Spotlight - Phase-2 - (2022-23) - Week-1 - Paper-1 - Compile (2020-P-1) - (Only Que.)

Spotlight_Phase-2_(2022-23)_Week-1_Paper-1 (JEE Advanced)
Spotlight
Phase-2
Corporate. Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Ph.: 011-47623456
MM : 198 WEEK-1_PAPER-1_JEE (Advanced) Time : 3 Hrs
Physics : Electrostatics, Capacitor, Current Electricity
Chemistry : General Organic Chemistry, Haloalkanes & Halorenes, Hydrocarbon Alchols, Phenol
& Ethers
Mathematics : Function, Inverse Trigonometric Functions, Limits, Continuity and Differentiability
INSTRUCTIONS TO CANDIDATE
1. Read each question carefully.

2. It is mandatory to use blue/black ballpoint pen to darken the appropriate circle in the answer sheet.
3. Mark should be dark and should completely fill the circle.
4. Do not use white-fluid or any other rubbing material on answer sheet.
5. Student cannot use log table and calculator or any other material in the examination hall.
6. Before attempting the question paper, student should ensure that the test paper contains all pages and no page
is missing.
7. Before handing over the answer sheet to the invigilator, candidate should check that Roll No., Centre Code and
Date of Birth have been filled and marked correctly.
8. Immediately after the prescribed examination time is over, the answer sheet to be returned to the invigilator.
9. Pattern of the questions are as under:
(i) The question paper consists of three parts (Physics, Chemistry and Mathematics). Each part has three
sections.
(ii) Section-1: This section contains 6 Multiple choice questions which have ONLY ONE correct answer.
Each question carries +3 marks for correct answer and –1 mark for wrong answer.
(iii) Section-2: This section contains 6 Multiple choice questions which have ONE or MORE correct answer(s).
Each question carries +4 marks for correct answer and –2 mark for wrong answer. +3 If all the four
options are correct but ONLY three options are chosen. +2 If three or more options are correct but ONLY
two options are chosen, both of which are correct. +1 mark if two or more options are correct but ONLY
one option is chosen and it is a correct option.
(iv) Section-3: This section contains 6 questions. The answer to each of the questions is a NUMERICAL
VALUE. For each question, enter the correct numerical value of the answer using the mouse and the on-
screen virtual numeric keypad in the place designated to enter the answer. If the numerical value has more
than two decimal places, truncate/round-off the value to TWO decimal places.. Each question carries +4
marks for correct answer and there is No negative marking.
1
PART-I : PHYSICS
SECTION - 1
Only One Options Correct Type
This section contains 6 single choice questions. Each question has 4 choice (A), (B), (C) and (D), for its answer, out of
which ONLY ONE is correct.
  1
1. An electric field E (r )  (rˆ) exists in space, where r is radial position vector from origin. What will be the total
r
charge enclosed in a sphere of unit radius centered at the origin?
(A) 40 (B) 20
(C) 80 (D) 0
2. Assume that z = 0 plane is the interface between two linear and homogeneous dielectrics (see figure). The relative

permittivities are r = 5 for z > 0 and r = 4 for z < 0. The electric field in the region z > 0 is E1   3 iˆ  5 jˆ  4 kˆ  kV/m .
If there are no free charges on the interface, the electric field in the region z < 0 is given by
z
r = 5
z=0
r = 4
 3 5  
(A) E2   iˆ  ˆj  kˆ  kV/m (B) E2   3 iˆ  5 ˆj  kˆ  kV/m
4 4 
 
(C) E2   3 iˆ  5 ˆj  5 kˆ  kV/m (D) E2   3 iˆ  5 ˆj  5 kˆ  kV/m
3. Two conducting spheres of radius r and 2r at very large separation. Each sphere is having charge Q. These
spheres are connected with a conducting wire of resistance R at t = 0. Then, the current flowing in the wire at
t = t is
– 3t – 3t
Q Q
(A) I  e 8  rR (B) I  e 8  rR
0 0
4 0 rR 8 0 rR
– 3t – 3t
Q Q
(C) I  e 4  rR (D) I  e 4  rR
0 0
8 0 rR 4 0 rR

4. A segment of a circular wire of radius R, extending from  = 0 to , carries a constant linear charge density,,
2
. The electric field at origin O is
y

x
O
1  1 
(A) 4 ( i j )
(B) i j
0R 4 0R 2 2
1 1
(C) 4 i j (D) Zero
0R 2 2
2
5. In the following RC circuit, the capacitor was charged in two different ways.
(i) The capacitor was first charged to 5V by moving the toggle switch to position P and then it was charged to
10V by moving the toggle switch to position Q
(ii) The capacitor was directly charged to 10V, by keeping the toggle switch at position Q.
Assuming the capacitor to be ideal, which one of the following statements is correct?
R C
P 5V
10V
Q
(A) The energy dissipation in cases (i) and (ii) will be equal and non-zero
(B) The energy dissipation for case (i) will be more than that for case (ii)
(C) The energy dissipation for case (i) will be less than that for case (ii)
(D) The energy will not be dissipated in either case
6. A thin rod of length I is placed along x-axis. One of its end is at the origin. The rod has a non-uniform charge
density  = ax, a being a positive constant. Electric potential at P as shown in the figure is
1 1
(A) 4  a I  b 1  I / b 
   
(B) 4  a I  b loge 1  I / b 
0 0
1 1
(D) 4  a I – b 1  I / b 
 
(C) 4  a I  b loge 1  I / b 
 
0 0
SECTION - 2
One or More Options Correct Type
This section contains 6 multiple choice questions. Each question has 4 choice (A), (B), (C) and (D), for its answer,
out of which ONE or MORE is correct.

7. For a point dipole of dipole moment p  pzˆ located at the origin, which of the following is (are) correct?
(A) The electric field at (0, b, 0) is zero
qp
(B) The work done in moving a charge q from (0, b, 0) to (0, 0, b) is 4   b 2
0
(C) The electrostatic potential at (b, 0, 0) is zero
qp
(D) If a charge q is kept at (0, 0, b) it will exert a force of magnitude 4   b 2 on the dipole
0
3
8. In the given circuit
(A) The potential of a point a with respect to b (Va – Vb ) is –6V

(B) The charge that flows through the switch S when it is closed is 54 C
(C) Final potential of b with respect to ground is 6V after switch is closed
(D) Change in energy stored in 6 F capacitors is 324 J after switch is closed
9. Five identical conducting plates 1,2,3,4 and 5 are fixed parallel plates equidistant from each other as shown in
fig. The junction of 1, 3 and the plate 4 are connected to a source of constant emf V0. d = distance between any
two successive plates. A = area of either face of each plate
5  0 A 
(A) The effective capacity of the system is  
3 d 
2  0 A 
(B) The effective capacity of the system is  
3 d 
4  0 A 
(C) The charge on the plate 3 is  V0
3 d 
2  0 A 
(D) The charge on the plate 5 is  V0
3 d 
10. Figure shows an ideal battery connected to a resistor and capacitor. The value of resistance in  is given as
R = Kq2 + Kq + K where K = 1; q = charge on capacitor in coulombs. Switch is closed at t = 0
(Given  = 10 V, C = 1 F and initially capacitor was uncharged). Choose correct option(s).
(A) Initially current in the circuit is zero (B) Initially current in the circuit is 10A
(C) Current in circuit when q = 1C is 5A (D) Current in circuit when q = 1C is 3A
4
11. In the circuit shown, two parallel plate capacitors of capacitance C and 2C consisting of plate of identical
dimensions. They are connected with an ideal battery of terminal voltage V as shown in figure I. Now the
capacitor, smaller in volume is completely inserted into the other capacitor larger in volume and kept in symmetric
position and then connection polarities of the plates are reversed as shown in figure II. Identity correct statements
(A) Capacitance of the new system in 10C (B) Capacitance of the new system is 7C
(C) Charge flown through the battery is 10CV (D) Charge flown through the battery is 7CV
12. The galvanometer shown in figure has resistance 5 . Main current of 6 A passes in circuit as shown. If current
through galvanometer is Ig, then
1 1
(A) Ig = A, when switch S is closed (B) Ig = A, when switch S is closed
10 15
1
(C) Ig = A, when switch S is open (D) Ig = 0 A, when switch S is open
6
SECTION – 3
Numerical Value Type
This section contains 6 questions. The answer to each question is a NUMERICAL VALUE. For each question, enter
the correct numerical value of the answer using the mouse and the on-screen virtual numeric keypad in the place
designated to enter the answer. If the numerical value has more than two decimal places, truncate/round-off the
value to TWO decimal places.
13. A thin hollow cylinder (opened at both ends) of radius and length both equal to L. This object carries a uniform
surface-charge density . The electrostatic potential at the point P on the axis of the cylinder (as shown in the
L
  
figure) comes out to be Vp  k  ln 1  2 Find the value of k.  You may use 
dx  
 ln x  x 2  a 2 .
2 2
0  x a 
5
14. Find the potential difference (VB – VA) in volts for the circuit shown in the figure.
R
15. A sphere of radius R has a uniform charge density  . A sphere of smaller radius is cut out from the original
2
R
sphere, as shown in the figure below. The centre of the cut out sphere lies at z  . After the smaller sphere
2
R R
has been cut out, the magnitude of the electric field at z   2 is n  . The value of the integer n is
0
_________________________
R/2
R/2
16. In a coaxial cable, the radius of the inner conductor is 2 mm and that of the outer one is 5 mm. The inner
conductor is at a potential of 10 V, while the outer conductor is grounded as shown. The value of the potential
 ln  p / q  
at a distance of 3.5 mm from the axis is 10V 1  ln r / s  , where p and q are co-prime integer and r and s are
   
also co-prime integer. Find the value of p + q + r + s
10 V
17. AB and CD are two uniform resistance wires (having equal value of resistance per unit length) of lengths 100
cm and 80 cm respectively. The connections are shown in the figure. The cell of emf 5 V is ideal while the other
cell of emf E has internal resistance 2  A length of 20 cm of wire CD is balanced by 40 cm of wire AB. Find the
emf E in volt, if the reading of the ideal ammeter is 2 A. The other connecting wires have negligible resistance
6
18. Three identical small electric dipoles are arranged parallel to each other at equal separation ‘a’ as shown in the
figure (a is very large in comparison to size of dipole). Their total interaction energy is 136 J. Now one of the
end dipole is gradually reversed, work done by the electric forces (in J) is N2. Find the value of N
PART-II : CHEMISTRY
SECTION - 1
This section contains 6 single choice questions. Each question has 4 choice (A), (B), (C) and (D), for its answer, out
of which ONLY ONE is correct.
19. In the given reaction
O
–
OH
(A)
O
The compound (A) will be
OH
OH
(A) (B)
CH3
O
OH
CH3
CH 2 OH
O
O
(C) (D)
CH3
CH3
OH
20. When the given alkyl bromides were subjected to hydrolysis in a mixture of ethanol and water (80%
EtOH/20% H2O) at 55ºC, the rate of the reaction follows the order
(CH3)3CBr > CH3Br > CH3CH 2Br > (CH3)2CHBr
The reason for this order is
(A) (CH3)3CBr react with SN1 mechanism while other reacts with SN2 mechanism.
(B) (CH3)3CBr react with SN2 mechanism while other reacts with SN1 mechanism.
(C) All react with SN1 mechanism.
(D) All react with SN2 mechanism.
21.
+
H
7
Re-arranged alkene product after re-arrangement at low temperature will be?
(A) (B)
(C) (D)
22. Isopentane on reaction with Cl2/h form A as major product (maximum amount). A on reaction with alcoholic OH–
/ form B as major product that on reaction with PhCO3H form C. Compound C on reaction with (H3O18)+ form
compound D as major product. D is
18
O H CH3
(A) CH2 — C — CH2 — CH3 (B) CH3 — CH — C — CH3

18
OH CH3 OH O H
OH
CH3
(C) CH2 — C — CH2 — CH3 (D) CH3 — CH — C — CH3
18
OH CH3
18
OH OH
23. Which of the following will not produce allyl halide as major product?
(A)
(B)
(C)
(D)
OCH3
NaNH2/liq NH3
24. In the reaction A. The major product is
Cl
8
OCH3 OCH3
(A) (B)
NH2
NH2
OCH3 OCH3
NH2
(C) (D)
Cl
SECTION - 2
This section contains 6 multiple choice questions. Each question has 4 choice (A), (B), (C) and (D), for its
answer, out of which ONE or MORE is correct.
OH
+
Conc. H2SO4 Conc. HNO3 H3O , H2O
25. 60-65°C X Conc. H2SO4 Y heat Z
OH
The correct statements about the above conversion are :
OH
HO 3S
(A) The compound X is
OH
SO 3H
OH
NO 2
(B) The compound Z is
OH
OH
HO3 S NO2
(C) The compound Y is

OH
SO 3H
(D) The above conversion are very inconvenient method because direct nitration of
OH
gives ‘Z’
OH
9
26. Which of the following reactions are correctly represent the product(s)?
C COONa
NaOH/Br2
(A) N H
C NH 2
OCH3 OCH3
(i) PhLi
(B)
(ii) H2O
Ph
Cl (Major product)
C Cl (i) NaN 3 14
(C) 14 NH2
– +
(ii) OH /H3O /
O
(i) AgOH
(D) CH3 CH2 CH2 C OH
(ii) Br 2/CCl4/
CH3 CH2 CH3
27.
(A) (B)
(C) (D)
28. Consider the following statements
Ph
H3C OH
S1 : C2H5 is a Z-isomer
C C
CH3
OH
C2H5
Ph
CH3
CH3
S2 : At least one of the conformer of Ph has a plane of symmetry
Ph
CH3
CH3
10
Ph
Ph
H
S3 : At least one conformer of H C2H5 has centre of symmetry
C2H5
S4 : Only one conformation of ethylene diammine has both centre of symmetry and plane of symmetry
simultaneously
S5 : The gauche form of meso tartaric acid is achiral
Which of the following options are correct?
(A) S1 and S5 both (B) S2 and S3 both
(C) S3 and S4 both (D) S2 and S4 both
29. The product (Y) of the following sequence of reactions would be :
Me OH
(I) CHCl3/NaOH Br 2/Fe
+ ( X) ( Y)
(II) H3O
(A) (B)
H3C OH
(C) (D)
Br CCl3
30. Consider the following statements about the electronic displacement in organic molecules :
S1 : Inductive effect is only applicable in solvent conditions and its effect is not observable in gaseous phase
S2 : Since inductive effect is time - variable effect, it does not affect the physical properties of molecules
S3 : The correct order of increasing –I effect is :- Cl < –F < –CN < –NO2
S4 : (CH2 = CH –) will exert +I effect if it is directly bonded with an alkyne carbon atom.
Which of the above is/are incorrect?
(A) S1 (B) S2
(C) S1 and S3 both (D) S2 and S4 both
SECTION – 3
31. Following carbocations are given, how many given carbocations can show rearrangement to get
stability?

 I
  
I

, II  , , , , , , 
I III
IV V VI VII VIII
11
  
OH
 CH2 
, , , , , , 
IX X XI XII XIII XIV XV
32. Consider the following reaction
HO Cl + NaOH (P)
P is the major organic product. Due to dehydrogenation of P, two mol of H2 is removed and P converts into
an aromatic compound A. In A, oxygen is first numbered atom according to IUPAC nomenclature. The E+
attack on A to form a major product by electrophilic aromatic substitution reaction. The numbering of carbon
(according to IUPAC) at which electrophile attack is x, then (x + 6)2 [x is the minimum number possible] is
33. Find the total number of monochlorinated products (including stereoisomers) formed from the optically pure
reactant given below :
H
h
CH2 CH C CH2 CH3 + Cl 2 
CH 3
34. In solvolysis of 1, 2-dimethyl propyl p-toluene sulphonate in acetic acid at 75°C, how many (alkene +
substitution) products will be formed(excluding streoisomers)?
35. A hydrocarbon having molecular weight 68 gives a compound on hydrogenation with one equivalene of H 2 gas
in presence of Pt catalyst than gives a single monochloride on chlorination. The number of dichlorides formed
on (including stereoisomers) chlorination of the hydrocarbon will be_____.
36. Consider the given reaction :
CH3 – NH
O O
HO C O + CH 3 MgBr
O O
SH OH
(X)
and find out the total number of moles of CH3MgBr required to react completely with 1 mole of the given
compound (X)
PART-III : MATHEMATICS
SECTION - 1
This section contains 6 single choice questions. Each question has 4 choice (A), (B), (C) and (D), for its answer, out
of which ONLY ONE is correct.
37. The range of function f (x) = ln(ex – e2x) is
(A) (–, 0] (B) (–, 0)
 1 
(C) (–, –2ln2] (D)  ,  ln 2 
 2 
  3 
38. The total number of solution(s) of ln|sinx| = –x2 + x, in   , is  then 32 is equal to
 2 2 
(A) 81 (B) 729
(C) 9 (D) 1
12
1 x
39. Consider the function f x cot sgn where [·] denotes greatest integer function, then which of
2x x
the following is INCORRECT?

(A) f (x) is left continuous at x = 1
(B) f (x) is discontinuous at x = 1
(C) f (x) is non differentiable at x = 1
(D) f (x) is continuous and differentiable at x = 2
400 x 2
40. The sum of the numbers of the form (6n ± 1) where n  N which are in the domain of f(x) = x ln(x –1) +
x
sin
7
is equal to
(A) 60 (B) 52
(C) 68 (D) 65
1
  4x 2  6  
41. If cos  cos  2    2  5 then the exhaustive set of values of x is
  x  1 
 1 1
(A) (–1, 1) (B)   , 
 2 2
 1  1 
(C) (–, –1)  (1, ) (D)  1,     , 1
 2 2 
3
x 5
42. Let f x sin(x – 5) + Bcos(x – 2) is continuous and differentiable in x  [7, 9] where [·] denotes the
A
greatest integer function and A, B  N then the minimum value of A + B is

(A) 63 (B) 64
(C) 65 (D) 66
SECTION - 2
This section contains 6 multiple choice questions. Each question has 4 choice (A), (B), (C) and (D), for its answer,
out of which ONE or MORE is correct.
x2 2x 3
log 2 tan
43. If the domain of the function f ( x ) 2 tan x x
4 x2 4x 3 ; (where[.] denotes the greatest integer function) is
1 1
n ,n , n I then n may be
4 2
(A) Zero (B) Less than –4

(C) Greater than 4 (D) 1
44. The graph of y = f (x) is given as shown
3
2
–1 1 3 6
13
Which of the following is/are correct?

(A) Range of function g(x) = f (x – 1) – 1 is [–1, 3]
 7
(B) Domain of function h(x) = 2f (2x – 1) + 1 is 0, 
 2
(C) Range of function p(x) = f (–|x|) is [1, 2]

(D) If |y| = f (x) + 1 then exhaustive set of values of y is [–4, 4]
x3
45. Let a function f : [–2, 2]  B be defined as f x min x 3 ,sin 1
,cos 1
sin x . Then
8
(A) Number of points of non-differentiability of f(x) is three

(B) If L.M.V.T is applicable to y = f(x) in (a, b), then b – a can be 3
(C) If L.M.V.T is applicable to y = f(x) in (a, b), then b – a can be 2
(D) If L.M.V.T is applicable to y = f(x) in (a, b), then b – a can be 1
a sin 1 x
46. Consider the functions f x sin 1
, where a  A = {x : x  [0, 2], x  Z} and g(x) = sin–1x, then
(A) There is exactly one value of a for which f(x) = g(x) has exactly three solutions
3 3
(B) If f(x) = g(x) has exactly three solutions, then the domain of f(x) is either [–1, 1] or ,
2 2
(C) There are four values of a for which f(x) = g(x) has a unique solution
(D) All the intersection points of f(x) and g(x) are of the form (p, p)
2
47. If f x log 1 log 1 x 2 2 1 , where [ ] and { } denotes the greatest integer function and fractional
4 9
part function respectively. Which of the following statement(s) is(are) true?
(A) Domain of f (x) is R (B) Domain of f (x) is R – I
1
(C) Range of f (x) contains only one integer (D) Range of f (x) is
2
48. Let f : R  R be a differentiable function such that f (0) = 1 and for any x, y  R, f (xy + 1) = f (x) f (y) – f (y) – x
+ 2 holds. Then
n
n n 1
(A) f k
k 1 2
(B) f (x) is increasing function x  R

(C) f (x) is decreasing function x  R
(D) f(x + 1) = f(x) + 1 x  R
SECTION – 3
 3 x  a, x0
49. Let f  x    then the least positive integral value of a for which f (x) is one-one, is
 256  x , 0  x  256
14
1
50. Let f : (–1, 1)  (–1, 1) be a continuous function and f (x) = f (x 2) x  (–1, 1) and f (0) = then the
2
1
value of 128f is
256
51. Let set A consists of 4 distinct elements and set B consists of 6 distinct elements, If the number of
injective mappings defined from A  B be m and the number of mappings from A  B which are not
10 n
surjective be n then the value of is equal to
m
   sin x.  5 x  1 x  x  2
52. If f :   ,   R , f  x    tan .sin  (where [·] denotes the greatest integer function)
 2 2 5 1
x
2   
is an even function. Then the least positive integral value of  is
f x
53. Let f x sin sin sin x for all x  R and g x sin x for all x  R then lim equal to
6 6 x 0 g x
x x
54. The number of solution(s) of the equation cos 1    cos   is (where [·] denotes the greatest integer function)
4 4
  
15

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Spotlight_Phase-2_(2022-23)_Week-1_Paper-1 (JEE Advanced)

MM : 198 WEEK-1_PAPER-1_JEE (Advanced) Time : 3 Hrs

Physics : Electrostatics, Capacitor, Current Electricity

Mathematics : Function, Inverse Trigonometric Functions, Limits, Continuity and Differentiability

1. Read each question carefully.

(C) The electrostatic potential at (b, 0, 0) is zero

8. In the given circuit

(A) The potential of a point a with respect to b (Va – Vb ) is –6V

The compound (A) will be

Re-arranged alkene product after re-arrangement at low temperature will be?

(A) CH2 — C — CH2 — CH3 (B) CH3 — CH — C — CH3

(C) CH2 — C — CH2 — CH3 (D) CH3 — CH — C — CH3

The correct statements about the above conversion are :

(A) The compound X is

(C) The compound Y is

28. Consider the following statements

32. Consider the following reaction

the following is INCORRECT?

greatest integer function and A, B  N then the minimum value of A + B is

(A) Zero (B) Less than –4

Which of the following is/are correct?

(C) Range of function p(x) = f (–|x|) is [1, 2]

(A) Number of points of non-differentiability of f(x) is three

(B) f (x) is increasing function x  R

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