Sri ChaitanyaIIT Academy, India 24-12-2022_Jr.

Super60-STERLING BT_Jee-Main_WTM-21_Key & Sol’s

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Jr.Super60-STERLING BT JEE-MAIN Date: 24-12-22
Time: 09:00AM to 12:00PM WTM-21 Max. Marks: 300

KEY SHEET
PHYSICS
1 2 2 1 3 1 4 2 5 4
6 1 7 4 8 1 9 3 10 3
11 3 12 1 13 1 14 1 15 2
16 1 17 1 18 4 19 2 20 1
21 11 22 9 23 4 24 18 25 5
26 12 27 8 28 7 29 10 30 1

CHEMISTRY
31 4 32 1 33 2 34 2 35 3
36 1 37 2 38 4 39 1 40 3
41 2 42 2 43 2 44 2 45 4
46 2 47 3 48 2 49 4 50 2
51 5 52 1 53 6 54 3 55 6
56 3 57 4 58 2 59 9 60 5

MATHEMATICS
61 4 62 3 63 1 64 3 65 4
66 1 67 1 68 1 69 4 70 3
71 2 72 4 73 2 74 1 75 3
76 4 77 4 78 2 79 3 80 1
81 1 82 3 83 8 84 2 85 3
86 400 87 2 88 8 89 2 90 12

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 Sri ChaitanyaIIT Academy, India 24-12-2022_Jr.Super60-STERLING BT_Jee-Main_WTM-21_Key & Sol’s

SOLUTIONS
PHYSICS
1. For  S HM    1 ,
 
x1  20 sin  5 t  
 4
Its amplitude ,A1  20
For SHM (2),
x 2  10 sin 5 t  3 cos 5 t 
 sin 5 t 3     
 10  2   cos  t   20  sin 5 t .cos  sin cos 5 t 
 2 2   3 3 
 
 20 sin  5 t  
 3
It's amplitude , A 2  20
A1 20
  1
A2 20
2. Comparing a  4 2 x  0 with standard equation of simple harmonic motion
a+ 2 x  0
 2  4 2 ,   2
2 n  2 , n  1 Hz
3. y  a sin  t   
 2 t  
y  0.8sin   
 0.2 2 
y  0.8cos10 t
4. 3
When t = 2 s, y= r
2
Now , y = r sin  t
3 3
 r  r sin   2 or sin 2  
2 2
 
or 2   or  
3 6
2 2
Hence , T =   12 s
  
 
6
5. x  a sin t
2 T  a
x  a sin  or x  a sin 
T 8 4 2

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 Sri ChaitanyaIIT Academy, India 24-12-2022_Jr.Super60-STERLING BT_Jee-Main_WTM-21_Key & Sol’s
6. Using slope of the curve we can write equation
a = -10x
Comparing it with a = - 2 x
 2  10
  10
 1
frequency f =  10 s 1
2 2

7. E1  E2
1 1
 m112 A12  m222 A22
2 2
but m1  m 2
12 16  22  25
100 16   2  25
  8 units
8. Comparing the given equation with standard velocity-displacement
equation of simple harmonic motion,i.e.,v = A2  x 2 , we get
 = 1rad/s and A = 3m
The magnitude of maximum acceleration of the particle in SHM
is = 2 A
 (1) 2 (3) m/s 2  3m / s 2
9. when
T 2 T A
t , then x = A sin  
12 T 12 2
1 1
KE  mv 2  m 2  A 2  x 2 
2 2
1 2  2 A2 
 m  A  
2  4 
31 2 2 
  m A 
42 
1 11 
PE  m 2 x 2   m 2 A 2 
2 42 
KE 3

PE 1
10. The average acceleration of a particle performing SHM over one complete oscillation
is zero.
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 Sri ChaitanyaIIT Academy, India 24-12-2022_Jr.Super60-STERLING BT_Jee-Main_WTM-21_Key & Sol’s
11. V 0  A
V0

A
V  A2  x2
V0 V0
 A2  x 2
2 A
3
x A
2
V ' A2  y 2
V0 A2
V ' A2 
A 4
3
V ' V0
2
12. From the figure T = 0.04 sec
1
f   25 Hz
T
13.  In option,
m
s
aT s 2 m  s2
  2
  M0 L0T 0 
v  m  m s
 
s
So,according to the result above relation does not depend on time.
14.  a  keq  (2k and 2k in series) parallel (k and k in parallel)
 k || 2k  3k
m m
T  2  2
keq 3k
15. When springs are connected in series.
1 1 1
 
K K1 K 2
1 1 1
2
 
m m1 m22
2

T 2  t12  t2 2

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 Sri ChaitanyaIIT Academy, India 24-12-2022_Jr.Super60-STERLING BT_Jee-Main_WTM-21_Key & Sol’s
16. Here two spring are in series
 Effective spring constant is given by
1 1 1
 
k k1 k 2
k1k 2
k
k1  k 2
 Time period of oscilliation
m 16
T = 2  2 .  k1  k 2 
k k1k 2
k1  k 2
 8
k1k 2
17. Damped oscillations are not periodic
18.  d  Force in the spring 1 and spring 2 is same.
 k1 A1  k2 A2 (i )
and A1  A2  A (ii )
 k1 A1  k2 A  k2 A1
k2
 A1  .A
k1  k2
19. Using the relation kx  constant
k1l1  k2l2  k (l1  l2 )
k (l1  l2 ) k (nl1  l2 )
k1  or k1 
l1 nl1
k (n  1)
or k1 
n
20. E  A2
21. Erest  3J
1
mean K.E = Ka 2  4
4
1
 Ka 2  8 J
2
From (i) and (ii)
1
Etotal  Erest  Ka 2
2
 3  8  11J

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 Sri ChaitanyaIIT Academy, India 24-12-2022_Jr.Super60-STERLING BT_Jee-Main_WTM-21_Key & Sol’s
22. m m 1
3  2 and 4 = 2
k k
3 m
Dividing 
4 m 1
m 9
 
m  1 16
16m  9m  9
9
 m  kg
7
 9
23. Fmax  m 2 a
2
 2 
 (1)   (1)  4 N
  
24. 1
KE  m 2 A2
2
1 2
 1(100) 2  6 102   18 J
2
25. P.E of the oscillating mass is given by
1 1
E  m x 2  kx 2 where k = m 2
2 2
Let k = m 2 be the velocity at mean position. when
mass M2 is attached
m1v1
v2 
m1  m2
If A1 be the new amplitude
1 2 1
kA1   m1  m2  v22
2 2
1 m1
 kA2 
2 m1  m2
A1 m1 1
  
A m1  m2 4

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 Sri ChaitanyaIIT Academy, India 24-12-2022_Jr.Super60-STERLING BT_Jee-Main_WTM-21_Key & Sol’s
26. Given equation,
3 2  30  x 2
Differentiating both sides, we get
dv
6v  2 x
dx
dv 1
v  x
dx 3
a 1  d d dx d 
  .....  a   
x 3  dt dx dt dx 
k
m
  12
n  12
27. From the given information it can be inferred that points A and B are equidistant from
mean position Hence from diagram it is clear that time period of oscillation is
 2  2  2  2  8 seconds.

28. U  2  20 x  5 x 2
dU
F   20  10 x
dx
At equilibrium position; F = 0
20 - 10x = 0
x=2
Since particle is released at x = -3, therfore amplitude
of particle is 5.

It will oscillate about x = 2

With an amplitude of 5.
 maximum value of x will be 7.

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 Sri ChaitanyaIIT Academy, India 24-12-2022_Jr.Super60-STERLING BT_Jee-Main_WTM-21_Key & Sol’s
29. In initial length l1  100 then l2  121
l T l
By using T = 2  1  1
g T2 l2
T1 100
Hence,   T2  1.1T1
T2 121
T2  T1
%increase = 100  10%
T1
30. T  16sec, t  2sec, V  0.4m / s
y  a sin t v  a cos t
 2   2 
0.4  a   cos  2
 16   16 
2 1
0.4  a  
16 2
a  1.44 m
CHEMISTRY
31. Conceptual
32. Conceptual
33. Conceptual
34. CH 3  COOH  HOOC  CH 2  COOH  HOOC  CH 2  CH 2  COOH  HOOC  C2 H 5
35. SYN addition
36. Conceptual
37. Conceptual
38. 1-Alkyne reacts with Li as follows:
Liq . NH 3
CH 3  C  CH   CH 3  C  CLi  1/ 2 H 2
39. Conceptual
40. Markovnikoff ‘s rule
HOCl
41. HC  CH   HC  CH
| |
OH Cl

HOCI
CH 3  C  CH   CH 3  C  CH
HOCl
OH Cl

OH Cl

CH 3  C  CHCl2 
 H 2O
 CH3 C CH
O

OH Cl

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 Sri ChaitanyaIIT Academy, India 24-12-2022_Jr.Super60-STERLING BT_Jee-Main_WTM-21_Key & Sol’s
42. Mg 2C3  H2O
 CH3  C  CH  Me  C  MeHg 2 / H  / H 2 O

O
43. Halogenation and Dehydrohalogenation to Alkyne
44. No chiral Carbon in product
45. Li- NH 3 (l ) gives trans addition
46. Symmetrical Compound gives single product
47. A  C2 H 2
(Polymerisation)
B  C6 H 6
48. Cis addition
1, 2 Cis is (ea)
49. Terminal Alkyne precipitate
50. Conceptual
51. Propyne, Butyne, Acetylene, Pentyne-1, Phenyl acetylene
52. CH 2  CH  OH
53. III, IV, V, VI, VIII, IX
54. Conceptual
55. CH 3 MgBr, NaH , NaNH 2 , Na, KNH 2 , CH 3CH 2 Li
56. CH 2  CH  C  N
57. II,III,V,VI
58.
59. 2 CHI 3  6 Ag  C2 H 2  6 AgI
mole ratio
1 : 6
60.

MATHEMATICS
61. ABC has P as mid-point of AB on x-axis
Q as mid-point of BC on y-axis
R as mid-point of AC on z-axis
 A  x1 , y1 , z1  , B  x2 , y2 , z2  & C  x3 , y3 , z3 
 P   , 0, 0 
 Q   0,  , 0 
 R   0, 0,  
 x1  x2  x3   , y1  y2  y3   & z1  z2  z3  
62. Using section formula.
63. Given AG  2 21
Since ‘G’ divides AP in the ratio 3:1 internally.
Let AG  3x then GP  x
 AP  4 x
 3x  2 21 
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8 21
AP 
3
64. P  x, y, z  divides the line segment joining the points A  x1 , y1 , z1  & B  x2 , y2 , z2  is
x1  x : x  x2
65. Find d.r’s of perpendicular lines and using a1a2  b1b2  c1c2  0
66. Using centroid of tetrahedron.
67. Let the source of light situated at A  a, 0,0  , Where a  0
Let OA be the normal to the mirror at 0.

NOA  NOB 
2

D.r’s of OA are  a, 0, 0  and d.c’s are 1, 0, 0 

1 1 1
 d.c’s of ON are ,,
3 3 3
1
 cos  
3
Let l,m,n be the d.c’s of the reflected ray OB, then as in the problem.
l 1 1 m0 1 n0 1
  ,  and 
2 cos  3 2cos  3 2cos  3
2 2 2
1 2 2
l , m , n
3 3 3
1 2 2
Hence d.c’s of the reflected ray are , ,
3 3 3
68. The required point, which divides BC in the ratio AB:AC
69. 1
Length of median through " C "  2 a 2  2b2  c 2
2
70. Conceptual
71. Let P  x, y, z  such that PA  PB  2K
72. Using cos 2   cos 2   cos 2   1 .
73. n
Substitutive l  m 

 n  n
 mn  n  m    m  m    0
   
2 2
 n  mn   m  0
n2 n
 2    0
m m
n1 n n n
If & 2 are roots, then 1 . 2  
m1 m2 m1 m2

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 Sri ChaitanyaIIT Academy, India 24-12-2022_Jr.Super60-STERLING BT_Jee-Main_WTM-21_Key & Sol’s
ll mm nn
 1 2  1 2  1 2 Since the lines are perpendicular 1  1    2
2 1 
74. x2 y 3 z 4
  
6 3 6
 R   4, 2, 6 
Required distance  16  4  36  2 14.
75. G is the centroid of ABC
G   2, 4, 2 
OG  2i  4 j  2 k
OA  3i  k
OG.OA 1
cos  GOA   
OG OA 15
76. Finding d.r’s and using a1a2  b1b2  c1c2  0
77. Substituting l  3m  5n in 5lm  2mn  6nl  0
 m  2 n  or  m   n
m n m n
   or  
2 1 1 1
m n
Case (i)  k
2 1
m l n
  
2 1 1
d.r's  1, 2,1
m n
Case (ii)  k
1 1
l m n
  
2 1 1
d.r's   2, 1,1
78.  x1  t  x2  x1   x1  tx2  tx1
 1  t  x1  tx2
tx2  1  t  x1

t  1  t 
Given point divides line segment joining  x1 , y1 , z1  &  x2 , y2 , z2  in the ratio t :1  t
internally.
79. Using cos 2   cos 2   cos 2   1
1
Here cos  
2
cos   3x
cos   x
1
Now  3x 2  x 2  1
4
3
x
4

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 Sri ChaitanyaIIT Academy, India 24-12-2022_Jr.Super60-STERLING BT_Jee-Main_WTM-21_Key & Sol’s
1 3 3
* d.c’s of L1 = , ,
2 4 4
1 3  3
* d.c’s of L1  , ,
2 4 4
80. Find length of AC (base diagonal)
81. Given 2  a, b, c  10
And a  b  c  19 and 2b  a  11& c 2  27a
Solving above conditions, we get a  3, b  7, c  9
82. Find the d.r’s of median and equating.
83. AB.CD
Projection of AB on CD  .
CD
84. Using section formula & mid-point formula
85. Triangle is equilateral i.c,       60
86. If P  x1 , y1 , z1  , Q  x2 , y2 , z2  & R  x3 , y3 , z3  are three consecutive vertices of a parallel then
the forth vertex of a parallelogram   x1  x2  x3 , y1  y2  y3 , z1  z2  z3 
87. 252
 cos   cos   cos   
9
5
 cos   cos   cos  
3
88. sin 2   sin 2   sin 2   sin 2 
 1  cos 2   1  cos 2   1  cos 2   1  cos 2 
4 8
4  .
3 3
89. D.r’s of angular bisector between the lines
Whose d.c’s  l1 , m1 , n1  &  l2 , m2 , n2  are
   
 l1  l2 m1  m2 n1  n2   l1  l2 m1  m2 n1  n2 
 , , and  , ,
     
 2cos 2 cos 2cos   2sin 2sin 2sin 
 2 2 2  2 2 2
90. Let OA  a, OB  b, OC  c
a  b  c 1
1
 a.b  b.c  c.a 
2
2 1
  abc  
2
1
 Volume   abc 
6 
1

6 2

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