Yashpatil TG~ @bohring_bot

JEE-MAIN Full Syllabus

Jee M ain D at e: 05-12-23
M ax. M ar k s: 300

KEY SHEET
PHYSICS
1 3 2 3 3 4 4 3 5 3
6 3 7 1 8 2 9 4 10 1
11 2 12 3 13 2 14 1 15 1
16 2 17 2 18 4 19 1 20 1
21 3 22 2 23 10 24 6 25 96
26 5 27 40 28 11 29 9 30 4
CHEMISTRY

31 1 32 4 33 2 34 1 35 4
36 1 37 4 38 2 39 2 40 2
41 3 42 3 43 1 44 2 45 1
46 4 47 2 48 3 49 3 50 4
51 4 52 5 53 3 54 222 55 534
56 9 57 34 58 0 59 1 60 4
MATHEMATICS

61 2 62 4 63 2 64 1 65 3
66 2 67 1 68 2 69 1 70 1
71 2 72 1 73 2 74 4 75 2
76 3 77 1 78 1 79 2 80 1
81 7 82 3 83 6 84 5 85 4
86 3 87 4 88 80 89 5 90 4

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SOLUTIONS
PHYSICS
1. The frequencies are in the ratio of 5 : 7 : 9 .Hence, it is a closed pipe.

v 5v 5  340
425Hz  5   or l   m  1.0 m
 4l  4  425 4  425
2. The given reactions are: 1 H 2  1 H 2  1 H 3  p 1 H 2  1 H 3  2 H 4  n

3 1 H 2  2 He 4  n  p Mass defect m   3  2.014  4.001  1.007  1.008  amu

 0.026amu Energy released  0.026  931MeV  0.026  931 1.6  10 13 J

 3.87  10 12 J This is the energy produced by the consumption of three deuteron atoms.
1040
Total energy released by 10 deuterons 
40
 3.87 1012 J
3

 1.29  1028 J The average power radiated is P  1016 W or 1016 J s .

Therefore, total time to exhaust all deuterons of the star will be

1.29 1028
t 16
 1.29 1012 s  1012 s
10
3. Mass of the ring M  L Let R be the radius of the ring, then

L
L  2  R or  Moment of inertia about an axis passing through O and parallel to
2
1
XX ' will be I 0  MR 2 Therefore, moment of inertia about XX ' (from parallel axis
2
1 3
theorem) will be given by I '  MR 2  MR 2  MR 2 Substituting values of M and R
XX 2 2
3  L  3L
2 3
I '   L   2  
 4  8
2
XX 2

4. The centre of mass will follow the same path.

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R 3R 3  100
mx  m  mR or x    150 m  The desired distance is
2 2 2
100  150  m or 250 m
5. From work energy theorem  KE  Wnet or K f  K i   P dt

2
1
2
3   t3 
or mv 2    t 2  dt or v    or
2
v  2m s
0
2 2   2 0

6. Conceptual
7. The colour for which i  c , will get total internal reflection:

1 1 1
i  c or sin i  sin c or sin 450  or  or for which   2 or   1.414
 2 
Hence, the rays for which   1.414 will get TIR.For green and blue   1.414 , so they
will suffer TIR on face AC only red comes out from this face.

8. When S1 ,S2 and S3 all are closed, both the capacitors are in parallel. Charges in the two
cases are shown in figure

From the figure it is clear that charge will flow through S1 .

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9. Let say, magnetic field is inwards.

VA  VB   B 2v  2r   4 Bvr ............ i 

VD  VC   B v  6r   6Bvr ............ ii 

Further VA  VC , therefore, from Eq (i) and Eq (ii) VD  VB  10 Bvr

10. Conceptual
11.  2  
 0 E 2   energy volume   energy  speed  
2
E
   2 
 
  
 0  0 0   1 speed of light  
  volume 

 ML2 T 2 L2 T 2 
 3    MLT 4 
 L 
12. displacement
Average velocity 
time

R2
H  2

v av  
4 ........ 1
T 2

v2 sin 2  v 2 sin 2
Here, H = maximum height  R  range 
2g g

2v sin  v
and T  time of flight  Substituting in Eq. (1) we get v av  1  3cos 2 
g 2

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13.

VA  VB  16 V  4i1  2  i1  i 2   3  4i1  16 V .......... 1

Using Kirchhoff’s second law in the closed loop we have

9  i 2  2  i1  i 2   0 ..............  2  Solving Eqs. (1) and (2), we get

i1  1.5A and i 2  2 A  Current through 2  resistor  2  1.5  3.5 A

   
14. FCAD  FCD  FCED  Net force on frame  3FCD

  3 2 1 4   F  ilB  24 N

15. Conceptual
16. FL lS  F  L   A  Y   3M   1  1  3a
l    S  S   B  B      a   2    2
AY l B  FB  L B  AS  YS   2M   b  c  2b c
17. When cylinder is displaced by an amount x from its mean position, spring force and
upthrust both will increase. hence,

Net restoring force = extra spring force + extra upthrust

 kx  Ag  1 a 1 k  Ag
or F    kx  Ax g  or a     x Now, f  
 M  2 x 2 M
18. V
V 2  VR2   VL  VC  But VL  VC  VR  V  200 V and
2
i  R  2A
R
19. Shortest wavelength of Brackett series corresponds to the transition of electron between
n1  4 and n 2   and the shortest wavelength of Balmer series corresponds to the

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transition of electron between n1  2 and n 2   . So, Z2     13.6   13.6 

16   4 


 Z2  4 or Z  2

20. Saturation current is proportional to intensity while stopping potential increases with
increase in frequency. Hence, f a  f b while I a  I b
21. Conceptual
22. U n C V dT CV 1 5
   
Q n
C P dT CP  7
23. Decrease in weight = decrease in upthrust

or mg  Vw g or m  V w or
 0.2    2 102   A  103   A  area of base 

or A  102 m 2  100cm 2  Side of the cube is 10cm .

24. M M
I 
V m

25. V 2 240  240
R 
P 600
26. mgh
U  h  4R
h
1
R
27.

28. n n
sin    sin   1 n can take 5,  4,  3,  2,  1,0,1, 2,3, 4,5
5 5
 Maxima = 11
29. Pitch = 1.5  0.3 mm Least count  0.3  0.006 mm  6 103 mm
5 50

30.

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CHEMISTRY
31. Benzoic acid Acidic nature more than Phenol and EWG increases Acidic Nature.
32. Inductive effect operate, through   bond and Resonance effect operate through  
bond.
33. CH 3 CH 3
O

 O3
Zn H 2O
 CHO

CH 3 CH3
5 – Keto – 2 – methyl hexanal

34. Br

CH  CH 2 CH  CH3 CH CH 3

   

H Br 
Br


35. Tertiary alcohol, will reacts fastest with Lucas reagent

CH 3 CH3
HC
CH3 C OH 
ZnC 2
 CH3 C C

CH 3 CH3
36. O CH 3
O O
OH 


CH3
O

Aldol type Condensation

CH3 CH 3
O
O O
H



,   Unsaturated Ketone

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37.
H3C CH 2 NH 2  CHC 3 
KOH
 H 3C CH 2  NC

Carbylamine test is not given by 20 &30 – amines.

38. For first Bohr orbit of "H" atom has

h h
Radius  r   0.529A 0 Mvr  2 r      2 0.529 A 0
2 mv

39. MgCO3   MgO CO 2 x 4.0gm 4.4 gm
84gm 40gm 44gm

x  8.4 gm .But MgCO3 is 50% pure. Hence amount of MgCO3 taken

100
 8.4   16.8gm
50
40. In sucrose - C1 of ñ  D  glucose C2 of ò  D  fructose
Maltose - C1 of ñ  D glucose C4 of ñ  D glucose
Lactose - C1 of ò  D  galctose C4 of ò  D  glucose
Amylose - C1 , C4 of glycosidic linkage
41. wt 1 3.50 1
m  m   0.62 molal
Gmw wt of solvent 58.5 0.0965

42. 2.303 100 0.693 0.693

k log  0.0105min 1 T50%    65.7 min 1
10 90 k 0.0105
43. Vitamin C – scury
Vitamin D – Rickets
Vitamin K – increases blood clotting time
45. O O O
44. Due to inert pair effect Pb 2 Is more stable than Pb 4 Cl Cl
O O
O O


 NiCl4 
46. 2
is 3d 8 , 4s 0 and Cl is weak field ligand so it forms outer orbital complex
47. " ns " electrons are present in ultimate shell but  n  1 d are in penultimate shell.
48. A and R is true R is the correct explanation of A, Antiseptic property is due to free iodine

49. automic weight  Cin ampears  t in seconds

m Find valency
Valency  96,500
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50. They are chemically Inert
51. I. Gatter – Koch reaction

CHC 2 CHO


H 2O
1000 C

II.

III. Rosenmund reduction

IV. Controlled reduction

52. All poly saccharides are non-reducing sugars (Starch, cellulose, glycogen, dextrin). and di
saccharide of sucrose is non-reducing sugar
53. Pepsin – proteins in to peptides
ZSM=5 convert alcohol to gasoline by dehydration
54. E ý W  KE
hc
ý W  KE
ü

6.63 ô1034 ô 3 ô108

9
ý 4.41ô1019  KE
300 ô10

KE ý 2.22 ô1019 û 222 ô1021

55. H 0at 298K   H f0  N 2   4 Hf0  H 2 O     H f0  N 2 H 4   2H f0  H 2 O 2  

  534.0 KJ mol 1
56. Initial pH  1   H    101  0.1M Final pH  2   H    102  0.01M

In case of dilution M1V1  M 2 V2 0.11  0.01 V2 V2  10 L

Volume of water added  V2  V1  10  1  9L

57. 100 vol  30% 20 vol  x x  6% 100 ml  6 gms 560 ml  ?  33.6gms

58. 1
Formal charge[valence electrons – lone pair electrons – Bond pair
2

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1
electrons]  4  0  8  4  4  0
2
59. Li 2 CO3 is less stable carbonate
60. H 4 P2 O7 has four OH groups

O O
HO P O P OH

OH OH
MATHEMATICS
61.    3 1 3 i i
cis  cos  isin  i  
6 6 6 2 2 2 i
1  i 3 1 w 
m m
 m
     iw  2cis     2i w     2i w 
   8i  3
m 3 3

2 i i  6  

 
n n
      
n
 n
   8 1  i   16i  2
n

2
 4cis 
  
4 cos  i sin 
  2 2 1  i 2

 4   4 4 
m
  8i  3  16i  2 Which is satisfy only when m  48 and n  24 m  n  72
n

62.     3 ,   5 ,      5 ,    3 Sum of the roots            

           3   5   15 Product of the roots          
 
  2    2   2  2     2  2    2   2  
  3   2  2   5   2   2    3       2   5       2 
2 2
   
  3 9  10  5 25  6  158 Required equation is x  15x  158  0
2

63. f  x   x 3  3x  9 ; f '  x   3x 2  3
f '  x   0 in  5,3 then f  x  is increasing function on  5,3
f  x  have greatest value at x  3 f  x    3  3  3  9  27
3

Let a,ar,ar 2 ....... be a G.P. with common ratio r  1 S  27  given 

a
 27 ............ 1 a  ar  f '  0  a 1  r   f '  0   3 .........  2 
1 r

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 r  1 
 2   a 1  r   3 1 1 1 4 2  
1  r   1  r   r  1   ,
2

1 a 27 9 3 3 3 3  r  4
 
1  r   3
2
r 
3
64. 1 22000  1
 finite G.P  Sn   22000  1   22 
1000
1  2  2  .......  2
2 1999
1
2 1
 41000  1   5  1 1
1000

  1000 C0 51000  1000 C1 5999  1000 C 2 5998  ........  1000 C999  5  1  1
 5 5999  1000 C1 5998  1000 C 2 5997  .......  1000 C999   Remainder is 0
65. A  adj A   A I A  x  yz  8   3  z  8   2  2  2 y 
 xyz   8 x  4 y  3z   28  60  20  28  68  A  adj A   68 I
66. In the word MUMBAI there are 5 adjacent pairs of letters of which only one gives AI
1
5 84
Required probability  
1 1 1 1 1 403
   
6 5 7 4 5
67. a  a  0  1  aRa  a  R R is reflexive aRb  a  b  1 b  a  1  bRa
R is symmetric 1R 2 ; 2 R1 but 2  1 R is not anti symmetric.
1R 2 ; 2 R 3 but 1 R 3 .  1  3  2  1 R is not transitivity
68.  1  x 1
h  x   f  f  f  x 
1
g  x   f  f  x    f   
1  x  1   1  x
 
1 x 
1 1 1 x 1
 f  g  x      x f  x  g  x  h  x    x  1
1 g  x  x 1  1 x x
1  
 x 
69. 2 2 1 2m 10!  2 2 1  2m
     
1!9! 3!7! 5!5! n ! 10! 1!9! 3!7! 5!5! n !
1  2 10! 2  10! 10!  2m 1 2m
    2  C1  2  C3  C5  
10 10 10

10!  1!9! 3!7! 5!5!  n ! 10!  n!

m
1 10 2
 C1  10C1  10C3  10C3  10C5  
10! n!
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1 10 2m
 C1  10C9  10C3  10C7  10C5  
10! n!
m
1 101 2
2   m  9, n  10  x  y  1  0, x  y  3  0 are perpendicular to each
10! n!
other.Orthocentre is the point of intersection which is  2, 1
 2  2m  2 n ;  1  m  n  Point is  2m  2n, m  n 
70. Given parabolas are symmetrical about the line y  x
The shortest distance occurs along the common normal which is perpendicular to the line
y  x The tangent at point A on
yx
B

dy dy 1 1 3
2 y 2  2 x  1 is parallel to y  x 4 y
2    1 y  and x 
dx dx 2 y 2 4
3 1 1 3
A  ,  Then the coordinates of B on 2 x 2  2 y  1 is B   , 
4 2 2 4
2 2
3 1 1 3 1
Shortest distance AB         
4 2 2 4 2 2
71. We know that eccentricity of a parabola and rectangular hyperbola are 1, 2 . Also
irrational roots occur in conjugate pair
Roots of f  x   0 are 1, 2,  2 f  x    x  1 x  2   x  2   x 3
 x2  2x  2
a  b  c  d  11 2  2  0
  
72.
 cos  
a
2
d sec 2  2
d 2
Put x  tan  ; dx  sec2 d I   .     d
0 1   tan  
a
1  tan  0 1   tan  
2 a
0  sin     cos  
a q


0 
 2 
2 4

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73. y

yx

2 2

y  x
As the area enclosed by x  y  a is the area of square (i.e. 2a 2 )
Area enclosed by x  y  x  y  2 is area of square shown as
Also the area enclosed by x  y  x  y  2 is symmetric about x-axisy-axis,
y  x and y   x
Both the statements are true but statement II is not the correct explanation of Statement I
x
74.
 t y  t dt  x y  x 
2
diff w r t x x y  x   x 2 y '  x   2 xy  x  x y  x   x 2 y '  x   0
0

dy dy dx dy
 x y  x   x y'  x   0 y  x
 0 y  x     nx  ny  nc  xy  c
dx dx x y
At point  2,3  2  3  c  c  6  xy  6

75. Three vectors a , b , c are coplanar   a, b , c   0

 1 3
2 1   0   2  6  0 No real values of  existsSet S is an empty set
 2 3
76.  
2a  b  5 SOBS 4 a  b  4 a.b  52 4  2    3  4 a.b  25  
2 2 2 2

   
25  4 a.b  25  4 a.b  0 a.b  0  a  b

 4  a.b   4  2   32  0  25  5
2 2
2a  b  4 a  b
2

77. Let a1  7i  6 j b1  6i  7 j  k a2  7i  2 j  6k b2  2i  j  k

i j k
a2  a1  14i  4 j  6k b1  b2  6 7 1  6i  4 j  8k
2 1 1

Shortest distance =
a
2 
 a1 . b1  b2  116
 116  2 29
b1  b2 116

78. 1  cos 2 x sin x

Lt  2 Lt   2 (or )  2 According as sin x is positive (or) negative
x0 x x  0 x
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79. f  5  f  2 
f be twice differentiable function f '  x   1  1  LMVT 
3
f  5  3  f  2   f  5   3  8  f  5  11 And also f ''  x   4
f ' 5   f '  2 
 4  f '  5   f '  2   12  f '  5   12  f '  2   12  5  17  f  5   f '  5   28
5 2
80.

81. 18
Cr 2  2  18Cr 1  18Cr  20C13  Cr 2  18Cr 1    18Cr 1  18Cr   20C13
18

Cr 1  19Cr  20C13 20Cr  20C13 20Cr  20C7  7  r  13

19

r  7,8,9,10,11,12,13 No of values of r are 7

82. 1 a 1 1
1  b 1  2b 1  0 Taking a , b, c common from R1 , R2 and R3 respectively
1  c 1  c 1  3c
1 1 1
1
a a a
1 1 1
abc 1  2  0 R1  R1  R2  R3
b b b
1 1 1
1 1 3
c c c
1 1 1 1 1 1 1 1 1
3   3   3  
a b c a b c a b c
1 1 1
abc 1 2 0
b b b
1 1 1
1 1 3
c c c

1 1 1
 1 1 1 1 1 1
abc  3     1  2  0 c2  c2  c1 ; c3  c3  c1
 a b c b b b
1 1 1
1 1 3
c c c

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1 0 0
 1 1 1 1  1 1 1
abc  3     1  1 1  0 2 abc  3      0
 a b c b  a b c
1
1 0 2
c
1 1 1
    3 a 1  b 1  c 1  3  3
a b c
83. x 2  y 2  2 x  2 y  8  0  x 2  y 2  2 x  8    2 y   0
It is of the form S   L  0 All the circles passes through the point of intersection of the
circle x 2  y 2  2 x  8  0 and y  0
Solving we get x 2  2 x  8  0  x  4 x  2   0 x  4, x  2
A   4, 0  B   2,0  AB  6
84. 2x  3
  x 2  3x  x 2  3x  2   1 dx t  x  3 x  dt   2 x  3 dx
2

dt dt 1 1
 t  t  2   1    t  1 t 1
2
c
c 2
x  3x  1
a  1, b  3, c  1  a  b  c  5
85.  4 1 dy 1 1
y 4  x ....(1) xy  k ...(2) P.I of (1), (2) is  k 5 k 5  Diff (1) wrtx m1   3 3
  dx 4 y
4k 5
dy  y 1
Diff (2) wrtx m2    3 Curves intersects at right angle
dx x
k5
6
1
m1m2  1  6  1  4k 5  1   4k   4
6

4k 5

86.  x2   x 2 x3   x2 
 x 1  x   ...     x    ...    x 2 1  x   ... 
Lt  2!   2 3   2! 
x 0 3
x
     
x      x 2        x 3     
Lt  2  2 3   10     0 ...(1)
x0 3
x
   
    0 ...(2)     10 ...(3) (1), (2)    ,   3
2 2 3 2
  6,   6,   9 so       3

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87. C.I fi xi f i xi C.F
0-6 a 3 3a a
6-12 b 9 9b a b
12-18 12 15 180 a  b  12
18-24 9 21 189 a  b  21
24-30 5 27 135 a  b  26
N   fi xi 504  3a  9b
 26  a  b
504  3a  9b 309
mean   243a  111b  3054 81a  37b  1018 Median class is 12  18
26  a  b 22
a  b  26
 a  b
2 a  b  26  2a  2b
median  12   6  14  4  a  b  18
12 2
 a  8 b  10   a  b   4
2

1  1
sin100  2sin 20 0 sin 400  sin100 sin  60 0  100  sin  600  100  sin100    cos 20 0  cos 600  sin 300
88. 1
2  2 4
 1 1 1
1 1 1
 . . sin100  cos 200   
2 4 2  2  16 2
 2 sin100 cos 200  sin100 

1 1  1
  sin 300  sin100  sin100     2sin100   1  4sin100 
1
32 32  2  64
1 1 1
  sin100     1  64  16   1  80
64 16 64
89. B and C will contain three digit number of the form 9k  2 and 9k   respectively.
We need to find the sum of all elements in the set B  C respectively.
S  B  C   S  B   S  C   S  B  C  Where S  K  denotes sum of elements of set k.
100
B  101,109,...992 ; S  B   101  992  54650 Case (i); If   2
2
B  C  B S  B  C   S  B   54650  274  400 which is not possible
Case (ii): If   2 then B  C   S  B  C   S  B   S  C   400  274
100
11  110     100  54950
110 110 110
54650    9k     109600 9  k     54950 9
k 11 k 11 k 11  2 
54450  100  54950   5
90. 2 ae  6 and
2a a a
 12 ae  3  6; e   a 2  18 b 2  a 2  a 2 e 2  18  9  9
e e 6
2b 2
2 9
LLR    3 2  4.24
a 3 2

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