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Sri Chaitanya IIT Academy., India.

A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI

A right Choice for the Real Aspirant


ICON Central Office – Madhapur – Hyderabad
Sec: Sr.Super60 Jee-Main Date:04-12-2021
Time: 09.00Am to 12.00 PTM-12 Max.Marks:300
Key Sheet
PHYSICS
1 1 2 1 3 3 4 1 5 2
6 2 7 1 8 1 9 2 10 2
11 3 12 1 13 2 14 3 15 1
16 2 17 2 18 2 19 2 20 2
12.56 to
21 0.28 to 0.29 22 0.5 23 6.00 24 12.57 25 19.6
26 3.2 27 37.12 28 1.00 29 8 30 64

CHEMISTRY
31 4 32 1 33 1 34 3 35 4
36 3 37 2 38 1 39 2 40 4
41 3 42 4 43 4 44 4 45 4
46 3 47 3 48 1 49 2 50 2
51 0 52 9 53 2 54 9 55 8
56 4 57 1 58 7 59 1 60 6

MATHEMATICS
61 4 62 3 63 2 64 2 65 2
66 4 67 2 68 1 69 2 70 3
71 3 72 2 73 3 74 2 75 4
76 3 77 3 78 4 79 4 80 4
81 0 82 -0.5 83 3 84 0 85 12
86 1 87 0 88 0 89 5 90 10
Sri Chaitanya IIT Academy 04-12-2021_Sr.Super60_Jee-Main_PTM-12_Key & Sol’s
SOLUTIONS
PHYSICS
1. Toque w. r. t triangle=0
Ah  g l h
Fb x '  mgx  0, Here Fb  m  Al , x  cos  , x1  cos ec cos 
sin  2 2
On substituting these values, we get
h  
  sin 1  
l  
m1  m2 d v  d 2 v2
2. Density of mixture  d   11
v1  v2 v1  v2
d  d2 d  d2
v1  v2  v, d  1 4 1  d1  d 2  8   1
2 2
d  d2 2
& 1    2  solving 1 &  2  we get d1  6, d 2  2
d1d 2 3
3 y 
3. Volume of liquid is same 5  2  4    5  4  y  1m
 2 
a 3 1 2 2g
Tan    ,a   4 m / s2
g 5 5 5
4. Conceptual
5. Conceptual
6. Shear modulus   F  100
 57.27 106 N / m 2
A 
4
10 
80
dv 10
7. F   A  15  2  10 4   12  10 6 D
dx 0.25
v r v P  gh r  gh
8. 3 ;    
v r v B B r 3B
9. 1 1  PV
PV 2 2  PV
3 3

 4T  4 3  4T   4 3   4T 4 3
P   r1   P     r2    P    r3
 r1  3  r2   3   r3 3
On simplifying , we get 3PV  4TS  0
10.
w

dx

dm   Adx
 2 x2
df  dmx 2 , F    A  c,
2
l  A 2l 2
At x  , F  0, C 
2 8
Sec: Sr.Super60 Page 2
Sri Chaitanya IIT Academy 04-12-2021_Sr.Super60_Jee-Main_PTM-12_Key & Sol’s

 A 2l 2 F  2 l 2 1 8
x  0, F  Stress     ,f 
8 A 8 2 l 2
4T 4T 6T
11. p1  p0  , p2  p1  ; p2  p0 
2R R R
dU dr
12. U  8 r 2T , p   80 T  2r  pe
dt dt
2  8.5  0.8  g 
v0  r 2 
9   17
13. n 
2  2.5  0.8  g  77
nv0  r 2
9  

2h t h h 1
14. t  t  h, 1  1    t2  2t
g t2 h2 4h 2
15. From law of floatation, weight  Fb
 1 
mg  1   vdwg 
 3 2 4 2 9 3
 1000  dl  dl  1000   dl  1500 kg / m
 5  3 9 3 4
mg  1   vd lg 
 9  
16. Conceptual
17. Fbottom  L2 h  g
h
Fside   g  hl
2
 gh 2l 1 2 L
 l h  g  h   20 cm
2 6 3
18. Conceptual
19. Conceptual
1 1
20. U  Fx   200  103  0.1J
2 2
2
mv T l
21. T  mg  , l  
r A y
22. Conceptual
r1r2 23
23. r   6mm
r2  r1 3  2
24. Conceptual
F1 F2 10 200  98
25.   4

A1 A2 100 10 A2
AV
26. 1 1  A2V2  V2 
AV 1 1

A2
 r12v1 2 2  2
V2 
=  2  8m / s
 r22 1
v22 8  8 32
h    3.2 m
2 g 2 10 10
 dl   0.72 
27. T  mg 1    4  9.8 1  
 db   10 

Sec: Sr.Super60 Page 3


Sri Chaitanya IIT Academy 04-12-2021_Sr.Super60_Jee-Main_PTM-12_Key & Sol’s

28. v  2 gh  2  10  5  10
V  AV  10  10 4  103 m3 / s
 Pr 4
29. Q Q  r4
8l
Q r
100  4 100  8%
Q r
2
2 V1  r1 
30. V r  
V2  r2 

CHEMISTRY
 III  III
  
 NH 4 NO2   N 2  2 H 2 O 

 3
31. NaN 3   Na  N 2 
2

 NH 4 2 Cr2O7   N 2   Cr2O3  s   4 H 2O 
 green 
243 K
H 2O
NO  g   NO2  g  
 N2O3   HNO2
X Y 
( Blue coloured
Solid)

..
Anion of HNO2 : NO2 N
O
O
Hyb.sp2
Shape : Triangular planar
32.
 N 2O 
33. Na  NH 3  g    NaNH 2   NaN3   N2 
X  Y  Z 
34. Conceptual
35. NH 3 is a weak reducing agent than PH 3 , because X-H bond strength decreases down
the group. Due to absence of H-bonding, only weak Vander Waals force of attraction
exists in PH 3 . It has lower critical temperature than NH 3
36. Conceptual
1
AgNO3 
 Ag  O2  NO2
2
0
500 C
37. 2 NaNO3   2 NaNO2  O2
0
800 C
4 NaNO3   2 Na2 O  5O2  2 N 2
38. Conceptual
39. Conceptual
40. In SF6 , S sterically hindered by six fluorine atoms hence, attack of H 2O molecule will
not occur, NF3 is not hydrolysed due to absence of vacant orbital either on N of F
atom.
Sec: Sr.Super60 Page 4
Sri Chaitanya IIT Academy 04-12-2021_Sr.Super60_Jee-Main_PTM-12_Key & Sol’s
TeF6 is hydrolysed due to large size of Te.
41. Conceptual

42.
43. Conceptual
44. Gas A is N 2O3
PCl3  sp 3  , H 3 Po3  sp 3 
SF4  sp 3 d  , H 2 SO3  sp 3 
45.
BCl3  sp 2  , H 3 BO3  sp 2 
XeF6  sp 3d 2  , XeO3  sp 3 
R .T 1
XeF2  H 2O  Xe  2 HF  O2 
46. 2
R .T
XeF6  3H 2 O  XeO3  6 HF
47. Bi 5 is unstable due to inert pair effect
48. Correct order SbH 3  NH 3  AsH 3  PH 3
   
  XeF3    SbF6  
XeF4  SbF5    XeF3    SbF6 
sp 3 d sp 3 d 2
bent T  shaped octahedral
49.
 Excess H 2O
XeO3  HF
X
XeF6
2H 2O
XeO2 F2  HF
Y 
50.
....

....
O
P ....
O H
H H
x=6,y=6,z=1

51. Y  Z  X  6 1  6  0
52. For any oxyacid of sulphur number of H-atoms=2;
H n1 S 2On2 , H 2 S 2 O3 , H 2 S 2O4 , H 2 S 2O5 , H 2 S 2O6 , H 2 S 2 O7 , H 2 S 2O8
Sec: Sr.Super60 Page 5
Sri Chaitanya IIT Academy 04-12-2021_Sr.Super60_Jee-Main_PTM-12_Key & Sol’s
n2
For H 2 S 2O4 ;  2  Oxidation state of sulphur atom  3
n1
n
For H 2 S 2O8 ; 2  4  Oxidation state of sulphur atom  6
n1
53. Conceptual
54. 1+5+3=9

x= 12, y=4,z=6 ..
P
600

..P
..
P
..
P
The value of x. y  12  4  8
55. z 6
b. p l. p
 A XeF4 4 2
 B  XeF5 5 1
56.  C  XeF5 5 2
 D  XeF6 6 1
 E  XeF82 8 1
28 7

57.
p 6
p  6, q  6;  1
q 6

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Sri Chaitanya IIT Academy 04-12-2021_Sr.Super60_Jee-Main_PTM-12_Key & Sol’s

58.
59. Conceptual

60.

MATHEMATICS
61.
 1
f  x    x    x  , X   2, 2
 2
5  5
lim f  x   lim   h 1 
x  2 h0
2  2
5
f  2  2  5
2
So , disc at x=2
Now defining function
3; 2  x  1
1
 ; 1  x  0
 1 2
f  x    x    x  
 2  3 ;1  x  2
2
 2; 2  x  3

By defining the function we can say that this it is disc at x=0.
62.
f  x   sgn  x  , g  x   x  x 2  5 x  6 

 
f  g  x    sgn x  x 2  5x  6   sgn  x  x  2  x  3 

Sec: Sr.Super60 Page 7


Sri Chaitanya IIT Academy 04-12-2021_Sr.Super60_Jee-Main_PTM-12_Key & Sol’s

1; x  x  2  x  3  0 x   0, 2    3,  

g  g  x    0 ; x  x  2  x  3   0 x  0, 2, 3

1; x  x  2  x  3   0 x   ,0    2,3

So f  g  x   is disc. at exactly points 0,2 &3.


63.
2 tan x  5 x  2  0
5x
tan x   1
2

64.
f  x  x  x  x 1 
f  0    lim
h  h  h 1   lim h  h 1
 1
h0 h h0
h  h 1
65.
 x  3e1/ x  4 

f  x    2  e1/ x , x  0
0 ,x 0

h
 3e 1/ h
 4
0
f '  0    lim 2  e1/ h
h 0 h
 1
3 1    4
h 7h  3
 lim   lim 3
h0 1 h0 h  1
2 1 
h

h
3e  4   0
1/ h
 1
3 1    4
1/ h h 7h  3
f '  0    lim 2e  lim    3 so mot diff . at x  0
h0 h h  0  1 h 1
2  1  
 h
66.

max 4  x 2 , 1  x 2 , 2  x  0

f  x  


min 4  x 2 , 1  x 2 0  x  2
 
y  4  x2 , y  1  x2

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Sri Chaitanya IIT Academy 04-12-2021_Sr.Super60_Jee-Main_PTM-12_Key & Sol’s

67. If f is differentiable everywhere. Then f will also be diff. everywhere and if two
functions are diff, then sum of then will also be diff. everywhere
68.
f  x  2 y   f  x   f  2 y   2 xy
f  x  h  f  x 
f '  x   lim
h 0 h
f  x   f  h   f  x   2 xy
f '  x   lim
h 0 h
f  0  h    0
f '  x   lim  2x
h 0 h
f '  x  f ' 0  2
69.
g  x   x   x  f  0   f 1 , h  x   f  g  x  
Let x  a  I
h  a    lim f
 x  f  0 
x a

h  a   lim f  g  x    f 1

x  a

h a 
  ha  
hence then is cont.
70.
f  x   x2 , x  Qc
 1, x  Q c
By short trick
x 2  1  x  1
71.
f  x   sin  x 
well define the given function as follows:-
0;0  x  1
0;1  x  2

0; 2  x  3
sin  x   
0;3  x  4
1;54  x  5

1;5  x  6

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Sri Chaitanya IIT Academy 04-12-2021_Sr.Super60_Jee-Main_PTM-12_Key & Sol’s
72.
  1
 x 1  sin x  , x  0
  
  1
f  x      x  1  sin  , x  0
  x
 0 ,x 0


 1
f  0  h   f  0 1  sin 
h
f '  0    lim d  lim   m.d  N .diff
h h0 h0 h
 1
f  0    lim h 1  sin 
h0
 h
h  1
 lim  1  sin 
h0 h h
 1
 1  sin 
 1  h
 lim   1/ h
h0
 h  
1  1
 lim 1  sin   0
h0
h h
 1
f  0    lim  h  1  sin   0
h0
 h
73.  2
 max x 2 ,  x  1 , 2 x 1  x 
f  x  

74.
f  x  h  f  x
f '  x   lim
h0 h
f  x. f  h  f  x f  h   f 0
 lim  f  x  lim
h 0 h h0 h
f '  x   f  x  . f ''  0 
f ' x  2 f  x
ln f  x   2 x  c : c  0
f  x   p2x
75.

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Sri Chaitanya IIT Academy 04-12-2021_Sr.Super60_Jee-Main_PTM-12_Key & Sol’s
1
f 1   lim x 2  2   0
x 1 x 
1
f 1   lim x 2  2   1
x 1 x 
Discont.at x  1
similarly for x  1
 1  1  1
f  x   x2  2   2    1  x2  2 
 x  x  x 
1
f  0    lim 1  x 2  2   1
x O x 
f  0 1  
 1 but f  0   0
So dicont.at x  0 at x  2, RHL  LHL  f  2   0
Co int .at x  2
2 2
76. f  x    x   x   x 
Discont. at every integer because [x] is discount. At every integer. But f(x) is cont. at
x=1.
77.
f  x   Sgn  4  2sin 2 x  2sin x 
 Sgn  sin x  2  2  2sin x  

f  x   0 when x 
2

1 x 
2
 1 sin x  1 not possible
So isolated pt.discont.
 x 3 x5   x2 x4 
 x    ....   x  1    .... 
3! 5!   2! 4!
78. lim    0 , f x is cont at x  0
 
x 0 x2
79.
RHD  at x  0   0; LHD  1
RHD  at x  1  2; LHD  2
RHL  at x  0   0  LHL
RHL  at x  1  LHL  x  1
Diff .and cot .at x  1
Non diff . x  0 but cont.at x  0
80. Conceptual
81.

Sec: Sr.Super60 Page 11


Sri Chaitanya IIT Academy 04-12-2021_Sr.Super60_Jee-Main_PTM-12_Key & Sol’s
 cos  sin x   cos x
 ,x  0
f  x   x2
 a ,x 0

for continuity lim f  x   f  0 
x0

cos  sin x   cos x


lim a
x 0 x2
 x  sin x   sin x  x 
2sin   sin  
 2   2 a
lim 2
x 0 x
 x  sin x   x  sin x 
2sin   sin    x 2  sin 2 x 
 2   2 
lim  a
x 0  x  sin x   x  sin x   4 
   
 2   2 
0
2  a  a  0
4
82.
 1  px   1  px 
 , 1  x  0
 x
f  x  
 2x  1
 ,0  x 1
x2
sin ce it is cont , so,
lim f  x   f  0 
x  0

1  p  h   1  p   h  1
lim 
h0 h 2

lim
1  ph   1  ph  
1
h0
h  1  ph  1  ph  2

2 p 1

2 2
1
p    0.5
2
83.

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Sri Chaitanya IIT Academy 04-12-2021_Sr.Super60_Jee-Main_PTM-12_Key & Sol’s
1 1
y 2
,t 
t t 2 x t
1
y
1 1
2
 2
 x  1 x  1
2

y
 x  1
2
1   x  1  2  x  1
x2  2x  1 x2  2 x  1
y 
x  2 x 2  2  4 x 2 x  x  2   1 x  2 
2

y
 x  1
 x  2  2 x  1
 1
by  x  R  2,   so disc. at 1/ 2 & 2 let we also include
 2
x  1because at x  1.t is not defined
84. Conceptual
85. By using L Hospital rule
2 f '  x   f ' 2x   4 f '  4 x
 lim
x 0 2x
Again
2 f '  x   12 f ''  2 x   16 f ''  4 x 
 lim  12
x 0 2
86.
1 2 
lim f  x   lim   2 x 
x 0 x 0 x
 e 1 
 e2 x  1  2x 
 lim  

x 0  x 32 x  1 
  
2x
e 1  2x
 lim 1
x 0 2 x2
f  x  f  y
 x  y
x y
f  x  f  y 
87. lim  lim  x  y 
x y x y x y

f '  0   0  f  x   C  f  0   0  C  0 f 1  0
88. f  x   x  1  x  2  cos x all three functions are cont. is [0,4] so sum of all these
functions is also a const. functions.

Sec: Sr.Super60 Page 13


Sri Chaitanya IIT Academy 04-12-2021_Sr.Super60_Jee-Main_PTM-12_Key & Sol’s

89.
90. f(x) should be a constant function.

Sec: Sr.Super60 Page 14

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