Sri Chaitanya IIT Academy 04-01-2020_Sr.

Icon All_GTM-12_Key = Sol's

Sri Chaitanya IIT Academy., India.

AP, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant
ICON Central Office , Madhapur – Hyderabad
Sec: Sr.Icon All GTM-12 Date: 04-01-2020

Time: 09.00am to 12.00 Max.Marks:300

Key & Solutions

MATHEMATICS
1 1 2 4 3 2 4 4 5 1
6 4 7 3 8 3 9 2 10 4
11 2 12 1 13 1 14 4 15 1
16 3 17 1 18 2 19 2 20 3
21 0005.33 22 0012.00 23 0004.50 24 0226.00 25 0006.00

PHYSICS
26 2 27 3 28 4 29 2 30 2
31 2 32 1 33 3 34 3 35 2
36 2 37 2 38 1 39 1 40 1
41 1 42 1 43 1 44 1 45 1
46 0027.50 47 0001.73 48 0048.00 49 0001.00 50 0003.33

CHEMISTRY
51 3 52 4 53 4 54 3 55 1
56 2 57 1 58 1 59 2 60 3
61 3 62 1 63 4 64 3 65 1
66 1 67 2 68 2 69 1 70 2
71 0001.51 72 0000.97 73 0004.00 74 0002.00 75 0002.53

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Sri Chaitanya IIT Academy 04-01-2020_Sr.Icon All_GTM-12_Key = Sol's
SOLUTIONS
MATHEMATICS
1 1 1
1. Clearly , ,   will be in A.P
x1 x2 xn
1 1 1 1 1 1
 2         
x x1 x3 x2 xr 1 xr
1 1
     say 
xn xn 1
n 1
1 n 1 1
  xr xr 1    xr  xr 1    x1  xn 
r 1  r 1 
1 1 x x
Now ,    n  1   1 n   n  1 
xn x1 x1 xn
n 1
  xr xr 1   n  1 x1 xn
r 1

2. iz  3  4i  iz  3  4i  z  5  9
3. 3,6,9,   ,12
1, 2, 4,5,   ,119
40C2  80C1  40C1
P  A 
120C2
199

357
4. a  5b  3c  0
Thus a, b, c are coplanar.
Hence a.  b  c   0
10 
5.  sinx dx  9  sinx dx
 0

9  sinx dx=18
0

6. Given x.
dy
 y  y 2 .x 3 .cos x 
 xdy  ydx   x.cos xdx
dx x2 y 2
d  xy  1
 2 2
 x.cos x dx    x sin x  cos x  c
x y xy
2b 2
7. Length of latus rectum 
a

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Sri Chaitanya IIT Academy 04-01-2020_Sr.Icon All_GTM-12_Key = Sol's
2
a
For xy  c 2 , a  b and  c2
2
a2
Required length  2.  2a  2 2c
a
cos x sin x
8. We have 27  81
 33cos x  34 sin x  2. 33cos x.34 sin x
2
 2.3 
1/2 3cos x  4 sin x 
 2.35/ 2 
9 3
9. Clearly, the direction ratios of normal to the plane are 4,  3,  2 .
Thus equation of plane will be 4x  3y  2z  d .
It will necessarily pass though  3, 2, 1
ie., d  12  6  2  20
Thus the equation of plane is
4x  3y  2z  20.
10. Clearly, the given curve intersect for a  R  0
dy 8 dy 4 x
For the parabola,  . For the ellipse, 
dx y dx a 2 y
For the curves to intersect orthogonally,
 8  4 x 
   2   1
 y  a y 
 a 2 y 2  32 x  16a 2 x  32 x  a 2  2
11. We have ax3  bx 2  cx  d  0
ax 4 bx3 cx 2
Let f  x      dx  e
4 3 2
 f  0  e

f  2   4a 
8b
 2c  2d  e 
12a  8b  6c  6d   e
3 3
2
  6a  4b  3c  3d   e  0  f  2   e
3
 By Rolle’s theorem, there exist at least one value of
x   0, 2  such that f '  x   0
 The equation ax3  bx2  cx  d  0 has atleast one real root in [0, 2]
12. log y  ax log 2
1 dy
 a log 2
y dx
dy
 2ax , a log 2
dx

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Sri Chaitanya IIT Academy 04-01-2020_Sr.Icon All_GTM-12_Key = Sol's
dy  a
  2 , a log 2  8log 2
dx  x 1
 2a.a  8;a  2
13. at x  1, 3 we have x  x
 f  x   a log e x  bx 2  x
a
 f ' x    2bx  1
x
According to question, f ' 1  0, f '  3  0
a
 a  2b  1  0,  6b  1  0
3
3 1
On solving, we get a  , b  
4 8
14. p  2e4 ln k  1  31
4
e ln  k   16
k  2
As k  2 , so k  2
Now , sum  5k  5  2  10
15. Common chord is 10 x  4 y  b  a  0 is passes through   4, 4 
40  16  a  b
 a  b  56
1 x 2  25 12 
16. cos  sin 1 
x x 2
x 2  25  12
x 2  169
x  13
17. T3  106
2

x 3. x log10
x

  105  103.10 
2

 x  10
18. Var  X   σ 2
2
a  a
Var  x   2 σ 2
c  c
a b  a2 2
Var  x+   2 σ  0
c c c
2
 aX+b  a 2
Var   2σ
 c  c

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Sri Chaitanya IIT Academy 04-01-2020_Sr.Icon All_GTM-12_Key = Sol's
 aX+b  a
S.D. of   σ
 c  c
19. A  B :  LCM of 4and 3  12  k
A  B = 12k
20. f x  xn 1
 f  2   2n  1
 9  2 n  1  23  2n  n  3
Clearly, f  x   x 3  1
3
f  4    4   1  65
21.
y

O
x
(-2,0)
(2,0)

4 y2  x2  4  x2     i 
1 2 x
y x  4  x2   y   4  x2 
2 2
2
2x
 Area  A   4  
2 2
 4  x 2 dx
0

Put  4  x 2   t  2 xdx  dt
0 4 4
4  t 3/2  2
A  t dt   t dt       64  0 
4 4 0  3 / 2 0 3
16
 A sq.units
3
x2 y 2
22.  1
36 9
 SP+S' P  2a  12
3 1
23. Given cos C   sin C=
1 2
1
Area of triangle  absin C
2
1 1 9
  6  3 
2 2 2
24. Let S1 and S2 refuse to be together

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Sri Chaitanya IIT Academy 04-01-2020_Sr.Icon All_GTM-12_Key = Sol's
And S3 and S4 want to be together only
Total ways when S3 and S4 are selected
 (8C2  2C1.8C1 )  44
Total ways when S3 and S4 are not selected
 (8C4  2C1.8C3 )  182
Total ways  44+182  226
 3 4  3 4  1 0 
25. BC =     BC   I
 2 3   2 3 0 1 
A A
 tr ( A)  tr ( )  tr ( )  ....
2 4
tr ( A)
  2tr ( A)  6
1 1
2

PHYSICS
26. Step 1:



  
Step 2:
3  180
  60
27. Step 1:
1 1 1
m 2 x 2   m 2  A2  x 2  
2 2 2
Step 2:
1 2
x2 
2
 A  x2 

2x  A2  x 2
2

A
x
3
28. Step 1:
B B R O Y G B V G W
0 1 2 3 4 5 6 7 8 9

Step 2:
R  23 102  5%
2300  5%
29. Step 1:

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Sri Chaitanya IIT Academy 04-01-2020_Sr.Icon All_GTM-12_Key = Sol's
dx
v  6t
dt
dv
a 6
dt
Step 2:
F = ma
=2x6
= 12N
30. Step 1:
90
v1i1  v2i2
100
Step 2:
90 10
2300  5  230 i
100 2

i2  45 A
31. QACB  U  W
60  30  U  U  30 J
QACD  U  W
40  30  W  W  10 J
2
I max  I1  I 2 
32.  
I min  I1  I 2 
33. Step 1:
x
20 10
2 i1 i2 4

i1  i2  i
20  x 10  x x  0
 
2 4 2
x  10
Step 2:
x0
i  5A
2
34. Step 1:
KQx
E 3/2
R 2
 x2 
Step 2:
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Sri Chaitanya IIT Academy 04-01-2020_Sr.Icon All_GTM-12_Key = Sol's
When E is max
dE
0
dx
R
x
2
35. c  c1  c2  c3
A A A
9 0 12 0 15 0
k 0 A 3  3  3

d d d d

9  12  15 36
k   k  k  12
3 3
36.
A  A0e  t
100  1600e  t
e 8  16
 8
e   24
1 1

 e    2 4  8  2 2
6
A  1600  e   
1600 1600
 6
  200
 12  8
2 
 
37. Rate of inflow = Rate of outflow
1 1  A2V2
AV
10 4  10 4 2 gh
1
h  5cm
20
38. Step 1:
 x2 
  KT   M  LT 
 
   M 1T 2
Step 2:
 F      
MLT 2   M 1T 2    
    M 2 LT 4
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Sri Chaitanya IIT Academy 04-01-2020_Sr.Icon All_GTM-12_Key = Sol's
39. From cm frame from work energy theorem
F 1 F
2 x  K  4x2  0  x   2x  F
2 2 2K K
1
40. x
T
x1 T2

x2 T1
2.8  104 300

x2 350
13.6  4 150 0
41. K   13.6ev;   A  3.31A0
4 13.6
I 2R
42. T  2  2
mgq q
43.  I  P  I 2R
P   I  I 2R
dp   Rt
0 I  ; (1  e  )
dt 2R R L
1 Rt L
 e Rt / L    ln 2  t  ln 2
2 L R
44. Take a small element of the plate of length dx at a distance x from the left end of the
plate. If t1 and t2 are the thickness of the dielectrics of k1 and k 2 respectively, then
d a  x xd
t1  and t2 
a a
The capacitance of element capacitor
  dA 
dC  0
t1 t2

k1 k2
0 adx

 d  a  x  xd 
 k a  k a
 1 2 

0 a 2 dx

d a  x x 
 k k 
 1 2
a
0 a 2 dx
The total capacitance C  
0
d a  x x 
 k k 
 1 2

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Sri Chaitanya IIT Academy 04-01-2020_Sr.Icon All_GTM-12_Key = Sol's
a 2
0 a dx
C
0
d a  k1  k2  
  x  
 k1  k1k2  
a
a  k  k 
ln   x  1 2  
0 a  k1  k1k 2  
d  k1  k 2 
 
 k1k 2  0

0 a  k1k2    a 
2
 k1  k2    ln a 
   ln     a  
d  k1  k2    k1  k1k2  k1 
0 a 2  k1k2    a   a 
 ln
    ln  
d  k1  k 2    k2   k1  
0 a 2  k1k2  k1
  ln
d  k1  k 2  k2
v
45. E  1 10 6 v / m
d
From conservation of energy P.E Increase by 0.5ev .  vel  2.7 105 m / s
di
46.  va  vb   E  L  iR
dt
Ldi
va  vb  E   iR
dt
 20  2.5  1   2  5
= 30 – 2.5
= 27.50

 
47. V  A cos  t  
 6

At t  0  v  A cos
6
2 3
  100 
100 2
= 1.73
T1T2 2 68
48. t   2  24 min  48
T1  T2 2
2 sin  2 10 1 0.1 2  10 F 10
49. T   1 50.  F N
g 10 2 3 5 3

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CHEMISTRY
28
51. nCO  1
28
46
nC2 H 5OH  1
46
36
nH 2O  2
18
54
nN2O5   0.5
108
z3
52. Electrostatic force of attraction 
n4
23 7 7
 F  He 4  2 3
 33    


 F  Li
2 3 4  3 2
2
53. At 273k, volume = V0
 t C 
Vt  V0 1 
 273 
 10 
V10  V0 1 
 273 
283
V10  V0
273
n
54. K P  K C  RT 
n  1
K P  KC  RT 
but given as, K P  2 KC
RT = 2
2 2
T   24.3605
R 0.0821
i 1
55. FOR AC  3 , 0.8  i  3.4
4 1
i 1
For BaC  2 , 0.9  i  2.8
3 1
i 1
For NaC , 0.9  i  1.9
2 1
For K 4  Fe  CN 6 
i 1
0.5  i 3
5 1
 
56. ECell  E Fe  E zn

ECell   0.41   0.76 
 0.76  0.41 =+0.35V
57. In CO32 , Resonance takes place
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Sri Chaitanya IIT Academy 04-01-2020_Sr.Icon All_GTM-12_Key = Sol's
O O O

C 
 C 
 C

O O O
O O O

B.O = 1.33
In CO2 , B.O  2
In CO, B.O  3
1
B.O
B.L
58. Boric acid is a lewis acid

Cl

Cl
59. forms same product in both S N 1 and S N 2 reactions
60. Conceptual
1
61. 
E
3 3 3
Co  H 2O 6   Co  NH 3 6   Co  CN  6 
62. Conceptual
63. Mol . weight and Eq .weight of HCl and NaOH are same.
Meq of NaOH  25  0.2  5
Meq of HCl  75  0.2  15
10
So, Concentration of HCl in n mixture =  0.1M
100
P H   log  H     log 101   1
64. V1M1  V2 M 2
50  1  0.5  V2
V2  100ml
x 1000
0.5  
126 100
x  6.3gms
65. (1) CCl3 is a strongly electron – withdrawing group. The addition of HCl to double bond
of 3,3,3  trichloropropene does not follow the Markovnikoff’s rule because intermediate
secondary carbonium ion is destabilized by the – I effect if CCl3 group
 
H
CCl3  CH  CH 2  CCl3  C H  CH 3
Less stable
Instead the addition follows anti-Markovnikoff’s rule because primary carbonium ion
becomes relatively more stable.

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  
H Cl
CCl3  CH  CH 2  CCl3  CH 2  C H 2  CCl3  CH 2  CH 2 Cl
66. (1) Conceptual
Tscl / Py
CH 3  CH 2  CH 2  OH   
67. LiAlH 4
CH 3  CH 2  CH 2  O  Ts  CH 3  CH 2  CH 3
68. (2) 2Cu2O  Cu2 S  6Cu ( s )  SO2 ( g )
Auto reduction is used for the extraction of copper from its ore with low copper content.
69. (1) Conceptual
70. (2) Conceptual
71. K SP   M g2  C2O42 

S  K SP  81106  9  103 mol / t

For 1t _____ 9 103 moles
1.5t ____   1.512 gm
72. Simple cubic  0.52
BCC  0.68
FCC  0.74
Total  1.94  x 
x
y   2  0.97
y
73. Stability of trans alkene is more compared to Cis alkene
O

Cl Cl
74.
75. B.L of B-terminal ‘H’=1.19 A0 B.L of B-bridge ‘H’ = 1.34 A0 Total B.L= 2.53A0

Sec: Sr.Icon All 13