Sri Chaitanya IIT Academy, India 29-10-2022_Jr.

C-IPL_Jee-Main_WTM-13_Key & Sol’s

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Jr.C-IPL JEE-MAIN Date: 29-10-2022
Time: 10:00AM to 01:00PM WTM-13 Max. Marks: 300

KEY SHEET
PHYSICS
1 2 2 3 3 2 4 2 5 4
6 3 7 3 8 2 9 1 10 1
11 1 12 3 13 2 14 2 15 2
16 3 17 4 18 2 19 3 20 1
21 1000 22 4 23 1600 24 64 25 4
26 7 27 3 28 7 29 6 30 40

CHEMISTRY
31 1 32 2 33 2 34 4 35 2
36 3 37 1 38 2 39 2 40 4
41 1 42 2 43 1 44 1 45 4
46 3 47 1 48 2 49 4 50 1
51 22 52 24 53 0 54 6 55 8
56 7 57 5 58 8 59 6 60 284

MATHEMATICS
61 1 62 3 63 4 64 2 65 2
66 2 67 4 68 3 69 4 70 3
71 3 72 2 73 1 74 3 75 2
76 3 77 1 78 4 79 2 80 3
81 3 82 1 83 6 84 5 85 9
86 0 87 4 88 6 89 13 90 0

SEC: Jr.C-IPL Page 1

 Sri Chaitanya IIT Academy, India 29-10-2022_Jr.C-IPL_Jee-Main_WTM-13_Key & Sol’s

SOLUTIONS

PHYSICS
1. GM 1 GM 4 GM 4
g 2
g  mg 1  m = (700) = 400 gwt
R (R ) 2
7 R2 7
2
2. Theory
3. d g d 1 d d 1 n 1 n 1
g d  g (1  )  g (1  )  1   1  d  R( )
R n R n R R n n n
4. V 1 e
mrava = mrpvpa(1+e)va = a(1-e)vp a 
Vp 1  e

GMm 1 GMm 1 Gm 1  e
From L.C.E  mva 2   mv p 2 By solving Va  ( )
a(1  e) 2 a(1  e) 2 a 1 e
3/2
5. T1  R  h1  24 24
24  R  6 R    2  T2 
3/2 3/2
  7R  3/2
= 6 2hr
    
T2  R  h2   2
3/2
T2  R  2.5R   3.5R  T2

6. 2 2 2     = 
We  Ws   Ws   Ws   Ws  
6 24 8 12 3 3 12 4
7. 1 1 2GM m m
kE = mVe 2  m = GM  gR 2 = mg
2 2 R R R
8. V  (3Ve )2  Ve 2  9Ve 2  Ve 2 V  8Ve 2 V= 2 2Ve = 2 2(11.2km / s ) V  31.7km / sec

9. 1 1 10000
pE  ( mve 2 )   (1) X (100)2 = - = -5000 J
2 2 2
10. 4
2G  R 3 d
Ve  3 Ve R V1  R1  R  V2  2V1 = 2(11) = 22 km/sec
R V2 R2 2R

11. du mv 2 1
F   6r 2  6r 2 mv2 = 6r3 mv 2  3r 3 E = U+K = 2r3+3r3= 5r3=5(5)3=5(125)
dr r 2
625 J
12. x y

U     Ex dx   E y dy  U     5dx   12dy  U  [5(7  0)  12(3  0)] =
7 3
 - [35-36] = - [-1] = +1 J
0 0  0 0 

13. GMm GM GM
V (magnitude) g   W=mg = GMm

1 GMm V

r (4r ) 16r 2
2
16r 2 16r r 16r

14. G 11G
U    (1X 2)  (2 X 3)  (3 X 1)  U   G 2  2  6  3 =  1  110GJ
Gm1m2
U 
r r 10 X 10 10
15. Because g poles  gequator

SEC: Jr.C-IPL Page 2

 Sri Chaitanya IIT Academy, India 29-10-2022_Jr.C-IPL_Jee-Main_WTM-13_Key & Sol’s

16. G (4)(1) G(1)(1) 24  x 2 1

 ( )  48-2x = x 3x = 48X = 16 cm
x 2
(24  x)2 x 4

17. Theory
18. 1 Rw2 Rw2 Rw2
g  g  Rw2 cos2 450 = g  Rw2 ( ) = g  g p  g  g  ( g  ) g 
2 2 2 2
19. Gm1m2 G (m1  m2 ) G (m1  m2 )
 m1r1w2 Gm12m2  m1 ( m2 d ) ) w2 w2  w
d 2
d m1  m2 d 3
d3

20. GM 2GM GM 3GM

V1    V2 = - V1+V2 = 
a a a a
2
3/2
21. T1  1012  1000
  
T2  1010  1

22. A
Area for one month = 4 weeks = AArea for 1 week =
4
23. g h 100 10
gh  h 2 g 100
(1  )   h 5 h 5 1
1      1  h  R  6400 = 1600 km
h 2 (1  R )  gh  64 R 64 8
(1  ) R 4 R 4 4 4 4
R
24. 2 X 10 X 6.4 X 106
U 
mgh mgR
 (h  R) U 
=6.4X107 J = 64X106 = 64 MJ
h 2 2
1
R

25. GM L r r 1
L=mvr = m r = m GMr L r 1  1   L2 = 4L1 = xL X=4.
r L2 r2 16r 4

26. GM GM 1 V1 r 16r 4 x
V0   V  2    X+y = 4 + 3 = 7.
Rh r r V2 r1 9r 3 y

27. T 3 R 3 1.02 R  R 3 0.02 R 3

T 2 R3 T  R3/2 X 100  X 100 = ( ) X 100 = ( ) X 100 = X 2  3%
T 2 R 2 R 2 R 2
28. L dA L L 1
 4.4 X 1015 m2 / s  dA  dt dA  X 4.4 X 1015 X 365 X 24 X 3600 = 6.94 X 1022 m2
m dt 2m 2m 2
29. Gm VA r R 1
V  B   VB  2VA VB  2(3V ) VB = 6V
r VB rA 4R 2
3/2
30. T1  R1  1
3/2
T1 1
      T2  8T1 T2 = 8 X 5 = 40 hrs.
T2  R2  4 T2 8

SEC: Jr.C-IPL Page 3

 Sri Chaitanya IIT Academy, India 29-10-2022_Jr.C-IPL_Jee-Main_WTM-13_Key & Sol’s

CHEMISTRY
31. Law of mass action not applicable to physical equilibrium
32. 1 1
Kc  
O2 5
x1 O2 5
33.  NH3  should be increased with time. And  N2  and  H 2  should decreased with time.
34. Precipitation reactions are irreversible
Qc 
 SO3 
2

 0.001
2
35.
 SO2 2 O2   0.0012 x 0.001
Qc  1000

36. N 2  3H 2 2 NH 3 12 0 1  x  2  3x  2x given 2 x  1  x  1
2

KC 
 NH 3 2  12
 N2  H 2 3  1  1
2
3
2
 16
1 0 nTotal  1    2  1   nTotal  1    2  1  
37. N 2O4 2 NO2 1   2  2 
2
P 2 NO2  P
Kp  1  4 2 P
PN 2O4 Kp   
1  1 2
 P
1 

2A  B 2C  D
38.  2  2x  2  x  2x x No. of moles g D at equilibrium=0.4So
2 2 0 0
2A  B 2C  D  2  2x  2  x  2 x x
1.2 1.6 0.8 0.4 Partial pressure of gas  no.of moles of gas organic vol ID
39. Kolbe’s electrolysis
40. Conceptual
41. Decarboxylation of sodium acetate
42. Methane
43. Above C17 are solids at room temperature
44. 2 bromo 2 methyl butane
45. Alkene treated with potassium tertiary butoxide instead of Ethoxide Hoffmann product
formed.
46. A  C2 H 6 B  C2 H 4

47. Only symmetrical alkanes i.e., Butane prepared in good yield by wurtz reaction.

SEC: Jr.C-IPL Page 4

 Sri Chaitanya IIT Academy, India 29-10-2022_Jr.C-IPL_Jee-Main_WTM-13_Key & Sol’s
48. Corey. House reaction
49. Some alkyl bromides more reactive than alkyl chlorides. There fore intra molecular
wurtz-Rxn occurs on the side of Br
Na  
Br 
-
Dry Ether
2 Na  
  NaBr    Nacl 

Cl Cl

Bicyclo (1,1,0) Butane

Red P wurtz reaction
50. CH3I  HI  4
CH 4  I 2 CH 3 I  2 Na  CH 3I 

453K

H 3C  CH 3  2 NaI

n
51. Active mass = = 5.6 / 22.4  1 M
V  lit  5.6 22.4

52. K C  K1 x K 2 x K 3

2a 2a a a a a
53. A B C  D a a 00 a  a a  a a a x
1
3 3 3 3 3 3 3 3 KC  3 3   0.25
2a 2a 4
x
3 3

54. N 2O4 2 NO2 at Equillibrium 1   2 total moles = 1   + 2 = 1  

  2  
2
P x 4 2 4  0.2 
2
 P  1     K P  1x 
1
 
KP   1 2
1   0.2 
2 6
1 
P 
1  

55. N 2O4 2 NO2 0 1   2 Total no.of moles at Equillibrium= 1    2 = 1   From

P1 P
ideal gas equation  2 BeforeAfter Equillibrium Equillibrium 6

16
n1T1 n2T2 1 x 300 1    600

  1
3
P 2 NO2
KP  8
PN 2O4

C2 H 5

H 7C3  C  CH 3

56. 7Carbons H

57. WURTZ REACTION

58. Total possible optically isomers
59. X is Benzene no.of  electrons  6
Na
60. 2CH 3I C2 H 6  2 NaI 2moles  1mole 2x142gms  1mole
dry Ether =284gms

SEC: Jr.C-IPL Page 5

 Sri Chaitanya IIT Academy, India 29-10-2022_Jr.C-IPL_Jee-Main_WTM-13_Key & Sol’s

MATHEMATICS
1      
61.   2   1  1  1 
 3 1 
sin 1  cot  sin 1  sec 1 2    sin  cot  sin  sin 12   cos  cos 6   sec  sec 4   
1 3
   cos      
 
  2 2  2    
  
        
 sin 1  cot       sin 1  cot     sin 1  0   0
  12 6 4    2 

 tan 
n
 r  r 1   r  r 1   1
r  tan 1 r  1
n n
62.  sin  1
   ta n 
1


r 1  r (r  1)  r 1  1  r r 1  r 1

 tan 1 1  tan 1 0  tan 1 2  tan 1 1  tan 1 3  tan 1 2  ........  tan 1 n  tan 1 n  1

 tan 1 n  tan 1  0  tan 1 n
     
63. sin 1  cos 2    cos 1  cos 2    2 cos  sin 2  
1
 sin 1  sin 2    sin 1 sin   2      2  2 
2 2 2 2 2 2
   3
tan 1  cot 4    cot 1  cot  4     cot 1  cot  4       4    4
2 2 2 2
   3
cot 1  tan 4    tan 1  tan  4     tan 1  tan  4      4    4
2 2 2 2
 
sec 1
 cos ec6  
2
 cos ec 1
 cos ec6  
2
 cos ec 1
 cos ec  6  2  
 5  
  6 cos ec 1  sec 6    sec1  s ec6    s ec 1  s ec  2  6  
  6  2  
2 2 2 2
 3
   2  6   6
2 2
sin1  cos 2  cos1 sin 2  tan1  cot 4  cot 1  tan 4  sec1  cos ec6  cos ec1 sec6
  3 3 5 3
 22   4  4 6 6  5 16
2 2 2 2 2 2
64.      1  1  1  1 1  1
 3  4   1      n  2    n  2    tan  n    tan  n  
Tn  cot 1  n 2    tan 1  2 1
  tan    1 1
 1
       2   2
 4  4n  3  3 tan  1
tan
 n2    1  n2    1   n  1  n  1  
 4  4     
  2  2
 
  1 1  1 


3
4 


3
4 


3
 cot 1 12    cot 1  22    cot 1  32    ........ 
4
 T    tan
n 1
n
n 1
1
 n    tan  n   
 2   2 
3 1 5 3 7 5
 tan 1    tan 1    tan 1    tan 1    tan 1    tan 1    ........  tan 1   
2 2 2 2 2 2
1  1
 tan 1     tan 1     tan 1    cot 1  1   tan 1  2 
2 2 2 2
n n
2n  n  1
 2 k  2 k   n 2  n  cot 1 1  n  n 2    tan 1  2 1 
23 23
65. 
K 1 k 1 2 n 1 n 1  n  n 1 
23 23
  tan 1  n 1 n   tan  n  1  tan  n 
1 1

n 1  1  n  n  1   n 1
 
 tan 2  tan 1  tan 3  tan1 2  .......  tan 1  24  tan 1  23
1 1 1

 24  1  1  23  1  25 
 tan 1  24   tan 1 1  tan 1    tan    cot  
 1  24   25   23 
 23
 n
  25  25
 cot 1   cot 1 1   2k    cot  cot 1  
 n 1  k 1    23  23
66. Given a1 , a2 , a3 ,.....an are in A.P d  a2  a1  a3  a2 ,.....  an  an1

SEC: Jr.C-IPL Page 6

 Sri Chaitanya IIT Academy, India 29-10-2022_Jr.C-IPL_Jee-Main_WTM-13_Key & Sol’s
  d  1  d  1  d    a a   a a   a  an 1  
tan  tan 1    tan    .......  tan     tan  tan 1  2 1   tan 1  3 2   .......  tan 1  n  
  1  a1a2   1  a2 a3   1  an 1an     1  a1a2   1  a2 a3   1  an 1an  
 tan  tan 1 a2  tan 1 a1  tan 1 a3  tan 1 a2  .....tan 1 an  tan 1 an1 
  a a   an  a1 a1   n  1 d  a1  n  1 d
 tan  tan 1 an  tan 1 a1   tan  tan 1  n 1     
  1  a1an   1  a1an 1  a1an 1  a1an

67. c is a right angle then a 2  b 2  c 2  a b 

 bc  ca 
 a  1  b 
tan 1    1

   b 
tan tan
bc ca  1 a
 bc ca 
 ac  a 2  b 2  bc  1  c  ac  bc 
2

 tan 1    tan 1 
1
  tan  2
 bc  ba  c 2
 ca  ab   c  ac  bc  4

68. Let x  sin     sin 1 x   sin  cos     1         

tan  sin 1        tan  sin sin          tan        tan  1
  2 2      4     4  4
69. cos hx cos h  2 x   1 199  1  200  200  100  10
cot h x   
sin hx cos h  2 x   1 199  1 198 198 99 3 11

70. sin h1  2   x, 2cos h1     x sin hx  2 , cos h1    

x
2
hx hx hx hx x x
cos   2sin cos  2 we know that sin      cos h2  sin h2  1
2 2 2 2 2 2
hx   2
sin    2  2  1   4  2   2   2   2   4
2  
log 1  ax   log 1  bx  log 1  ax  log 1  bx 
71. Lt  k Lt  Lt  k a b  k
x 0 x x 0 x x 0 x
f  x  discontinuous when x  3 x  2  0 x  3 x  2  0  x  1 x  2   0
2 2
72.
x  1 , x  2 =0  x  1, x  2 x  1, 2
73.  x 
 1 
, x  0
 f 1  0   f 1  0  Hence f  x  exists every where
1  x , x  0  
1 x
2

f  x 
x  
   f  x  
1
1 x  x 
, x  0  1 , x  0
1  x 
 1  x 
 2



74. Now   x    is an int egral multiple of  tan   x     0 x f  x   0 x

f 1  x  0 x
75.  x3 , x  0

clearly f  x  is continuous at x  0 3 x 2 , x  0

f  x   x sgn  x   0 , x  0
3
f  x   0 , x  0
1

 x3 , x  0  3 x 2 , x  0
 

f 1  0   f 1  0   0 f  x  is derivable at x  0
Lt f  x   f 1 f 1  Lt x  x  ......  x  n ,  0 from 
2 n
76.
x 1 x 1 x 1 0  
1  2 x  3 x ......  nx
2 n 1
0 n  n  1
 Lt  1  2  3  ....  n f  x  
x 1 1 0 2
3 x 2 , x  0 6 x, x  0 f 111  0   6 6, x  0
77.  
 x3 , x  0   f 111  x   0 , x  0
f  x   x 2 x  0 , x  0 f  x    0 , x  0 f 11  x   0 , x  0
f 11  0   6
 1

 6 x, x  0  6, x  0
 x3 , x  0
  3 x , x  0
3
 
f  x  is thrice different as e at R  0
78.  
f 3  Lt 
x3
1
 f is discontinuous at x  3
x 3x3
  x  3
 
f 3  Lt 
x 3 x3
 1

79. Lt
f  x2   f  x   0 
 from 
L.H Rule Lt f  x  2 x  f  x   f  0 2  0  f  0  0  f  0  1
1 2 1 1 1 1

x 0 f  x   f  0  0  x 0 f 1
 x  0 f 1  0 f 1  0

SEC: Jr.C-IPL Page 7

 Sri Chaitanya IIT Academy, India 29-10-2022_Jr.C-IPL_Jee-Main_WTM-13_Key & Sol’s
1
1  f 1 x  x 1  f 1 x   1  f 1 x   f 1 
 f 1  x   x  Lt 
x0 f 1
 
 x  f 1
1 Lt
x0 x 

f 1

0
80. Lt   1  from  e  
e  
 from 
x 0 
 f 1  0
f 1 1 x   0 f 1 1
Lt 6
f 1 f 1
e
x0
e  e  e2
3

3 
81. sin 1 x  sin 1 y  sin 1 z   sin 1 x  sin 1 y  sin 1 z 
2 2
 x  y  z 1  x 201  y 201 x  y   1  1  1  1   1  1  1  1  3
402 402

 x 603 
 y 603 x y
804     
 1  1  1  1 
804
 
82. 1 1
tan x tan 2 x tan 3x 1
R2  R3 1
tan x tan 1 2 x tan 1 3x
1 1
tan 3x tan x tan 2 x  0 1
tan 1 2 x tan 1 3x tan 1 x  0
1 1
tan 2 x tan 3x tan x 1
tan 1 3x tan 1 x tan 1 2 x

let tan 1 x  a, tan 1 2 x  b.tan 1 3x  c a b c

b c a  0  3abc  a 3  b3  c 3  0
c ab
 a3  b3  c3  3abc  x  0 satisfies above equation no of values of x is 1
 a  b  c  0
 tan 1 x  tan 1 2 x  tan 1 3x  0
83. u, v, w are the roots of x 3  10x  11  0 then u  v  w  0, uv  vw  wu  10, uvw  11
let u  tan  , v  tan  , w  tan  tan(     )   tan    tan   0  11  11  1  tan 
1   tan  tan  1  10 11 4

     3cos ec2  tan 1 u  tan 1 v  tan 1 w  3cos ec2 (     )  3cos ec 2

3  2
2
 3 2  6
4 4
2
84.  4x 
 2
 3x 
  2  2
 tan 1  5 x   tan 1 x  tan 1  x   tan 1    tan 1  5 x   tan 1  
 x
y  tan 1  2 
 tan 1 
 2 x   tan 1  5 x  x

  tan 1  3 

3 3
 1  5x   1   1  x 5x    1 x  2  
   
 3  
 3

dy 5 
  k  5,   25,  5
dx 1  25 x 2
k
6 tanh 
85.  2 tanh  
3    1  6 tanh    tanh 2   9  tanh 2   6 tanh   9
 1  tanh  
2
1 5  5 tanh   4  4 tanh 2 
2

 1  tanh 2  
5  4 
 1  tanh 
2


86. x2  x  1  0 ,  x  R
e x 2 x  1 , x  0 1 
2

87. f  x  
1
f  0   f 1  0  a  e0  0  1 a  1
a ,x 0
Clearly f is continuous at x  0 Lt f  x   Lt f  x   f  0
x 0 x 0
a  6b 1  6 7
Lt  e x  x  Lt  ax  3  b e0  0  b 1  b now    3.5
2

x 0 x 0 2 2 2
88. w.k.t f  x   f  x  , f  0 f  4  f  4  3  2  3  6
1 1 1

89. 1  x  2 1  x3  8 2  2 x3  16 2  6  2 x3  6  10 4  2 x3  6  10
2 x3  6  3, 2, 1,0,1, 2,3, 4,5,6,7,8,9

  1  2 sin x  0  0  2 cos x 1
90. f    Lt   a  Lt
a  0.25
 4  x 4   4 x  0 

x 04 4
4

SEC: Jr.C-IPL Page 8