08-01-2022 SR - super60-II Jee-Main PTM-12 Key & Sol's

Sri Chaitanya IIT Academy 08-01-2022_Sr.
Super60-II_Jee-Main_PTM-12_Key & Sol’s
Sri Chaitanya IIT Academy., India.

A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant

ICON Central Office – Madhapur – Hyderabad
Sec: Sr.Super60-II Jee-Main Date:08-01-2022
Time: 09.00Am to 12.00 PTM-12 Max.Marks:300
Key Sheet
PHYSICS
1 3 2 1 3 2 4 4 5 4
6 4 7 3 8 1 9 2 10 2
11 2 12 1 13 2 14 3 15 3
16 3 17 1 18 2 19 2 20 4
21 10 22 2 23 2 24 9.6 25 15
26 6 27 1 28 4 29 3 30 -6
CHEMISTRY
31 1 32 3 33 2 34 3 35 2
36 1 37 1 38 4 39 2 40 2
41 2 42 1 43 3 44 1 45 2
46 1 47 1 48 3 49 1 50 4
51 100.00 52 6 53 2 54 25 55 00.01
56 -28.60 57 -02.00 58 309.17 59 400 60 41.8
MATHEMATICS
61 1 62 2 63 4 64 3 65 3
66 4 67 3 68 1 69 3 70 2
71 2 72 4 73 2 74 2 75 4
76 4 77 2 78 1 79 4 80 4
81 6 82 15.65 83 2 84 9 85 2
86 0 87 0.5 88 1 89 20 90 0.67
Sec: Sr.Super60-II Page 1

Sri Chaitanya IIT Academy 08-01-2022_Sr.Super60-II_Jee-Main_PTM-12_Key & Sol’s
SOLUTIONS
PHYSICS
1.
A) Position of unstable equilibrium x  a
1 ca c c
B) Total energy mv 2  2  0  mv 2   v 
2 2a a ma
C) To reach at x   particle must cross point B : E A  E B
1 2 ca ca 2c
mv  2  0  2  v 
2 2a 2a ma
2
2. u  5 gR
 v2  u 2  2 gR
 5 gR  2 gR  3gR
Tangential acceleration at B is
a1  g (downwards)
Centripetal acceleration at B is
v2
ac   3 g
R
 Total acceleration will be a  ac2  at2  g 10
(1,1)  
3. W   F . ds
(0,0)

Here ds  dxiˆ  dyjˆ  dzkˆ
(1,1)
W  ( x 2dy  ydx )
(0,0)
(1,1)
W  ( y 2 dy  x.dx ) (as x = y)
(0,0)
(1,1)
 y3 x2  5
 W     J
3 2  (0,0) 6
4. h  2l sin 
A is the lowest point and B the highest point. At B, in critical case tension is zero. Let
velocity of particle at B at this instant be vB . Then

mvB2
mg sin  
l
or vB2  gl sin 
Now v A2  vB2  2 gh
 ( gl sin  )  2 g (2l sin  )
 vA  5 gl sin 
5. In equilibrium ( Fnet  0)
T  kx …………………(i)
kx
2T   mg …………….….(ii)
2
Solving these equations, we have
2mg 2  1  10
x   0.4 m
5k 5  10
Let v be the speed of block placed horizontally, then
2 2
1 2 1 v 1 2 1  x  x
mv  m    kx  k    mg  
2 2 2 2 2 2 2
5 2 mgx 5 2
or mv   kx
8 2 8
8  gx 5kx 2 
or v   
5 2 8m 
Substituting the values, we have
8 10  0.4 5  10  0.16  8
v    1.6
5  2 8 1  5
= 1.26 m/s
6. a  g sin    g cos 
3 4
 10   0.5  10   2 m / s 2
5 5
Velocity of block at B or at C,

20h
v  2 as  2  2  h / sin  
3
For not to leave contact anywhere
v  2 gR
20h
or  20 R
3
or h  3R
or h  1.5m
7. Let lower spring compresses maximum by x metre.
From conservation of mechanical energy,
Decreases in potential energy of block
= increases in elastic potential energy of both the springs
1 1
(2) (10)( x  1)   10  x 2   10  ( x  1)2
2 2
2 2
or 20 x  20  5 x  5 x  5  10 x
 10 x 2  10 x  15  0
or 2 x 2  2 x  3  0
2  4  24
 x
4
or x  1.82 m
At equilibrium position net force on the block should be zero. So, let it is at distance y
from where it was released.
Then,
mg  Ky  K ( y  1)
or 20  10 y  10( y  1)
or 20 y  30
 y  1.5 m
8. After 1s, their vertical velocities are 10 m/s each. Let v be the horizontal component
of velocity of 1 kg, then from conservation of linear momentum I horizontal direction.
v
Horizontal component of 2 kg block will be .
2
2u
Total time of flight is  4s . In rest of the time i.e., in 3s they have separated by
g
90m
 v
  v    3  90
 2
v
or v = 20 m/s and  10 m / s
2
Just after explosion, v1  (10) 2  (v 2 )
 10 5 m / s

2
2 v
and v2  (10)     10 2 m / s
2
9. Velocity is zero where total energy is completely potential
3B 2 A B
Hence  2
 2
16 A r r
2r0 4A
At r or
3 3B
Left hand side,
2
 9B   3B 
LHS  A    B 
 16 A 
2
 4A 
 
3B 2
 = RHS
16 A
10. Let a be the acceleration of wedge leftwards and ar the relative acceleration of block
down the plane. Then absolute acceleration of block in horizontal direction will be
( ar cos   a ) towards right. Net force on the system in horizontal direction is zero.
Therefore, acceleration of COM in horizontal direction will be zero or acceleration of
wedge towards left is equal to the acceleration of block towards right.
 ar cos   a  a
or 2a  ar cos  ………..(1)
Now let N be the normal reaction between the block and the wedge. Then free body
diagram of wedge gives
N sin   ma ……………..(2)
Free body diagram of block with respect to wedge is:
Net force on block perpendicular to plane is zero
Hence,
N  ma sin   mg cos
Solving Eqs. (1), (2) and (3), we get,
2 g sin 
ar 
1  sin 
Acceleration of block vertically downwards
a y  ar sin 
2 g sin 2 
ay 
1  sin 2 
 acceleration of COM is
ay g sin 2 
acom  
2 (1  sin 2  )
11. Conceptual
 dp 
12. F  2 Bt
dt
    A
 When a and u are at 450 F and p will also be at 450. This will happen at t 
B
  A
 F  2B
B
13. Initially x-coordinate of centre of mass is :
(4 M )(0)  M (5R )
xi  R
4M  M
Let x0 be the x-coordinate of shell when the small sphere reaches the other extreme
position. Then finally x-coordinate of centre of mass is
(4M )( x0 )  M ( x0  5 R)
xf 
4M  M
 x0  R ……………….(1)
All the surfaces are smooth, therefore, centre of mass will not move in x-direction
 xi  x f
or R  x0  R
or x0  2 R
14. Speed of ball before collision is
1
v  u cos 600  (20)    10 m / s
2
Since, collision is perfectly inelastic (e = 0), the ball will not bounce. It will move
along the plane with velocity v1
10 3
v '  v cos 300   5 3m / s
2
 Maximum height attained by ball
2
H
2 2
u sin 60

0
v ' 
2g 2 g sin 300
2
 3
(20) 2  
 2  (5 3) 2
 
20 10
300 75 450
    22.5 m
20 10 20
R
R
15. t 2 
V 2V
2 R 4t
t1  
eV e
16. After colliding with ground, horizontal components of velocity, i..e.,
10 sin 300  5m / s will remain unchanged while its vertical component will become
zero. Collision with wall is elastic.
Hence, it will only reverse the direction of velocity of ball, magnitude will remain
unchanged, i.e., 5 m/s
Therefore,
BC  CB  BA 30
t   6 s
V 5
10
17. a1  t  t , a2  10 m / s
10
m a  m2 a2
aCM  1 1 ( m1  m2 )
m1  m2
(a  a )
 1 2
2
 t
 5  
 2
At t = 0, aCM  5 m / s 2 and at t = 10s, aCM  10m / s 2
1
So, the graph is a straight line with intercept 5 m/s2 and slope m/s2
2
18. Let v be the horizontal velocity of wedge at topmost point and vr the relative of block
with respect to wedge.
vr is at 600 with horizontal. Absolute velocity of block will be the resultant of vr and v
and since it is given at 300 with horizontal, vr and v should be equal in magnitude.
Now, applying conservation of linear momentum in horizontal direction and
conservation of mechanical energy
1 v0  2  v  1 vb cos 300
3
or v0  2v  v
2
7
or v0  v …………….(i)
2
1 1 1
 1  v02   2  v 2   1  ( 3v) 2  1  10  1.45
2 2 2
or v02  5v 2  29 ……………..(ii)
Solving Eqs. (i) and (ii) , we have
v0  7 m / s
19. At t = 0,
m v  m2v2
VCM  1 1
m1  m2
(1)(20)  (1)(10)
  5m / s
2
Upto 5 s vCM is constant
 d1  vCM t  25 m
After that retardation of centre of mass is :
 g 0.2  10
a   1m / s 2
2 2
v2 (5) 2
 d 2  CM   12.5
2a 2
Total distance d  d1  d 2  37.5 m
20. P1  m1 v1 (at time t)
 (1) (15   gt )
or P1  15   gt (till their velocities become equal)
P2  m2v2
  m1 g 
 (2)  t
m
 2 
or P2   gt (again till their velocities become equal)
Finally P1  P2  initial momentum of 1 + 15 kg m/s
But P2  P1 as mass of 2 is more, although their velocities are equal
21. PD = 2 V
q  10  C
22. Starting from a, we can write the equation:
Va  2  1  2  2  4  2  1  12  2  2  4  2  2  Vi
From this equation we can see that on reaching point f or h net drop or up in the
potential is zero. Hence,
Va  V f  Vh
 1 q  
23. E . ( r1  r2 )
4 0 r 3
(9  109 ) (2  109 ) ˆ
 ( i  5 ˆj  k )ˆ
(3 3) 2
2 ˆ
 (i  5 ˆj  k )ˆ
9 3
2
Component of this electric field along x-axis is  N /C
9 3
24.
X 2 L 2L
 i
0   ( Fm )(2 L  x )    0  (i )(2 L  x ) dx
X L L 
2 x 
2
 i
 0 [2 L In x  x ]2LL
2
0 i 2 (0.4) 0 i 2 L
 [2 L In (2)  L]  …………………. (i)
2 2
 (0.4) (2  10 7 )(4)  3.2  107 N  m
mL2 (0.1)(1) 2 1
I0    kg  m2
3 3 30

  0  9.6  106 rad / s 2
I0
25. There is no resistance in the circuit. Hence, energy will be conserved.
1 1
E  C1V 2  C2V 2 (at t = 0)
2 2
1 1
  1  (2500)   2  100  1350 J
2 2
At the given instant energy stored in the capacitors is:
1 q 2 1 q22
U 1 
2 C1 2 C2
1 (400) 1 (100)
   225 J
2 1 2 2
1 1
E  U  Li 2 or 1125   5  i 2
2 2

 i  15 2 A
26. Given RA  RB
  A N A  B N B
 In 2    At  In 2   B t
or   (4 N 0e )  ( N 0 )  e
 TA   TB 
e (  A  B ) t  8
 ( A  B )t  In 8  3( In 2)
 In 2 In 2 
    t  3 In (2)
 1 2 
or t = 6 min
P P
27. r or r
Bq q
re  2r
Pe P 
  2  
1  2 
 Pe  P
Now, de-Broglie wavelength
h 1
 or 
P P
Now, as Pe  P  e  
or x=1
mv
28. r
Be
nh nh
L  mvr   Vr 
2 2 m
e e
M  iA    ( r 2 )  ( r 2 )
T  (2 r / v)
evr neh
 
2 4 m
nehB
Now, U   MB cos1800 
4 m
29. The potential energy is maximum at x  1
So, for given values potential energy is minimum at x  3 and so, KE is maximum
here
30. Wspring  W100 N  k (on A)
 10  1 2
Wspring  (100)    (2)(2)
 100  2
Wspring  4  10  6 J

CHEMISTRY
31.  A and B are in thermal equilibrium and B & C also,
therefore according to zeroth law of thermodynamics A & C are also in
thermal equilibrium, which means temperature in system A is equal to
temperature in system C.
 Apply Boyle’s law, PAVA  PCVC
PV 0.755 atm  4.31lit
PC  A A   1.251atm
VC 2.6 lit
32. Conceptual
33. For adiabatic compression,
work done is positive
From the diagram it is clear that wirr  wrev .
Further in an adiabatic process,  q  0
E  w
 Eirr  Erev
Consequently the increase in temperature for irreversible process is greater
than in reversible process
 H irr  H rev
34. Silver mirror test is given when ammonical silver nitrate is reduced to silver.
Benzaldehyde, Fructose and glucose (containing hemiacetal linkages) give silver
mirror test.
On the other hand, HC  CH reacts with ammonical silver nitrate to give white
precipitate, but silver is not reduced .
H  C  C  H  2 AgNO3  2NH4OH  Ag C  CAg   2NH4 NO3  2H2O
White ppt
35. Compound which forms most stable carbocation during electrophilic
addition is more reactive towards Markownikoff’s addition.
Resonance stabilized carbocation

1
36. (i)   D  glucose (aq )    D  glucose ( aq ) ; H o  1.16kJ mol
1
(ii)   D  glucose( s )    D  glucose( aq ) ; H o  10.72kJ mol
1
(iii)   D  glucose( s )    D  glucose(aq ) ; H o  4.68kJ .mol
To obtain reaction
(iv)   D  glucose( s )    D  glucose( s )
(iv) = (ii) + (i) – (iii)
 H o  10.72 – 1.16 – 4.68 = 4.88 kJ mol-1

37. Y to Z is an endothermic reaction indicates that Z has more energy than Y by
100kCal. Likewise Z to X is an exothermic reaction indicates that X has 80kCal less
energy than Z. This can be visualized diagrammatically as shown below:
80kCal
100kCal
E
X
From the above diagram it is clear that order of enthalpy of formation is

Y < X < Z.
38. At equilibrium between phases, the molar heat capacity(q/ΔT) is infinity because there
is no change in temperature(ΔT=0)
39. C6 H 8  2 H 2  C6 H 12 , H r  ?
H r  H C ( R)  H C ( P)
  stoichiometric coefficient
 3680  2  ( 241)  ( 3920)
 242 KJ/mol
40. In thiamine the negative charge in conjugate base at 3rd position is in resonance with
adjacent carbonyl groups which is more stabilized than the negative charge in
conjugate base at 4th position.
41. Dimethyl amine is a good nucleophile which substitutes the F atom on the benzene by
SNAr mechanism. Cyano group being an electron withdrawing group facilitates the
substitution.
42. [Co(en) 2 Cl2 ] exists as cis and trans isomers. Cis isomer is optically active and has d
and l forms, whereas trans isomer is optically inactive.
43. Zirconium is purified by first converting into its volatile iodide followed by
decomposition to give pure metal. This proess is called Van-Arkel method
44. In ‘1’ the shaded plane contains 5 particles(4 at corners and one at body centre) and
thus has maximum packing fraction.
45. C3 H 8  5O2  3CO2  4 H 2O
H  {6(C  O )  8(O  H )}  2(C  C )  8(C  H )  5(O  O )
= 8a1  5a2  2 a5  6a3  8a4
46. Product of PV increases, so T increases. Since ΔT > 0, therefore ΔH > 0. The process
is reversible because the graph is curve.
47. PV  RT at T K
P (V  V )  R (T  1) at (T  1) K
PV  PV  RT  R  PV  RT for 1 mole
 PV  R
Work done W   PV   R
48. CONCEPTUAL
49. E  Q  W heat absorbed system Q is +ve work done by the system, W is –ve.
E  7.1J  (394 J )
 307J
50. E  q  w . Since in the process, change in the internal energy is equal to work done
therefore q  0 . That means the process is adiabatic.
51.
After step 1, the pressure at point 2(let it be P2) as shown in the above figure is
1 20
P2   2atm
10
In step 2, the initial pressure is P2=2atm and volume is V2=10lit. The final state is
denoted with point 3 in the above diagram. Let the final volume be denoted with V 3
which is equal to 2lit. Therefore, final pressure(P3) is
2  10
P3   10atm
2
Now work done is given by the area of the shaded region as shown in the diagram,
W  (20  10)  2  (10  2)  10  100 lit.atm
52. 4 mol of CH4 releases energy equal to 1 mol of C4H10. Since no of moles is directly
proportional to volume of the gas under given conditions,
Therefore, 4 x 1.5L = 6L of CH4 per hour gives same energy as that of 1.5L of butane
per hour.
53. Primary alcohols give red colour in Victor-Meyer’s test. There can be two possible
primary alcohols for the formula C4H10O,
CH3
OH
OH
i) H3C ii) H3C
54. PCl3  3H 2O  H 3 PO3  3 HCl
Each mole of PCl3 gives 1 mole of H3PO3 and 3 moles of HCl. For 5 moles of PCl3
obviously 5 moles of H3PO3 and 15 moles of HCl are obtained. Since H3PO 3 is dibasic
acid, 10 moles of NaOH is required to neutralize it and 15 moles of NaOH for
neutralizing 15 moles of HCl
55. BOH  B   OH 
C  C C C
pH  9
5
( H  )  109 and (OH  )  10  C
105  01    104  100%
 0.01%
56. q p  qv  ( ng ) RT
1(2)  300
28  qv 
1000
qv  28.6
57. W   Pext (V2  V1 )
 nRT nRT 
  Pext   
 P2 P1 
1 1
  Pext nRT   
 P2 P1 
1 1 
 2  1  8.314  300   
 2 10 
 1995.3J  1.99kJ
58. Given S  s   3F2  g   SF6 ; H  1100 KJ ……(1)
S  s  S  g  ; H  275 KJ ……(2)
1 F g  F g ; H  80 KJ ……..(3)
2 2
SF6 g   S g   6 F g  ;
To get ,
 2   6   3  1
SF6  S  6F , H  1855 KJ
1855
Avg. B.E =  309.17
6
1 1
59. X 2  Y2  X  Y ; H  100kJ
2 2
1 1
or 100kJ  H X  X  H Y Y  H X Y  If HY Y  a 
2 2
1 1
or 100 kJ  2a  a  2a
2 2
or a  200 kJ
 H X  X  2  200  400kJ mol 1
60. According to Hess’s law,  sub H   fus H   vap H
57.3  15.5  x (or ) x  41.8 kJ mol 1

MATHEMATICS
1
61. Slope of required tangent =
2
6
1
Equation of tangent in terms of slope to y  6 x is y  x  4
2
2 1
2
1
y  x3
2
2y  x  6
 (5, 4) does not lies on x  2 y  6  0 :
x  2y  6  0
x2 y 2 43 1
62. Given ellipse   1; eE  
4 3 4 2
 1 
Focus of ellipse   2 , 0 
 2 
= [1, 0]
Focus of hyperbola = [1, 0]
1
 aeH  1 eH   2
1/ 2
1
 Hyperbola equation is x 2  y 2 
2
 3 1 
 it does not pass through  , 
 2 2
x2 y 2
63.  1 y  kx  2h is a tangent to ellipse
3 2
 (2h) 2  3(k ) 2  2
4h 2  3k 2  2
 4h 2  3k 2  2
 locus of (h, k) is 4 x 2  3 y 2  2
x2 y2
 1
1 2
2 3
1 2
Eccentricity e  2 3  3 4 2  7
1 6 3
2
64. Line having equal intercepts is
x y
 1
P P
x  y  P …………………………….(1)
x2 y 2
Give hyperbola is   1 ………(2)
4 1
(1) is normal to hyperbola (2)
2
a2 b2  a  b 
2 2
(using the condition 2  2 

l m m2
4 1 (4  1) 2 25 5
 2 2 2
3  2  P 
1 1 P P 3
5
 (1) becomes x  y  ……………………..(3)
3
x2 y2
(3) is tangent to 2  2  1
a b
25
a 2 (1) 2  b 2 (1) 2   3(a 2  b 2 )  25
3
1
65. y  mx  …………. (1)
m
(1) is tangent to circle ( x  3)2  y 2  9
 rd
m (3)  0  1
 3 m
2
m 1
2
 9( m2  1)  (3m  1 / m) =
3m
2
2
 1
m2
Let m2 = t
2
 9  t  1 
 3t  1
t
2 2
 9t  9t  9t  1  6t
 3t = 1
1
t = 1/3, m2 = 1/3; m  
3
1
y x 3;  3 y  x  3 which is lies above the x-axis
3
66. y  2 x  a 2  22   b 2 …(1)
(1) passes through (-2, 0)
 o  4  4a 2  b2
 4a 2  b 2  4
4a2 + b2 = 16
AM  GM
4a 2  b 2
 4a 2 b 2
2
8  2ab
ab  4
67.  '  t   1  2t  0 ; t = 1/2
 Max value of   t 
5 1 1
=  
12 2 4
563 8 2
=  
12 12 3
2
 eE 
3
2
2b
 10
a
2b2 = 10a
b2 = 5a
a 2 1  eE2   5a
 4
a 2 1    5a
 9
5
a 2    5a
9
a = 9 ;  b2 = 5(9) = 45
 a2 + b2 = 81 + 45 = 126
x2 y 2 a 2b 2 2.1 2
68.   1 Product of perpendiculars = 2 2
  ; k  2
2 1 a b 2 1 3
69. PQ is double ordinate
R(x 1, y1) is point of trisection
R divides PQ in the ratio 2 : 1
 2bt  4bt bt 2  2bt 2 

 ,    x1 y1 
 3 3 
2
 2bt 3bt 
 ,    x1 y1 
 3 3 
2bt
 x1 ; bt 2  y1
3

3x1 9 x12
t ;  b 2  y1
2b 4b
2
9 x1  4by1
 locus of (x1, y1) is 9x2 = 4by
16  b2
70. eE 
16
16  b 2
=
4
foci of ellipse   4eE , 0 

=  16  b2 , 0 
x2 y2
 1
144 / 25 81 / 25
144 81

eH  25 25  225  15  5
144 144 12 4
25
 12 5 
Foci of the hyperbola =    , 0 
 5 4 
=  3, 0
16 – b2 = 9  b2 = 7
x2 y 2
71.  1
2 1
Let P  
2 cos  , sin  be a pt on ellipse
x y
Tangent at ‘P’cos   sin   1 ---------(1)
2 1
x y
   1 ……..(2)
2 sec  cos ec
(2) meets x-axis at Q and y-axis at R
Q   2 sec , 0 
R  0, cos ec 
Mid point of QR = (x 1 y1)
 2 sec  cos ec 
 ,    x1 y1 
 2 2 
1 1
 x1 ;  y1
2 cos  2sin 
1 1
cos   ; sin  
2 x1 2 y1
1 1
cos 2   sin 2   1 ;  2  2  1
2 x1 4 y1
1 1
 Locus is 2  2  1
2x 4y
72. From triangle SA1L
b2 / a
0
Tan30 
ae  a
1 b2 a 2  e 2  1
 2  2
3 a  e  1 a  e  1
1
 e 1
3
1 1 3
e 1 
3 3
x 2 1  1/ x 2  1  1/ x  dx
2
73.  dx   2
 1   1  1  1  1
x  x 2  1  2  cot 1  x  
2
 x   1 cot  x  
 x   x 
 x   x
1
Put cot 1  x t
x
1  1
 dt  .
2 
1  2 
dx
 1  x 
1  x  
 x

dt  1
I     ln cot 1  x    c
t  x
74. Given line y = 2x, tangent is parallel to y = 2x
slope of tangent = 2
2
Equation of tangent y  2 x  4  2   2 ; y  2 x  14
2 x  y  14  0 ……..(1)
  a 2l b 2 m   4  2  2  1 
Point of contact is (x 1, y1) =   ,  , 
 n n   14 14 
 8 2  2 2 64 20 84
= ,  ; x1  5 y1  14  14  14  6
 14 14 
75. Normal at ‘P’ Normal at ‘Q’
2 2
a x b y ax by
  a2  b2   a 2  b2
a sec  b tan  sec  tan 
ax by ax by
   a 2  b 2 …(1)   a 2  b2
sec  tan     
sec     tan    
2  2 
ax by
ax cos   by cot   a 2  b 2 ..(1)   a 2  b2
cos ec cot 
ax sin   by tan   a 2  b 2 ….(2)
Find the point of intersection of (1) and (2)
a  a 2  b 2   cos   sin   a 2
 b2 
k  
ab  sin   cos   b
76.
y2 = 4ax ….(1) ; y = ax …………..(2)
a2x2 = 4ax
ax2 = 4x
x(ax – 4) = 0
x = 0, x = 4/a
4 
 P   , 4
a 
4/ a
Now required area =  2
0
a x  ax dx 

4/ a 4/ a
 x3/2   x2 
= 2 a  a 2 
3 / 2  0
3/2 2
2  4   a  4  
= 2 2.       
3  a   2  a  
4 a 8 8 32 8 8
= .    
3 a a a 3a a 3a
1 8 1
 Given area = ;    a  24
9 3a 9
77.
95 2
e 
9 3
2
 b   2 5  5
L   ae,   3. ,    2, 
 a   3 3  3
Equation of tangent at
 5 x  2  y  5 / 3 2x y
L  2,   1    1  2x  3y  9
 3 9 5 9 3
92
Area of quadrilateral PQRT = 4   27
2 | 2.3 |
x2 y 2
78.  1
6 2
Equation of variable tangent is y  mx  a 2 m 2  b 2 ……(1)
Equation of perpendicular line drawn from centre (0, 0) to tangent (1) is
1  x 
y
m
x ….(2) m  y 
 
Eliminate ‘m’ from (1) & (2)
 x  2 x
2
y2  x2 6x2  2 y 2
y    x  a 2  b2 ;  
 y  y y y
2
x 2
 y 2   6x2  2 y 2
79. Product of perpendicular from foci to any tangent = b2
 b2 = 20 x 55
2 2
SS1 = 2ae  2ae   40    35  52  82  52  7 2 = 5 113
4a 2 e 2  25  113
4a2 - 4 x 20 x 55 = 25 x 113  4a2 = 25 x 289
 2a = 5 x 17 = 85
80. Given ellipse
x2 y2
 1
5/3 5/ 2
5 5
a2  ; b2 
3 3
5 5
a ; b
3 2
2ab S11
Tan  2
x1  y12  a 2  b2
5 5 3 8
2. . .  1
3 2 5 5 12
= 
5 5 5
1 4    
3 2
81. Any point on x + y = 1 can be taken as P(t, 1 – t)
The equation of chord having ‘P’ as mid point is
y(1 – t) – 2a(x + t) = (1 – t)2 – 4at -------------(1)
(1) Passes through (a, 2a)
2a(1 – t) – 2a(a + t) = (1 – t)2 – 4at
2a – 2at – 2a2 – 2at = 1 + t2 – 2t – 4at
t2 – 2t + 2a2 – 2a + 1 = 0  two distinct chords
 D > 0  4 – 4 (2a2 – 2a + 1) > 0
4[ 1 – 2a2 + 2a – 1] > 0
–2a2 + 2a > 0
2a2 – 2a < 0  2a(a – 1) < 0
0<a<1
Length of latusrectum = 4a  0, 4 
 Length of latusrectum = 1, 2, 3
Sum = 1 + 2 + 3 = 6
82. Equation of circle ‘C’ is
2 2
 x  2    y  1    x  2 y  0
x2 + 4 – 4x + y2 – 2y + 1 +  x – 2  y = 0
x2 + y2 + x (  – 4) – y(2 + 2  ) + 5 = 0 . ……(1)
(1) cuts x 2 + y2 + 2y – 5 = 0 …….(2)
Common chord of (1) & (2)
x    4   y  2  2   2 y  10  0 ….. (3)

(3) is diameter of C1  (3) passes through (0, -1)
 0  1 2  2   2  10  0
2  14  0;   7
 Equation of circle ‘C’ is
x 2  y 2  11x  y  12   5  0
121
r  36  5
4
121  124 245
r 
4 4
2r = 15.65
83. S1 = S11
xx1  yy1  x12  y12 ………(1)
(1) touches y2 = 8x
2
 2   y1   x1  y12  x12 
2 y12  x1 y12  x13
x13  y12  x1  2 
 Locus of mid point (x1 y1) is 2y2 = x(y2 – x2)
84. Centre of circle = (1, 2) radius = 1
Line intersect the circle  d < r
|38 k | | k  11|
d  1
5 5
|k – 11| < 5
 –5 < k – 11 < 5
6 < k < 16
k = 7,8,9,10,11,12,13,14,15
 f x  1  f  x  1  f x 
Lt  1 x  1  Lt  x   Lt  1 2 
x x 3 x x 3 x 
 e3
x 0 x  0 x  0
85. e e  e e ; e
f  x
 Lt 2
x 0 x2
86. Put x = 0
0 1 3
t= 1 0 4  0
3 4 0
87. sin 1 cos   x  2  x  2 
sin 1  cos 0   sin 1 1   / 2  k
1
 k  0.5
2
88.  ,  are roots of x 2   a  2  x  a  1  0
2 2
     a  2    1  a  2   2       2   a  2   2 1  a 
= a 2  4  4a  2  2 a
= a 2  2a  2
2
=  a  1  1
It is minimum when a = 1
n
 1
89. f  x    x   sum of coefficients = 64
 x
n
 1 n
1    64  2  64  n  6
 1
r
6 r  1  62 r
Tr 1  Cr  x  .   6 Cr  x 
6
x
For indendent of x, 6 – 2r = 0  r = 3
6
 T4  C3  20
90. Let a, b, 12 three numbers in G.P.
 b2 = 2a …………(1)
Let a, b, 9 three numbers in A.P.
2b = 9 + a ….......(2)
From (1) and (2)
b2 = 12[2b – 9] = 24b – 108
b2 – 24b + 108 = 0
(b – 6) . (b – 18) = 0
 b = 6, b = 18
If b = 6 then a = 3
If b = 18 then a = 27
27, 18, 12 are in G.P.
 common ratio = 2/3
Common ratio = 0.67

08-01-2022 SR - super60-II Jee-Main PTM-12 Key & Sol's

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Super60-II_Jee-Main_PTM-12_Key & Sol’s

Sri Chaitanya IIT Academy., India.

A right Choice for the Real Aspirant

Sec: Sr.Super60-II Page 1

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Resonance stabilized carbocation

Sec: Sr.Super60-II Page 11

From the above diagram it is clear that order of enthalpy of formation is

Sec: Sr.Super60-II Page 14

(using the condition 2  2 

 2bt  4bt bt 2  2bt 2 

Sec: Sr.Super60-II Page 17

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Sec: Sr.Super60-II Page 22

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