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Sec: SR.

IIT_*CO-SC(MODEL-A) GTM-2 Date: 05-01-23


Time: 3 HRS JEE-MAIN Max. Marks: 300
KEY SHEET
PHYSICS
1 4 2 2 3 2 4 3 5 3
6 3 7 2 8 4 9 3 10 3
11 3 12 3 13 3 14 1 15 1
16 2 17 1 18 4 19 4 20 2
21 15 22 43 23 21 24 700 25 144
26 102 27 3 28 2 29 225 30 10

CHEMISTRY
31 C 32 D 33 C 34 D 35 D
36 A 37 D 38 C 39 A 40 A
41 B 42 A 43 D 44 B 45 A
46 C 47 C 48 B 49 C 50 C
51 152 52 117 53 5 54 127 55 1
56 6 57 0 58 64 59 3 60 1

MATHEMATICS
61 C 62 A 63 C 64 C 65 A
66 C 67 B 68 A 69 C 70 A
71 D 72 B 73 C 74 B 75 D
76 D 77 D 78 B 79 C 80 B
81 26 82 2 83 26 84 32 85 1
86 29 87 3395 88 88 89 28 90 18915
Narayana IIT Academy 05-01-23_SR.IIT_*CO-SC(MODEL-A)_JEE-MAIN_GTM-2_KEY&SOL
SOLUTIONS
PHYSICS
1. Let they meet at time t.
2h 2  80
t   4sec
g 10
Time taken by ball B to meet A = 2 sec
1
Using S  ut  at 2
2
1
80  u  2   10  2 
2

2
u  30
M M M
2. Mass of pieces by , ,
4 4 2
Conserving momentum
  
P1  P2  P3  0
  

P3   P1  P2 
So, P3  P12  P22
M
P3  v
2
So v  25
A N
3. 
A0 N 0
2 105 N
3

2.56 10 N0
N 1 N
 N 0
N 0 128 128
After 7 half life activity comes down to given value T= 7 x 5= 35 days
4. L0  angular momentum of shell about O
As shell is rolling
So Vcm   R
2 5
L0  mVcm R  I  1  R  R  R 2  R 2
3 3
So a= 5
44.8
5. No. of moles = 2
22.4
3
Gas is mono atomic so Cv  R
2
3
Q  nCv T  2  R  20   60 R  60  8.3  498J
2
6. By Hooke’s Law
So F  L
F1 L1 10  L  L 
   1
F2 L2 20  L2  L 
L  2 L1  L2

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Narayana IIT Academy 05-01-23_SR.IIT_*CO-SC(MODEL-A)_JEE-MAIN_GTM-2_KEY&SOL
7. To free the electron from metal surface minimum energy required, is equal to the work function of
the metal.
So Assertion A, is correct.
hv  w0  K .Emax
f hv  w0
 K .E.max  0
Hence reason R, is correct. But R is not the correct explanation of A
8. By work energy theorem
Work done by net force = K .E.
1 1
 w  m 2f  mi2
2 2
1
w   0.5   0.25    4 
2 2

2
w  16 J
9. radius of particle in cyclotron
2mK .E.
r
qB
So ratio of new radius to original
rn  K .E.n
  4  2 :1
r0  K .E.0
10. at r , X C  X L
1
  r L
r C
So if   r , then X C will increase and X L will decrease.
Hence to left of r circuit is capacitive.

Z  R2   X C  X L 
2

At r , Z  R 2  O 2  R
dp dm
11. F 
dt dt
 Ma  10  1
 2a  10
a  5m / sec 2
12. By principle of homogeneity
 P    2  and b  v 
a
v 
a
     PV 
b 
13.  a  b2  2ab cos    4  a 2  b2  2ab cos  
2

Put a=b, we get


2a 2  2a 2 cos   8a 2  8a 2 cos 
3
cos  
5

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4
2G    R 3
2Gm 3
14. Vescape  
R R
Vescape   R2
 if  is 4 times and Radius is halved.
 Vescape will remain same
15. BH  B cos 
B 0.5G G
B  H  
cos  cos 30 0
3
16. VP max  4Vwave
  4
 A  4   A 
k 2
2 A 20
   5
4 4
1
17. E   KC  v 2
2
 % change
1 1
K 2CV 2  K1CV 2
K  K1
2 2  2  100
1 2 K
K1CV 1
2
15  10
  100  50%
10
18. Distance travelled by particle before stopping
 200  100 106  0.5m
2
V2 v2m
S 
2a 2qE 2  40 106  105
D
19. Fringe width  
d
1  5000A 0

1   5000 1010   5  104 m.........( I )


D
d
2 
D
 2d 
 6000  1010   x(let ).........( II )

Divide (II) & (I)


 2 3000 1010 x
 10

1 5000 10 5 104
x  3  104 m or 0.3mm
3  10
20. Frequency at 1000 nm =  3  1014 Hz
1000 109
Available for channel band width
2
  3  1014  6  1012 Hz
100
Bandwidth for 1 channel = 8000 Hz
6 1012 600
 No. of channel    107  75  107
8 10 3
8
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2
dQ 2 V
21. i R  we know 
dt R
V 2 
 In ‘t’ time, Q    t
 R 
Given that, (for same source, v= same)
v2 V2
Q0   20   60.........(i )
R1 R2
 R2  3R1.........(ii )
If they are connected in parallel then
RR 3R1 R1  3R 
Re q  2 1   1
R1  R2 3R1  R1  4 
To produce same heat, using equation …….. (i)
V2 v2 3  20
Q0   20  t  t   15 min
R1  3R1  4
 
 4 
1 
22. I    0 E02  C
2 
21 2  0.22
 E0    12.873
 0C 8.85  1012  3  108
E 12.873
B 0   4.291 108  43  109
C 3 108
23.

Q  1 
   T
t  R 
R: Thermal resistivity
L L1
 R1  1 
K1 A K (120)
L1  4cm
A  120cm 2
2.5
R2 
 2 K 120 
Now, Req of this series combination
Req  R1  R2
Where Leq  4  2.5  6.5
5
Leq 4 2
 
K eq  A  K (120) 2 K (120)

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6.5 4 5
 
K eq 120  K (120) 4 K (120)
6.5 21

K eq 4 K
26  5
K eq  K  1   K
21  21 
 a  21
24. A= 10 cm
1
 Total energy = KA2
2
By energy conservation, we can final v at x=5
1 1 1
K (10) 2  K  5   mv 2
2

2 2 2
75K
V
m
Now, velocity is tripled through external mean so the amplitude of SHM will charge and so the total
energy, (but potential) energy at this moment will remain same)
2
1 1  75 K  1
 K (5) 2  m  3   KA
2

2 2  m  2
 25 K  675 K  KA2
 A  700
 x  700
l
25. 1 
A
  2.4 
2
  31.4
1     314
  2.4 
2
4
4
2.4  2.4 0.6  2.4
   10  
4 10
1.44
   0.144  
10
144 103  
Q T
26. I  2  1 2
Q1 T1
Q2 T2 225 T2
  
Q1 T1 300 500
500  225
 T2
300
375  T2  1020 C  T2

27. d  cot
2
cot 30  x cot 2 450
2

3 x

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iC
28. iB  100  A 
iB
ic  10mA
R0
power   2 
Rin
2
 10  2
Power    
 0.1  1
power  100  100  2
Gain  2  104

29.

3 3
1
2 2 1
V  15
3 1

2V 30
V  45cm
3
1
1 3 2 1 1  1
 
V 2 2 V 10 30
15 15
1 1 1 4
    V  7.5
V 10 30 30
v  225mm
30.

15
i  5A
3
15  5(1)  10Volt
CHEMISTRY
4.640  10 3
31. Moles of Fe3O4   20
232
2.52 103
Moles of CO   90
28
So limiting Reagent = Fe3O4
So moles of Fe formed = 60
Weight of Fe= 60 x 56 = 3360 gms
32. ( A)Cr   Ar  3d 5 4s1

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( B )m  l to  l
(C ) According to Aufbau principle, orbitals are filled in order of their increasing energies.
(D) Total nodes = n-1
33. LiCl  NaCl  KCl  CsCl (Covalent character)
34. In deionized water no common ion effect will take place so maximum solubility
35. So equal & similar charge particle will repel each other, hence will never precipitate.
78 Pt   Xe  4 f
14
36. 5d 9 6 s1 (Exceptional electronic configuration)
37. For ZnS, KCN is used as depressant.
For Gold and Silver  leaching (Cyanide process)
38. In option (A) and (C) reducing action of hydrogen peroxide is shown.
In option (A) it is in acidic medium, in option (B) it is in basic medium
Or
For reducing ability H 2O2 changes to O2 , i.e. oxidize, so in option ‘A’ & ‘C’, O2 is formed but ‘A’
is in acidic medium so option ‘C’ is correct.
39. NCERT Table 10.1.5
Metal Li Na K Rb Cs
Colour Crimson red Yellow Violet Red Blue
Violet
 / nm 670.8 589.2 766.5 780.0 455.5
40. Caesium is used in devising photoelectric cells.
Boron fibres are used in making bullet – proof vest.
Silicones being surrounded by non-polar alkyl groups are water repelling in nature.
Gallium is less toxic and has a very high boiling point, so it is used in high temperature thermometers
41. P4  3 NaOH  3H 2O  PH 3  3NaH 2 PO2
Oxoacid= H 3 PO2 (hypo phosphorus acid) or (phosphinic acid)
42. CaCO3  H 2 SO4  CaSO4  H 2O  CO2
43.

44.

45.

Electron with drawing group on carboxylic acid will increase the rate of esterification.

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46.

47. Buna- N is synthetic rubber which can be stretched and retains its original status on releasing the
force.
48. DNA contains    D  2  deoxyriborse
RNA contains    D  riborse
49.

Histamine is nitrogeneous compound it does not contain sulpher


50. Phenol are weakly acidic. Phenol is more acidic than alcohol & H 2O statement (I) is correct. (II) is
incorrect.
dRT
51. Assuming ideal behaviour P 
M
100
P atm, T  257  273  530 K
760
d  0.46 gm / L
0.46  0.082  530
So M   760
100
 151.93  152
52. Given data is for 1 moles and asked for 5 moles so value is 23.4  5  117kJ
53. M  d  V  1.02  1.2  1.224 gm
Moles of acetic acid= 0.0204 moles in 2L
So molality = 0.0102 mol/kg
Now T f  i  K f  M
i  1   for acetic acid
0.0198  1     1.85  0.0102
  0.04928
 5%
54. At anode
2 H 2O  O2  g   4 H   4e 
At cathode

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2 H   2e  H 2 ( g )
it
Now number of gm eq. =
96500
0.1 2  60  60
  0.00746
96500
0.00746
VO2   2.27  0.0423
4
0.00746
VH 2   22.7  0.0846
2
VTotal  127 ml or cc
K  E 1 1 
55. l n 2   a   
 K1  R  T1 T2 
 K  532611  10 
l n 2    
 K1  8.3  310  300 
Where K 2 is at 310 K & K1 is at 300 K
K 
l n  2   6.9  3  l n10
 K1 
K
l n 2  l n103  K 2  K1  103
K1
K1  K 2  103
So K=1

56. 4 FeCr2O4  8 Na2CO3  7O2  8 Na2CrO4  2 Fe2O3  8CO2


2 Na2CrO4  2 H   Na2Cr2O7  2 Na   H 2O
B

57. 3MnO42  4 H   2 Mn 7O4  Mn 4O2  2 H 2O


Mn 7  no. of unpaired electrons is ‘0’
  0 B.M
58. Meq. Of H 2 SO4 used by NH 3 = 1.25  1 2  25
25 103 14  100
% of N in the compound =  63.6
0.55
Or
Meq. Of H 2 SO4 = Meq. Of NH 3
12.5 1 2  25 meq. of NH 3
= 25 millimoles of NH 3
So Millimoles of ‘N’= 25
Wt. of N= 14  25  103
14  25 103
%N   100  63.66
0.55
 64%
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59.

No. of compounds containing asymmetric carbons are three.


60.

No. of carbon atoms present in B is 1.

MATHS
61. Let matrix A is singular then A  0
Number of singular matrix = All entries are same + only two prime number are used in matrix
 10  10  9  2  190
190 19
Required probability = 4  3
10 10
dy dv
62. y  vx  v x
dx dx
dv dv dx
 x  v 2  16   
dx v  16
2 x
 l n v  v 2  16  ln x  ln C

 y  y 2  16 x 2  Cx 2
As y (1)  3  C  8
 y (2)  15
a  2 b  4 c  7 2(6  4  28  2)
63.   
3 1 1 32  12  42
84 28 112
a  2, b   4, C  7
13 13 13
 2 a  b  2c   6
64.
f ( x )  x 3  3 x , x  1
2, 1  x  2
x 2  2 x  6, 2  x  3
9,3  x  4
10, 4  x  5
11, x  5
2 x  1, x  5
Clearly f(x) is not differentiable at

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x  2,3, 4,5  m  4
1 2

  x  3x dx   2.dx 
27
I 3

4
  2 1
a.c 10
65.  
c 3
  6  2 10
    2
1 4  4 3
iˆ ˆj kˆ
And 3   4  6iˆ  ˆj  kˆ
1 2 2
 2   8  6    1
   3
66.

Area of ABC 
1
2
 2  .1  2
2

 
4
2
So, required area = 8 x  2 x dx 
0
2
32 2 2 13 2
 8 2  
3 2 6
67.
2 1 1
1  3 2  0    3
1 4 
7 1 1
And 1  3 2 0 K 6  K 3
K 4 3
68. X 2  1  2i   2  1  2i,  2  1  2i
Hence  8   8
4
a 8   8  2a 8  2  2
4
 2 5  50
69. pq q
  p  q   q
   p  q   q

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  p  q   q  q
   p  q   t  p  q
Now by taking option C
 p  q   p  q
 p   q   p  q
t
Hence C
70.
1 2 22 
 
A  1/ 2 1 2
1/ 22 1/ 2 1 
 
A  3 A  A  32 A
2 3

A2  A3  ......... A10
3  39  1
 3 A  3 A  ......  3 A 
2 9
A
3 1
310  3
 A
2
71. A  1, 2,3
R  (1,1), (1, 2), (1,3), (2,1), (2, 2), (2,3), (3,1), (3, 2), (3,3)
72. a2  1, a3  3, a4  6
n(n  1)
an 
2

n(n  1)
S 
n2 2  7 
n

1 3 6 10 15
S      .....
7 2 73 7 4 75 75
S 1 3 6 10 S 1 2 3
 3  4  5  6  .....  6  2  4  5  .....
7 7 7 7 7 7 7 7 7
S 1 2 3
6 2  3  4  5  .....
7 7 7 7
S 6 1 1 1/ 7 2
6 .  2  3  .........
7 7 7 7 1  1/ 7
S 1
6 6 2 
7 76
7 7
S 3
6 216
73.

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3/ 22/ x
tan  / 4  1
1 6 / 2x
 x1  10, x2  2 / 5
 AA1  52 / 5
74.

 22  x 
2
3 2 3 2
AT  a  b2  x /9
4 4 16
dA  3 1  22
 0  x     0
dx  2  9 8  8
 4 3  9  11
   
 36  2
a  x/3
 
 11/ 2   1  66
a   
 4 3  9  3  4 3  9
 
 36 
 1 
2sin 1  2 
75. 1   4 x  1   1   / 2  sin 1 1   / 2
 4x2 1
1
Always  1  2 1
4x 1
 1   1 
x   ,  , 
 2  2 
76. General term
10
 3 1  2  2  5 3  x  1 2 3
3 r  2 r 5 r
Tr 1 
r r r

r1 r2 r3
3r1  2r2  5r3  0.............(1)
r1  r2  r3  10...............(2)
From equation (1) and (2)
r1  2(10  r3 )  5r3  0
r1  20  7r3
(r1 , r2 , r3 )  (1, 6,3)
10
 3  2   5
1 6 3
Constant term =
16 3
 29.32.54.71
l 9

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 x
5
77. I   cos   x     dx
0  2
2 4 5
 I   cos  x dx   cos  x   dx   cos  x  2 dx
0 2 4
4
 sin  x   sin  x      sin  x  2  
2 5

I       
   0   2   4
I 0
78. PQ is focal chord

mPR .mPQ  1
2t 2 / t
  1
t 3 1 3
2

t2
t  1  0  t  1
2 2

 P & Q must be end point of latus rectum: P (1, 2) & Q (1, 2)
2b 2
  4 & ae  1
a
We know that b 2  a 2 1  e 2 
a  1 2
b2
 e2  1  2   e2  3  2 2
a
1
 3 2 2
e2
23 2
79. OP 
2

3
OP 
2
1
AP  OA2  OP 2 
2
tan   3
3 AP 5
 sin     AN   BN
10 AN 3
Area of ANB   AN 2  sin 2 
1 1
2 6

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Narayana IIT Academy 05-01-23_SR.IIT_*CO-SC(MODEL-A)_JEE-MAIN_GTM-2_KEY&SOL

80. x
 x1  24   x  24
1
5 5

2 
 x12   24 2  194
 
5  5  25
  x12  154
x1  x2  x3  x4  14  x5  10
x12  x22  x32  x42 49
 2
 a
4 4
x12  x22  x32  x42  4a  49  x52  154  4a  49
 100  105  4a  4a  5  4a  x5  15
81. z  2 1

 x  2  y 2  1..........(1)
2

&
z (1  i )  z (1  i )  2
Put z  x  iy
 x  y  1.........(2)
PA  17, PB  13
Maximum is PA & Minimum is PD
Let D  2  cos  , 0  sin  
 mcp  tan   2
1 2
cos    ,sin  
5 5
 1 2   1  2i
D2 ,   z1   2  
 5 5  5 5
25  4 5
z1  & z2  1
5
 z2  1
2


 5 z1  z2
2 2
  30  4 5
  30
  4
    26
82.
dy 2 1 2 cot 2 x 
 y  xe tan
dx 2 cos x  cos 2 x
4

dx dx cos ec 4 xdx
 2 cos4 x  cos 2 x   cos4 x  sin 4 x   1  cot 4 x
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 1  1
1 2 
t 1 2   tt 
   4 dt      dt 
t 1 1
tan  
t 1  1
2
2  2 
t    2  
 t
cot x  1

1
2
tan 1 2 cot 2 x  
 tan 1  2 cot 2 x 
 IF  e

 tan 1 
  xdx
2 cot 2 x
ye
  x2   
 tan 1
2
 c  y  
2 cot 2 x
ye cc 0
2  4  32
 2  1  2
x 2  tan 1        tan 
2 1
2 cot   2  tan  

2 cot 2 x
y e y   e 3 
 e  3
2  3  18 18
2
  3 2  2
3
83. Points P(1,2,-1) and Q(2,-1,3) lie on same side of the plane.
1  2  1  1 1
Perpendicular distance of point P from plane is 
12  12  12 3
2  1  3  1 1
Perpendicular distance of point Q from plane is 
1 1 1 2 2 2
3

 PQ is parallel to given plane. So, distance between P and Q= distance between their foot of
perpendiculars.

 PQ  (1  2) 2  (2  1) 2  (1  3) 2  26  PQ  26  d 2
2

84. 3cos 2 2  6 cos 2  10 cos 2   5  0  3cos 2 2  6 cos 2  5(1  cos 2 )  5  0


3cos 2 2  cos 2  0  cos 2  0 OR cos 2  1/ 3

   4 , 4   2  (2n  1).
2
   / 4.  3 / 4.........  15 / 4
Similarly cos 2  1/ 3 gives 16 solution.
85. 2  cos 2   2  0  cos 2   2  2
y  2  2

Both graphs intersect at one point.


 1 1  1 
86. 50 tan  3 tan 1  2 cos 1   4 2 tan  tan 1 2 2 
 2 5 2 
 1  1  1 
50 tan  tan 1  2  tan 1  tan 1 2    4 2  tan 1 2 2 
 2  2  2 
 1  1  1
50 tan  tan 1  2   4 2   50  tan tan 1   4  25  4  29
 2 2 2  2

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87. f ( x)  (c  1) x  (1  c ) x  2k .........(1)
2 2

& f ( x  y )  f ( x)  f ( y )  xy xy  R
f ( x  y )  f ( x) f ( y )  xy
lim  lim  f '( x)  f '(0)  x
y 0 y y 0 y
1
f ( x)   x 2  f '(0).x   but f (0)  0    0
2
1 2
f ( x)   x  (1  c 2 ) x...........(2)
2
 as f '(0)  1  c 2
3
Comparing equation (1) and (2) We obtain , c  
2
1 2 5
 f ( x)   x  x
2 4
20 20
5 20
Now 2 f ( x)   x   x  2870  525  3395
2

x 1 x 1 2 x 1
x2 y 2
88.  1
a 2 b2
b2 11 b2 7
Given e 2  1  2
  1  2
 b2  a 2
a 4 a 4
x2 y2
   1 Now given
a
2 2
 7 
 a
 2 

2a  2
7a
2
  
 4 2 2  14  a 2  7  4 2 2  7   
7
a  4 2  a 2  32  b 2   16  2  56
4

89. P1 : r .  2i  j  3k   4 , P1 : 2 x  y  3 z  4
x2 y3 z 2
P2 0  5  0  5 x  5 y  z  23  0
1
1 1 0
Let a,b,c be the d’r of line of intersection
16 13 15
Then a  ;b  ;c 
15 15 15
  13;   15
90. b1  1, 2,3,..........100
Let A= set when b1 , b2 , b3 are consecutive
97  97  ..............  97
n( A)   97  98
98 times
Similarly when b2 , b3 , b4 are consecutive
N ( A)  97  98
97  97  ..............97
n  A  B   97  98
98 times
Similarly when b2 , b3 , b4 are consecutive

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