Sri Chaitanya IIT Academy., India.

A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI

A right Choice for the Real Aspirant

ICON Central Office – Madhapur – Hyderabad
Sec: Sr.Super60,BT-1 & All Jee-Main Date:13-03-2021
Time: 09.00Am to 12.00 GTM-14 Max.Marks:300
Key Sheet
PHYSICS
1 3 2 3 3 3 4 2 5 3
6 3 7 3 8 4 9 4 10 3
11 4 12 3 13 1 14 4 15 1
16 2 17 2 18 2 19 1 20 1
21 9 22 8 23 6 24 3 25 5
26 98 27 3.85 28 8 29 480 30 10

CHEMISTRY
31 2 32 4 33 3 34 1 35 2
36 1 37 2 38 2 39 1 40 4
41 1 42 4 43 3 44 4 45 4
46 2 47 4 48 3 49 4 50 2
51 4 52 2 53 6 54 3 55 80.0
56 4.0 57 4.0 58 8.0 59 5 60 4

MATHEMATICS
61 1 62 4 63 4 64 2 65 2
66 1 67 2 68 1 69 3 70 4
71 3 72 1 73 4 74 3 75 3
76 1 77 4 78 2 79 3 80 2
81 2 82 1 83 0.94 84 5.0 85 55
86 126 87 25 88 8.33 89 9.0 90 7.0
Sri Chaitanya IIT Academy 13-03-2021_Sr.Super60 & All_Jee-Main_GTM-14_Key & Sol’s

SOLUTIONS
PHYSICS
01. Consider the expression for the energy of a photon E  h to get the dimensions of h as
those of (energy × time). Again the expression for the force F acting on a charge q
moving with velocity  in a magnetic filed is qBsin  . This gives the dimensions of
qB as those of (force/velocity). Use these to determine the dimensions of the quantity
under consideration, noting that n is a dimensionless quantity.
02. Here, 2F&3F capacitors are connected in series.
Their equivalent capacitance is

1 1 1 6
  or CS  F
CS 2 3 5
Net voltage, V = 16V – 6V = 10 V
The equivalent circuit diagram as shown in figure below.
Charge on each capacitor,
6
q  CSV   10  12C
5
12C
The potential difference between A and B    6V
2F
03. Total time of flight is T = 4s and if u is its initial speed and  the angle if projection.
Then
2u sin 
T  4 or u sin   g …………. (i)
g
After 1s velocity vector makes an angle of 450 with horizontal i.e.,  x   y
u cos   u sin   gt
u cos   u sin   g  t  1s 
u cos   2g  g (Using (i))
Or u cos   g ……………… (ii)
Squaring and adding (i) and (ii), we get
2 2
u 2 sin 2   u 2 cos 2    2g    g 
2
u 2  5g 2  5 10  m 2s 2
 u  22.36ms1
Dividing (i) by (ii), we get,
usin  2g
 2
u cos  g

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Sri Chaitanya IIT Academy 13-03-2021_Sr.Super60 & All_Jee-Main_GTM-14_Key & Sol’s

tan   2or   tan 1  2 

04. As field due to current loop 1 at an axial point

0 I1R 2
 B1  3/2
2  d2  R 2 
Flux linked with smaller loop 2 due to B1 is
0 I1R 2
2  B1A 2  3/2
r 2
2d2  R 2 
The coefficient of mutual inductance between the loops is
2 0 R 2 r 2
M 
I1 2 d 2  R 2 3/2
 
Flux linked with bigger loop 1 is
0 R 2r 2 I 2
1  MI 2  3/2

2 d2  R 2 
Substituting the given values, we get
2 2
4  10 7   20  102      0.3  10 2   2
1  3/2
2 2
2 15  10 2    20  10 2  
 
11
1  9.1  10 weber
1 T
05. Fundamental frequency of vibration of wire is   where L is the length of the
2L 
wire, T is the tension in the wire and  is the mass per length of the wire
As   A
Where v is the density of the material of the wire and A is the area of cross-section of the
wire.
1 T
 
2L A
Here tension is due to elasticity of wire
 L   Stress TL 
 T  YA    As Y  
 L   Strain AL 
1 YL
Hence,  
2L L
Here, Y  2.2  1011 N m 2 ,   7.7  103 kg m 3
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Sri Chaitanya IIT Academy 13-03-2021_Sr.Super60 & All_Jee-Main_GTM-14_Key & Sol’s
L
 0.01,L  1.5m
L
Substituting the given values, we get
1 2.2  1011  0.01 103 2
  Hz  178.2Hz
2  1.5 7.7  103 3 7
06. Using Gauss’s theorem for spherical surface of radius r outside the sphere with the
charge q
r r
1
0 Eds 0 0   r  dV
r
1  
E4r   q    4r 2  dr 
2

0  R
r 

E4r 2

 q  2R   4r
2 2

0 2 0
The intensity E does not depend on R if
q  2R 2
 0 or q  2R 2
0
07. Efficiency of a perfect engine working between 30 C & 270 C (i.e.
T2  270K &T1  300K )
T 270K
engine  1  2  1   0.1 ………. (i)
T1 300K
Since efficiency of the refrigerator  ref . is 50% of engine
ref .  0.5engine  0.05 (Using (i))
If Q1 is the heat transferred per second at higher temperature by doing work W, then
W W 1kJ
ref .  or Q1    20 kJ  asW  1kW  1s  1kJ 
Q1 ref . 0.05
Since ref . is 0.05, heat removed from the refrigerator per second, i.e.,
Q 2  Q1  ref .Q1  Q1 1  ref .   20kJ 1  0.05   19kJ
 0 2nI  0 2nIr 2
08. As B C  & Bh 
4 r 4  r 2  h 2 3/2
3/2
Bh  h 2 
So  1  2 
Bc  r 
Fractional decrease in the magnetic field will be
B  Bh  Bh 
 c  1  
Bc  Bc 
  h 2  3/2   3h 2  3h 2
 1   1  2    1   1  2   2
  r    2r  2r

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Sri Chaitanya IIT Academy 13-03-2021_Sr.Super60 & All_Jee-Main_GTM-14_Key & Sol’s
09. Let V  V0 sin t (as V = 0 at t = 0)
 
Then VR  V0 sin t and VC  V0 sin  t  
 2
V and VR are in same phase. While v lags V (or VR ) by 900 . Now VR is in same phase
with initial potential difference across the capacitor for the first time when,
 3
t    2  
2 2
3
t 
2
13.6Z
10. Using, E n   2 eV
n
2
13.6  3
 For Li  Z  3  E1   1 2 eV  122.4eV and



2
13.6   3
E3  2
 13.6eV
 3
E  E 3  E1  13.6  122.4  108.8eV
11. Terminal velocity = 
Viscous force upwards = wight of sphere downwards
4 
Or 6r   r 3       g
3 
For gold and silver spheres falling in viscous liquid,
    19.5  1.5 18 2
 g g   
s s   10.5  1.5 9 1
 0.2
Or  s  g   0.1ms 1
2 2
12. BE of deuteron  1 H 2   2  1.1MeV  2.2MeV
BE of helium atom  2 H 4   4  7 MeV  28MeV
1H 2  1H 2  2 He 4  Energy released
Energy released = BE of helium – 2 × BE of deuteron
=28 MeV – 2 × 2.2 MeV = 28 MeV – 4.4 MeV = 23.6 MeV
13. Energy of oscillation = 9 – 5 = 4J
1 8
mA 22  4J  2  2
2 2   0.01
2 
  T    0.01  s
0.1 100
14.    K   min
1 1
As  K  = constant and  min  
energy V

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Sri Chaitanya IIT Academy 13-03-2021_Sr.Super60 & All_Jee-Main_GTM-14_Key & Sol’s
Thus, when the accelerating voltage V is halved,  min becomes two time but  K
remains the same.
1   K  2 min  2      K
1  2   
15. The direction of polarization is parallel to electric field
 X || E
The direction of wave propagation is parallel to E  B
 k || E  B
3 D 4 D
16. x1  1 ; x 2  1
d d
 4
 As, x1  x 2  1 
2 3
17. From graph, V = 6t
Heat developed in the resistance,
4 4 2 4

H
V2
dt  
 6t 
dt or H 
36 t 3
 64J
0
R 0
R R 30
18. Here, R 0  4k, R i  1k, I b  20 A, I c  1mA
V0 I c R 0 1 103  4000
Av     200
Vi I b R i 20  106  1000
19. Process A  B occurs at constant pressure. Hence the work done in his process is

WAB  PV  P  VB  VA   10   2  1  10J

Process B  C , occurs at constant volume. Hence, WBC  0 .
Given Q = 5 J, i.e. total work done is Wt  5J .
Therefore, we have Wt  WAB  WBC  WCA or 5 = 10 + 0 + WCA or WCA  5J
0.5mm
20. Least count of the screw gauge   0.01mm
50
Main scale reading = 3 mm
Vernier scale reading = 35
 Observed reading = 3 + 0.35 = 3.5
Zero error = -0.33
 Actual diameter of the wire = 3.35 – (-0.03) = 3.38 mm
21. According to Wien’s displacement law,
 m T  constant
T    1500 nm TA  3
   m A TA    m B  TB  or A  m B  or
TB   m A 500 nm TB
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Sri Chaitanya IIT Academy 13-03-2021_Sr.Super60 & All_Jee-Main_GTM-14_Key & Sol’s
According to Stefan’s Boltzmann law, rate of energy; radiated by a black body
E  AT 4   4 R 2T 4 [Here, A  4 R 2 ]
2 4 2
E  R   T   6cm  4
 A  A   A      3  9
E B  R B   TB   18cm 
A
22. Modulation index,   m
Ac
Here,   80%  0.8, A c  10V
 A m   0.810V   8V
23. Here,
Mass of the disc, M = 1 kg
Radius of the disc, R = 2 m
Moment of inertia of the circular disc about XY is
MR 2
I XY   2 kg m 2 (Given)
2
According to theorem of parallel axes, the moment of inertia of the circular disc about
X1Y1 is
MR 2 3 3 2
I X1Y1  I XY  MR  2
 MR 2  MR 2   1kg    2m   6kg m2
2 2 2
24. As P – V diagram is a straight line passing through origin, therefore,
P  V or PV 1  constant
In the process, PV x = constant, molar heat capacity is given by
R R
C  where x = -1 here and   1.4 for diatomic gas.
 1 1 x
R R 5 R
C    R   C  3R
1.4  1 1   1 2 2
W
25. As P 
t
W  Pt   0.5W  5s   2.5J
According to work-energy theorem
W  Kf  Ki
1
W  m 2  u  0 
2
1 2  2.5 2  2.5
 m 2  2.5or  2   or   5ms 1
2 m 0.2
   0 
26. AS 1     , (Source at rest, observer is moving away from the source)
  
 1   1 
Or        0 or    1   0
  
Or 330(0.94 – 1) =  0

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Sri Chaitanya IIT Academy 13-03-2021_Sr.Super60 & All_Jee-Main_GTM-14_Key & Sol’s

Hence,  0  19.8ms 1
Now, using equation of motion
2
 20  u 2 19.8
s  m  98m  u  0 
2a 22
27. Given, i  600 and x = 1 km = 103 m . When the total internal reflection just takes place
from lateral surface, i = C i.e. C  60 0
1 1 3 2
 sin C   sin 600   
  2 3
The time taken by light to travel same distance in a medium,
2
 103
x
t  3 8  3.85s
c 3  10
H H HL
28. Current I   
n N/L N

I 
 4  103   0.12
 I  8A
60
3RT
29.  rms 
M
Where R is the gas constant, T is the temperature in kelvin and M is the molecular mass
of the gas.
1
For the same temperature,  rms 
M
  H
 rms 2 
M O2  H
or  rms 2 
32
4
  rms  O 2 M H2   rms  O2 2

Or   rms  O 2 
  rms  H 2  1920  480ms 1
4 4
2gh
k 2 k2 2
30.   1 2 For a solid sphere, 2 
R R 5
Substituting the given values, we get
2  10  7
  10 ms 1
 2
1  
 5

CHEMISTRY
34  30
31. 30 mL O 2 is obtained by g H 2O2 / mL
11200
34  30  100
M   2.68M
11200  34

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Sri Chaitanya IIT Academy 13-03-2021_Sr.Super60 & All_Jee-Main_GTM-14_Key & Sol’s

32. S2O32  Ss 

Or 4e  S22  2S0
33. 2NO  N 2  O 2
2
Rate = k  NO 
Hence, order of reaction is 2
H 2  I 2  2HI
Rate = k  H 2  I 2 
Hence, order of reaction is (1 + 1) = 2
Therefore these reactions are most likely to be elementary reaction that occurs in one
step.
34. H  E a f   E a  b   180  200  20 kJ mol 1 (in absence of catalyst)
H  E a  f   E a  b   180  100   200  100  20 kJ mol 1 (in presence of catalyst)
Catalyst’s have no influence on H
35. For ‘n’ moles, the van der Waals’ equation is
 an 2 
2 
 p  V  nb   nRT
 V 
Where, n = 2 moles
R  0.0821Latm K 1 mol1
T = 27 + 273 = 300 K
V = 5L
a = 4.17
nRT an 2
so p   2
V  nb V
2
2  0.821 300 4.17  12  49.26 16.68
  2
   10  0.66  9.33atm
 5  2  0.711 5 4.926 25
11.2  103  6.023  1023  2
36. Number of atoms in N 2   6.023  1020
22.4
0.015  2  6.023  1023
Number of atoms in NO   6.023  1020
30
 2
37. Na 2SO 4  2Na  SO 4
van’t Hoff factor for Na 2SO 4  3
Tf  i  k f  m  3  1.86  0.01
 0.01 
 m  1  0.01  0.0558K
38. Conceptual
39. Conceptual

40. 2Ca  NO 3 2   2CaO  4NO 2 brown gas   O 2
41.

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42. Nitration takes place at activated benzene ring.

43. B2 H 6  2LiH  2LiBH 4
44. (1) Dimer of ICl3 , hybridization of I is sp3d 2 shape square planar.
(2) sp3d 2 , shape square planar.
(3) dsp 2 , shape square planar.
45.

46. Conceptual
47. Conceptual
48. (1) PdCl 2 .4NH 3   Pd  NH 3  4  Cl2 two moles of AgNO 3 as it produces 2Cl  ions after
ionization
2
Pd  NH3  4  Cl2  Pd  NH3  4   2Cl  2AgNO3  2AgCl  whiteppt   2NO3
2
(2) NiCl2 .6H2O   Ni  H2O 6  Cl2   Ni  H 2O 6   2Cl  2AgNO3  2AgC  whte ppt   2NO3
2
(3) PtCl4 .2HCl  H 2  PtCl6    PtCl6   2H  AgNO3  no ppt . Therefore zero moles of
AgNO 3 is required
(4) CoCl3.4NH3  Co  NH3 4 Cl2  Cl  Co  NH3 4 Cl3    Cl  AgNO3  AgCl  white ppt   NO3
49. All these can remove hardness of water.

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1) NaOH 2) Na 2CO3 3) Na 6  PO3 6
50. B2 H 6  H 2O  H3BO3  A   H 2  B
2H 3BO3  A   red heat  B2O3  C   2H 2O
B2O 3  CuSO 4  on strong heating  CuO.B2 O3 or Cu  BO 2 2  D   SO3
A  H3BO3 ; B  H 2 ; C  B2O 3 ; D  Cu  BO 2  2
1 1
51. X 2  Y2  XY; H  100kJ
2 2
a
Let the bond dissociation energy of X 2 , Y2 and XY be a : : a (the given ration) kJ mol1
2
respectively
a a
   a  100
2 4
 a  400
100x = 400
x=4
2.303 a
52. t log
K ax
0.693 0.693
K 
t1/2 5600
a 50000  0.693
Or log 
a  x 5600  2.303
10 50000  0.693
log 
a  x 5600  2.303
Or  a  x   0.22mg
  a  x   10  0.02  100  2mg
53. 2Cr  OH 3  4OH   KIO3  2CrO42  5H 2O  KI
Change in oxidation number of effective element (I) in
KIO3   5   1  6
mol.wt
Equivalent weight of oxidation 
6
6 3 2 4
54. Cr2  6e  2Cr   1; Sn  Sn  2e   3
4
55.  t  0  8,000cm 1
9
56. 1 and 20 amines can be distinguished using Azo dye test, Hoffmann’s mustard oil
0

reaction, Carbyl amine test and Hinsberg reagent.

57. It has 4 properly oriented nitrogen atoms.
58. C2 H 6  H 2O  CH3COOH  4H   4e 
g.Eq.of K 2Cr2O 7  g.Eq.of C 2H 6O
n  6  12  4  n  8
59. Conceptual
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60. Conceptual

MATHEMATICS
sin  nx
1
x 1
61. e    dx
 1 x
2 x
1 1 1 1 1 1
 nx.esin x   esin x dx   esin x dx  nx.esin x  C
x x
62.  t ,2t  satisfy x  2y  1  0
2

t 2  4t  1  0 t1  t 2  0
t 1t 2  1
Point of intersection of normal
 a  t12  t 22  t1t 2  2  , at1t 2  t1  t 2  
1 1
1  1
x x
e e dx
63. I  2 x
dx 
; 
1 2
  1 2
x

x 1  e  x 1  e 2 
   
1 1
1
Substitute e x  t   2 e x dx  dt
x

dt 0 e
I   2
   tan 1 t  1    tan 1 t 
1 t e 

1 
I  tan 1    tan 1 e 
e 2
 
I   tan 1 e  tan 1 e     2 tan 1 e
2 2
2 7 7
64. 1  x  2x   1  x 1  2x  
0 1 2 3 4
 7 C0 x 1  2x   7 C1 x 1  2x   7 C 2 x 1  2x   7 C3 x 1  2x   7 C 4 x 1  2x   .....
Coefficient of x 4 is  7 C2  4  7 C3   6   7C 4  1
 21 4  210  35  84  35  210  91
65. 13, a1 ,a 2 ,a 3 ,.......,a 20 , 67 are in A.P.
 13  67 
 a1  a 2  a 3  ......  a 20  20    800
 2 
Now AM  GM
a 1  a 2  a 3  .....  a 20 1/20
  a1a 2a 3 .....a 20 
20
 800  1/20
    a1a 2a 3......a 20 
 20 
20
Or a1a 2a 3 .......a 20   40 

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Sri Chaitanya IIT Academy 13-03-2021_Sr.Super60 & All_Jee-Main_GTM-14_Key & Sol’s
20
 Maximum value of a1a 2a 3 ......a 20 is  40 
66. Conceptual
6
67. C3 . 3C3  7C3 . 4C3  8C3 . 5C3  720
2
3 
68. f  x   0if  tan 1 2x   1
 
 
 tan 1 2x  or tan 1 2x  
3 3
 2x  3 or 2x   3
 2x  3
69.

1
1
Area  S  2  
x  x dx 
3
0

70. f  g  x   x
f  310 x  1  210  310.x  1  1  x
210  310 x  1  1  x
x  610  1  210  x
210  1 1  2 10
x  10 
6  1 310  2 10
71. E , E , N, Q , U
(i) E …………….. = 24
4!
(ii) N ……………….. =  12
2
(iii) QE …………….. = 3! = 6
3!
(iv) QN ……………. =  3
2!
(v) Q U E E N = 1
Total = (i) + (ii) + (iii) + (iv) + (v) = 46th
dy 2sin x cos y
72.    tan ysec y dy   2sin xdx  sec y  2cos x  C
dx tan y
73. e = 3/5, 2ae = 6, a = 5
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b 2  a 2 1  e 2 
 9 
b 2  25  1  
 25 
b=4

1 
Area  4  ab   2ab  40
2 
ˆi ˆj kˆ
74. n  n1  n 2  6 7 8   9, 18, 9   1, 2, 1
3 5 7
1 x  1  2  y  1   z  3  0  x  2y  z  0
Foot to z
x 1 y  2 z 1 1 4 1
  
1 2 1 6
x  0, y  0,z  0
x1  x 2  ......  x 25
75.  x  40
25
x 2  x 2  ......  x 25  60  A  x  25
1000  60  A  39  25  975
A = 975 – 940 = 35
 3  1  3   1  1  3   3  1  3  12  9 21
76.                
 4  2  8   4  2  8   4  2  8  64 64
dy a cos t
77.    cos t
dx a sin t
d 2 y cosec 2 t  cos ec 3t
 
dx 2 a sin t a
2
d y  2 2
2
at t  
dx 4 a
 x 2  x 2   n 2  x 2 
78. 1    i    i          
 n  n    n  n  

n2  1

12
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Sri Chaitanya IIT Academy 13-03-2021_Sr.Super60 & All_Jee-Main_GTM-14_Key & Sol’s

n2  1
So standard deviation 
12

Mean  x  
 xi  n  n  1   n  1
n 2n 2

So coefficient of variation   100 
 n  1  100
x 3  n  1
1 1 1 1 
79. Augmented matrix  1 2 4  
 
1 4 10  2 
R 2  R 2  R1 & R 3  R 3  R1
1 1 1 1 
 0 1 3  1 

 
0 3 9  2  1
R 3  R 3  3R 2
1 1 1 1 

 0 1 3  1 
 
2
 0 0 0   3  2 
 The system of equation will have solution if
 2  3  2  0    1,2
80.   p  p     p  q   T    p   q     p     q 
 p  q

2 1
81. a2  b  c 
2
1
 a  b 2 2
  b  c  c  a  
2
 2
(4 + 4 + 16) = 12 minimum.
82. 
N  64log8 5  4log 2 5
11
log11 25
 5
log8 64
 / 300

5 2
 5   25  5 

30  20 600
  2  log 2 N  1
300 300 300
1
83. c   a  b   b ca
3

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1
  c.b  a   c.a  b   b ca
3
1
 c.a  b   c.b  a  b ca
3
1
 c.a  b  c b cos    a
 3
But a & b are not collinear
1
So a.c  0&cos   
3
2 2
sin  
3
f  3   f 1 1
84.  f  c  , for some c such that 1 < c < 3
3 1
f  3  2
f 1 c  2
2
 f  3  6
 n 12
85. Adj  Adj  A    A
4
A  2834
A  12
x  y  z  12
x  y  z  12
12 1
C31  11C2  55
10
10 10 1 1 1 1
86.  abc  abd  acd  bcd    abcd      
a b c d
10
1 1 1 1 10
We need coefficient of a b c d in  abcd      
8 4 9 9

a b c d
10
1 1 1 1 1 1 1 1 10!
 we need coefficient of 2 6 1 1 in        2520
a b c d a b c d 2!6!1!1!
N = 2520
N
 126
20
1 1 
87. tr  1  
 r r  1
 1  n  n  2  675
 t r  n  1  n  1  n  1  26  n  25
88. Tn 
  n  3   n  1   1
 n  1 n  2  n  3 2
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1 1 1 
Tn    
2   n  1 n  2   n  2  n  3 
1  1 1   1 1   1 1  
S          .......
2  2.3 3.4   3.4 4.5   4.5 5.6  
1
S 
12
89. Conceptual
90. Conceptual

Sec: Sr. Super60 & All Page 17