 2

PS  2  8
Also cos    PS  PR cos   4.  
PR  5 5

Harmonic Mean between PA and PB =

2  20  2  20  2  16

8
 PS  C is
2 20 2 5 5

correct
 8 
Hence  PS PC   
 5
  
20  16   PR 
2

 PR is the Geometric Mean of PS and PC  B is correct

 1
Now angle between the two tangents is 2 , then  As tan   
 2

 1 
2. 
1
1  1   4
2 tan    tan  2   tan 1    D is incorrect
 2 1  3
 1 
 4
2at1 2t
52. Slope of AS = 2
 2 1
t1  a t1  1

2 a ( t3  t 2 )
Slope of BC = = 2
a (t32  t22 ) t3  t2

2t1 2
 2
  1
t  1 t3  t 2
1

4t1  t3t12  t12 t 2  t3  t 2

 yt. t1  0  t3  t2  0 . C) is correct.
t12 ( t 2  t3 )  4 t1  t3  t 2

lly, t 22 (t1  t3 )  4 t 2  t1  t 3

(-) t12 t 2  t12 t 3  t 22 t1  t 22 t 3  4(t1  t 2 )  t 2  t1

t1t 2 (t1  t 2 )  t3 (t12  t 22 )   5(t 2  t1 )

t1t2  t3 (t1  t2 )  5

  t1t2  5  A) is true.
Now t12 ( t 2  t3 )  4 t1  t3  t 2

t1 (t1t2  t3t1 )  4t1  t2  t3

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t1 (5  t2t3 )  4t1  t2  t3

t1t2t3  t1  t2  t3

t1t2t3  t1  t2  t3

1 1 1
    1 B) is correct
t1t2 t2t3 t3t1

53. P(-1,B) and Q(-2,C)

Hence image of point P from lie 2x + 3y + 9 = 0
x 1 y  2  2  6  9 
  2  
2 3  13 

X = -5 ; y = -4
P  (5, 4)

58
Now length of PQ  9  49  58  2a a
2

We know that, 2ae = PQ

1 1
2 ae  2  ae   a 2e2 
2 2

b2  a 2 (1  e2 )

58 1 58  2 56
b2    b2   b2   b  14
4 2 4 4

b2  14 length of minor axis  2 14  56

Equation of line PQ is
43
( y  3)  ( x  2)
3

3y – 9 = 72 + 14
7x – 3y + 23 = 0
On solving 7x – 3y + 23 = 0 and 2x + 3y + 9 = 0 we get
 32 17 
A   , 
 9 27 

54.
And  
Re z1 z2  0  Re  a  ib  c  id   0  ac  bd  0.....  2  a

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Narayana IIT Academy 30-08-15_Sr.IIT-IZ-CO-SPARK_JEE-ADV_(2012_P1)_CTA-1_Key&Sol’s

Now from (A) and (B),

Also

[From (A) and (D)]

And [From (A) and (D)]

Further [From (B) & (D)]

Also and
z1  z2 a
55. Let z1, z2 be two points on the given line then   1
z1  z2 a

z1  z2 zc
Also  i   2
z1  z2 zc

z c z c
From (A) and (B) i 0
a a
z1  z0  z2  z0  z3  z0  
56.
z3  z0 ei 7 /11
 i /4  ei17/44
z2  z0 e

 
 BSC  17  BAC  17
44 88
z 2  z0 
Similarly  e i / 4  ACB 
z1  z0 8

 17 15
 ABC      .
8 88 22

57.

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Narayana IIT Academy 30-08-15_Sr.IIT-IZ-CO-SPARK_JEE-ADV_(2012_P1)_CTA-1_Key&Sol’s
This is possible only when N  4r  2 and 2n  2 is multiple of 3 i.e.,
2  4r  2   2 is multiply of 3
i.e., 8r  2 is multiple of 3 r  2

58.
D C(1, 1)
2

(0, 1)  45°
1
Q(1, y)

A P B(1, 0)
(0, 0) (x, 0)

tan 1 = x and tan 2  1  y

Since, 1  2 =45°

tan 1  tan 2
 =1
1  tan 1 tan 2


x  (1  y)
=1  y  2x …(i)
1  x(1  y) 1 x

Now, Perimeter= 1  x  y  (1  x) 2  y 2

By using (i), we get

Perimeter=2
59. Equation of chord of circle with mid point (h, k) is xh + xk = h2 + k2 or
 h  h 2  k2
y   x  , it touches the hyperbola
 k  k

60.

sol :
sin a  5  1  P  2 5  15

Integral value of P = 7

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