SRI

CHAITANYA IIT ACADEMY, INDIA 10‐12‐22_ Sr.S60_NUCLEUS&STERLING_BT _ Jee‐Main_PTM‐13_KEY &SOL’S

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU    MAHARASTRA  DELHI    RANCHI 
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.Super60_NUCLEUS&STERLING_BT JEE-MAIN Date: 10-12-2022
Time: 09.00Am to 12.00Pm PTM-13 Max. Marks: 300
KEY SHEET
PHYSICS
1) 1 2) 4 3) 3 4) 3 5) 2
6) 2 7) 1 8) 2 9) 4 10) 2
11) 4 12) 3 13) 2 14) 3 15) 4
16) 3 17) 4 18) 3 19) 4 20) 3
21) 20 22) 4 23) 13 24) 80 25) 8
26) 3 27) 12 28) 65 29) 6 30) 14

CHEMISTRY
31) 2 32) 1 33) 1 34) 1 35) 1
36) 4 37) 3 38) 3 39) 1 40) 4
41) 3 42) 4 43) 3 44) 2 45) 1
46) 4 47) 1 48) 2 49) 4 50) 3
51) 4 52) 20 53) 4 54) 5 55) 5
56) 40 57) 8 58) 9 59) 3 60) 186

MATHEMATICS
61) 1 62) 4 63) 1 64) 3 65) 2
66) 3 67) 3 68) 3 69) 3 70) 1
71) 4 72) 4 73) 2 74) 3 75) 2
76) 2 77) 2 78) 3 79) 1 80) 2
81) 1 82) 6 83) 1 84) 4 85) 2
86) 1 87) 6 88) 2 89) 2 90) 1

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 SRI CHAITANYA IIT ACADEMY, INDIA 10‐12‐22_ Sr.S60_NUCLEUS&STERLING_BT _ Jee‐Main_PTM‐13_KEY &SOL’S

SOLUTIONS
PHYSICS
1. 3
 n2  n1  2 1 D  L 
n  D  , L T  , D  L2T 1  M o L2T 1
 x2  x1   L
2. Figure (a) can be simplified as follows

Figure (b) can be simplified as follows

Figure is balanced wheatstone bridge, which can be simplified as follows

5 5
Hence ratio is C : C :C  5:5:3
3 3
3. Potential difference across upper branch is 6 V

 C1   3 
V2  V    10    3V
 1
C  C 2  3  7 
Hence. Potential difference across 5 F capacitor is 3 V
Thus, charge in 5 F capacitor is Q5  F  5  3  15  C
4. Conceptual
5. Conceptual
6. 3C  3C 
Ceq  , Total charges q   E
3C 3C 
2 3CE 2CE 2E
Charge upon capacitor 2 F , Q2    
3 3  C  3  C 1  3
C
If C  1 F ; q '  E , Hence Q2 is maximum at C  3 F
Hence graph (B) is correct
7. Before closing the switch
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 SRI CHAITANYA IIT ACADEMY, INDIA 10‐12‐22_ Sr.S60_NUCLEUS&STERLING_BT _ Jee‐Main_PTM‐13_KEY &SOL’S

After closing the switch

q q q C
q1  q2  2Q V AB  V AC or 1  2 1  1 or q1  2q2
C1 C2 q2 C2
4Q 2Q
Solving, we get q1  , q2 
3 3
Q Q 4Q
Charge flown through K is    q1      5Q / 6
2 2 3
8. Capacitors 1 F ,2 F and 3 F are in parallel, and their total capacitance is 6 F .
Thus, we have three capacitors in series, each of capacitance 6 F across the 12 V
power supply. So potential drop across each is 12 / 3  4V . So options (3) is correct.
Charge on 2 F capacitor is CV  2  4  8C . So option (1) is correct.
Charge on 6 F capacitor 6  106  4  24C . So option (2) is wrong.
Thus, correct options are (1), (3), and (4)
9. V t
V  kt
4 3 4S 4s
 r  kt  r  k ' t1/3 p  p0   p0 
3 r kt1/3
1
pv / s is a straight line
t1/3
10.

The charge in capacitor after placing the dielectric

Q1  C1V , The induced charge on dielectric surface
 1  1  2 6
Qinduced  Q1 1   , Qinduced  3  1    3    1.2 nC
 K  5/ 3 5 5
11. In the given circuit A, B, C and D are at the same potential by symmetry.

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 SRI CHAITANYA IIT ACADEMY, INDIA 10‐12‐22_ Sr.S60_NUCLEUS&STERLING_BT _ Jee‐Main_PTM‐13_KEY &SOL’S
R  R2 a ar    ar
Req  1 , R1  ar , R2  r Req  1     2   
4 2 4 2 8
12. Given E  24V , R  2, R1  4, R2  6, C1   4 / 3  F , C2  4  F . As the
capacitor offers a very high resistance to the current in the steady state, so the current
is prevented to pass through the capacitors. Now, the total resistance in the circuit is
Req  R  R1  R2  2  4  6  12
E 24
Hence, the net current in the circuit is   2A
Req 12
Therefore, the terminal potential difference across is
AB  24  2  2  20V
Note : As the capacitors and resistance are in per parallel the potential difference of 20
V is available to both the capacitors and the resistors.
6
VB  V y  20   12V ... (i)
10
20  4 / 3
VB  Vx   5V ... (ii)
4 / 3 4
From eqs, (1) and (ii), Vx  V y  12  5  7 V
13. 5
I1  1A
23

5 5
I2   A
33 6
V A  0  3I1 or V A  3V
VB  0  3I 2 or VB  2.5V
Potential difference across capacitor is
1
3V  2.5V  0.5V  V
2
Q  CV  2  1/ 2  1C
14. U U 
Fx   4 x Fy    3 F  4 xiˆ  3 ˆj
x y
 
At 1,2  F  4iˆ  3 ˆj F  F  5
15.

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 SRI CHAITANYA IIT ACADEMY, INDIA 10‐12‐22_ Sr.S60_NUCLEUS&STERLING_BT _ Jee‐Main_PTM‐13_KEY &SOL’S
The velocity remains same in the vertical direction (along the surface) and the velocity
become e times and opposite in the horizontal direction (  ar to the surface)

d
Time from O to A, t1  (uniform)
o
u cos 45
d
Time from A to O, t2 
eu cos 45o
d  1
Total time t  t1  t2  1 
o  e
eu cos 45
Time for vertical motion (O to O)
1 2 2u sin 45o
0  u sin 45o T  gT  T  t T
2 g
o
d  1  2u sin 45
 1   
u cos 45o  e  g
2 o
 1  2u sin 45 cos 45
o
u2 3 gd
d 1     sin 90o   3d
 e g g g
1 1
1  3 e 
e 2
16. LO  mv.2 R  I cmo
 m0 R.2 R  mR 20  3mR 2o
17. In equilibrium kx  F attraction
2
1 1  V 
kx  0 E 2 A K 0.2d  0  A
2 2  0.8d 
1 0 AV 2  AV 2
K  0
2 0.64d 2  0.2d 0.256d 3
18.  dx xdx R 1 l 1/2
  dR 
 olA 0
dR  x , dR  x dx
A  0 LA 0

1 2 3/2 2 1
A ol , R  l  l
 0lA 3 3 0A
19. 4
VA  VP  x  1
40
VA  VQ  2   2 
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 SRI CHAITANYA IIT ACADEMY, INDIA 10‐12‐22_ Sr.S60_NUCLEUS&STERLING_BT _ Jee‐Main_PTM‐13_KEY &SOL’S
x
(1) - (2) VQ  VP   2  2sin  t
10
x  20sin  t  20
dx
   20cos  t. cm / s
dt
  20 cos  t
20. GMm  GMm  1 1 
E1      GMm  
Rh  R   R R  h 
GMm 1 1 1
E2  , E1  E2 ,  
2 R  h R R  h 2 R  h
1 3 R
 , h   3.2  103 km
R 2 R  h 2
21. 1 1
T   sec t  10T  2sec
f 5
a  a0e kt
a0
 a0e  k 2 e2k  2  2k  ln 2
2
a0 ln 2
 a0ekt ekt  1000 kt  ln1000 t  2.303log10 103
1000 2
2  2.303  3
t  20s
0.7
22. Let at some instant, length x is inside water.

W   m ALg , FB   w Axg
Acceleration of rod
W  FB  m ALg   Axg   x
a   g 1   
m  m AL  m L 
vdv  x  v L x 
 g 1   0 vdv  g 0 1  dx
d  L  L
L
v2 x2  1   1 
g x  g L  v  2 gL  1  
2 2 L  2   2 
0

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 SRI CHAITANYA IIT ACADEMY, INDIA 10‐12‐22_ Sr.S60_NUCLEUS&STERLING_BT _ Jee‐Main_PTM‐13_KEY &SOL’S
23.

55  50sin 37o   2  3 a 55  50  0.6  5a a  5 m / s 2 a y  5  0.6  3 m / s 2

a x  5  0.8  4m / s 2

4
: N1  20  2a y  2  3 N  26 N : f   N1  2a x   26  2  4  
13
24.  
y  0.3sin  0.157 x  cos  200 t   0.3sin  x  cos  200 t 
 20 
 2   2  2 1 
 2 A sin  x  cos  t     40m L  4.  80m
    T   20 2
25. Applying Kirchhoff’s first law at junction M. we get the current I1  3 A . Applying
Kirchhoff’s first law at junction P. we get the current I 2  1 A

Moving the loop from MNOP, we get

VM  5 I1  I1  2 I 2  VP or VM  VP  6 I1  2 I 2  20V
Energy stored in the capacitor is
1 1
CV 2   4  106  20  20  8  104 J
2 2
26. nR T1  T2  2 25
W  30 
 1  1

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 SRI CHAITANYA IIT ACADEMY, INDIA 10‐12‐22_ Sr.S60_NUCLEUS&STERLING_BT _ Jee‐Main_PTM‐13_KEY &SOL’S

x2 y2 2 5 2
 1  1 1  f  3

f k 2  2k  5 
f  k  11 f 3 f

27. h 3 3
For fig min y  y   2cm n  y  1cm
1 1 3
1 1
2 4 2
 Av  Av 4 4  10 1 4  10
F  F1  F2  1  2      8  4  12 N
y h  y 10 2 10 1
28.
G  5  9  45  1
G G
S S
i 10
1 1
ig 1
5  2 10 G 10 45
 S'   S'  
5 2 7 i
1 7 i
1
ig ig
i 7 i 63 65 ig 2
 1  45    1  
ig 10 ig 2 2 i 65
29.

  2T 2s  
b  R cos     h g  h cos    
 2 R  gb  2
30.  k2 
l   R  r  1  
 2
 R 
k2 2
For solid sphere   0.4 l   R  r 1  0.4 
R2 5

T  2
l
 2
 R  r 1.4
g g

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CHEMISTRY
31.
d
ZM
3
a  NA
 Z  4; M  286; d  9.53 g / cm3 
Z M 4  286
a3    200  1024 a  5.85 Ao
d  N A 9.53  6  10 23
32. Conceptual
33.

If all the ions along one of the body diagonals are removed,
1 1
Number of A ions removed = 2  (corner share) 
8 4
Number of B ion removed = 1
Number of C ion removed = 1
(Since body diagonal ions are inside the cube so they do not share with other ions)
1
Number of A ions left = 4   3.75
4
Number of B ions left = 4  1  3
Number of C ions left = 4  1  3
Thus, formula is A3.75 B3C3 = A5 B4C4
34. In glucose and fructose molecules; C3 , C4 and C5 atoms involve in osazone formation
As these carbon atoms have same configuration in both the molecules, the resultant
osazones are identical
35. a) The two   Cl atoms are more effective in stabilizing the anion through inductive
effect
b) F atoms shows – IE where by electron pair on N becomes less available
c) O atom is MeOH is more electronegative than N atom in MeNH 2 . So, the e pair
on O in MeOH is less available MeOH is weaker base than CH 3 NH 2
d) R  NH 2  NH 3  Ar  NH 2
O
36. CH3
C

CH3

+I HC

37.
O
O 1) O3
O 2) Zn/H2O
O
O
O
O O

38. In an ideal solution the nature of molecular interactions are unchanged. So, heat is
neither liberated nor absorbed. For an ideal solution, Vmix  0 and it obeys Raoult’s
law
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39.
H 3C H 3C
HCN / CN- OH

H3C
H3C CN
(A)

H 3C
OH

H 3C COOH
(B)
40.
 CH 3 3 C  CH 2  CH 2  OH 
K 2Cr2O7
  CH 3 3 C  CH 2  COOH
 A
2 CH3  NH
  3 3 C  CH 2  COCl 
SoCl
2  CH 2 
 B
 CH3 3 C  CH 2  CO  N  CH3 2 
LiAlH 4

C 
 CH 3 3 C  CH 2  CH 2  N  CH 3 2
 D
41. 1000  K f  w 1000  5.12  1
T f  , So, T f   0.4 K
W m 250  51.2
42. w  1000  R  T i
  i CRT  i  , For 1% solution,  
M V M
st
43. After 1 ionization
N  :1s 2 2 s 2 2 p 2 O  :1s 2 2 s 2 2 p3
F  :1s 2 2 s 2 2 p 4 Ne :1s 2 2s 2 2 p5  order of subsequent IP :
 ns2np2    ns2np4    ns2np3    ns2np5  N  F  O  Ne  or  Ne  O  F  N
44. As temperature increases, intermolecular force of attraction will become weakes. This
lowers with surface tension and viscosity of the liquid
45. PM
d   For the same gas at two different pressures and temperatures,
RT
d1 P1 T2 1.400 760  273 d  1.55 gL1  1.55kgm 3
  
d 2 P2 T1 d 760  303
46. a) NH 4 NO2  N 2  2 H 2O

b) 2 NaN3  3N 2  2 Na

c)  NH 4 2 Cr2O7  N 2  4 H 2O  Cr2O3

d) NH 4 NO3  N 2O  2 H 2O


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47. 1 1
The mean free path   or   [  is molecular diameter]
2
2 N  2
Thus, the path is largest for smallest  . Here  is smallest for H 2
48. In oxoacids of halogens, acidic strength  EN of the central atom
 HClO4  HCrO4  HIO4
49. CH 3 and OH are activating and O , P  directing groups, where as NO2 group is
deactivating and m-directing
50. As temperature increases, the no.of molecules possessing low velocity decreases and
the no.of molecules with high velocity increases. The most probable velocity shifts to
a higher velocity.
51. Benzoic acid is stronger than any alicyclic / aliphatic acid except formic acid CH 3
group destabilises benzoate ion in para and meta position O-methyl benzoic acid is
stronger than benzoic acid due to ortho effect
52. For NaCl : 1  iCRT  2  0.05  0.0821  300  2.46atm
x
For unknown compound  2  CRT   0.0821  300  0.123x atm
200
Total osmotic pressure,   1   2 4.92  2.46  0.123x x  20 g

 
53. 3
Volume of unit cell  a3  100  1010  1 1024 cm3
No.of atoms in fcc unit cell = 4
4  24 4  1024
Mass of unit cell =  4  1024 g , Density =  4 gcm 3
25 24
2.4  10 1  10
54. Ag   aq   Cl   aq   AgCl  1 mole of Cl  ion = 1 mole of AgCl
Moles of the compound = MVL  0.15  0.1  0.015 , Moles of AgCl formed = 0.03
 No.of Cl  ions furnished by a formula unit of CoCl3 xNH 3  2
 Formula of the compound = Co  NH 3 5 Cl  Cl2  x  5
 
55. Nylon – 6, Nylon – 6,6, Dacron, glyptal, and Bakelite are step –growth or
condensation polymers.
56. 3RT1 2 RT2

M1 M2
57. pKa1  pka2
Piso 
2
58. In simple cubic lattice, packing efficiency is 52%. The co-ordination number of each
x 52
atom = 6. x : 52 and y = 6   8.67
y 6
59. Magnetic moment,   n  n  2  BM
60. 3 3 o
For bcc, r  a r  4.29  1.86 A  186 pm
4 4
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 SRI CHAITANYA IIT ACADEMY, INDIA 10‐12‐22_ Sr.S60_NUCLEUS&STERLING_BT _ Jee‐Main_PTM‐13_KEY &SOL’S

MATHEMATICS
61. f  x  is not strictly increasing
62. x
 5 4 
f  x    3sin t  4cos t  dt  f ' x   3sin x  4cos x, x   4 ,
5
3 
4
These values of x is are in third quadrant where both sin x and cos x are negative
 5 4 
Then f '  x   0 for x   ,  ,
 4 3 
Hence, f  x  is decreasing for these values of x . Then the least value of function
4
3
4 3 1
occurs at x  .  f min imum    3sin t  4cos t  dt   2 3
3 5
2 2
4
63. Is one-one when
23  ln1  b2  3b  10  b2  3b  2  0  b  1,2
64. f  x  T   f  x  2T   .....  f  x  nT   f  x 
 n  n  1 
n 
nf  x 1  2  3  ....  n   2  3
lim  lim 

n  f  x  1  22  32  ...  n 2 
n  n  n  1 2n  1 2
6
65. 1 1
 
lim 1   x  ln  tan x   lim 1 ln  tan x   1
 
x x
4 4
66. 1
f  f  x   x  f ' g  x  g ' x   1  g ' x    1   g  x
5
f ' g  x 
g ''  x   5  g  x   g '  x 
4

67.

   x  1 x  2 x  3  sin  x  4 

68.
f  x   x 2  3x  2

3 7
Not differentiable at x  3, ,
4 4
69.
 
f k 2  2k  5  f  k  11

k 2  2k  5  k  11  k   3,2 

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 SRI CHAITANYA IIT ACADEMY, INDIA 10‐12‐22_ Sr.S60_NUCLEUS&STERLING_BT _ Jee‐Main_PTM‐13_KEY &SOL’S
70. 8 x 43  13 x38 8 x 9  13 x 14
 dx  dx
x  1  x 
13 5 4 8 13 4
 x 1 x

Let 1  x8  x13  t ,  8x9  13x14  dx  dt

dt 1 1 x39
   C  C  C
t4

3t 3

13 3
 
8 13 5 13
3 1 x x 3 x  x 1
71.
P ' Q '  PQ cos  90o    
4
t2 1
 t 2  1  P ' Q 'min  2 2

72. 9  16  25 32
Distance of line from centre 
25 5
32 7
Shortest distance  5
5 5
73. 4
A.M.  ,  ,  ,     1
4
G.M.  ,  ,  ,   1          1
4
So, equation is  x  1  0
74.   1,   1,   1,  1 as   12     12     12    12  0
a
 The roots of given equation is equal to 1 S2  2  6
a0

 
75. 5
A1B 1  B 1A1  C  A1  B 1
5
 I 
76.

77. x2 y 2
x  y  2 and  1
9 4

Ar. Of ellipse – Ar. Of square    2  3  8  6  8

78.  f ' x  
   1
dy  f ' x   dx
f  x  e x
 1   y  f  x  , I . F .  e  
dx  f  x  f  x
ye x x ye x
  e dx  C   e  x  C
f  x f  x
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 SRI CHAITANYA IIT ACADEMY, INDIA 10‐12‐22_ Sr.S60_NUCLEUS&STERLING_BT _ Jee‐Main_PTM‐13_KEY &SOL’S
79. dy y

dx
tan   dx x  
y dy dy
1 .
x dx

2
 dy  2 y dy
   1
 dx  x dx
80. 2
dy ex
Let f  x   y  2 xy 
dx  x  12
81.  a dy xa . y ay1
a  a 1
x .y   ; y 
a a
,   a x  a m
a dx a 1 x1
x x
1 y 1 2 1
  a .x11 a 1  a 
2
A  y1  mx1 x1  1  y1x1 1  a 
2 m 2 2
For A to be constant 1  a  0
82. dy d 2 y  dy 
2
2 2
y  cos x  2, 2 y   sin 2 x, y      cos 2 x
dx dx 2  dx 
d2y   dy 2 
   
2
y 4  y3  cos 2 x  2  cos 2 x  2      cos 2 x   6
dx 2   dx  
83. 2
t 2 f  x  1   x  1 f  t 
2
2tf  x  1   x  1 f '  t 
lim  1  lim 1
t  x 1 f  t   f  x  1 t  x 1 f 't 
  x  1  2 f  x  1   x  1 f '  x  1   f '  x  1
84. Conceptual
85. e2
xy 1  y  dx  dy if  0  1 and f  2  
k  e2
1 1 y  y
 xdx  dy  xdx  dy
y 1  y  y 1  y 
1 1  1 1 
 xdx     dy   xdx     dy
 y 14 y   y 1 y 
x2 O2
 log y  log 1  y   log C , f  0   1   log1  log 2  log C
2 2
log C  log 2  C  2

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 SRI CHAITANYA IIT ACADEMY, INDIA 10‐12‐22_ Sr.S60_NUCLEUS&STERLING_BT _ Jee‐Main_PTM‐13_KEY &SOL’S
86. f  x   x2
1
 1
A  2   2  x 2  x 2 dx  
  2 3
0
87. Conceptual
88. f  x   f  z   f  x  z  and f  0   0 f '  0   4  f  x   4 x
4
So, area bounded     4 x  x 2 dx  
0
89. 1 1

Required area  4  x 2  x 6 dx   4 x 1  x 4 dx 
2
0 0

x2  sin
90. 1 1
   5 
Ar  4  1  x 2/5 dx  4  x  x 7/5  
 7 0 7
8
0

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