Professional Documents
Culture Documents
CHEMISTRY
31) 2 32) 3 33) 1 34) 2 35) 1
36) 3 37) 1 38) 3 39) 4 40) 1
41) 1 42) 1 43) 4 44) 3 45) 1
46) 1 47) 4 48) 1 49) 1 50) 1
51) 5 52) 2 53) 4 54) 32 55) 5
56) 800 57) 5 58) 27 59) 557 60) 8
MATHEMATICS
61) 3 62) 1 63) 2 64) 2 65) 2
66) 3 67) 4 68) 1 69) 2 70) 2
71) 2 72) 3 73) 3 74) 1 75) 4
76) 3 77) 3 78) 1 79) 2 80) 2
81) 7 82) 8 83) 5 84) 3 85) 2
86) 5 87) 111 88) 60 89) 3 90) 5
SOLUTIONS
PHYSICS
1. Total magnetic field induction at O is
B BLR BRP BMS BSQ
0i i 2i 107 2 10
0 0 0 0 104 T
4 r 4 r 4 r 0.020
2 ni 2 nir 2
2. B1 1 and B2 0
4 r 4 r 2 h 2 3/2
3/2
B h2
So, 2 1 2
B1 r
Fractional decrease in the magnetic field will be
B B2 B2
1 1
B1 B1
h 2 3/2 3h 2 3h 2
1 1 2 1 1 2 2
r 2 r 2r
3. Force on wire, F Bil sin 90 Bil . It acts perpendicular to the magnetic field as well as
the length of Wire . The acceleration in the wire.
F Bil
a
m m
4. The current through loop in anti location. Hence, magnetic field at the points within the
loop in perpendicularly outward to the plane. The magnetic field lines from a closed path.
A tangent to the field lines gives the directions of forces at same point. Thus, magnetic
field at O is perpendicularly inward to the paper
5. There is a uniform magnetic field B inside the current carrying long solenoid acting along
the axis of solenoid. The magnitude of force on the electron of charge (- e) moving with
velocity v in a magnetic field B is
F e v B evB sin
Here angle between v and B is zero, i. e. 0 and sin Therefore, F = 0. It
means the electron will continue to move with a uniform velocity along the axis of the
solenoid.
6. For small element of wire
πa
13. M=l×Area of loop=l× a 2 + ×4 kˆ
4×2
π ˆ
=l×a 2 +1 k= 1 a
2 2
14. If the current flows out of the paper, the magnetic field at points to the right of the wire
will be upwards and to the left will be downward. Now, magnetic field at C is zero. The
field in the region BX¢ will be upwards (+ve) because all points existing in this region are
to the right of both the wires. Similarly, magnetic field in the region AX will be
downwards (–ve). The field in the region AC will be upwards (+ve) because points are
closer to A as compared to B. Similarly, magnetic field in region BC will be downward (–
ve).
ax bt
2
15. Given y xt e
It is transverse type y x, t e
ax bt
2
b
Speed, v
a
The wave is moving along x-direction.
16. When a satellite is moving in on elliptical orbit, it’s angular momentum r p about
the centre of earth does not change its direction. The linear momentum mv does not
remain constant as velocity of satellite is not constant. The total mechanical energy of S is
constant at all locations. The acceleration of S (= centripetal acceleration) is always
directed towards the centre of earth.
17. The position of centre of mass of electron and proton remains at rest, at their motion is
due to (internal) forces of electrostatic attraction, which are conservative. No external
force, what so ever is acting on the two particles.
18. In x-direction
mv 0 0 mvx mv mvx vx v
v v
In y-direction 0 0 m mv y vy
3 3
\Velocity of second mass after collision
2
v 4 2 2
v' v 3v
2
v' v8
3 3
19. From geometry l 2 x 2 y 2 but y is constant, hence on
dl dx
differentiating, we have, 2l 2x
dt dt
dl dx
But v Hence, horizontal velocity of block, vx
dt dt
lv x.vx
l.v v
or vx
x sin
20. For minimum mass of m, mass M breaks off contact when elongation in spring is
maximum. At the time of break off, block A is at lowest position and its speed is zero.
At an instant t1
dv mg kx 0
x
k
0
mg kx ma v
dx m
0
v dv g x dx
0
m
where x0 is maximum elongation in spring
kx02 2mg
0 gx0 x
2m k
At the time of break off of block B
M
Mg kx0 Mg 2mg m
2
21. Let R and R¢ be the radius of bubble of volume V and 2V respectively. Then
4 3 4
R V and R '3 2V
3 3
3
R'
2 or R ' 2 R As W s 4 R 2
1/3 2
So, 3
R
w ' R '2
W ' s 4 R '2 2 22/3 4 Or W ' 4 W
2 1/3 1/3
And
w R
3R 5R
1. 3. 9R a2
n1Cv1 n2Cv2 2 2
22. Cv / mix R a3
n1 n2 1 3 4 4
23. Volume of water in the vessel of base area A ' and height h is V A h ' .Averege velocity of
out flowing water when height of
2 gh 0 2 gh
water changes from h to 0 is v V Avt
2 2
2 gh
When vessel is filled to height 4 h, then volume in vessel 4V 4vt 4 A t
2
24. When jar is placed in vacuum, the liquid level rises up to the top of jar. The force exerted
by liquid on the base of jar =force due to vertical column of liquid of height
a b c vertical downward
K2 1
For cylinder,
R2 2
2
acylinder g sin
3
For rotation, the torque fR l . MR 2 / 2
(where, f = force of friction)
M
But R a f a
2
M 2 M
f . g sin g sin
2 3 3
s f / N , where N is normal reaction,
M
g sin
tan
s 3
Mg cos 3
For rolling without slipping of a roller down the inclined plane, tan 3 s .
CHEMISTRY
31. ArSE reaction at para position
32. reductive amination of benzaldehyde
33. Greater the polarity, more is the solubility in water.
34. NH 2 is more reactive than -OH
35. 1,4 addition
36. Hybridisation of Iodine in both compounds is sp3d
37. conceptual
38 . conceptual
39. CrF6 exists
40. conceptual
41. vap H 40.66 kJ mol 1
T 100 273 373 K , E ?
H E ng RT E H ng RT
H 2O(l ) H 2O g ng 1 0 1
E H RT 40.66 103 8.314 373 37559 J / mol or 37.56 kJ / mol
vf
42. S nR1n 2 8.314 1n10 38.3J / K
vi
43. PbO2 Pb 2 PbO, G 0 spon tan eous
SnO2 Sn 2 SnO , G 0 non spon tan eous
Thus O.S . for lead 2; O.S for tin 4
44. Specific heat is constant
45. H 2O C CO H 2 O2 CO H 2 CO2 H 2O
C O2 CO2 (131 282 242) KJ 393 kJ
46. 3N 2 H 4 l 4 NH 3 g N 2 g
1mol N 2 H 4l would produce 5/3 mol gases
3 mol N 2 H 4 produces 5 mol of gaseous products
P 1.0 atm, T 27C 300 K
Work done by system
PV RT n 8.314 J / mol / K 300 K 5 / 3mol 4157.0 J
47. All spontaneous processes are those where total entropy i.e. system + surroundings
increases
Thus, (a), (c), (d) are true.
Basically, time moves in the direction where entropy of universe increases.
Now, in (b), we have a closed system, i.e. even through matter can’t move into or out of
system, energy can.
Clearly, (b) can also be true if entropy of surroundings increase more than decrease of
entropy of system.
Sec: Sr.Super60_ NUCLEUS&STERLING_BT Page 8
SRI CHAITANYA IIT ACADEMY, INDIA 18‐11‐23_ Sr.Super60_NUCLEUS&STERLING_BT _Jee‐Main_RPTM‐15_KEY &SOL’S
48. In AB : 600 J heat is added
E 178
1 8.3 300 175.51
1000
280
nCaO 5.0 qv E
56
For n moles qv E 5 175.51 877.55 kJ
q 877.55 kJ
51. PI
P Ka
COOH P SH
Ka
2
2.05 8.00 10.05
5.02 5
2 2
52. d, e are correct statements
53. ii,iii,iv,v are incorrect
64
54. 26 64 32
2
55. Ma3bcd type of complex 5 stereo isomers
56. X 2 Y2 2 XY
H BE x x BE y y 2 BE x y
If BE of x y a, then BE of x x a
a
And BE of y y
2
H f x y 200kJ
a
400 or a 800kJ
2
The bond dissociation energy of x2 800kJ / mol
57. Net work done WA WB 25 20 5 unit
58. P1 20 atm P2 10 atm
V1 15 L V2 60
C p ,m 30.96
T P
S nC p1n 2 nR1n 2
T1 P1
7308 10
30.961n 8.3141n 21.46 5.76
3654 20
(temperature calculated using PV =nRT)
S 27.22 JK 1mol 1
59. 2CO O2 2CO2 H 560 kJ
2 mol 1mol
V 1L P1 70 atm P2 40atm
H U PV (Since volume remains constant)
560kJ U V P
U 560 kJ 1 30 0.1 kJ 557 kJ
60. H vap 3600 J
BP 177C 450 K
H
S 8J / K
T
MATHEMATICS
61. Explanation:
S1 :R is obviously true. To test the assertion let
f (x) = (x – a) (x – c) + (x – b) (x – d) = 0 then
f (a) = (a – b) (a – d)>0
f (c) = (c – b) (c – d)>0
If > 0 then f(a) > 0, f(c) < 0 there is a root between a and c.
Thus assertion A is false. S 2 : D 0 b 2 4ac
4 K 2 4 K 3 3K 6
K 2 3K 2 15 K 18 2 K 2 15K 18 0
2 K 2 12 K 3K 18 0
3
2 K K 6 3 K 6 0 K 6,
2
62. Both A and R are true but R is not correct explanation of A.
A L.H.S. 1 & R.H.S. 2
Hence A is true. 0
36a 4 2 2a 9a 0
2 2
36a 2 8 8a 36 a 2 0
8a 8 0 a 1
b 6a
3 3 a 1 f 3 0
2a 2
9 18a 2 2a 9a 2 0
9a 2 20a 11 0
9a 2 9a 11a 11 0
9a a 1 11 a 1 0
a 1 a
11 11
0 a 1or a
9 9
63. 2 3 7 5 7 2 2 3 9 5 9 4 x 2 6 x 8 0
2 1 3 1 3 1
64. 2 3
1 1 1 2 2 2 1
2
3 1 2 2 6
1 6 2 1
4 4
2 3
4 2 2
3 3 2 2 2
R.V=
2 2
6 4 2 6 68
7
2 2
Sec: Sr.Super60_ NUCLEUS&STERLING_BT Page 11
SRI CHAITANYA IIT ACADEMY, INDIA 18‐11‐23_ Sr.Super60_NUCLEUS&STERLING_BT _Jee‐Main_RPTM‐15_KEY &SOL’S
x
65. x[1 – log105] + log10 (2 + 1) = log106
x[log1010 – log105] + log10 (2x + 1) = log106
x log102 + log10 (2x + 1) = log106
log102x (2x + 1) = log106
(2x)2 + 2x – 6 = 0
2x = 2 2x = – 3
x = 1, which is not possible
+ve integer
66. tn an3 bn 2 cn d
t1 a b c d 1
t2 8a 4b 2c d 6
t3 27 a 9b 3c d 18
t4 64a 16b 4c d
7 a 3b c 5
19a 5b c 12
37 a 7b c 22
12 a 2b 7
1
18a 2b 10 6a 3 a
2
1
6 2b 7 b c 0 d 0
2
67. d 28
a 23
23 n 1 28 86
23 n 1 63
63
n 1
28
63
n 1 1
28
C.T’S:23,51,84
68. a1 + 5x = 2
a1 = 2 – 5x
now a1.a4.a5 = (2 – 5x) (2 – 5x + 3x) (2 – 5x + 4x)
= (2 – 5x) (2 – 2x) (2 – x)
= 8 – 12x + 4x2 – 20 x + 30 x2 – 10x3
p = 8 – 32x + 34x2 – 10x3
dp
= – 32 + 68 x – 30x2 = 0
dx
2 8
x= ,
3 5
d2p
= 68 – 60 x
dx 2
d2p
for x = 8 , <0 common diff. = 8/5
5 dx 2
A(–4, 0) O B(4, 0)
x y
Equation of AM =1 ... (1)
–4 h
Equation of BNO x y = 1 ... (2)
4 h4
Eliminating h from (1) and (2), we get
x2 + 2xy – 16 = 0
71.
4
y2 x 3
3
3 y 6 4 x 12
4x 3y 6 0
72. x 1 x 3 y 2 Ky 0
x 2 y 2 4 x Ky 3 0
f 2 C
K2
3 K 2 3
4
x2 y2 4 x 2 3 y 3 0
C1 : 2, 3 , C2 : 2, 3
r1 2 r2 2
d 2 r12 r22 4 1
cos
2r1r2 8 2 3
73. a>100
74. The only doubtful point is x = 0.
Sec: Sr.Super60_ NUCLEUS&STERLING_BT Page 13
SRI CHAITANYA IIT ACADEMY, INDIA 18‐11‐23_ Sr.Super60_NUCLEUS&STERLING_BT _Jee‐Main_RPTM‐15_KEY &SOL’S
1 1
2
h h
LHL = lim ƒ(0 – h) = lim (– h 1)
h 0 h 0
= lim (1 – h)2 = 1
h 0
1 1
2
RHL = lim ƒ(0 + h) = lim ( h 1) h h
h 0 h 0
2
2
= lim (1 h ) h = lim (1 + h)2 [(1 + h)1/h]–2
h 0 h 0
78. Solving the homogeneous equation, by using y = vx, we find the solution x + y = c(x2 +
y2) y(–1) = 1 x + y = 0 which is a straight line.
79. A I adj A I
A adjA Aadj A I A I Aadj A I
I A adj ( A) I
i.e. 3 log x = t
10
t 2 t 2 0
t = 2, t = – 1
t = – 1 is not possible
x log 3 = 2
10
x = 2 log 10 3
a = 2, b = 3
a+b=5
84. 9x – 9x2 – x + 1 = 0
3
(x – 1) (9x2 –1) = 0
Sec: Sr.Super60_ NUCLEUS&STERLING_BT Page 15
SRI CHAITANYA IIT ACADEMY, INDIA 18‐11‐23_ Sr.Super60_NUCLEUS&STERLING_BT _Jee‐Main_RPTM‐15_KEY &SOL’S
x =1, ± 1
3
cos = 1 = 0
cos = 1/3 = cos–11/3
cos = – 1/3 = – cos–11/3
= , cos 1
centre is ( , 1)
equation of the circle is (x – )2 + (y – 1)2 = r2
Which passes through (2sin–1 tan , 4) ( , 4)
4
0+9=r 2
r=3
85. subtract one form other
2 x 2 2 0
2x 0 x
2
2
2 2 1 0
2 2
2
2 2 1 0
4
4 1 2 4
2
4
2
86. 28, A1, A2 …….A11, 10 are in A.P.
Let d is common difference
10 = 28 + 12d
18 3
d =
12 2
Find, A1, A2 etc
We will get 5 numbers of integral A.M.’s.
87. a, b, c are in G.P.
b2 = ac
log6a + log6b + log6c = 6
abc = 66
b3 = 66
b = 62 = 36
ac = 36 × 36 = 24 × 34
b – a = N2
36 – a = N2
a is factor of 24 34
a = 27 is possible value
36 – 27 = 9 = 32
a = 27, b = 36, c = 48
a + b + c = 111.
Sec: Sr.Super60_ NUCLEUS&STERLING_BT Page 16
SRI CHAITANYA IIT ACADEMY, INDIA 18‐11‐23_ Sr.Super60_NUCLEUS&STERLING_BT _Jee‐Main_RPTM‐15_KEY &SOL’S
88. APBO is a square
A
(6,8) M
O P
45°
B
In OMB
OM = 10 cos 45°
=5 2
5 6 – 5 8 c
5 2 =
5 2
c = 60
/2
cos ec 2 x 2cot x cos ecx 1 sin x
89.
2cos ecx cot x 2cos ecx cot x 2 cos x 0
2
1
6K 3 6K 3 K
2
1 1 1 1
90. DC’s are ,0, , 0, ,
2 2 2 2
1 9 1 10 5
Cos 60 60 Sin 4 cos 4
2 16 16 16 8