Sri Chaitanya IIT Academy., India.

A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI

A right Choice for the Real Aspirant

ICON Central Office – Madhapur – Hyderabad
Sec: LIIT Jee Mains Date: 26-03-2023
Time: 02.30 pm to 05.30 pm GTM-02 Max.Marks:300
PHYSICS
1 2 2 3 3 2 4 2 5 3
6 2 7 2 8 4 9 2 10 2
11 4 12 4 13 2 14 2 15 1
16 4 17 4 18 4 19 3 20 1
21 41 22 9 23 5 24 4 25 4
26 4 27 2 28 2 29 5 30 8

CHEMISTRY
31 4 32 4 33 2 34 3 35 3
36 1 37 2 38 2 39 4 40 3
41 3 42 1 43 3 44 4 45 2
46 3 47 1 48 3 49 2 50 4
51 4 52 6 53 2 54 5 55 2
56 7 57 1 58 4 59 6 60 1

MATHEMATICS
61 3 62 3 63 1 64 3 65 3
66 2 67 3 68 3 69 3 70 3
71 4 72 1 73 3 74 1 75 1
76 2 77 4 78 1 79 3 80 2
81 2 82 3 83 5 84 144 85 2
86 7 87 9 88 5 89 480 90 2
Sri Chaitanya IIT Academy 26.03.2023_LIIT_Jee-Main_GTM-02_Key & Sol’s

SOLUTIONS
PHYSICS
1. A  40i
 
B  25cos 37 i  25sin 37 j
A  B  20i  15 j
2. 1  0.01cm
 2  0.01cm
 
 1 O 2  1   2  0.02cm
5 1
3. sin       300
10 2
2 2 2
tmin   
vbr cos  3 5 3
10
2
unbalanced force
4. a=
Total.mass
5. T-100=10  g/2   T=150N
V=5  2  =10m/s
1
TS 150  ×5×22
P= = 2 =750w
t 2
6. Conceptual
7. y1 +y 2
A1 A 2
8. =
t1 t 2
1
9. p 0 + Pv 2 =P
2
1
= ×1.2×40 2
2
F=  P-Po  A
dp
10. K=
 -dv/v 
V1 -V0 V1 -V0 V1
11.   0
R1 R1 R2
q q q q
12. Let q qµC be the change on two capacitors C1 and C 2 . Then + =30or + =30
C1 C2 1 1.5
50
13. According to ohms law R= 10 since voltmeter is non-ideal It always gives less value
5
when compare to
14. Current decreases balancing length increases

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Sri Chaitanya IIT Academy 26.03.2023_LIIT_Jee-Main_GTM-02_Key & Sol’s
T
15. =0.17sfit T= -0.17.4=0.68s
4
1 1
f= = =1.47Hz
T 0.68
16. Resistance needed to connect in series R=
17 . No Work
µ1 µ1 µ1
18. B= 0 - 0 + 02 +....
2r 2  2r  2  2 r 
19. 2 n  6
 t x 
λ= v then Y=8sin2     When t=1,x=150cm
n  ( 1 ) (200 3) 
 3 
20. Fc  9 N max
21. For Ka X-ray line ,
1 2
1 1  2  1
=R  Z-1  2 - 2  =R  z-1 1- 
λ 1 2   4
1 3 2
 = R  z-1 ..….(i)
λ 4
mz 2e 4 mz 2e4  1 1 
22. E n =- 2 2 2 So, hv = + 2 2  - 
8e 0n h 8e 0h 16 25 
4
23. Radiation T
So =2T1 and By wein'sdisplacement law
1

T

So  2  1  3000 A
2
By Einstein’s photoelectric equation
he
=eV+θ
λ
he he 1 1
F= -ev= - 13.6ev 12  2 - 2  =4.00-2.5
λ 3100A° 2 4 
  1.45ev
  
 1.45    or  145
 100 
24. Q  n  2 R  T   W+U
25.

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Sri Chaitanya IIT Academy 26.03.2023_LIIT_Jee-Main_GTM-02_Key & Sol’s
yA  W -W  /L
W2 -W1 =  l2 -l1  y= 2 1
L yA  l 2 -l1 
 y  l2  l1 2  10 5
 y   l  l  25  10 5
 max 2 1

 y  2
 y   100%  25  100%  8%
 max
m
26. dm =
πR
 dl 
2
2M
=  Rdθ 
πR
2Mdθ
=
π
Ycm=
Δl Δl
27. Fc = A c Ycand F1 = A1Y1
l l
FC
It follows that =2
F1
28. For system
F=3a
3  3a  a=1m/s 2
For 1 kg
3-f1 =11
F1 =3-1=2 Newton.
7
29. Fraction decayed 
8
N 7 1
Fraction undecayed, =1- =
N0 8 8
n
N 1
 =   gives
N0  2 
n
1 1 t t 15
  =    n=3 =3  T= = =min=5min
8  2 T 3 3
30. ε rms =6v/m  ε 0 =6 2
ε0 6 2
C= =
B0 B0
6 2
B0 = 8
=2 2×10-8
3×10

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Sri Chaitanya IIT Academy 26.03.2023_LIIT_Jee-Main_GTM-02_Key & Sol’s
CHEMISTRY

31. Because of formaion of scn
32. XeF6  H 2O  XeOF4  2 HF
XeF6  2 H 2O  XeO2 F2  4 HF
XeF6  3 H 2O  XeO3  6 HF
33. π =L.CST
6.576= 1  2  0.1  0.0821  300
1.67
  84%
2
34.
NO2 NO2 NO2

1) NH  H S 
2) NaNO2  HCl 0 50 C 
 3 2
 
3) CuCl  HCl

NO2 NH 2 Cl
35. Grphite& diamond contains dangling bond while fullerene does not contain dangling
bond.
36. H  H O O  H O O  H
H  Bond energy of reactants - Bond energy of product
H   B.E.H  H  B.E.O O    2 B.E.O  H  B.E.O O 
 436  499  2  460  142
H  935  920  142  127kJ
37.
O
CH 2  OH
O OH
,

38.

NH
N Resonance
sp 2

N
N
sp 2 H
Resonance
39.
NH 2 is stronger activating group than OH
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Sri Chaitanya IIT Academy 26.03.2023_LIIT_Jee-Main_GTM-02_Key & Sol’s
OH


Ph  N 2 Cl 

 HO NH 2

C6 H 5  N  N
NH 2
40.
3 1
P4  NaOH  aq.  PH 3  NaH 2 PO2
Oxidation state of P in PH 3  3
Oxidaton state of P in NaH 2 PO2  1
41.
Br
|
Br
CH 3  CH 2  CH 3 
hv  CH 3  CH  CH 3
2

 C3 H8 
alc . KOH
 CH 3  CH  CH 2
Br
|
HBr Peroxide
 CH 3  CH 2  CH 2
42.
O
O
I2
 CHI3 +
Ca  OH 2 Ca
Yelow 
O O
ppt
O


  CaCO3
O
43. The net reaction of a concentration cell has no redox changes
Cu  s  Cu 2  aq   2e
At node:
Cu 2  aq   e Cu 2  aq 
At cathode:
Cu  s   Cu 2  aq  2Cu 2  aq 
Net reaction:
Redox reaction not a concentration cell.
44.
CH 3
CH 3
D D
D2  Ni

 synaddition

D D

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Sri Chaitanya IIT Academy 26.03.2023_LIIT_Jee-Main_GTM-02_Key & Sol’s
CH 3 CH 3
Br Br
Br  H O
 2
Anti addition
 H2 H
H OH HO H
CH 3 CH 3
CH 3 CH 3

 I  B D THF D D
 2
 II  H O OH
2
 6

2


OH OH
2
45. CO x CN - are strong field ligaudi so e 2 get back paired giving d10 & d8 in Ni Ni  CO 4
respectively

CO CO CO
CO

-
CN - CN - CN -
CN

CN
46. More stable is the carbocation higher is the rate of dehydration
47. Remaining give SO 2
π =L.CSO32 +H +  H 2OSO 2

48. NaCl  H 2 SO4   NaHSO4  HCl 
conc .

2 NaCl  H 2 SO4 
Hight temperature
 Na2 SO4  2 HCl 
conc .

49. CH 3COOH  OH   CH 3COO   H 2O

20 20

 20

20
So, CH 3COO     0.1M
200
1 1 1
pH  7  pK a  log C  7  2.37 
2 2 2
-1
log10 =7+2.37-0.5=8.87
50. Solubility, thermal stability and basic strength of group – 2 hydroxides increases down
the group. % covalent charater increases with decreasing size of cation.
51. 4 (A, E, F, G)

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Sri Chaitanya IIT Academy 26.03.2023_LIIT_Jee-Main_GTM-02_Key & Sol’s

CHO CHO
 CHOH  3
Ac O
2
  CHOAc 3 Ac  CH 3CO
CH 2OH CH 2OAc

Molecular mass increased by 168 unit

52. 6
53. Pb  NO3  2 &AgNO3
54. CH 4 ,CF3CFCl 2 ,H 2O  g  ,O 3 ,CO 2
55. x  2 and y  1
So, 2  1  3 .
56.  a,c,d,f,g,h,i 
57. Total number of lines without any condition  6
4
3

1
In absence of Balmer series
Missing transition 4  2,3  2
 No transition corresponding to 2  1 also
Because no e  will be found at n  2
 Energy of third most energetic photon
=E 4 -E 3 =1.51-0.85=0.66eV
x+y
58. x  4, y  3 and =3.50
x-y+1
x 2 25
59. Hence   6.25
4 4
M0 92
60. 1    1      0.2
M eq 2  115 3
α2 0.2
K p =4Peq =4×4.8× =0.8atm
1-α 2 1-02 2

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Sri Chaitanya IIT Academy 26.03.2023_LIIT_Jee-Main_GTM-02_Key & Sol’s
MATHEMATICS
2 4 6
61. Given expression = cos 2 cos 2 cos 2
14 14 14
62. tan   cot   2cos ec 2
 
63. sin  x    sin 2 x
 12 
64. 2  x  1   x  3  2 x
  x  5  2 x
 x  5.5, 5
65. x1, x2, x3, x4  ve  be the roots
x1 x2  x3  x4 4
Clearly  x1 x2 x3 x4
4
 x1  x2  x3  x4  1
66. We know that for a circular determinant
a b c
b c a
 
c a b
 
   a  b  c   a 2  b 2  c 2  ab  bc  ca 
1 2 2 2
  a  b  c   a  b    b  c    c  a  
2
a b c
  b c a   0  a  b  c  0
c a b
 
Using this property ,we get
x  3  6  0,2  x  7  04  5  x  0  x  9
67. 24  23  3
1   2   3  3
Number of solutions = 5C2
1   2   3  1 Number of solutions = 3C2
Total 10  3  30
2 x  3; x  1
68. f x=  2 for f  x  to be on to ,Range should be
p x+1; x  1
 ,  
p2  1  5 p2  4  2  p  2

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Sri Chaitanya IIT Academy 26.03.2023_LIIT_Jee-Main_GTM-02_Key & Sol’s
y

px211
x
x1 0

x 1

y1
It should be note that p  0
Thus p  2, 1,1,2
x3
69.   1;sin x  x   ......;
6
1

6
 2  x,0  x  1

70. g  x    2  x,1  x  2
 4  x, 2  x  3

71. We know the shortest and greatest distance between two
Curves always lie along the common normal. Let the normal
To the y  e x at Q  , e  meets the line y  x at P.

Y y  ex

y=x

X
0

 1 
dy   dy  
x
 e 1     e  1    0  Q   0,1
dx  dx 
 
1 1 1
 normal  y  1  1 x  0   x  y  1  0  PQ   
4 4 2
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Sri Chaitanya IIT Academy 26.03.2023_LIIT_Jee-Main_GTM-02_Key & Sol’s
 1ifx  0

72. f  x   x  x  1   2 x  1if 0  x  1
1ifx  1

 f  x  is increasing in  0,1
73. (3) Given equation of lines 3 y 2  4 xy  3 x 2  0
 3 y 2  3 xy  xy  3 x 2  0    
3 y  x y  3x  0
x
y , y  3x AP0  75
3
AM
In AMP,sin 75   AM  3sin 75
3
Now ,length of chord of contact AB=2AM
2  3sin 75   6sin 75

y  3x
yx
75
A X
3P Y
3
3
A
15 M
15 B
M

0  0,0 

74. Equation of chord of circle with mid point  h, k  is xh +yk= h 2  k 2 o

2 2
 h  h  k
Or y     , it touches the hyperbola
 k  k
1n.c  2.n c2  3.n c3  ...  n.n cn
75. The required mean x  1 n
c1  n c2  ....  n cn
n n n
n nn1cr 1 n 1
 r . c r  r .
r
n  cr 1 n 2 n1
 
 r n0  r 1 n  r n1  n
 n
c
r  n
cr  n
c r
 2  1
r 1 r 1 r 1
76. Conceptual
77. r   1,1,1    4,6,8  as 4i  6 j  gk  2  2i  3 j  4k 
as  2i  3 j  4k  . i  2 j  k   2  6  4  0
as point  2,3, 4  satisfies the plane x  2 y  z  0
It is of course parallel to the plane x  2 y  z  10
x y z
Line   satisfied by both points  0,0,0  and  2,3, 4  .
2 3 4
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Sri Chaitanya IIT Academy 26.03.2023_LIIT_Jee-Main_GTM-02_Key & Sol’s

78. We have , a. p  a.
b  c  
a b c 
 1
a b c  a b c
   
ca a c a 
a.q  a    0
a b c  a b c 
   
Similarly, a.r  0, b. p  0, b.q  1, b.r  0, c. p  0, c.q  0
and c.r  1   a  b  c .  p  q  r   a. p  a.q  a.r  b. p  b.q  b.r  c. p  c.q  cr
 111  3
79.
2
Consider a  b  c2   a  b  c2  a  b  c2  

  a  b  c2  a  b  c 2    a  b  c2  a  b2  c
1
 a 2  b 2  c 2  ab  bc  ca
2
2 2
 a  b   b  c    c  a 
2
  
Whhen a=b=1,c=2, it gives minimum value (Since a,b,c not all Equal)
1
 Minimum value of  a  b  c2    0  1  1  1  1
2
1

 x  x 2 m  x m  2 x 6 m  7 x m  14 
7m m
80. dx
1
  x x 7 m 1
x 2 m 1
x  2 x
m1 6m
 7 x  14 
m m
dx
1
   2 x 7 m  7 x 2 m  14 xm  x m 7 m 1
 7 x 2 m1  x m1  dx
m1
1 7m 2m m
  2 x  7 x  14 x  m  c
14  m  1
81. f  x   x  cos  x   2
f '  x   1  sin x and f '  0   1
f ''  x    cos x and f '  0   1
dx 1 1
Now ,   g ' y  
dy dy f ' x 
dx
f

0 f  0  3

f  3  0
1
When y  3 then x  0  g "  y    1........1
f ' 0 

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Sri Chaitanya IIT Academy 26.03.2023_LIIT_Jee-Main_GTM-02_Key & Sol’s
 f " x 
 g " y   2
 or g” g " 3  1......... 2 
 f ' x  
Hence , g '  3  g " 3  1  1  2
2 2
82. Consider two circles  x  4   y 2  16  x  7  y2  1
And proceed f  x  minimum at x  6  f min  12  0  2 3  k 2  12
2
83. Tangent to parabola y  mx  is also tangent to hyperbola.
m
4 1 3 9
 c 2  a 2 m 2  b 2  2  3  m  2  Area  .6. 
m 2 2 2
2
49 q 7 q
84.  2 or  .........1
 a  a
2 p 3 r
y
  a  ..........  2  And  .......... 3 
 a
A

4 p 9

49
B c
p r
q
12 p+q+r
\ 1 +  2  +  3 gives = =1    144
Δ a
1 t2
85. y 2 where t  tan  D  9 y 2  4  y  1 5 y  1  0 11y 2  24 y  4  0
t  3t  5

2
 y2
11
1 1 1
7 7 6
86. 1   1  x 4
 .dx =  x 1-x 4   +7×4  × 1-x 4  x 3dx
  0
0 0
1 1 1
6 6 6
 28  1  x 4
 dx  28  1  x 4
 dx  28 I  28 1  x 
4
dx
0 0 0
1
29 I  25  1  x 4  dx
0

Sec: LIIT Page 13

Sri Chaitanya IIT Academy 26.03.2023_LIIT_Jee-Main_GTM-02_Key & Sol’s
1
7
29 1  x 4  dx
0
1
7
4 7
4 1  x  dx
0

87. When e   x   e 21  log  x   2

e2   x   e3 2  log  x   3
8 10
 1dx   2dx  9
3 8

4  34 256  81 175 35
4
7
88. p. p  4
   
5 625 625 125 25
x 3x
89. case  i  x  0 y  x  60   60
4 4
LHS= ve not possible
Case  ii  Let 0  x  60
x 5x
y   x  60   60  0  x  48
4 4
Case  iii  x  60
x 3x
y    x  60    60
4 4
3x
 60   0  x  60,80
4

15

48 80
60

Required area  480

360 333
90.  2109   1396 
360 333 60 111
  301 7  2    200  7  4   2360  4333   64    64 
60 111
 1  63   1  63 2

Sec: LIIT Page 14