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Spotlight_Phase-2_(2022-23)_Week-1_Paper-2 (JEE Advanced)

Spotlight
Phase-2

Corporate. Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Ph.: 011-47623456

MM : 198 WEEK-1_PAPER-2_JEE (Advanced) Time : 3 Hrs

Physics : Electrostatics, Capacitor, Current Electricity

Chemistry : General Organic Chemistry, Haloalkanes & Halorenes, Hydrocarbon, Alchol Phenol &
Ether

Mathematics : Function, Inverse Trigonometric Functions, Limits, Continuity and Differentiability

INSTRUCTIONS TO CANDIDATE

1. Read each question carefully.


2. It is mandatory to use blue/black ballpoint pen to darken the appropriate circle in the answer sheet.
3. Mark should be dark and should completely fill the circle.
4. Do not use white-fluid or any other rubbing material on answer sheet.
5. Student cannot use log table and calculator or any other material in the examination hall.
6. Before attempting the question paper, student should ensure that the test paper contains all pages and no page
is missing.
7. Before handing over the answer sheet to the invigilator, candidate should check that Roll No., Centre Code and
Date of Birth have been filled and marked correctly.
8. Immediately after the prescribed examination time is over, the answer sheet to be returned to the invigilator.
9. Pattern of the questions are as under:
(i) The question paper consists of three parts (Physics, Chemistry and Mathematics). Each part has three
sections.
(ii) Section-1: This section contains 6 questions. The answer to each of the questions is a Single digit
integer, ranging from 0 to 9. Each question carries +3 marks for correct answer –1 mark for wrong
answer.
(iii) Section-2: This section contains 6 Multiple choice questions which have ONE or MORE correct answer(s).
Each question carries +4 marks for correct answer and –2 mark for wrong answer. +3 If all the four
options are correct but ONLY three options are chosen. +2 If three or more options are correct but ONLY
two options are chosen, both of which are correct. +1 mark if two or more options are correct but ONLY
one option is chosen and it is a correct option.
(iv) Section-3: This section contains 6 questions. The answer to each of the questions is a NUMERICAL
VALUE. For each question, enter the correct numerical value of the answer using the mouse and the on-
screen virtual numeric keypad in the place designated to enter the answer. If the numerical value has more
than two decimal places, truncate/round-off the value to TWO decimal places.. Each question carries +4
marks for correct answer and there is No negative marking.

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Spotlight_Phase-2_(2022-23)_Week-1_Paper-2 (JEE Advanced)

PART-I : PHYSICS
SECTION - 1
Integer Value Type
This section contains 6 questions. The answer to each of the questions is a Single-digit integer, ranging from 0 to 9.
The answer will have to be appropriately bubbled in the OMR as per the instructions as follows. Examples- If the correct
answer to question numbers X, Y and Z (say) are 6, 0 and 9 respectively, then mark 6, 0 and 9 in OMR respectively.

X 0 1 2 3 4 5 6 7 8 9

Y 0 1 2 3 4 5 6 7 8 9

Z 0 1 2 3 4 5 6 7 8 9

1. Consider a rectangular prism with cross section of a right angled triangle as shown. Co-ordinates of vertices
are A, B, C, D and E are  2, 0, 0  ,  2, 2, 0  ,  0, 2, 2 ,  0, 0, 2  and  0, 2, 0  respectively..

There exists an electric field xiˆ  2 yjˆ  kˆ N/C everywhere. If charge enclosed by the prism is (N N) 0
then, find the value of N.

2. In a parallel plate capacitor the distance between the plates is 10 cm. Two dielectric slabs of thickness 5 cm
each and dielectric constants K1 = 2 and K2 = 4 respectively, are inserted between the plates. A potential of 100
V is applied across the capacitor as shown in the figure. The value of the net bound surface charge density at
2000
the interface of the two dielectrics is 0. The value of N is____
N

K2 = 4
10 cm 100 V
K1 = 2

3. Consider a square surface of side 2a, a circular area is removed from the square symmetrically of radius a, A
q 3
charge q is placed at distance a on the axis of circle. The electric flux through remaining part is N
6 0 N
Find the value of N.
4. A bob of simple pendulum has mass m and charge q. It is given a horizontal velocity v at its lowest position
qE
as shown in figure. A horizontal electric field of strength E exist in space as indicated. If mg , then
3

the minimum value of velocity v, so that the bob completes the vertical circle is given by v min n 2gl .
Find value of n.

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Spotlight_Phase-2_(2022-23)_Week-1_Paper-2 (JEE Advanced)

5. A thin disc of radius R carries a uniform surface charge density . The potential at the edge of disc is
2
R 2 R3
given by V . The electrostatic potential energy of the disc is . Find the value of n.
n 0
0

6. Two insulating hemispherical shells, each of radius R, are placed very close to each other with their
centres almost coinciding as shown in figure. Both of them are uniformly charged, one with total charge
Q, and the other with total charge q. The magnitude of the net electric force exerted by one hemisphere

Qq
on the other is given by F 2
. Find the value of n.
n 0R

SECTION - 2
One or More Options Correct Type
This section contains 6 multiple choice questions. Each question has 4 choice (A), (B), (C) and (D), for its
answer, out of which ONE or MORE is correct.
7. A block of mass m is attached to a spring of force constant K, the other end of the spring is attached to the wall.
Charge on the block is q. A horizontal electric field E is acting in the direction as shown in figure, and the block
is released with the spring in unstreched position

E
K
q.m

Smooth

m
(A) Block will execute SHM (B) Time period of oscillation is 2
k

qE
(C) Amplitude of oscillation is (D) Block will oscillate but not simple harmonically
k

8. Capacitor C1 of capacitance 1 F and capacitor C2 of capacitance 2 F are separately charged fully by a


common battery. The two capacitors are then separately allowed to discharge through equal resistors at time
t=0
(A) The current in each of the two discharging circuits is zero at t = 0
(B) The currents in the two discharging circuits at t = 0 are equal and not zero
(C) The currents in the two discharging circuits at t = 0 are unequal
(D) Capacitor C1 loses 50% of its initial charge sooner than C2 loses 50% of its initial charge

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Spotlight_Phase-2_(2022-23)_Week-1_Paper-2 (JEE Advanced)

9. A dielectric slab of thickness d is inserted in a parallel plate capacitor whose negative plate is at x = 0 and
positive plate is at x =3d. The slab is equidistant from the plates. The capacitor is given some charge. As one
goes from 0 to 3d
(A) The magnitude of the electric field remains the same
(B) The direction of the electric field remains the same
(C) The electric potential increases continuously
(D) The electric potential increases at first, then decreases and again increases
10. For the circuit shown in figure, if source of voltage 15 volt is ideal, then

(A) Current through PR is 5 A (B) Current through RS is 7.5 A

2
(C) Current through RS is 6 A (D) Potential difference VPQ  VPR
3
11. Inside a thin-walled metal shell with radius R = 20 cm there is a metal ball with the radius r = 10 cm, which
has a common centre with the shell. The ball is connected with a very long wire to the earth via an opening
in the shell, as shown in figure. Charge is given to outer shell such that charge appearing on outer surface
of shell is 10–8 C, then

(A) The electric potential on the surface of metal shell is 450 V


(B) The electric potential on the surface of metal shell is 225 V
(C) The electrical capacity of the obtained system of conducting bodies is 44 pF
(D) The electrical capacity of the obtained system of conducting bodies is 22 pF
12. A charge q is located at a perpendicular distance a from the centre of a square plate of side length 2a as
shown in figure.

2a

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Spotlight_Phase-2_(2022-23)_Week-1_Paper-2 (JEE Advanced)

q
(A) Electric flux through the plate is 8
0

q
(B) Electric flux through the plate is 6
0

Qq
(C) If plate is uniformly charged with Q, then electric force on plate is
24 0 a2

Qq
(D) If plate is uniformly charged with Q, then electric force on plate is 2
12 0a

SECTION – 3
Numerical Value Type
This section contains 6 questions. The answer to each question is a NUMERICAL VALUE. For each question, enter
the correct numerical value of the answer using the mouse and the on-screen virtual numeric keypad in the place
designated to enter the answer. If the numerical value has more than two decimal places, truncate/round-off the
value to TWO decimal places.
13. Two point like charges q1 = 1.0 nC and q2 = 4.0 nC are fixed in free space. At every point on the curve shown,
the net electrostatic potential V created by these charges is 900 volts. Find the separation r between
them.(approximately)

14. A rod of finite length having linear charge density  subtends an angle of 15° symmetrically at a point P which
is also the centre of curvature of a circular arc having same linear charge density  as shown in the figure. If

bk 1
the net electric field at the point P is , then find the value of b. k 4
R 0

15. A frame made of thin wire of resistance per unit length r is connected to a battery of emf E between terminals
A and B as shown in figure. The frame ABC is an equilateral triangle of side length a and successive triangles
are of decreasing side length by half and number of triangles tends to infinite. The current through the battery
E
is given by I n 1 . Find the value of n.
2ar

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Spotlight_Phase-2_(2022-23)_Week-1_Paper-2 (JEE Advanced)

16. Conducting shell of radius R carrying charge Q, another charge Q is placed at 3R distance from centre of shell.
14KQ
If the potential at point P due to charge on shell is , then the value of n is
nR


17. A hemispherical shell of radius R is placed in a uniform electric field E as shown in figure

R 2E
If  = 45°, the electric flux through the hemispherical shell is . The value of N is
N

18. For the charging of a capacitor of capacitance C = 200 F in R-C circuit the variation of current with respect to
time is shown in the figure. Find the value of resistance R in SI unit using the data shown in the figure.

I
E
R

t
5
(in milli second)

PART-II : CHEMISTRY
SECTION - 1
Integer Value Type
This section contains 6 questions. The answer to each of the questions is a Single-digit integer, ranging from 0 to 9.
The answer will have to be appropriately bubbled in the OMR as per the instructions as follows. Examples- If the correct
answer to question numbers X, Y and Z (say) are 6, 0 and 9 respectively, then mark 6, 0 and 9 in OMR respectively.

X 0 1 2 3 4 5 6 7 8 9

Y 0 1 2 3 4 5 6 7 8 9

Z 0 1 2 3 4 5 6 7 8 9

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Spotlight_Phase-2_(2022-23)_Week-1_Paper-2 (JEE Advanced)

19. Find the number of geometrical isomers of the given compound.

C6H5 – CH = CH – CH – CH = CH – CH = CH – COOH
CH3

NaOEt
20. Br ()n Br + CH2(CO2Et)2 Cyclic product
EtOH
For which value of n, the formation of six membered ring takes place?
21. For the compounds A and B, maximum number of H-atoms participating in hyperconjugation are x and y
respectively. Then the value of (x + y) is

(A) (The carbocation can also, rearrange)

C(CH3 )3

(B)

22. A compound (A) having molecular formula C7H11Br is an optically active tertiary alkyl halide. A reacts
with HBr in the absence of peroxide to give geometrical isomeric products (B) and (C). Treating (A)
with potassium tert.butoxide gives (D). (D) on reductive ozonolysis gives two moles of formaldehyde
and one mole cyclopentane-1, 3-dione. (A) in the presence of peroxide reacts with HBr to give (E).
The total number of chiral carbon in one molecule of (E) is :

NBS ag. AgNO3 H


23. (x) (y) z

The sp2-hybridised carbon atoms present in one molecule of the end product z is :

CH3
24. H3C CH CH CH3 EtOH
(X) (SN1 + E1) . Total number of products major and minor (including

Br
stereoisomers) are :
SECTION - 2
One or More Options Correct Type
This section contains 6 multiple choice questions. Each question has 4 choice (A), (B), (C) and (D), for its
answer, out of which ONE or MORE is correct.
25. Identify the product (D) and (F) in the following sequence of reactions

Sn/HCl (i) MnO4 / OH  /  Br2/Fe


(B) +
(C) (D)
(ii) H
NO2BF4
(A)
(i) MnO4 / OH /  Br 2/Fe
+ (E) (F)
(ii) H

NH2
COOH Br COOH
(A) (D) is (B) (D) is
COOH COOH
Br

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Spotlight_Phase-2_(2022-23)_Week-1_Paper-2 (JEE Advanced)

NO2
COOH Br COOH
(C) (F) is (D) (F) is
Br COOH COOH

Br (i) Ag 2O, H2O


26. N CH 2 CH3 (ii) Heat (A) + (B)
CH3I
CH3
(i) Ag 2O, H2O CH3I (i) Ag 2O, H2O
(C) (D) (E) (F)
(ii) Heat (ii) Heat

(A) (A) is an alkene, (D) is 3° amino alkene and (F) is a conjugated diene
(B) (A) is an alkene, (D) is 3° amino alkene and (F) is a non-conjugated diene
(C) (F) is CH2 = CH – CH2CH = CH2
(D) (F) is CH2 = CH – CH = CH – CH3
27. The product(s) (A) obtained in significant amount of the given reaction

Ph
Br NH3
(A)

Would be

Ph NH2

NH 2 Ph
(A) (B)

Ph
Ph
(C) (D)

18
O
H2O/H
28. Major organic product of the reaction will be?

18
OH 18 OH 18
O O
(A) (B)

18 18
OH OH
O
(C) (D)

29.

B, C, D are mono chlorinated products. Choose the correct statement(s).

(A)

(B)

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Spotlight_Phase-2_(2022-23)_Week-1_Paper-2 (JEE Advanced)

(C) May be B = C4H9CH2Cl, C = C3H7(CH)Cl – CH3 and D = (C2H5)2CH – Cl


(D) The % of C4H9CH2Cl is 20.8 at room temperature

Na/dry ether
30. CH3Br CH3CH2Br Products

Possible product(s) formed in the above reaction is/are


(A) CH3CH2CH3 (B) CH4
(C) CH3CH2CH2CH3 (D) CH2 = CH2
SECTION – 3
Numerical Value Type
This section contains 6 questions. The answer to each question is a NUMERICAL VALUE. For each question, enter
the correct numerical value of the answer using the mouse and the on-screen virtual numeric keypad in the place
designated to enter the answer. If the numerical value has more than two decimal places, truncate/round-off the
value to TWO decimal places.
31. How many among the following reactions may give chiral carbon containing alkene?

conc. H2SO4 alc. KOH


(i) 
P1 (ii) P2

OH
Br

Mg/Dry ether conc. H2SO4


(ii) 
P3 (iv) P4

Cl HO OH
Cl

COOH
COOH
NaOH(aq) NaOH(aq)
(v) COOH
electrolysis
P5 (major) (vi) electrolysis
P6 (major)
COOH

Li/Liq NH 3
(vii) P7 (viii) H2/Pd/BaSO 4
P8

32. Among compounds given below if 'x' is the number of compounds which can undergo electrophilic aromatic
substitution faster than anisole as well as cumene
Then find value of (3.x).

OCH3 OCH3 CH3 OCH3 OH O CH 3


OCH3

CHO , NH2 , , , , , ,
OCH3
O
CH 3 NO 2 CCl3 OCH3 O C
CH3
Cl
(I) (II) (III) (IV) (V) (VI) (VII) (VIII)

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Spotlight_Phase-2_(2022-23)_Week-1_Paper-2 (JEE Advanced)

OCH3 OCH3 OCH3

O
, ,
C
C NH CH3 CH3
O
NH CH3
(IX) (X) (XI)

33. Trans-2-methyl cyclopentanol undergoes dehydration using POCl3 in pyridine, the major product is x-
methylcyclopentene. x is the locant number of methyl in IUPAC naming, the value of (x + 4) 2 is
+
CH3MgBr (I) CO 2; H 
34. In a given reaction sequence H CC H G + CH4 G 2+ + H I
(1 eqv) (II) H2 O; Hg /H
(III) KMnO 4

Let the number of –COOH group in compound H is x and number of (sigma) bonds in compound I is y.
Then find the value of (x2 + y2)
35. 1.70 g of an organic compound is subjected to Kjeldahl's method for the estimation of nitrogen present. The
ammonia evolved, neutralized 12.75 mL of 1 M H2SO4. The percentage of nitrogen in the compound is
36. What is the degree of unsaturation of the final product (C) formed in the following reaction?
SOCl 2 AlCl 3 Zn-Hg
HOOC C6H4 CH2 C6 H5 (A) Anhy (B) (C)
(Ortho)

PART-III : MATHEMATICS
SECTION - 1
Integer Value Type
This section contains 6 questions. The answer to each of the questions is a Single-digit integer, ranging from 0 to 9.
The answer will have to be appropriately bubbled in the OMR as per the instructions as follows. Examples- If the correct
answer to question numbers X, Y and Z (say) are 6, 0 and 9 respectively, then mark 6, 0 and 9 in OMR respectively.

X 0 1 2 3 4 5 6 7 8 9

Y 0 1 2 3 4 5 6 7 8 9

Z 0 1 2 3 4 5 6 7 8 9

37. Let f(x) = | x2 – 9 | – | x – a |. If the number of integers in the range of a so that f(x) = 0 has 4 distinct real root is
n, then the value of n – 9 is

3 4
38. The exhaustive set of real values of x satisfying the equality       5 (where [ ] denotes the greatest
x x

 b b
integer function) is  a,  where a, b, c  N and is in its lowest form. Find the value of
 c  c

5 a b c abc

    7 
39. If f : R    ,  is a function defined by f ( x )  tan1  x 4  x 2   tan1   and f is surjective then
 4 2   4 
2
1 1
cos 2 is
1

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Spotlight_Phase-2_(2022-23)_Week-1_Paper-2 (JEE Advanced)

40. Let g(x) and f(x) are twice differentiable functions and satisfies f (x) = g(x), f(1) = 4, g(1) = 2, f(2) = 9 and
f 4 g 4
g(2) = 3, then is
5

 2x   3cos y  4 sin y 
41. Consider,   sin1  2 
, x  [ 1, 1] ,   cos1   , y  [0, 2] and
 1 x   10 

  2 tan1( z 2  4z  5), z  R . If ,  and  are interior angles of a triangle such that ( + ) is minimum then

a b
x  tan y  z  , where, a, b, c N. Then the least value of a b c 2 is
c

  
42. If x   0,  satisfies the inequality | tan x  3 |  | 4 sin2 x  3 |  tan(tan1 x )   0 , then find the value of
 2 3

1 1 2 3x
tan cot cos
6 30 x 4

[Note : [.] denotes greatest integer function.]

SECTION - 2
One or More Options Correct Type
This section contains 6 multiple choice questions. Each question has 4 choice (A), (B), (C) and (D), for its
answer, out of which ONE or MORE is correct.

43. If f1(x) = sin2x, f2(x) =  


x
4
, where {·} denotes fractional part function, then

(A) Fundamental period of the function f(x) = f1(x) – f2(x) is 4


(B) The function f(x) = f1(x) – f2(x) is non-periodic function
(C) Number of solutions of the equation f1(x) = f2(x), x  [0, 4] is 9
(D) Number of solutions of the equation f1(x) = f2(x), x  [0, 4] is 4

    x2 
44. Let the function f : Df  0,  be given by f (x) = cos–1  log1 2    , then (where Df is domain of f (x))
 2
 2  1  x 

(A) f (x) is one-one function (B) f (x) is many-one function


(C) f (x) is onto function (D) f (x) is into function
45. If f(x) = min(sinx, {x}) and  is a root of the equation 1 + sinx = x ({.} and [.] denote the fractional part and
integral part functions respectively), then

f x f x
lim 1
(A) xlim x 1 0 (B) x x 1

f x f x
lim 0
(C) xlim x 1 1 (D) x x 1

46. f : [0, )  [0, ) be a differentiable function satisfying the relation f(x + y) = f(x) + f(y) + y f x , x, y  0 and
f(0+) = 0 and a function g(x) = 4(x – 4) f(x) is defined in the interval [0, 4], then the value of c  (0, 4) at which
g(c) = 0 is

8
(A) 3 (B)
3

7
(C) 3 (D)
3

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Spotlight_Phase-2_(2022-23)_Week-1_Paper-2 (JEE Advanced)

47. Let p, q, r, s  R satisfy the constraint given by cosec–1p + sec–1q + cos–1r  7 2 s – 25 – s2. Then the
possible value(s) of s lies in the interval.
(A) (0, 5) (B) (5, 10)
(C) (6, 12) (D) (12, 15)

2 2 2
1 x 1 x 1 x
48. f ( x ) cos sin sin x2 6x 8 be a real valued function then
3 3 3 12

(A) f (x) is a one-one function (B) Domain of f (x) is [–3, 3]

2 2
19
(C) Domain of f (x) is [–3, ] (D) Range of f (x) is ,
6 6

SECTION – 3
Numerical Value Type
This section contains 6 questions. The answer to each question is a NUMERICAL VALUE. For each question, enter
the correct numerical value of the answer using the mouse and the on-screen virtual numeric keypad in the place
designated to enter the answer. If the numerical value has more than two decimal places, truncate/round-off the
value to TWO decimal places.

 5   5   5  14k  5 
49. If k = sin1  sin   cos1  cos   tan1  tan  , then the value of is
 7   7   7  5

  17  
50. The number of integral solutions of the equation sgn   2 
 1   x (where {  } and [  ] denotes the
 1  x  
fractional part function and the greatest integer function respectively), is
51. If f(x) = sin–1xcos–1x, then the value of [f(x)max] – [f(x)min] is, where [·] denotes greatest integer function.

1 2 8
x ... ,x 0
52. If f x x x x then the value of  for which 'f' is continuous at x = 0 is ([·]
if x 0

denotes the greatest integer function)


53. The number of value(s) of 'c' when Lagrange's Mean Value Theorem is applicable for the function

x 2, x 0
f x 3
in the interval [–3, 3] is
x , x 0

54. Number of integer solution of the equation [cot–1x] + 2[tan–1x] = 0 is , (where [.] represents the greatest integer
function), Then, the value of 10 is

  

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