Sri Chaitanya IIT Academy 05-02-2022_Sr.

Super60-II_Jee-Main_PTM-15_Key & Sol's

Sri Chaitanya IIT Academy., India.

A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI

A right Choice for the Real Aspirant

ICON Central Office – Madhapur – Hyderabad
Sec: Sr.Super60-II Jee-Main Date: 05-02-2022
Time: 09.00Am to 12.00 PTM-15 Max.Marks:300
KEY SHEET
PHYSICS
1 2 2 2 3 1 4 2 5 3
6 3 7 4 8 3 9 4 10 3
11 4 12 4 13 4 14 1 15 3
16 3 17 2 18 4 19 3 20 2
21 5 22 4 23 20 24 10 25 12
26 5 27 6 28 10 29 6 30 1

CHEMISTRY
31 4 32 2 33 2 34 4 35 2
36 3 37 4 38 1 39 1 40 1
41 3 42 3 43 4 44 1 45 4
46 3 47 2 48 4 49 4 50 2
51 4.65 52 96 53 12 54 1 55 50
56 9 57 4 58 6 59 7 60 4

MATHEMATICS
61 2 62 2 63 2 64 4 65 1
66 3 67 4 68 1 69 1 70 3
71 1 72 4 73 2 74 3 75 3
76 4 77 2 78 2 79 1 80 2
81 15 82 2 83 1.73 84 25 85 200
86 1.5 87 3 88 30 89 1 90 7

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SOLUTIONS
PHYSICS
1. U  Q  W
 400  4.2  1000
 1680  1000  680J
2. W  U    100   100 J
3. If W is the work done by the gas, then U  Q  W . So, that leads to
100  60  20  x .
x  60 cal
3/2
4. P V   constant
 1
T V   constant
3
Since  
2
 1
 V1  3
1 1/2
T2  T1    T1  2  2  T1  2 
 V2 
4/3 4/3
5. P V1   P1 V2  ;
4/3
V  4/3 4/3
P1  P  1   P  8  P  23 
 V2 
P1  16 P .
6. Adiabatic curves are more steeper than isothermal
7. V1  L1 ,V2  L2
For an adiabatic process
 1  1
T1 V1   T2 V2 
 1
T V  = constant
 1  1
T1  L1   T2  L2 
5 2
 1 1
T1  L2  L  L  3 3
    2   2 
T2  L1   L1   L1 
T 400 1
8. Efficiency   1  2 or   1   or   50%
T1 800 2
f
9. In an ideal gas, internal energy  nRT
2
5 3
U   RT  4  RT  11RT
2 2

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4MgL
10. Y so maximum permissible error in Y
 D 2l
Y  M g L 2D l 
  100         100
Y  M g L D l 
 1 1 1 1 1 
    2     100
 300 981 2820 41 87 
 0.065 100  6.5%
11. 16MSD  20VSD
 VSD  4 / 5 MSD
LC  1 MSD  1VSD
 4  4
 1   MSD  1   1mm   0.2 mm
 5  5
g l T
12.  2 ( l and T are least, and the number of readings are maximum.)
g l nT
13. As measured value is 3.50cm, the least count must be 0.01cm 0.1mm
For venier scale with 1 MSD = 1mm and 9 MSD = 10 VSD,
Least count = 1MSD-1VSD=0.1mm
14. Leat count of the instrument
Value of main scale division
L.C 
No.of divisions on verier scale
Here n vernier scale divisions   n  1 M .S .D .
n 1
1V .S .D  M .S .D
n
L.C  1 M .S .D.  1V .S .D

 1 M .S .D 
 n  1 M .S .D  L.C.  0.5  29  0.50
n 30
0.5 1 1 1
 L.C.     0  1min
30 30 2 60
0.5
15. Least count   0.01mm
50
1 1 1 1
Diameter of ball D  2.5mm   20  0.01  2.7mm  MS    0  1'
30 30 2 60
   m D  0.01 
    m  D  2%  3  2.7   100%  3.1%
   
 RT VH  H M He
16. V   1.68
M VHe  He M H
17. Suppose m kg of ice into water . As the net heat changes is zero, so

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mL  mi si  T ice  mw sw  T w
m80  2  0.5   20   5 1  20 
m 80   100  20 m  1kg
Mass of water remaining in the beaker is 6kg
18. 9  K  65   s 
3  K  45  s 
9 60   s
  135  3 s  65   s
3 K 5  s
70  2 s
 s  35
19. As per Equi-partition law:
Each degree of freedom contributes
1
k BT Average Energy
2
1 3
In monoatomic gas D.O.F. = 3  Average energy  3  k BT  k BT
2 2
W 500
20.   0.2    2500J
1 1 1
R  1  W  2500  500  2000 J
21. ne nh  ni2
16 2

ne 
n i
2

1.5 10  
1.5 1.5 1032
 5  109 / m3
22 22
nh 4.5 10 4.5  10
hc
22. KE    hc

hc
e  3V0     ____(i )
0
hc
eV0    ____(ii )
20
Using (i) and (ii)
hc hc
  t  40
40 t
t1 t1 t1 t1
N0 N0 2 N0 N0
N0 2 2 2

23. 2 4 8 16
4  t 1  80 t 1  20 days
2 2

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24. When switch S1 and S 2 are closed

12  6 6  12
2
12  6 6  12
72 72
2  4  2  4  10
18 18
3R  4 R 12 R 2 12 R
25. Req   
3R  4 R 7R 7
12 R.C
T  Creq 
7
26. Fpeat  8  62  10V
2

Erms  5 2
E
27. C   E  CB  3  108  20  109
B
 60  108  10 9  6
28. u  5 gR
v 2  u 2  2as
v 2  5 gR  2 gR
v 2  3 gR

R
u

v 2 3gR
ac    3g
R R
at  g
atotal  ac 2  at 2  9 g 2  g 2  10 g
L 1 6g
29. mg 1  cos    I  2   sin  / 2
2 2 L
2
30.   2100   70 rad / s P  
60
P 220 220  7
    1 Nm
 70   70  22

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 Sri Chaitanya IIT Academy 05-02-2022_Sr.Super60-II_Jee-Main_PTM-15_Key & Sol's

CHEMISTRY
31. Conceptual
32. Zero order
k2 1
33.  2 at 17 0 C   10 3  0.5  10 3  5  104
k1 2
2
34. r  k SO2  O2 
35. Conceptual
36. Na4  Fe  CN 5  NOS  
2.303 50  20
37. k log
23 50  40
2.303
k log 3  0.047ms 1
23
38. Conceptual
39. Cu , Zn, Sn
2.303 a  x1
40. k  log
t2  t1 a  x2
2.303 a
41. k  log
t ax
oxygen x atoms

OV = x

42. TV  2 x
2 2x
Ti  x  
3 3
Ti2 x Ox  Ti2 O3
3
43.  hydrogen is absent in PhCHO
44. Glucose,Fructose and Maltose can reduceTollens reagent
45. Order is 1.0 with respect to both acetone and H  while zero with respect to Br2 .
46. A) NH 3 has higher boiling point than AsH 3 and PH 3 on account H-bonding. SbH 3 has
highest boiling point on account of highest molecular weight.
B) As the size of element increases, the strength of M  H bond decrease and thus
stability decreases.
C) Basicity decreases down the group. (Drago rule)
D) HEHangle  0  : NH 3  107.8; PH 3  93.6, AsH 3  91.8, SbH 3  91.3
47. Ni :Mond’s process, Cu:Electrolysis, Zr: van-Arkel process, Ga: Zone refining
48. II  Hyperconjugation
III  -M effect
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Due to Hyperconjugation basicity increases and due to –M basicity decreases
H 2O
H  C  H  R  MG  X   R  CH 2  OMgX   R  CH 2  OH
49. O

50. CrCl3 soluble in excess NaOH and forms green solution

k 2 log 25
51.   4.65
k1 log 2
k Ea  k Ea
52. Ea  1 1 2 2
k1  k2
53. XeF4  6 H 2 O  2 Xe  XeO3  12 HF
54. First order
 1 
55. pB   B pB0     75  50 torr
 1  0.5 
8 103  60
56. Number of Faraday’s   5  106
96000

= Eq of HO formed
1000
  HO    5  10 6   10 5 M
500
pOH  5, pH  9
57. Complexes  i  ,  iii  ,  iv  and  v  are optically inactive due to the presence of plane of
symmetry.

OH
58. HCHO  CH 3CHO  CH 3COCH 3  
HOCH 2  CH 2  CHO  HOCH 2  CH 2COH3  CH3  CH  CH 2  CHO
OH
CH 3 CH 3

CH  C  CH 2  COCH 3  CH 3  CH  CH 2  COCH3  CH3  C  CH 2  CHO

OH OH
2
59. In basic medium S conc. is high so all II & IV group cations of Q.A gets ppt
60. PbI 2 , AgI , CdS , PbCrO4

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MATHEMATICS
61. n U   140, n  F   60, n  H   74, n  C   75
n  F  H   42, n  F  C   18, n  H  C   30, n  F  H  C   8
 n  F  H  C   n  F   n  H   n C   n  F  H  C   n  F  H   n  F  C   n  H  C 
 60  74  75  8  42  18  30  127
i) Number of students who do not play any of three games
 n U   n  F  H  C   140  127  13
ii) Number of students who play cricket only
 75  10  8  22   75  40  35
iii) Number of students who play football and hockey, but not cricket
 n  F  H   n  F  H  C   42  8  34
62. Let f  x   x 3  4 x 2  x  6
Zeroes of f  x   1, 2,3  A  1, 2,3
Also, let g  x   x 3  6 x 2  11x  6
Zeroes of g  x   1,2,3  B  1, 2,3
 i  A  B  1
 ii  B  A  1
 iii  A   B  A  1, 2,3
63. U   x : x  N and 2  x  12
 U  2,3, 4,5,6,7,8,9,10,11,12
A   x : x is an even prime  A  2
B   x : x is factor of 24  B  2,3, 4,6,8,12
 A  B  2  2,3, 4,6,8,12  
 A  B is an empty set, is a true statement.
But, A  B  B  A ' is not correct.
Again, A '  3, 4,5, 6, 7,8,9,10,11,12 , B '  5, 7,9,10,11
A ' B '  3, 4, 6,8,12  B  A , which is true and  A  B  '  A ' B ' is the De
Morgan’s law, which is also true.
64. Given x 2  16 y 2  144
x2 y 2
 2  2  1(An ellipse whose major axis is x -axis______(i)
12 3
and x  y 2  25 ( a circle with radius r  5 units)_______(ii)
2

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From the graph of (i) and (ii), we note that A  B have four points.
65. When x  1, y  7  N , so 1,7   R .
When, x  2, y  2  3  5  N , so  2,5   R .
Again for x  3, y  3  2  5  N , so  3,5  R .
6 6
Similarly for x  4, y  4   N and for x  5, y  5   N .
4 5
Thus R  1,7  ,  2,5  ,  3,5 
Hence Domain of R  1,2,3 and Range of R  7,5
66. Recall that a b stands for a divides b. For the elements of the given sets A and B, we
find 2 6,2 10,3 3,3 6,5 10
 R   2, 6  ,  2,10  ,  3,3 ,  3, 6  ,  5,10 
 R 1   6, 2  , 10, 2  ,  3,3 ,  6,3  , 10,5 
67. R   x, y  : x, y  N , 2 x  y  41
Reflexive : 1,1  R as 2.1  1  3  41 . So, R is not reflexive.
Symmetric: 1,39   R but  39,1  R . So, R is not symmetric.
Transitive:  20,1  R and 1,39   R . But  20,39   R , so R is not transitive.
68. Reflexive: 1,1 ,  2,2  ,  3,3  R, R is reflexive
Symmetric: 1,2   R but  2,1  R, R is not symmetric
Transitive: 1,2   R and  2,3  R  1,3  R, R is transitive.
69. Arranging the given data in ascending order, we get 2,3,5,7,8,9,10,11,14 . Here n  9 ,
which is odd.
1 th
Median   n  1 observation
2
1 th
  9  1 observation = 5th observation = 8
2
Thus, M  8
The values of  xi  M  are: 6, 5, 3, 1,0,1, 2,3, 6

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9
  xi  M   6  5  3  1  0  1  2  3  6   27
i 1
9

x i M
27
 M .D.  M   i 1
 3
9 9
Hence, M .D.  M   3 .
70. When each observation is multiplied by 2, then variance is also multiplied by 2 2 .
 New Variance  2 2  23.33  93.32

71. Mean x 
fx i i

3  9  20  98  63  44  39  60 336
 8
f i 42 42

    f         42          62
f x  x 3 7  3 5  4 3  14 1  7 1  4 3  3 5  4 7
i i
M .D. x   2.95
i 21
72. Variance of a data is not changed, if each item is increased or decreased by the same
quantity.
n 2  1 99
 Variance    8.25
12 12
73. On the basis of the given information, following diagram is obtained.
B

x/2

x/2 

A P
3x
1 1

tan   tan          3 6  3
1 1 19
1 .
3 6
74. Let AB be the tower of the height h,D be the point x m away from B and C be another
point b m above D.

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In triangle ABD,
h  x tan  ___(1)
In triangle BCE,
x  b cot  ___(2)
From (1) and (2), we get
 h  b tan  cot 
75. Let BC be the declivity and BA be the tower.

Using sine rule in ABC , we get

BC AB
0

sin 75 sin 300
80sin 300
 AB 
sin 750
40  20 2
 AB 
3 1
 40  6 2 
76. Let AB be the pole of height h. Also, let D and C be the initial and final positions of the
man.

In triangle ABC, x  h cot 2 ____(1)

In triangle ABD, h   2h  x  tan  _____(2)
Put the value of x from (1) into (2), we get
 1 
1 2  tan 
 tan 2 
 1  tan 2  
1 2   tan 
 2 tan  
 tan 2   4 tan   1  0
 tan   2  3

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tan   2  3 (rejected as otherwise 2  150 0 )


 tan   2  3 
   150
77. Let z  x  iy, z1  x1  iy1 and z2  x2  iy2 ,
z  z  2 z  1   x  iy    x  iy   2 x  1  iy
 2 x  1  y 2 ____(i )
Since z1 and z 2 both satisfy(i), we have
2 x1  1  y12 and 2 x2  1  y22
 2  x1  x2    y1  y2  y1  y2 
 y  y2 
 2   y1  y2   1  _______(ii)
 x1  x2 
Again z1  z2   x1  x2   i  y1  y2 
y  y2
Therefore, tan   1 , where   arg  z1  z2 
x1  x2
 y  y2  
 tan  1  since   
4 x1  x2  4
y y
1 1 2
x1  x2
From (ii), we get 2  y1  y2 , i.e., Im  z1  z2   2
78. p:7 is not greater than 4, q:paris is in France
 p  q : 7 is not greater than 4 or Paris is in France
  p  q  : 7 is greater than 4 and Pairs is not in France
79. Let a, b, c be the direction ratios of the required line. Then, equation of line passing
x 1 y  2 z  4
through 1, 2, 4  and having Dr’s  a, b, c  is   _____(i )
a b c
Now, as line (i) is perpendicular to the lines
x  8 y  19 z  10 x  15 y  29 z  5
  and  
3 16 7 3 8 5
 3a  16b  7 c  0 ____(ii )
3a  8b  5c  0 ____(iii )
On solving (ii) and (iii), we get
a b c a b c
  i.e.,  
24 36 72 2 3 6
So, the required equation is
x 1 y  2 z  4
 
2 3 6
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 Sri Chaitanya IIT Academy 05-02-2022_Sr.Super60-II_Jee-Main_PTM-15_Key & Sol's
80. The semi-elliptical arc has been shown in the figure. We choose the coordinate axes as
shown in the figure.
1
Here OA  .8  4m and OB  2m
2

 The equation of the ellipse is

x2 y 2
2
 2  1 , i.e., x 2  4 y 2  16 ____(i )
4 2
Let h metres be the height of the arc at a distance of 1.5m from one end, then
OM  4m  1.5m  2.5m , and so the point P is  2.5,h 
Since P lies on ellipse(i)
2
5 25
    4 h 2  16  4 h 2  16 
2 4
39
h  1.56m (approx.)
4
81. We have n  A  3, n  B   6 , so that maximum number of element in A  B  3 . Also,
n  A  B   n  A  n  B   n  A  B 
 Minimum of n  A  B   n  A  n  B   Maximum of n  A  B   3  6  3  6
The number of elements in A  B is maximum when sets A and B are disjoint.
Therefore,
n  A  B   n  A  n  B   3  6  9
Required sum  9  6  15
82. Equivalence relation on the set 1,2,3 containing 1,2  and  2,1 are
A1  1,1 ,  2, 2  ,  3,3  , 1, 2  ,  2,1
A2  1,1 ,  2, 2  ,  3,3 , 1, 2  ,  2,1 ,  2,3 ,  3,1 ,  3, 2  , 1,3
So, only two equivalence relation exist.
1 n 2 1 n 2
83. Hence,   i 
x  1  7 and   xi  1  3
n i 1 n i1
n
2
   xi  1  7n _____(i)
i 1
n
2
and   x  1
i 1
i  3n _____(ii )

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 Sri Chaitanya IIT Academy 05-02-2022_Sr.Super60-II_Jee-Main_PTM-15_Key & Sol's
Adding (i) and (ii), we get
 n  n
2   xi  1  10 n    xi2  1  5n
 i 1  i 1
n
2
n x i
xi2  n  5n   xi2  4n  i 1
4
i 1 n
Subtracting (i) and (ii), we get
n

n x i
4 xi  4n  i 1
1
i 1 n
2
 n 
1 n   xi 
 Standard deviation  
n i1
xi2   i 1 
 n 
 
 4  1  3  1.73
84. Hence N  10, x  12,  x 2  1530
3
C.V.   100  25
12
85. In the following figure OP is the tower.

OP  100m
In right angled triangle POA.
100
tan 30 0 
OA
 OA  100 cot 300  100 3
In right angled triangle POB,
100
tan 450   OB  100 cot 450  100
OB
In right triangle AOB, using Pythagoras theorem, we get
Sec: Sr.Super60-II Page 14
 Sri Chaitanya IIT Academy 05-02-2022_Sr.Super60-II_Jee-Main_PTM-15_Key & Sol's

AB 2  OA 2  OA 2  OB 2  3  100 2  100 2  4  1002

 AB  2 100  200m
86. Let the observer be at point A. Also, let D be initial position of the car and C the position
after 3 minutes.

In ABD , BD  h cot 300

In ABC , BC  h cot 60 0
CD  BD  BC  d  h cot 30 0  h cot 600
h  cot 30 0  cot 600 
Speed of the car 
3
Time required to travel distance BC
h cot 600  3
  1.5 minute
 0
h cot 30  cot 60 0

     
87. Let v1  i  2 j  k , v2  3i  2 j  k and v3  c   a   b   i  j   j  k
   
  i      j   k
  
Since, v1 , v2 , v3 are coplanar. (Given)
1 2 1
 3 2 1  0
   
Applying C2  C2   C1  C3  , we have
1 4 1
 
3 0 1  0  4  3     0   3   3
 
 0 
88. Max.distance  l  r
Min.distance  r  l
l is distance between point and centre.
89. Given that  is the angle between asymptotes.

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 Sri Chaitanya IIT Academy 05-02-2022_Sr.Super60-II_Jee-Main_PTM-15_Key & Sol's
b b

tan   a a
b b
1 
a a
x2 y 2 b
[The equation of two asymptotes of the hyperbola 2  2  1 are y   ]
a b a
2
2b a 2ab
  2 2
 2
a a b a  b2
a 2  b2
cos   2
a  b2
2   a2  b2
2cos    1  2
2 a  b2
2   a2
cos    2 2
 2  a b
 b 2  a 2  e 2  1  a 2 e 2  a 2
 a 2  b 2  a 2e2
2   a2 1   1
cos    2 2  2  cos   
2 a e e 2 e
 1 0 0   1 0 0  1 0 0
 
90. A2  0 1 0 0 1 0  0 1 0
  
    
 a b 1  a b 1  0 0 1 
A 2  A4  A6  A8  I 3
1 0 0   2 0 0   4 0 0 
 0 1 0  0 2 0  0 4 0
     
 0 0 1   0 0 2  0 0 4 
7 0 0 
 0 7 0   7 I 3  7 A8  kA8
 
0 0 7 
k  7

Sec: Sr.Super60-II Page 16