Sec: OSR.

IIT_*CO-SC GTA-7(P2) Date: 21-04-24

Time: 3HRS 2023_P2 Max. Marks: 180
KEY SHEET
MATHEMATICS
1 A 2 C 3 D 4 B 5 ABC
6 AC 7 ABD 8 60 9 506 10 6
11 31 12 40 13 180 14 4 15 11
16 8 17 10

PHYSICS
18 A 19 D 20 B 21 C 22 ABC

23 AD 24 ABCD 25 5 26 2 27 4

28 3 29 5 30 9 31 0.10 32 110

33 15 34 7.50

CHEMISTRY
35 A 36 A 37 B 38 C 39 BC

40 ABC 41 AB 42 3 43 24 44 1

45 6 46 4 47 6 48 6 49 1

50 30 51 1
Narayana IIT Academy 21-04-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-7(P2)_KEY&SOL
SOLUTIONS
MATHS
1. We have
10a  3b 0  T  25a 2  b 2 15a  2b 
A.adj(A)    and AA   
 0 10a  3b   15a  2b 13 
So 15a  2b  0 and 10a  3b  13
2 2 3 
The only solution to this system is a  and b  3 , which gives A   .
5 3 2
This matrix clearly satisfies the equation.

1 n
 1 1 1   1 1 
2. f (n)    cot
k
 tan k    1 cot

 k  k
 tan 1 k 

k  n
1
  n  tan 1 k    tan 1 k   0  n
k
10 10
   2n  (n  1)    2(2n  1)  99
n n

3. On solving, we get   6,   7

x
3  2 cos 2    1
3  cos(x)  x x 2
4. cos(xy)  cos (xy  x)   2 cos  xy   cos   
2  2 2 2
Hence
2
x2  x x  x  x   x
cos  2 cos  xy   cos  1  0   cos  cos  xy     1  cos 2  xy    0
2  2 2  2  2   2
x
xy   n
2
x x
xy   2m 
2 2
The above two equations imply that x is an even multiple of 
Putting x  2n in the original inequality gives that xy must also be an even multiple of pi.
5. x  tan a, y tan  
(tan   tan )(1  tan  tan )
f
sec 2 . sec2 
= sin      .cos     
sin  2  2 
=
2
 1 1
 f   , 
 2 2
6.
7. f 2 (x)  [e x  e x ]f (x)  1  0
(f (x)  e x )(f (x)  e  x )  0
x
 e x ; x  0  e x ; x  0 
x
f (x) can be e , e ,  ,  x 
x
e ; x  0   e ; x  0 

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1 0 1

e dx  e  e 1 ,  e x dx   e x dx  2e  2
x

1 1 0
1 0 1
2
e dx  e  e 1 ,  e x dx   e x dx  2 
x

1 1 0
e
8. By triangle inequality,

| x  1|  | x  4 |  5; equality when x  [4,1]

| y  2 |  | y  7 |  9; equality when y  [2, 7]
| z  3 | 2 | z  10 |  7; equality when z  10

9. Let the given integral be I. Applying King’s Rule gives


2
1 tan x  cot x
4 0
2I  2
dx
  
(ln sin x  ln cos x)2   
2
So substituting u  ln sin x  ln cos x , du  (tan x  cot x)dx gives

1
8I 
  
2du
 2
u  
2
 
And substituting u  , du  d gives
2 2

2 1 2
8I   2 d  .   2
    1 
1
So the answer is
4
e e
10. I n   (ln x) dx  n
(x ln x)n |1e  n  (ln x) n 1 dx  e  nIn 1
1 1
 In  nI n 1  e  I n 1  (n  1)I n 2
 In  (n  1)(In  2  In 1 )
dy 3t
11. On differentiating, 
dx 2
Family of tangent lines:
3 3t 2 3t t3
y  t  (x  t )  y  x 
2 2 2
3
x dy 4  dy 
y   
dx 27  dx 
4
a
27
12. 16k  24k 2  25
4

= (4k 2  5)2  16k 2

= (4k 2  4k  5)(4k 2  4k  5)
k
Thus, t k 
16k  24k 2  25
4

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1 1 1 
   
8  (4k 2  4k  5) (4k 2  4k  5) 
1 1  1
S    0 
8  5  40
(n 100)2
1
13. Let Sn   r
r (n 10)2
Note that Sn is a strictly decreasing function of n, and has 180n  9901 terms.
Thus,
180n  9901 180n  9901
 Sn 
n 2  200n  10000 n 2  20n  100
By the sandwich theorem, lim Sn  180
n 
p2
14- 15.  (p1r  3). p2 C r   p1p2  6 2p2 1
r 0

 1
x 
 x
16-17. Here, f (x) 
1  
2
 1
 x     x    3   2
 x  x 
1
Put x   t; x  1  t  0
x

t 1
y 
t  3t  2 t 2  2  3
3

t
1 1
t2  
t t  1  t2  2  3  6
3 t
1
y
6
1
 f max 
6
1 1 1 5
Max value achieved when t 2   t  1  x   1  x 
t x 2

PHYSICS
18.

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Narayana IIT Academy 21-04-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-7(P2)_KEY&SOL
2x 2sin   mg
mg
sin    1  sin   tan 
4x
dy mg

dx 4x
D
2
mg dx
4 R x
dy 

mg  D 
y n  
4  2R 
19.

Q
 
2
U     heat dissipated
2C
20.

4I0  4W / m 2
I0  1W / m 2
2
  (  1)t


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2 
  0.5  200 
600 3

I  I0  I0  2 n I0 cos
3
1.75  1    
x
3
x2  x  0
4
1  1  3 1
x 
2 2
1

4
2

   1 
2
2
I m ax  I1  I 2  1    2.25W / m
 4
21. Let principal quantum number of initially excited energy level be n.
Photon of maximum energy is emitted during transitions n  1 .
Hence, E max   E n  E1  …. (1)
Since, difference between energy of two consecutive levels decreases when n increases, therefore,
photon of minimum energy is emitted during transition n  (n  1)
Hence, E min  E n  E (n 1) ….. (2)
22.

B
  gt
= 2m / s
1
S  gt 2
2
= 5  0.04
= 0.2
  200 4
B  0     104  0.3  2
2 0.6 6
= 0.04 mV
E
23. i
r  R  r1
di E i2
 
dR (r  R  r1 ) 2 E

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diE
 dR  2
i
i max  dR min
24.

m at 0  1  0 is at 2f
x 0 x I  f 2  (f  a)(f  2a)  f 2
f 2  2af  af  2a 2  f 2
af  2a 2
Real object & real image  converging
1   2  0 (T1  T2 ) T1  T2
25.  
1   3 a 0 (T1  T3 ) T1  T3
5.2  3.9 80  60
Or 
5.2  2.6 80  T3
1.3(80  T3 )  2.6(20) or T3  40º C

26. T  (273  27)k  300k

  1000 hz
  0.2 m
M  124.5 gm / mol
Wave velocity V  v  200m / s
 RT
V 2
M
27. Total increase in length of rods
L L
= LT  T  3 T
2 2
Let the compression in spring A is x A , B is x B
And C is x C  k A x A  k B x B  K C x C
 kx A  2kx B  kx C  x A  2x B  x C
3
And x A  x B  x C  LT
2
3
2x B  x B  2x B  5x B  LT
2
3
 x B  LT
10
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Narayana IIT Academy 21-04-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-7(P2)_KEY&SOL
Energy stored
1 1 1
E  kx 2A  (2k)x 2B  kx C2
2 2 2
1 1
 k(2x B ) 2  kx B2  k(2x B )2
2 2
 2kx B  kx B  2kx B  5kx 2B
2 2 2

 9 2 2 2
E  5k  L  T 
 100 
9 9
 k 2 L2 T 2  k 2 L2 T 2    4
20 5
28.
29. Since platform is massless it cannot possess any angular momentum, thus torque of spring forces
about every median must be zero. Therefore by torque of spring forces about every median must be
zero. Therefore by torque balance one can readily see that all the three spring tension must be equal.
Also displacement of centroid is arithmetic mean of displacement of the three vertices.

d2 y
Now Fext  m 2
dt
d2  5x 
 6kx  m  2  3 
dt
d2x 18k
Or   x
dt 2 5m
5m
 T  2
18k
18k
w
5m
Now velocity at the mean position is given by

u  u max  A  A 

5m
Au
18k
30.

1  372  273  645K

2  15  273  258K
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Narayana IIT Academy 21-04-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-7(P2)_KEY&SOL
3  157  273  430K
Final pressure and temperature will be same in all the parts
P A PA
nl  0  ….(i)
R1 R
P A PA 2
n2  0  ….(ii)
R 2 R
P A PA 3
n3  0  ….(iii)
R3 R
  
(i) and (ii) gives 2  1  1  2  2
1  2 1
  
(iii) and (ii) gives 2  3   3  2  2
3  2 3
3 3
1   2   3  3   2  
  2 2  2
1   
 1 3 
2 2  2  2
31. MR 2    MR 2  mR 2  
5 24  5  30
5 5m
  1
4 2M
1 5m m
    0.1
4 2M M

32. 0  M  VC  0.1 Mva

GMm 1 1 GM  0.1M 1 v 2 1 Mv a2 2GM 11va2
va  10v c   mv c2   0.1M va2   M a  
R 2 2 R 2 100 2 10 R 10

2GM 10 10
va    11  110 km / s
R 11 11

mg
33. v sin 2   2 cos 2   15m / s
qB

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Narayana IIT Academy 21-04-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-7(P2)_KEY&SOL
2
 mg sin  
(qB) 2     (mg sin  )
2
 2 
3 3
80  10  10  
mg sin  3 2 2  15m / s
   1
qB 2 10  0.4
34.

Condition to come out of plane is that y max  L

Let us assume that at any instant velocity makes and   with line of greatest slope.
ma x  mg sin   qy B  mg sin  cos 
Along the direction of motion
md
 mg sin  cos   mg sin 
dt
d d dy
m x m  qB
dt dt dt
qBy
 vx      constant
m
Let’s say disc is initially at origin, with velocity
u 0 at  to x – axis
 0  0 cos   constant
qBy
 x     v0 (1  cos )
m
At y maxi , y  0 & x    0
v0
 y max  (1  cos ) . For y to be max   0º
qB
qBL
 v0 
2m

CHEMISTRY
35.

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36.

37. Fact
38. dU  TdS  pdV
However, because dU is an exact differential, its value is independent of path. Therefore, the same
value of dU is obtained whether the change is brought about irreversibly or reversibly.
Consequently, eqn. applies to any change – reversible or irreversible – of a closed system that does
no additional (non – expansion) work. We shall call this combination of the First and Second Laws
the fundamental equation.

39.

40. 2Cl 2  2Ca(OH) 2  Ca(OCl)Cl  CaCl2  2H 2O

Bleaching Powder

Ca 2 gives bricks red colour in flame


H /
43. MN 2  S2O82   MnO4  SO42
6

Cr2O72  SO32 
H
Cr 3  SO42
6

MnO4  S2O32 
OH
 MnO2  SO24
6

MnO4  H 2S 
H
Mn 2  S
0
H
MnO4  SO 2  Mn 2
 SO3
6
6  6  6  0  6  24.00
44. X is Na[A  (CN) 2 ]

N  C  AU  C  N
  4,   4

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46. 2rn  n
 
2 r0  n 2  n  
 13.4
n  4
2r0 2  3.14  0.53
47. Increases in pressure or addition of C affect the second equilibrium hence concentration of A 2
changes which further affect the first equilibrium. Addition of inert gas at constant volume
does not affect the equilibrium.
48-49.

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