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CHEMISTRY
31 32 33 34 35 36 37 38 39 40
D D C A A C C A C D
41 42 43 44 45 46 47 48 49 50
D B B B B B C B B C
51 52 53 54 55 56 57 58 59 60
12 4 6 3 4 33600 2 3 3 9
MATHEMATICS
61 62 63 64 65 66 67 68 69 70
B C B B C C C A B C
71 72 73 74 75 76 77 78 79 80
D B B D B B D C A D
81 82 83 84 85 86 87 88 89 90
2 2 48 0 2 18 14 2454 4 7
IIT_IC & IR Rev_01 M, Ex Dt: 19.02.2024
Solutions
PHYSICS
1. (D)
Sol.
5. (A)
Sol.
2. (A)
Sol.
3. (B)
Sol.
6. (D)
Sol.
7. (D)
Sol. If we give the following inputs to A and B,
4. (C)
then corresponding output is shown in table
Sol.
2
IIT_IC & IR Rev_01 M, Ex Dt: 19.02.2024
The above table is similar to OR gate. Sol.
8. (B)
Sol. From the equation, v iˆ 2 ˆj
x t 13. (D)
1
y 2t 10t 2
2
So
∴ y 2 x 5x2
9. (B)
Sol. From the given data, least count of
measuring instrument 0.1s Mean value of
time for 20 oscillations is given by
t t t
t 1 2 3 39.7 s
3
Absolute errors in the measurements
∆t1 = t – t1 = 39.7 – 39.6 = 0.1 s;
∆t2 = t – t2 = 39.7 – 39.2 = –0.2 s
∆t3 = t – t3 = 39.7 – 39.5 = 0.2 s
∴ Mean absolute error 14. (D)
t t2 t2 0.1 0.2 0.2 Sol.
= 1 0.17
3 3
0.2 (Rounding off up to one decimal
place) Accuracy of measurement 0.2s
10. (D)
Sol.
15. (C)
Sol. As, V
GM
2 R3
3R2 r 2
Graph (C) most closely depicts the correct
variation of V(r).
16. (A)
Sol. Work done is equal to area under the curve
11. (B) on PV diagram.
Sol. Hence, from the diagram: W2 > W1 > W3
17. (D)
Sol. Initially and when Sis turned to position 2
charge (q) will remain constant.
12. (D)
2
IIT_IC & IR Rev_01 M, Ex Dt: 19.02.2024
22. (8)
Sol.
18. (A)
Sol.
19. (C)
Sol.
23. (25)
Sol.
Momentum conservation
20. (C)
Sol.
Angular momentum conservation
21. (2)
Sol.
3
IIT_IC & IR Rev_01 M, Ex Dt: 19.02.2024
25. (9)
Sol. Current passing through the diode ID = I – I1
24. (76)
Sol. V = y3 + 2
26. (2)
Sol. We know that
27. (50)
Sol. Image will coincide with object, if light fall
perpendicularly to mirror. Which is possible
if light converge at C of mirror. In the
absence of mirror, light will be converging
at centre of curvature.
Distance = 12 + 8 + 30 = 50 cm.
28. (250)
Sol. Band width,
R R
2 1 232 212
L L
R
20
L
R 5
L 250 mH
20 20
29. (4)
4
IIT_IC & IR Rev_01 M, Ex Dt: 19.02.2024
Sol. 34. (A)
Sol. Oxymercuration-demercuration reaction.
Stable positive charge forms the product.
35. (A)
Sol. Ketones will not give Tollen’s test.
36. (C)
Sol. Intramolecular hydrogen bonding occurs in
I, while intermolecular hydrogen bonding
30. 60 occurs in II.
Sol. 37. (C)
Sol. Phenolphthaleine is a weak organic acid and
changes colour from colorless to light pink
in basic medium.
38. (A)
Sol. Theoretical.
39. (C)
Sol. Distillation at reduced pressure decreases
the boiling point.
40. (D)
Sol.
CHEMISTRY
31. (D)
41. (D)
Sol. On the basis of electronegativity data (Size
Sol. Initial moles of Cr3+ = 0.25 × 0.2 ⟹ 0.05;
& effective nuclear charge): Cl > S > P > Si
Final moles of Cr3+ = 0.25 × 0.1 ⟹ 0.025;
32. (D) Moles of Cr3+ reduced,
Sol. Wacker process = CuCl2, PdCl2, O2. 0.05 – 0.025 ⟹ 0.025;
t 96.5
∴ eq. of Cr3+ reduced, 0.025 × 3 = ;
33. (C) 96500
Sol. Substitution favoured by less hindered t = 75 sec
nucleophile, elimination favoured by bulkier
base. 42. (B)
Sol. Molarity of H2O2 = 1M
5
IIT_IC & IR Rev_01 M, Ex Dt: 19.02.2024
Gm eq of H2O2 = gm eq of K2Cr2O7 Sol. Conceptual
2×1×2=x×6
51. (12)
2
∴ x = moles Sol. Mn2 , Mn4 , Cr 6 12
3
52. (4)
43. (B)
Sol.
Sol. With increasing size of surrounding atom,
bond angle also increases.
With increasing electronegativity of
surrounding atoms, bond angle decreases.
44. (B)
Sol. For isothermal process
V
W nRT ln 2 49.26 ln 2 34.04
V1
53. (6)
45. (B) Sol. 10 → 4, 9 → 4, 8 → 4, 7 → 4, 6 → 4, 5
Sol. → 4,
2CH 3COOH Ca OH 2
CH 3COO 2 Ca 2 H 2O 54. (3)
CH 3 N C CH 3 NH CH 3
20 10 0 0 LiAlH 4
0 0 10 Sol.
methyl isocyanide
20 1
C 0.1 M pH 7 5 log 0.1 9 CH 3CH 2CH 2 N C
LiAlH 4
CH 3CH 2CH 2 NH CH 3
200 2 propyl isocyanide
and caprolactam.
46. (B) 55. (4)
Ea Sol.
Sol. log K log A
2.303RT Ni Ni 2 2e
2H 2e H 2
47. (C) 2
.059 H
Sol. Double bond is unstable at bridge-head. Ecell E o
log10
Ni 2
cell
2
48. (B) 0.059 2
0 0.236 log10 H
Sol. 2
or log H 4 pH 4
56. (33,600)
Sol.
49. (B) no. of Fe atoms At.wt of Fe
% of Fe 100
Sol. (probability density) can be zero for 3p
2
molecular weight
orbital other than infinite distance. It has one
radial node.
6
IIT_IC & IR Rev_01 M, Ex Dt: 19.02.2024
Sol. NH 4OH NH OH
4
0
u v v w w u 25
1 0
1C C C
64. (B)
pH = 11, [n+] = 10–11 ⟹ [OH]– = 10–3 1 1
Now, Cα = 10–3 ⟹ α = 2% Sol. sin 3x 3x n (1)n
4 8 6
65. (C)
58. (3)
Sol.
Sol. (C) On observation the given points are
collinear. Hence number of parabolas = 0
66. (C)
9 7 5 3 1 5
Sol. Total probability = 11
C3 33
67. (C)
59. (3) Sol.
Sol. Conceptual
60. (9)
Sol.
68. (A)
Sol.
No. of chiral centres = 9
MATHEMATICS
61. (B)
Sol. The general term in binomial expansion of
642
12 1
5 7 6
is given by
642 r r
16
12
Tr 1 642
Cr 5 7
642
Total number = 107 , but first term for 69. (B)
6
3x13 2 x11
r = 0 is also integral. I dx
(2 x 4 3 x 2 1) 4
62. (C)
3x13 2 x11
Sol. Ni = 5Ck × 4C5–k 4
dx
N1 = 5 × 1, N2 = 10 × 4, N3 = 10 × 6, N4 = 5 16
1 3
x 2 2 4
× 4, N5 = 1 x x
∴ N1 + N2 + N3 + N4 + N5 = 126
3 2
3
5
63. (B) I x x
4
dx
Since, u v + w 0 u v + w 0
2 3 1
Sol. 2 2 4
x x
u v w 2 u v v w w u 0
2 2 2
3 1 3 2
Let 2 t , 2 3 5 dx dt
⟹ 9 16 25 2 u v v w w u 0 x 2
x4
x x
7
IIT_IC & IR Rev_01 M, Ex Dt: 19.02.2024
dt
1 t 41
Then, I 2 C
t4 2 4 1
1 1 1
I C
2 (3) 3 1
3
2 2 4
x x t2 2t 1
4 1 5 t 2 t 6
1
1 x 12 Area PXQ 4
I C 2
6 (2 x 3x 2 1)3
4 9 6 1
70. (C)
5 x2
1 2 25
Sol. Let, I x e dx 5 t
2 4
Put x 2 t 2 x dx dt
1
2
I x 4 .x.e x dx For maximum area, t
2
et t 2 dt 1 t 2
I e (t 2t 2) C 25 125
(2) 2 Maximum area = 5
4 4
1 4 5
g ( x) ( x 2 x2 2) g (1) 73. (B)
2 2
Sol. Common chord of the given two circles s = 0 &
71. (D)
s ' 0 is s s ' 0
dy y x2 y2 y x2 y2
Sol. 2 1
dx x y 2 x x x 3x y 2 0 ; vertex (0, 0) given
Putting y = vx
“Z” is foot of perpendicular of A(0, 0) on the
dy dv
v x directrix
dx dx
dv x2 v 2 x2 3 1
v x v Z , . Since A is midpoint of SZ; focus
dx x 5 5
v x 1 v 2
dv
v x 3 1
dx S ,
dv 5 5
dx
1 v2 74. (D)
dv
dx c
1 v2
Sol. P = :sin cos 2 cos ,
1
tan v x c
y
1
Q = :sin cos 2 sin
tan x c
72. (B)
x ⟹ sin
2 1 cos
tan 2 1
Parametric equation of the parabola y 2 4 x are
x t 2 and y 2t
Now, Q = : sin cos 2 sin
⟹ sin
2 1 cos
8
IIT_IC & IR Rev_01 M, Ex Dt: 19.02.2024
1 2 1 Now, shortest distance between
tan
2 1 2 1
Hence, P = Q x 1 y 2 z 3 x 2 y 4 z 5
L1 and L2
75. (B) 2 3 4 3 4 5
Sol. Given that, z i
Shortest distance =
and z 2 z 4 1 i
i 2 i 4 4i d
iˆ 2 ˆj kˆ iˆ 2 ˆj 2kˆ
1
1 4 1 6
2 4 i 4
2 2
78. (C)
On comparing real and imaginary parts, we Sol.
get Given function:
40 4
log10 x3 x
1
f x
4 x 2
2 2 4
2
and
For domain of f x
2 4 20 2 16 8
4 – x2 ≠ 0
1, 4, 3, 4
x 2 (i)
Hence, equation is
And x3 x 0
x 3 4 x 3 4 0
2
⟹ x x 1 x 1 0
x 7 x 12 0
2
Sol.
2
1
Required area is 2 x 2 dx =
0
1 x 2
2 x 1, 0 1, (ii)
sq unit
3
From (i) & (ii), we get the domain of f x as
77. (D)
1, 0 1, 2 2,
Sol. Direction ratio of line
79. (A)
Let P(4, 3, 8), Q(3, 5, 7)
Sol.
Now, direction ratio of PQ = –1, 2, –1
1
In B put t =
∴ PQ L1 z
l 64 0 l2 1
dt dz
Now, point Q (3, 5, 7) satisfies the line L1 z2
a 1 & b 3
9
IIT_IC & IR Rev_01 M, Ex Dt: 19.02.2024
1
sin dz sin
z2 z dz
B 1 1
1 1 z
2
1 2
1
z z
=–A
A A2 B
85. (2)
∴ A B
e e B2 1 Sol. a 1
1 A2 B 2 1 b 2
1 1
A A2 A A 1 A a. f ( x) f bx …(1)
x x
= 1 A2 1 A 1 1
2
1 = 0.
1 1 b
1 2 A2 1 1 2 1 x af f ( x) x …(2)
x x x
From Equation (1) + (2)
80. (D)
1 1
C 30 C 10
4 a f ( x) f f f ( x)
Sol. Required probability = 75 1 75 1 x x
C1 C1 75
1 1
x b x
81. (2) x x
Sol. Conceptual f ( x) f (1/ x) b
2
82. (2)
x
1 a
Sol. x
86. (18)
f(x)
4t
3
Sol. lim 6
dt . Apply L’ Hospital
x 2 x-2
4f 3 x .f ' x
lim dt
x 2 1
83 (48)
Sol. 1
4f 3 2 .f 1 2 4x 63 18
48
87. (14)
4 4
x3 / 2
Sol. 3 x dx 2 3
1
3
Since, x y ∈ I, the only possible case which 4
1
88. (2454)
Sol. Case I: 4 letters are different,
C4 4 P4 1680
8
(i)
Case II: 2 letter are same & 2 are different,
4
P
3
C1 7 C2 2 4 756 (ii)
P2
Case III: 2 letters are same & 2 are same,
84. (0) 4
P4
Sol. 3
C2 2 18 (iii)
P2 2 P2
Total words = 2454
10
IIT_IC & IR Rev_01 M, Ex Dt: 19.02.2024
ellipse E1
89. (4)
Sol. Since both curves are symmetrical about the line P1 and Q1 are images of P,Q w.r.to x – y – 2
y=x =0
=2( distance of t , t 2 1 on the parabola
a 160, b 292
y x 2 1 from y x 0 )
t2 1 t
2 t t 1
2
2
2
3
The minimum value of t 2 t 1
4
3 2
Minimum distance is k 4
4
90. (7)
Sol. Let P(4, 0) & Q(0, 3) are two points on given
11