Sec: SR.

IIT_N-SC/N-C GTM-12 Date: 26-12-19

Time: 3 Hrs Max.Marks: 300
KEY SHEET

PHYSICS
1 C 2 D 3 D 4 D 5 C

6 A 7 B 8 A 9 C 10 D

11 B 12 D 13 B 14 C 15 A

16 D 17 D 18 C 19 B 20 A

21 16 22 –1.54 23 600 24 0.59 25 7.00 to

7.10

CHEMISTRY
26 C 27 B 28 B 29 C 30 B

31 D 32 A 33 B 34 D 35 A

36 D 37 D 38 C 39 C 40 C

41 D 42 A 43 A 44 D 45 A

46 7.38 47 9000 48 11.60 49 2 50 4

MATHS
51 A 52 B 53 A 54 C 55 B

56 C 57 D 58 D 59 C 60 D

61 D 62 C 63 B 64 B 65 D

66 C 67 B 68 C 69 B 70 B

71 7.09 72 1.50 73 0.50 74 2.33 75 1.57

Narayana IIT Academy 26-12-19_Sr.IIT_N-SC&NC_JEE-Main_GTM-12_Key&Sol
SOLUTIONS
PHYSICS
1. Reference NCERT, exemplary problems 7.9
2. Conceptual
3.

4. Ans=d,refer NCERT 2 VOLUME(DIFFRACTIN CHAPTER)

5. Ans=c

According to the question , the observed meniscus of liquid in a capillary tube is of convex upward which is
only possible when angle of contact is obtuse. It is so when one end of the glass capailary tube is immersed
in a trough of mercury. Hence , the combination will be of mercury+glass as shown in fig
Ncert_exaplary-qno8
6.

7.

SR.IIT_N-SC Page. No. 2

Believe you can and you’re halfway there.

Narayana IIT Academy 26-12-19_Sr.IIT_N-SC&NC_JEE-Main_GTM-12_Key&Sol

8.

9.

10. Reference NCERT (ADDITIONAL EXERCISE PROBLEMS)

11.

SR.IIT_N-SC Page. No. 3

Believe you can and you’re halfway there.

Narayana IIT Academy 26-12-19_Sr.IIT_N-SC&NC_JEE-Main_GTM-12_Key&Sol
12. Due to the presence of external positive charge on the face ABCD, the usual expression for pressure
on the basis of KTG will not be valid as ions would also experience electrostatic forces other than the forces
due to collisisons with the walls of the container. Due to presence of positive charge the isotropy is also lost.
Reference NCERT exemplary problem 13.9
13. ans=b

14. ans=c
Refere Ncert exercise problem
15.

16. Reference NCERT exemplary problem no 9.8

17. Reference exemplary problems 19.10

18.

SR.IIT_N-SC Page. No. 4

Believe you can and you’re halfway there.

Narayana IIT Academy 26-12-19_Sr.IIT_N-SC&NC_JEE-Main_GTM-12_Key&Sol

19.

20.

21.

SR.IIT_N-SC Page. No. 5

Believe you can and you’re halfway there.

Narayana IIT Academy 26-12-19_Sr.IIT_N-SC&NC_JEE-Main_GTM-12_Key&Sol

22.

23.

SR.IIT_N-SC Page. No. 6

Believe you can and you’re halfway there.

Narayana IIT Academy 26-12-19_Sr.IIT_N-SC&NC_JEE-Main_GTM-12_Key&Sol

24.

25.

SR.IIT_N-SC Page. No. 7

Believe you can and you’re halfway there.

Narayana IIT Academy 26-12-19_Sr.IIT_N-SC&NC_JEE-Main_GTM-12_Key&Sol

CHEMISTRY
26. G  nFE
0 0
cell

2746  103  26  96500  E  E  1.09V

30. i) ‘C-O’ bonds are equivalent in CO32 due to resonance .
ii) ‘H-S’ bond is stronger than ‘H-Te’ bond.
31. C8 H18  l   12.5O2  g   8CO2  g   9 H 2O  l 
n  8  12.5  4.5  H  U  4.5 RT .
32. A  XeOF4 ; B  XeO2 F2 ; C  XeO3
 2
33. A   Au  CN 2  ; B   Zn  CN 4 
37. Aromaticity
8a a
45. TC   TC
27 Rb b
SR.IIT_N-SC Page. No. 8

Believe you can and you’re halfway there.

Narayana IIT Academy 26-12-19_Sr.IIT_N-SC&NC_JEE-Main_GTM-12_Key&Sol
46.   CRT
 0.6 3.6  1
     0.082  300  7.38atm .
 60 180  0.1
7.3 1
48. N   102
36.5 20
50  0.01  250  N1  N1  2  103
40  2  103  20  N b  N b  4  103
pOH  3  log 4  3  0.6  2.4  pH  14  2.4  11.6 .
49.  5  n  MnO4  5 An   5  n  Mn 2  5 AO3
 5  n   1.2  103  n  2 .
5 2  103
MATHS
Let A  2cos  ,sin   be any point on the ellipse x  4 y  4 …..(1)
2 2
51.

Equation of tangent at A to (1) is x cos   2sin   y  2 …..(2)

2 2
(2) intersects the ellipse x  2 y  6 …..(3)

At P and Q ; Let T(h,k) be the point of intersection of the tangent at P and Q to (3);
then equation of tangents from T to (3) is
x 2 2

 2 y  6 h  2k  6   xh  2ky  6 
2 2
 2

x
2
k 2
3  y  2
h 2
 
 6  2hkxy  6hx  12ky  3 h  2k
2 2
0
2 2
We need to show that h  k  9

Equation of chord of contact of tangents from T to (3) is xh  2ky  6 ….(4)

cos  sin  1 2 2
Since (2) and (4) represent the same line, we have,   ; or h  k  9
h K 3

 x  1 6
52.   lim           1
x  3 
 6     
2
53. Let a  yz ; b  zx ; c  xy

SR.IIT_N-SC Page. No. 9

Believe you can and you’re halfway there.

Narayana IIT Academy 26-12-19_Sr.IIT_N-SC&NC_JEE-Main_GTM-12_Key&Sol
2 2 2
4a  9b  16c  6ab  12bc  8ac
  2a    3b    4c    2a  3b    3b  4c    2a  4c 
2 2 2

 2a  3b  4c
2 3 4
 2 yz  3 zx  4 xy   
x y z
 a 35
54. tan15  2 3a 
a  35 3 1
 a 2 2 70 2
sin15   RS  a
RS 3 1 2
70
RS 
2
55. It is fallacy
 a 2b   a 2a 
56. 3a 4b   3b 4b   a  b
   

57.
x,y
P(8,9)

C(3,4)

 x  3 x  8   y  4  y  9   0
2 2
x  y  11x  13 y  60  0
58. R(0,4,5) & S(3,0,5)
x y z
  ORS is 0 4 5  20 x  15 y  12 z  0
3 0 5
x  6 y  8 z  20
And L :  
3 4 15
And Point of intersection is (6,8,20)
x  x
59. 2e   0    2 xe x  0    0
x
2 2 2
60. Z   1  i   2  Z  Z
Z Z 1 i 1 1
1 1

SR.IIT_N-SC Page. No. 10

Believe you can and you’re halfway there.

Narayana IIT Academy 26-12-19_Sr.IIT_N-SC&NC_JEE-Main_GTM-12_Key&Sol
2
 Z 0  Z   Z : y  x 1
1 1 1 i 1

2 2 2 2
x y 12 1 a a
61. 2
 2
  1  e  1    e  2  1  2
 2
3
E 16 2 H
a b b b
12
 2
And passes through 0,  12  2  1 b  12 & a  36
b
2

2 2
H : 
x
36 12
y
 1 S 0, 4 3  
dx
62. I 
  
4 x 1 3 x  2 5

dx

3/ 4
 x 1 
4
   x  2 2
 x2
4
x 1 4 2t  1 3
Substitute t  x ,x  2 
x2 1 t
4
1 t
4

Now dx 
1  t 8t   2t  1 4t 
4 3 4 3

1  t  4 2

3 7 7 3 3
8t  8t  8t  4t 12t
 dt  dt
1  t  4 2
1  t  4 2

3
12t 1
Then I  . dt
1  t  4 2
t
3 1


1 t
4 2

1/ 4
4 4 4  x 1 
3
 dt  tc   c
3 3 x  2
63.

SR.IIT_N-SC Page. No. 11

Believe you can and you’re halfway there.

Narayana IIT Academy 26-12-19_Sr.IIT_N-SC&NC_JEE-Main_GTM-12_Key&Sol
x+7y=7 y+2x-1

L 0
1
L 0
2

y=1+7x  L : 38 y  41x  38
1
P(0,1)
38
I  
x 41
64.  
 C CCCC
Given CC AAA A 
AAAA
7 8
9
 N  1. C ,6  504
6
1 2 3
65. P 1  ; P  2   ; P  3  ; Rolled 3 times
6 6 6
1 1 2 6
 p  4   1,1,2   3. . . 
6 6 6 216
1 2 3 2 2 2 44
& p  6   1,2,3 or  2,2,2   6. . .  . . 
6 6 6 6 6 6 216
50 25
p   ; p  25& q  108
216 108
2 2
66. Coefficient    144    144    12
3
67. ax  bx  c  0  Roots   ,  , 
2
x  px  1  0  Roots   , 
c c
Here    
a a
3 2
c bc b c 2 2
  a. 3   c  0  1   2  a  ab  c
a a a a
68. Area bounded by curves = 48
 45   45 
Line divides in   :  48    15 : 49
 4   4 
1    
69. Put   sin x   , 
 6 2
1    1    
 f  x   sin  sin  cos  cos sin   sin  sin     
 6 6   6 
1  1 1 4
 f  x   sin x  f ' x    f '  
6 1 x
2 4 15
SR.IIT_N-SC Page. No. 12

Believe you can and you’re halfway there.

Narayana IIT Academy 26-12-19_Sr.IIT_N-SC&NC_JEE-Main_GTM-12_Key&Sol
7  cos 2 x
70.   2  2  sin x    2,6
2  sin x
71. x  15
8 12   10  6   12  2   9  8   5 12 
M .D.   7.09
8  10  12  9  5
72.

a
tower A
l
B

 h
tan 1 h  a
4 a
2
 1 h 1 h
& tan     2 3
6 3 2
l a
2 3 27 .2  h 2
2 3
 h  2916  h  54  36    
2

px
x.e  q sin x 1
73. Clearly   0  L  lim 3

x 0 x 6
1
 3L 
2
x x x
x  f  t dt   tf  t dt  x  x   f  t dt
2 4
74.
0 0 0
x
  f  t dt  x f  x   x f  x   2 x  4 x  f  x 
3

 f  x   2  12 x  f '  x 
2

 f  x   f '  x   2  12 x
2

1 1 12 1 7
 f    f '   2   2    2.33
6 6 36 3 3
75.
SR.IIT_N-SC Page. No. 13

Believe you can and you’re halfway there.

Narayana IIT Academy 26-12-19_Sr.IIT_N-SC&NC_JEE-Main_GTM-12_Key&Sol

S(1,0)

Z:x=-1

2
Z is given by y  4 x


And L: x=y meets at P z   4, 4   t , 2t t  2
1   2

Normal chord at P meets curve again at
Q  t ' Where t '  3  Q  9, 6 
P(4,4)

4
m 
1 3


2

3 Q(9,-6)
S(1,0) m 
2 4

SR.IIT_N-SC Page. No. 14

Believe you can and you’re halfway there.

Narayana IIT Academy 26-12-19_Sr.IIT_N-SC&NC_JEE-Main_GTM-12_Key&Sol

SR.IIT_N-SC Page. No. 15

Believe you can and you’re halfway there.