Spotlight_Phase-1_(2021-22)_Day-4_In-CLass Assignment_Chemistry

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Day-4_In-Class Assignment_Chemistry

Topic : Thermodynamics

Only One Option Correct

1. Consider the PV diagram for a reversible adiabatic expansion of three gases SO 2, CO and He. From the same
initial state to twice the initial volume. What can be said about these curves?
(A) The slope of PV diagram depends upon the molar mass of the gas
(B) The decrease in temperature will be maximum for SO2
(C) Greater the degree of freedom of the gas, lesser is the decrease in temperature
(D) The slope of the PV curve does not depend upon the degree of freedom of the gas
2. A reaction inside a cylindrical container with movable piston causes the volume to change from 12 lit to V
lit while the pressure outside the container remains constant at 0.975 atm. If a total work of –585 J is done
7
during the process, find the additional height by which the piston rises if the diameter of the piston is m
22
(1 atm lit = 100 J)
(1) 5 cm (2) 7.5 cm
(3) 10 cm (4) 12.5 cm
3. Consider the given statements

T2
S1 : In an isochoric process, Ssys is equal to nCv ln .
T1

T2
S2 : In an isobaric process, Ssys is equal to nCp ln .
T1

Which of the following is correct?

(A) S1 and S2 both are true (B) S1 and S2 both are false
(C) S1 is true and S2 is false (D) S1 is false and S2 is true
4. A block of ice at –15°C is supplied with heat and the temperature of the system is monitored. Enough heat
is supplied to convert the ice into steam at 110°C. Out of the given curves, select the one which correctly
represents the plot qualitatively.

T(K) T(K)

(A) 258 K (B) 273 K

q q

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 Spotlight_Phase-1_(2021-22)_Day-4_In-CLass Assignment_Chemistry

T(K) T(K)

(C) 258 K (D) 258 K

q q

5. Consider the given thermodynamic data

1
Fe s O2 g FeO s , H 266.5 kJ
2

1
C s O2 g CO g , H 110.5 kJ
graphite 2

The values of standard entropies of species are given (in J/mol–K)

FeO(s) = 57.5; C(graphite) = 5.75;
Fe(s) = 27.5; CO(g) = 197.75
Find the minimum temperature above which the reduction of FeO with graphite [FeO(s) + C(graphite)  Fe(s)
+ CO(g)] is spontaneous (Assume C is converted to CO only)
(A) 1248 K (B) 1150 K
(C) 860 K (D) 963 K
6. For 1 mole of an ideal monoatomic gas undergoing reversible adiabatic expansion, a curve was plotted for log
Y vs log X and the slope of the curve was found to be 2.5. Then the parameters X and Y respectively are
(A) P, V (B) V, T
(C) T, P (D) V, P
7. q amount of heat is supplied to a system at temperatures T 1, T2 and T3 and the change in entropy of the system
at T1, T2 and T3 are respectively S1, S2 and S3. Then
(A) S1 > S2 If T1 > T2 (B) S1 > S2 If T1 < T2
(C) S2 = S3 If T2 > T3 (D) S2 > S3 If T2 > T3
8. One mol of an ideal monoatomic gas is filled in a container and it is subjected to following changes

V (L)

20 B

10 A
C

300 600 T (K)

The (approx) work involved in cyclic process A – B – C – A is

(use ln2 = 0.7 and R = 8.3 JK–1mol–1)
(A) –696 J (B) –996 J
(C) 696 J (D) 996 J

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Spotlight_Phase-1_(2021-22)_Day-4_In-CLass Assignment_Chemistry

9. The heat of formation of C 2 H 5 OH(l) is –66 kcal/mol. The heat of combustion of CH 3 OCH 3 (g) is
–348 kcal/mol. Hf for H2O and CO2 are – 68 kcal/mol and –94 kcal/mol respectively. Then the H and E at 25°C for
the isomerisation reaction C2H5OH(l)  CH3OCH3(g) are respectively (in kcal/mol)
(A) 18, 17.301 kcal/mol (B) 26, 28.709 kcal/mol
(C) 22, 21.404 kcal/mol (D) 30, 28.522 kcal/mol
10. A(g)  2B(g) ; rH = 20 kJ/mol at 300 K

Cp, m (A) = 20 J/K-mol and Cp, m (B) = 5 J/K-mol

On increasing temperature enthalpy of the reaction will

(A) Increase (B) Decrease
(C) Be unaffected (D) First increases then decreases
11. Four mole of an ideal gas initially at 1.5 atm and 300 K is heated in closed vessel to 600 K and the pressure was
found to be 4.5 atm. If Cv is a function of temperature and varies as Cv, m = a + bT where the value of a is 25 JK–

kJ
1mol–1 and b is 0.03 JK–2mol–1. Find the value of U in
mol

(A) 46.2 (B) 56.17

(C) 60.75 (D) 11.52
12. A sample of 1 mole of an ideal gas is expanded to twice its initial volume of 1 lit in a reversible process
which is carried out by the process P = kV3 where k = 5 atm/lit3. If the value of Cv is 20 JK–1mol–1, then find
the value of S for the process (in J/mol–K) (use R = 8.3 J/mol–K)
(A) 22.4 (B) 47.8
(C) 61.19 (D) 88.16
13. Consider the given representations
(i) dU = TdS – PdV
(ii) dH = TdS + VdP
(iii) dG = VdP – SdT
Which of the given representations is/are correct?
(A) (i) and (ii) only (B) (ii) and (iii) only
(C) (i) and (iii) only (D) (i), (ii) and (iii)
14. A gas undergoes a reversible adiabatic expansion from a state (P1, V1, T1) to a state (P2, V2, T2). The gas is then
isothermally compressed to the same initial volume V1 to a state (P3, V1, T2). Then select the incorrect option
out of the following.
(A) P3 > P1
(B) Heat is released in the given operation
(C) Work done by the gas is greater than the work done on the gas magnitude wise
(D) No heat is exhanged in the path (P1, V1, T1) to (P2, V2, T2)
15. One mole of an ideal gas was subjected to two different processes separately
(i) The volume was doubled isothermally and reversibly and Gibbs energy change was G1
(ii) The volume was doubled isothermally and irreversibly and Gibbs energy change was G2
Then the ratio G1 : G2 is
(A) 1 (B) –1

1 1
(C) (D)
2 2

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 Spotlight_Phase-1_(2021-22)_Day-4_In-CLass Assignment_Chemistry

16. One mole of an ideal monoatomic gas is caused to go through the cyclic process as shown. State C is repre-
sented by (P0, V0, T0)

A
2P0

C
P0 B

V0 4V0

The value of change in internal energy along path CA is given by

(A) 3 P0V0 (B) 4.5 P0V0
(C) 8 RT0 (D) 10.5 RT0
17. Standard heat of formation of CaO(s) is –635 kJ/mol
2CaO(s)  2Ca(s) + O2(g). Select the correct statement at standard state for the given reaction
(A) 1270 kJ heat is released in the above reaction. (B) 635 kJ heat is released in the above reaction.
(C) 1270 kJ heat is absorbed in the above reaction (D) 635 kJ heat is absorbed in the above reaction
18. Calculate the heat of given reaction (in kJ) CH2 = CH2 + H2  CH3CH3

Bond BDE (kJ mol )

–1

C=C X
C–C Y
C–H Z
H–H W
(A) X + 2Z – W + Y (B) – X + 2Z – W + Y
(C) X – 2Z + W – Y (D) X – 2Z + W + Y
19. How much work (approx.) is done when 2.21 g of Barium azide decomposes in a container of changeable
volume against a constant pressure of 1.00 atm at 298 K ? (Molar mass of Ba is 137 g/mol and volume of
Ba(N3)2 (s) is negligible) Ba(N3)2(s)  Ba(s) + 3N2(g)
(A) –74.35 J (B) –24.78 J
(C) –8.18 J (D) –2.01 J
20. An ice cube is added to 32.75 g of liquid H2O at 40.0°C. The final temperature of the 42.75 g equilibrated
mixture is 10°C. The original temperature of ice cube is [CP of water and ice are 4 J/g-K and 2 J/g-K respectively
and H°fusion = 333 J/g]
(A) –5°C (B) –10°C
(C) –15°C (D) –20°C
21. Consider the following thermodynamic data, A + B  C + D

Temperature Equilibrium
constant
25°C 1
35°C 0.8
45°C 0.65

Select the incorrect statement.

(A) G° at 25°C is 0 (B) S° at 25°C is positive
(C) H° of reaction is negative (D) S° of reaction at 25°C is negative

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Spotlight_Phase-1_(2021-22)_Day-4_In-CLass Assignment_Chemistry

22. 1 mol of Sn(s, grey) changes to Sn(s, white) at 5 atm. If H – U of process is negative and density of
Sn(s, grey) and Sn(s, white) are x and y respectively. Then select the correct statement.
(A) x must be greater than y (B) y must be greater than x
(C) x must be equal to y (D) x and y cannot be compared
One or More Option Correct
23. Consider the graph for a reaction :

ln Keq

10

1
T K 

Select the correct statement(s)

(A) Reaction is endothermic (B) Reaction is exothermic
(C) S° of reaction is more than zero (D) S° of reaction is less than zero
24. One mol of an ideal gas expand from 1 L to 10 L in reversible isothermal process. Select the
incorrect(s) statement(s) about this process.
(A) W = 0 (B) S = 0
(C) q>0 (D) H = 0
25. Consider the graph for 1 mol of monoatomic ideal gas

A B
V

D
T

Select correct statement(s)

(A) S A B  0 (B) HBC  0

(C) WCD  0 (D) WA B  0

26. 1 mol of monoatomic ideal gas is compressed from point A(P 1 , 8 L, 75 K) to B(P 2 , 1 L, T 2 K) in
reversible adiabatic process. If gas is expanded irreversibly and adiabatically from B to C (P3, 8 L, and
T 3K) against the constant external pressure of 1atm. Select the correct statement(s) (Take 1atm L =
101. 3 J and R = 8.31 J/mol K)
(A) T3 > T2 > 75 K
(B) T2 > T3 > 75 K
(C) Magnitude of work done in A to B is more than that of B to C
(D) Magnitude of work done in A to B is less than that of B to C

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 Spotlight_Phase-1_(2021-22)_Day-4_In-CLass Assignment_Chemistry

27. Consider the two equilibrium that takes place in different containers at same temperature T
Equilibrium (I) P(g)  Q(g) H°r = X kJ, S°reaction = A J/mol K
Equilibrium (II) R(g)  S(g) H°r = Y kJ, S°reaction = B J/mol K

1
Below graph is plotted for lnKeq v s for the equilibrium I and II
T

Equilibrium (I)

ln Keq
Equilibrium (II)

0 1
T

Correct statement(s) is/are

(A) X > Y (B) Y > X
(C) A > B (D) B > A
Integer Type
28. 1 mol of a monoatomic ideal gas adiabatically expands in vacuum then how many functions are zero?
Ssystem, Ssurr, Suniverse, H, T, U w, q

29. How many species have zero value of standard heat of formation H aq , OH aq , H2O  l  , Br2(l), H2(g), Pblack
 

30. An organic compound 'P' contain H, C and 'O' only. 1 mol of P on complete combustion produce 3000 kJ
heat at standard state. If H0f of CO2(g), H2O(l) and P(s) are – 400 kJ/mol, – 300 kJ/mol – 1200 kJ/mol
respectively 1 mol of P require 6 mol of O2 for complete combustion and P contain C and O in molar ratio
x
of 1 : 1. The molar mass of P is x g/mol then is
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