Spotlight_Phase-2_(2022-23)_Week-1_Paper-2 (JEE Advanced)

Spotlight
Phase-2

Corporate. Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Ph.: 011-47623456

MM : 198 WEEK-1_PAPER-2_JEE (Advanced) Time : 3 Hrs.

ANSWERS
PHYSICS CHEMISTRY MATHEMATICS
1. (2) 19. (8) 37. (8)
2. (3) 20. (3) 38. (5)
3. (2) 21. (4) 39. (2)
4. (2) 22. (2) 40. (2)
5. (3) 23. (8) 41. (6)
6. (8) 24. (6) 42. (5)
7. (A, B, C) 25. (B, C) 43. (A, C)
8. (B, D) 26. (B, C) 44. (B, C)
9. (B, C) 27. (A, B, D) 45. (B, D)
10. (A, B, D) 28. (D) 46. (B)
11. (A, C) 29. (B, C, D) 47. (B, C)
12. (B, C) 30. (A, B, C, D) 48. (A, B, D)
13. (09.00) 31. (04.00) 49. (03.00)
14. (00.00) 32. (15.00) 50. (09.00)
15. (07.00) 33. (49.00) 51. (05.00)
16. (15.00) 34. (53.00) 52. (36.00)
17. (02.00) 35. (21.00) 53. (01.00)
18. (25.00) 36. (09.00) 54. (20.00)

13
 Spotlight_Phase-2_(2022-23)_Week-1_Paper-2 (JEE Advanced)

Physics Solution

1. Answer (2)
q
Flux through square  6 
0

q
Flux through circle  2  (1  cos )
0

q  1 
 1
2 0  2


q  3 
Hence   2
6 0  2 

There will be no flux due to electric field in z 3 2

x
direction 4(3  2 2)
Due to electric field in x direction
4. Answer (2)
ODCE = 0

2
ABCD   x 2  dx  2
0

Due to electric field in y dir

1
OAD = 0 BCE  2  2   2  2  2
2


Charge = 2  2 0 
2. Answer (3) When tension becomes zero
qEsin = mg cos ...(i)
E1
4 0 mv 2
qE cos mg sin ... (ii)
I
E2
8 1 1
0 mv 2 mv12 mgl 1 sin qEl cos ... (Iii)
2 2
0.05E1 + 0.05E2 = V
(E2 – E1)0 =   v 2 2gl

2000 5. Answer (3)

0
3 R 2
r 2 R3
3. Answer (2) dU 2 rdr U
r 0 0 3 0

6. Answer (A)
2a 7. Answer (A, B, C)

qE
In equation b. Kx = qE or x 
K

14
Spotlight_Phase-2_(2022-23)_Week-1_Paper-2 (JEE Advanced)

Amplitude = Distance between unstretched position increases continuously as we move from x = 0 to x

to equilibrium position = 3d.
8. Answer (B, D) 10. Answer (A, B, D)
Instantaneous charge on a capacitor
15
q = q0[1 – e–t/RC] IPR  5 A
3
= CV[1 – e–t/RC]
QR and QS are at same potential
Instantaneous current i(t) = dq/dt
15
 1  t / RC V Ieq  5A
 CV  e  et / RC 3
 RC  R
11. Answer (A, C)
At t = 0, i0 = V/R
Since,V and R are the same for both capacitors, kQ kQ
0
the initial current in the two is same and non-zero. R r
During discharge: instantaneous charge
Q
q(t) = q0e–t/RC  Q
2
Let q= q0/2 at t = t,
kQ kQ
q t / RC
Vshell
Then 0  q0e R R
2
t = RC In 2 kQ 9 109 10 8
450 V
If 1 and 2 are the times in which the two 2R 0.2
capacitors lose 50% of their charge.
4 0 Rr
C1 , C2 4 0R
1 RC1 ln 2 C1 1 R r
Then   RC ln 2  C  2
2 2 2
2 0.2
Ceq C1 C2 4 0R 2 44 pF
2 9 109
 1  .
2
12. Answer (B, C)
9. Answer (B, C)
Even after introduction of dielectric slab, direction 1 Q
of electric field will be perpendicular to the plates 6 0
and directed from positive plate to negative plate
Q Qq
F Flux 2
4a 24 0 a 2
(+)
(–) 13. Answer (09.00)

x=0 x=d x = 2d x = 3d


Further, magnitude of electric field in air  
0

q1 q2
 k k
Magnitude of electric field in dielectric  K  r12 r22
0

Similarly electric lines always flows from higher to r2

2

lower potenital, therefore, electric potential  4

r1

15
 Spotlight_Phase-2_(2022-23)_Week-1_Paper-2 (JEE Advanced)

Let RAB = x, then

r2
 2
r1 2ar
Req
7 1
kq1 kq2
V
r1 2r1
E
 I 7 1
9 9
2ar
9 10 4 10
 9 10 900 16. Answer (15.00)
r1 2r1
4KQ 2KQ
3 Vs
100 3R 5R
r1
14KQ
 r1 = 3 cm Vs
15R
and r2 = 6 cm
17. Answer (02.00)
Distance = 9 cm
 = (R2 cos 45°) × E
14. Answer (00.00)
  R 2E
 As E1 E2 0 =
2
 b=0
18. Answer (25.00)
15. Answer (07.00)
t
I e
R

 Intercept of initial slope of l versus t on the

time axis is equal to time-constant
 = RC = 5 × 10–3

3
5 10 5000
 R 6
25
200 10 200

Chemistry Solution

19. Answer (8)

All the  bonds are stereogenic centre.
Number of geometrical isomers = (2)3 = 8.
20. Answer (3)

O
COO Et
C
COO Et
C

O Product (i f n = 3)
Product (if n = 2)

21. Answer (4)

Number of H-atoms participating in hyperconjugation.

16
Spotlight_Phase-2_(2022-23)_Week-1_Paper-2 (JEE Advanced)

(4)

C(CH3)3

(0)

22. Answer (2)

(A)
Br

23. Answer (8)

(Z)

24. Answer (6)

OCH3
OCH3
*

25. Answer (B, C)

NO 2 NH 2
COOH Br COOH
–
NO2BF4 Sn/HCl (i) MnO4 /OH/ Br2/Fe
+
(i) H
COOH COOH
(A) (B) (C) (D)

NO2 NO2 NO2

– – COOH COOH
(i) MnO 4 /OH / Br 2/Fe
+
(ii) H
COOH Br COOH
(A) (E) (F)

26. Answer (B, C)

CH3
+ CH3 CH3 +
CH2 CH2 N CH3 N N N CH3
CH3 CH3 CH3
(A)
(B) (C) (D) (E) (F)

27. Answer (A, B, D)

Ph Ph Ph
Br NH 3 Br NH2
+

17
 Spotlight_Phase-2_(2022-23)_Week-1_Paper-2 (JEE Advanced)

Ph Ph
Ph Ph
Br +

28. Answer (D)

H
18
18 18 18 18 O H
O O O CH3 O CH3
H H2O O
CH3
O H O H

29. Answer (B, C, D)

Monochlorination of alkanes results in number of products. Their percentage yield is decided by reactivity-
probability principle.

In C4H9CH3, 1° H are 6.

Therefore, percentage of compound

6 1
  100
(6  1)  (6  3.8)

6
  100  20.8%
28.8
30. Answer (A, B, C, D)

This problem is based on Wurtz reaction involving mixture of two different monohaloalkanes.
 
CH 3  CH3 CH2  CH 4  H 2 C  CH2

2CH CH  CH CH CH CH
3 2 3 2 2 3

 
CH 3  CH 3 CH 2  CH3 CH 2 CH 3

31. Answer (04.00)

18
Spotlight_Phase-2_(2022-23)_Week-1_Paper-2 (JEE Advanced)

32. Answer (15.00)

Those molecule in which electron density in benzene ring is higher than anisole O CH3 can show

electrophillic aromatic substitution faster (II, III, V, VII, X)

33. Answer (49.00)
Dehydration with POCl3 is E2 mechanism so answer is 3-methylcyclopentene
so, x = 3
x+4=7
(x + 4)2 = 49
34. Answer (53.00)

CH3 MgBr
C  C– MgBr
+
H CC H CH4 + H
O C O
–
O C O
O (G) O O
H 2O H+ C
H C CH2 C OH H C C C OH


Hg /H
2+ + C
KMnO4 H
COOH
CH2 (H)
COOH
 O
CH3 C O H (I )

Number of –COOH group in H = 2, number of  bonds in I = 7, Then x = 2 and y = 7, x2 + y2 = 4 + 49 = 53

35. Answer (21.00)
14 12.75 2 100
Percentage of nitrogen = = 21%
1000 1.70

19
 Spotlight_Phase-2_(2022-23)_Week-1_Paper-2 (JEE Advanced)

36. Answer (09.00)

SOCl2 AlCl3

COOH COCl
O
(A) (B)

Zn-Hg HCl
Conc. HCl

(C)

Degree of unsaturation of (C) = 9

Mathematics Solution

37. Answer (8)

For tangency, x2 – 9 = x – a
 x2 – x + a – 9 = 0
Put D = 0  1 – 4a + 36 = 0

37
 a
4

y
| x2  9 |  | x  a | (0, 9)
| x2  9 |

x
37 –3 O 3 37
4 4

37
Similarly 
4

 37   37 
 For 4 distinct solution, a   ,  3   ( 3, 3)   3, 
 4   4 

Hence, number of integers are 17.

38. Answer (5)

3 4 3  4

Case I: If x < 0 then   and   is –ve hence      can never be equal to
x x x x

Case II: If x > 0

20
Spotlight_Phase-2_(2022-23)_Week-1_Paper-2 (JEE Advanced)

3 4 3 4
We have  ;    
x x x x

3 4
Since each of   and   is an integer..
x x

 3 possibilities are there :


(1)    0 and    5 
3 4
x x 

(2)    1 and    4  As       5
 3  4 3 4
x x   x   x

(3)    2 and    3 
3 4
x x 

3 3
Now, if    0  0 1  03x  x3
x x

4 4 1 x 1 2 4
and  x   5  5
x
6   
6 4 5

3
x
5

These two equations are not possible. Hence no solutions in these cases.

3  3 1 x 3
Now, if    1  1 2   1  x3
x x 2 3 2

4  4 4 1 x 1 4
and  x   4 5      x 1
x 5 4 4 5

not possible simultaneously  no solution

3 3 1 x 1 3
Again if    2  2 3     1 x 
x x 3 3 2 2

4 4 1 x 1 4
and  x   3  3
x
4   
4 4 3
 1 x 
3

4
Common solution 1  x 
3

 4
Hence x   1, 
 3

 a = 1, b = 4, c = 3;  a + b + c + abc = 1 + 4 + 3 + 12 = 20
39. Answer (2)

 1   2 
f ( x )  tan –1  x 4 – x 2  – 2  tan–1    tan –1   x 2 – 1   tan–1  – 2 
 4   2 

For f to be surjective, tan–1 – 2 = –1   = tan1

Now, verify the options.
40. Answer (2)

21
 Spotlight_Phase-2_(2022-23)_Week-1_Paper-2 (JEE Advanced)

We have f(x) = g(x)

On integration f(x) = g(x) + c
Put x = 1 f(1) = g(1) + c  c = 2
i.e. f(x) = g(x) + 2
 f(x) = g(x) + 2x + c1
Put x = 2 9 = 3 + 4 + c1  c1 = 2
 f(x) = g(x) + 2x + 2
 g(4) – f(4) + 10 = 0
and |f(x) – g(x)| < 2 if x  (–2, 0)
If f(2) = g(2)  x = –1
41. Answer (6)

–1  2 x 
Given   sin   ; x  [–1, 1]
 1 x2 

   2 tan–1 x  x  [–1, 1]

 –  
Hence, range of  is  ,  ...(i)
 2 2

 3cos y – 4 sin y 
  cos–1   ; y  [0, 2]
 10 

Now, 3cosy – 4siny  [–5, 5]

  2 
 Range of  is  , ...(ii)
 3 3 

Also  = 2tan–1(z2 – 4z + 5), z  R

 = 2tan–1((z – 2)2 + 1)

 
 Range of  is  ,   ...(iii)
2 

 
If  +  is minimum, then   and   .
3 2
Also, , ,  are angles of a triangle.

  
Now,   ,  and  
6 3 2

 
  2 tan–1 x   x  tan  2– 3
6 12

 3 cos y – 4 sin y 1
b  cos   
3 10 2

3 cos y 4 sin y 4
 –  1  cos(y + ) = 1 where tan  
5 5 3

4
y +  = 2  y = 2 –  = 2 – tan –1
3

22
Spotlight_Phase-2_(2022-23)_Week-1_Paper-2 (JEE Advanced)

 
y   2 tan–1  z 2 – 4 z  5 
2 2
 z2 – 4z + 5 = 1  (z – 2)2 = 0  z = 2

 –4  4 8 – 3 3 8 – 27 a – b
Now, x  tan y  z   2 – 3    2  4– – 3   
 3  3 3 3 c

a = 8, b = 27, c = 3
 a + b + c = 38
42. Answer (5)

–1 
tan x – 3  4 sin2 x – 3  tan(tan x ) – 0
3

3 
tan x  3, sin2 x  tan(tan–1 x ) – 0
4 3


 x is the solution of the inequality
3

  2  3    

tan cot –1 

cos  ·     tan  cot –1  2 · 1    tan(tan–1(10)  10
   4 8     
  30·    10 2  
  3 

 [10] = 31
43. Answer (A, C)

f1(x) = sin2x f2(x) =  

x
4

2 1
Period (T1) = = Period (T2) = = 4
2 1
4

y = f1(x) – f2(x) = sin 2 x   

x
4

Period (T3) = 4

y x
y= 4 y=1

  3 2 5 3 x
O 7 4
2 2 2 2

y = –1
y = sin2x

23
 Spotlight_Phase-2_(2022-23)_Week-1_Paper-2 (JEE Advanced)

Number of points of intersection of f1(x) = sin2x & f2(x) =  

x
4
is 9, x  [0, 4]

44. Answer (B, C)

 x2 
–1  log1/2   1
2 
1  x 

1 x2 x2
  2
 2 but 0  1
2 1 x 1 x 2

1 x2
  1
2 1  x2

 x2 
 0  log1/2   1
 1 x 2 

 x2  
 0  cos–1 log1/2  
2 
1  x  2

y 
2
x
–1 0 1

45. Answer (B, D)

y
y=x–1
1

1  x
2
y = sinx

min (sinx, {x})

x 1, x
=
sin x, x

x 1
LHL = xlim 1
x 1

sin x
RHL = xlim 0
x 1

46. Answer (B)

 f x y f x f y y f x

Replacing x and y by 0 we get f (0) = 0

24
Spotlight_Phase-2_(2022-23)_Week-1_Paper-2 (JEE Advanced)

f 0 h f 0 f h
 f 0 lim lim
h 0 h h 0 h

f x h f 0
Again f x lim
h 0 h

f x f h h f x f x
= lim
h 0 h

f h
= lim
h 0 h
f x

 f x f x

x2
 f x
4
 g(x) = x2(x – 4)
 g(x) satisfies the Rolles theorem for [0, 4]
 g(c) = 0

8
c=
3
47. Answer (B, C)

  
cosec–1p   – ,  – {0}, cos–1r  [0, ], sec–1q  [0, ]
 2 2


(cosec–1p + sec–1q + cos–1r)min = –
2

5
and (cosec–1p + sec–1q + cos–1r)max =
2

RHS = 7 2s – 25 – s 2

 2  49  
= –  s – 14 s  –
 2 2  2

2
   
= – – s – 7  –
2  2 2


 cosec–1p = – , sec–1q = 0, cos–1r = 0
2

 
and  s – 7  =0
 2


 s= 7
2

25
 Spotlight_Phase-2_(2022-23)_Week-1_Paper-2 (JEE Advanced)

48. Answer (A, B, D)

2 2 2
1 x 1 x 1 x
f (x) cos sin sin x2 6x 8
3 3 3 12

2 2 2
1 x 1 x 1 x
sin sin sin x2 6x 8
2 3 3 3 12

2 2
(x 3)2 , x [ 3,3]
12 6

2 2
19
Hence range is ,
6 6

49. Answer (03.00)

1  5  1  5  1  5 
k = sin sin    cos cos    tan tan  
 7   7   7 

1  2  1  5  1  5 
= sin sin   
7   cos cos  7   tan tan  7   
 

 2   5   5  1  2   5   2  
1 1 1
= sin sin    cos cos    tan tan     = sin sin    cos1 cos    tan1 tan  
 7   7   7   7   7   7 

 2    5    2   5
=       =
7
   7   7  7

5
14   5
14k  5 7
 =3
5 5

50. Answer (09.00)

  17  
sgn   2  = 1
 1  x  

 1 + x2  17
 x2  16
 x  [–4, –3, –2, –1, 0, 1, 2, 3, 4]
51. Answer (05.00)

1   1 
y = f(x) = sin–1xcos–1x = sin x   sin x 
2 

2
 1 1 2 2  1 
= sin x  (sin x ) =   sin x  
2 16  4 


If sin–1x = , y is maximum
4

1 2
at x = , ymax =  [ymax] = 0
2 16

26
Spotlight_Phase-2_(2022-23)_Week-1_Paper-2 (JEE Advanced)


If sin–1x = , y is minimum
2

2 9 2 2
at x = –1, ymin =   = 
16 16 2

 [ymin] = –5 [ymax] – [ymin] = 0 – (–5) = 5

52. Answer (36.00)

1 2 3 ...8 1 2 8 1 2 3 ... 8
x 8 x ... x
x x x x x

Using sandwitch theorem

lim f x 36
x 0

53. Answer (01.00)

9 27
f c 6
3 3
 2c = 6 or 3c2 = 6

c = 3 or c 2
54. Answer (20.00)
[cot–1x] + 2[tan–1x] = 0
 [cot–1x] = 0, [tan–1x] = 0
Or [cot–1x] = 2, [tan–1x] = –1
Now [cot–1x] = 0
 x  (cot1, )
[tan–1x] = 0
 x  (0, tan 1)
Hence for [cot–1x] = [tan–1x] = 0, x  (cot1, tan1)
[cot–1x] = 2  x  (cot3, cot2]
[tan–1x] = –1  x  [–tan1, 0)
Hence the solution set is (cot1, tan1)  [cot2, – tan1]

  

27