Sri Chaitanya IIT Academy., India.

AP, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI

A right Choice for the Real Aspirant
ICON Central Office , Madhapur – Hyderabad
Sec: Jr.C-120 WTA-13 Date: 30-10-2022
Time: 10.00AM to 01.00PM 2020_P2 Max.Marks:198

KEY SHEET

PHYSICS
1 9 2 5 3 7 4 8 5 4 6 2

7 ABC 8 ABC 9 AB 10 BC 11 ABC 12 AC

1.99 to 0.51 to 0.13 to
13 0.20 14 15 16 1.41 17 18 0.80
2.00 0.52 0.14

CHEMISTRY
19 3 20 9 21 6 22 6 23 2 24 3

25 AB 26 BC 27 ABD 28 AB 29 ABCD 30 CD

31 41.2 32 24 33 7.84 34 8 35 7 36 10

MATHEMATICS
37 5 38 4 39 3 40 6 41 0 42 7

43 BC 44 BCD 45 ACD 46 AB 47 CD 48 BC

49 2.73 50 1.73 51 0.56 52 27.00 53 50.00 54 1.41

Sri Chaitanya IIT Academy 30-10-2022_Jr.C-120_Jee-Adv(2020-P2)_WTA-13_Key & Sol’s

SOLUTIONS
PHYSICS
1. Linear velocity of both wheel will be same 60 12  10     72 rad / s
2. Time at which centre of mass is at highest point is
u 10 
   1sec Rotation of the rod  t    A 2 R j  g j
g 10 2

2R
A
3. 1 12 2 2 7 m 2 10 17
 mgR  m 2  mr   m 2  N  mg  N  mg  mg  mg
2 25 10 R 7 7
4. 10 
3
g sin  g sin  2 g sin  g sin  g sin  5 1
aC    g sin  aP   arel  
I 1 3 I 2 6 6
1 1 1
mR 2 2 mR 2
1
srel  116  8 m
2
5. 3  4
m0 .2 R   mR 2  m(2 R) 2     0  4 rad / s
2  11 R
6. mg sin   T cos   ma  a  2m / s 2
7. m 2
m r  mg ,
2
For ( A), T  mg For ( B), T   m r
2

g 1
 K.E. of system  mA A2
r 2

2
1  g  mgr
 (m)    (c) Tension is central force on A, so angular momentum remains
2  r  2
conserved.
8. Parallel axis theorem, check the distance carefully. I D  I B (symmetric)
9. 3R 2 a F 1.5
F1  f  3a f R  F1  4.5a a  f   30  10 N
2 R 4.5a 4.5
kxmax
This is f max  10 N so less is also possible  4N Alternative f max   10 N
mR 2
1
I
10. 0 2m0 2
For (b) :2m0l  6ml 2   T  2m 2l 
3l 9l
For (c) : I A  2m(3m) ; I B  m(3l ) 2
2

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Sri Chaitanya IIT Academy 30-10-2022_Jr.C-120_Jee-Adv(2020-P2)_WTA-13_Key & Sol’s

11. 1  Mg sin   2 2 4
  Mg sin     g sin  V  0  2  g sin  l V  3 gl sin 
2

M  3  3 3

V 4 gl sin 
  For pure rolling
R 3 R2
mg sin   f f  R 2 1  Mg sin   2
   R;    Mg sin     g sin 
  3
2
M MR M 3
2
2 4 V 4 gl sin 
V 2  0  2  g sin  l; V  gl sin  ;  
3 3 R 3 R2

mg sin   f f  R 2
For pure rolling    R; 
M MR 2
2
12. l  ml 2
 9g 9g 9 g 3l
 0  I ; mg  mgl    ml 2   ;   ;  N1  2mg  2m
2  3  8l 8 8l 4
27mg 5mg
N1  2mg  
16 16
13.  F t  p or F t  MVcm ……(1)
[here impulse by frictional force is supposed to be zero since f   F ]
Now take linear momentum about horizontal surface so that change in linear
momentum by frictional force becomes zero.
 L1  0, L f  I   MVcm R
Vcm
Since pure rolling is taking place,   …..(2)
R
2 2 7
L f  MR 2  MVcm R  MVcm R  MVcm R L f  MVcm R
5 5 5
7
( F t )  (h' )  L f  L1  ( F t )h  MVcm R ……(3)h = Vertical height from horizontal
5
7 MVcm R 7 2
surfaceFrom (1) & (3), h'   R  R  R Hence
5 MVcm 5 5
2 2
h  R   0.5  0.2 cm above centre of sphere.
5 5

14. 1
mg (2.4)  mg (1)  /  2
2

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Sri Chaitanya IIT Academy 30-10-2022_Jr.C-120_Jee-Adv(2020-P2)_WTA-13_Key & Sol’s

Since the case is of rolling without slipping.


  r   Where r is of radius of the sphere
r
2
Also, l  mr 2    4.43 m / s After point A, the body takes a parabolic path.
5
The vertical motion parameters of parabolic motion will be
1
uy  0 s y  1m ay  9.8 m / s2 t y  ? s  ut  at 2
2
1
l  4.9 t 2 y t y   0.45sec Applying this time in horizontal motion of parabolic path,
4.9
BC  4.43  0.45  2 m 1.99 (or) 2.0
15. 2
For solid sphere I AB  MR 2  I (given)…..(i)
5
1 3
For solid disc I AB  I  Mr 2  Mr 2  Mr 2  Mr 2
2 2
I AB  I AB (given)…..(ii)Form (i) and (ii)
2 3 2 2
MR 2  Mr 2  r  R R  0.516 R
5 2 15 3.873
16. 1 2mgl sin  2mgl sin 
 l 2  mgl sin    A  
2 l ml 2
2 g sin 
 A  In the similar position
l
4 g sin   t 1 tA
 B   A B    2  1.41
l B t A 2 tB
Fy  10sin 30o
17. 
Fx  10 sin 30 o
a

2
10 cos 30  f  2a   l  fr   2  r 2   ……(2)(where r is radius of
f
o N
20N

3
2
sphere) From (1) and (2), we get fr  Newton,
3
f 2 3
N  20  10sin 30o  25 f   N      0.08  3  0.14
N 25
18. 1
W  I  2 Let x is the distance of CM from A I  Mx2  4M  l  x 
2

2
dI
and if I is minimum, W will be minimum  2Mx  4M  2  l  x    1
dx
 2Mx  8M l  x 
dI 4
  10Mx  8Ml 10Mx  8Ml  0 x  l  0.8L
dx 5

Sec: Jr.C-120 Page 4

Sri Chaitanya IIT Academy 30-10-2022_Jr.C-120_Jee-Adv(2020-P2)_WTA-13_Key & Sol’s

CHEMISTRY
19. 3 
U  nCv T   R  1 U  3cal
2 
20. V2
For isothermal reversible expansion S  nR  2.303log  1.954  2  2.303 1  9
V1
21. KCl  s   K   g   Cl   g  , H1  181kcal mol 1
KCl  s   H2O l   K   aq   Cl   aq  , H2  1.0 kcal mol 1
Let the enthalpy of hydration of K+ is 2a kcal mol-1
K   g   H2O l   K   aq  , H3  2a Cl   g   H2O l   Cl   aq  , H4  a
H 3  H1  H 2  H 4 2a  181  1  a
 
3a  180, a  60 hyd H of K  2a  60  2  120 20x  120 x6
NH 2
22.

Except Acl the molecules undergoes tautomerism

H
23. O O O O

C C C C
CH 3 CH 2 CH 3 CH 2 CH 2 CH 3

H
O O

C C
H 3C CH CH 3
Acetyl acetone
24. Here
O
X  7   OCH 3 ,  NH 2 ,  OH ,  NH  C  CH 3  N  CH 3  2 ,  SH ,  SCH 3 

Y  4  NO 2 ,  CHO ,  C  N ,  PH 3 
X Y  7  4  3
25. 5 7
n = 1 CV  R CP  R T1  250 C  298K V1  1L T2  373K V2  10L
2 2
7 T V
H  nCP T   2  75  525cal S  nCV n 2  nR n 2
2 T1 V1
5 373 10 373 5
 2 n 2 n 5 n  2 n10 E  nCV T   2  75  375cal
2 298 1 298 2
G can be calculated
26. C2 H6  g   2C  g   6H  g  H c c  6H c  H  620kJ mol 1
C3 H8  g   3C  g   8H  g  ; 2H C C  8H C  H  880kJ mol 1
Hence, H C C  80 kJ mol 1 ; H C  H  90 kJ mol 1
27. Heat released in reaction = heat gained by calorimeter system
100  0.5 200  0.2
=1.5 ×1.4=2.1 kJ neq  H 2 SO4    0.05 neq  NH 4OH    0.04 (Limiting
1000 1000
2.1
reagent)  neut H NH4OH  By strong acid     52.5kJ / eq
0.04
diss H NH4OH   52.5   57  4.5kJ / mol

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Sri Chaitanya IIT Academy 30-10-2022_Jr.C-120_Jee-Adv(2020-P2)_WTA-13_Key & Sol’s
diss HCH3COOH  57  48.1  4.5  4.4kJ / mol
28. Conceptual
29. Conceptual
30. Conceptual
31. H   H of products    H of reac tan ts 
H o  H of  CO  g   H of  H 2O  g   H of CO2  g   H of  H 2  g 

 110.5   241.8   393.5  0 41.2

32. Conceptual
33. 2MgCl  Mg  MgCl2 H  ?
Mg  s   1/ 2Cl2  g   MgCl H1  125 kJ mol 1
Mg  s   Cl2  g   MgCl2 H2  642 kJ mol 1
H  H2  2H1  642   2 125  392 kJ mol 1
50x  392
x  7.84
n 1
34. The number of geometrical isomers is calculated by the formula 2n 1  2 p  p  
 2 
3 1
In the given compound, n  3 . So, p  2
2
Substituting we get 231  2 2  22  4  8
35. (I) Acyclic isomers

(II) Cyclic isomers:

CH 2 CH OH CH 2 CH CH 3

CH 2 O

36. The number of chiral isomers can be calculated using the following relation for
symmetrical carbon atom with even number of chiral centers: a  2n1  241  8
The number of meso forms  m  is given by m  2 m /21  m  221  2

Therefore, total isomers  a  m  8  2  10

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Sri Chaitanya IIT Academy 30-10-2022_Jr.C-120_Jee-Adv(2020-P2)_WTA-13_Key & Sol’s

MATHEMATICS
37.
15
x

x 2  82  152
cos   For obtuse angled  1  cos  0  16 x  x 2  161  0 8
16 x
 x  161
2
 x  13 …(i) and x 2  16 x  161  0
 ( x  23) ( x  7)  0 or x  7 …(ii)  7  x  13
 x 8, 9, 10, 11, 12 Hence, number of possible values of x is 5.
38. a, b, c and in AP  2b  a  c.
B B  AC   AC 
or 4R sin B = 2R[sin A + sin C] or 2.2sin .cos  2sin   .cos  
2 2  2   2 
B  AC   AC B
or 2sin  cos     900  
2  2   2 2
AC   AC 
or 2 cos    cos   …..(i)Now, LHS = K (1  cos A) (1  cos C )
 2   2 
= K .2sin 2 A / 2.2sin 2 C / 2 = K(2 sin A/2.sin C/2)2
AC AC 
2

= K cos  cos [using eq.(i)]

 2 2 
AC AC  2  AC 
2

= K 2cos  cos   K cos   RHS

 2 2   2 
AC AC AC AC AC
 cos A  cos C  2cos .cos  2cos . 2cos  4cos 2 K  4
2 2 2 2 2
39. 1 a 2  b2  c2
  ab  a 2  b 2  c 2  3ab  a 2  b 2  2ab  c 2
2 2ab
 3ab  (a  b) 2  c 2  3ab  (a  b  c) ( a  b  c) ….(i)
1 1 a  b  2c
Now   On multiplying numerator and denominator by 3,
a  c b  c ab  c (a  b  c )
3(a  b  2c) 3(a  b  2c)
  [using Eq. (i) for 3ab]
3ab  3c(a  b  c) (a  b  c) (a  b  c)  3c (a  b  c)
3(a  b  2c) 3 1 1 3
    
(a  b  c) (a  b  2c) (a  b  c) a  c b  c (a  b  c)
40. Here, A  B  C  
 B C  C  A  A B 
cos   cos   cos  
Let E =  2 
  2 
  2 
 BC  C  A  A B 
cos   cos   cos  
 2   2   2 
 B C  C  A  A B 
cos   cos   cos  
  2   2   2 
 A B C 
sin   sin   sin  
2 2 2

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Sri Chaitanya IIT Academy 30-10-2022_Jr.C-120_Jee-Adv(2020-P2)_WTA-13_Key & Sol’s
A  B C  B C  A C  A B 
2cos cos   2cos cos   2sin cos  

2  2  2  2  2  2 
sin A sin B sin C
 BC   B C   AC  C  A
2sin   cos   2sin   cos  
  2   2   2   2 
sin A sin B
 A B   A B 
2sin   cos  
 2   2   sin B  sin C   sin C  sin A   sin A  sin B 
 =   
sin C  sin A   sin B   sin C 
 sin B sin A   sin C sin B   sin A sin C 
=       as A, B, C are angles of
 sin A sin B   sin B sin C   sin C sin A 
triangle  0  A, B, C    sin A,sin B,sin C  0
 1 
 E  222  as x  x  2, if x  0   E6

41. We have , sin 3 A  sin 3 B  sin 3 C  3sin A.sin B.sin C

 k 3a3  k 3b3  k 3c3  3k 3 abc
 sin A sin B sin B 
 a  b  c  k 
 a 3  b3  c 3  3abc  a  b  c  0 [ a  b  c  0, then a 3  b3  c3  3abc]
a b c
Now, b c a On apply, C1  C2  C3 , we get
c a b
abc b c 0 b c
 bca c a = 0 c a =0
cab a b 0 a b
42. a 2  b 2  c 2  2 R 2 (1  cos 2 A  1  cos 2 B  1  cos 2C )
 2 4 6    1  
 2 R 2 3  (cos  cos  cos   2 R 2  3      7 R 2
 7 7 7    2 
a 2  b2  c2
 7
R2
43. 2  ab sin C a 2b 2  4 2  a 2b 2 cos 2 C = a2b2  42  b2c2  42  c2a2  42
 ab cos C  bc cos A  ca cos B
44. b 4 ba 43 1
ac  3 and bc  4    
a 3 ba 43 7
3
1
 B A ba c 1  cos( B  A) 4  3 c 4  1 cot c
tan   cot   cot 
 2  ba 2 1  cos( B  A) 4  3 2 1
3 7 2
4
C 1
1 1 c 1  tan 2 1
c 2  7 63
 cot  cot  7 Or cos C 
7 7 2 2 C 1 8 4
1  tan 2 1
2 7

Sec: Jr.C-120 Page 8

Sri Chaitanya IIT Academy 30-10-2022_Jr.C-120_Jee-Adv(2020-P2)_WTA-13_Key & Sol’s
 cos C  cos( A  B) or cos C  cos( B  A)
 C  A  B or C  B  A

  ( A  B)  A  B or   ( A  B)  B  A B 
2
b 4
   k (let )  b  4k , a  3k Now, ac  3
a 3
C

b = 4k
2R 3k

A B 1 1 2
3 7 k2  3 7k
k2   k  1  R  2k  1
7
74 74
45. (a 2  2ac  c 2 )  (a 2  4ab  4b 2 )  0 or (a  c)2  (a  2b)2  0
a 2  c 2  b 2 7b 2 7 b2  c2  a 2 1
a  c and a  2b cos B   2  cos A  
2ac 8b 8 2bc 4
46. 2a b  2b c  a  b  c (a  b  c )  a  b  c  2(a b  b c  c 2 a 2 )
2 2 2 2 4 4 4 2 2 2 2 4 4 4 2 2 2 2

a 2  b2  c2 1
(a 2  b 2  c 2 )2  2c 2 a 2   cos B or B  45O or 135O
2ca 2
47. If ABC has sides a, b, c
A

c b

B C
a

7 5
2 
 A
tan   
( s  b) ( s  a )
s
abc
 2 2  4  2sin P  sin 2 P  2sin P(1  cos P)
2 s( s  a) 2 2 2sin P  2sin P 2sin P(1  cos P)
P

b7/2
c  5/ 2

2sin 2 ( P / 2) ( s  b) ( s  c) ( s  b)( s  c) [( s  b) 2 ( s  c) 2 ]
  tan 2 ( P / 2) Q a2 R
 = =
2
2cos ( P / 2) s( s  a) ( s  b)( s  c) 2
2 2
 7  5
4  4  2
 =  
2  2 3
 2
 4 
48. A
Given , cos B  cos C  4 sin 2
2
A

c b

 BC   B C  2 A
B
a  2 cos 
C
 cos    4sin
 2   2  2
A   B C  A  B C   BC 
 2sin cos    2sin   0  cos  2   2 cos  2   0
2  2  2    
A B C B C B C 1
As sin  0  cos cos  3sin sin  0  tan tan 
2 2 2 2 2 2 2 3
( s  a) ( s  c) ( s  b) ( s  a) 1 sa 1
.    2s  3a  b  c  2a Locus of A is an
s( s  b) s ( s  c) 3 s 3

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Sri Chaitanya IIT Academy 30-10-2022_Jr.C-120_Jee-Adv(2020-P2)_WTA-13_Key & Sol’s
ellipse.
49. a 2  b2  c2
Using , cos C 
2ab
A

b  x2 1 2x 1  c

300 3 ( x 2  x  1)2  ( x 2  1)2  (2 x  1)2

C a  x2  x  1 B
 
2 2( x 2  x  1) ( x 2  1)
 ( x  2) ( x  1)( x  1) x  ( x 2  1) 2  3( x 2  x  1)( x 2  1)  ( x 2  2 x( x 2  1)  3( x 2  x  1)
 
 2  3 x 2  (2  3) x   3  1  0  x    2  3  and x  1  3
But x    2  3   c is negative, x  1  3 Is the only solution.
50. a c
Since, A, B, C are in AP.  2 B  A  C i, c. B  600   2sin C cos C    2sin A cos A
c a
 a b c 1
 2k (a cos C  c cos A) u sin g , sin A  sin B  sin C  k 
 
 2k (b)  2sin B [using b  a cos C  c cos A ]  3
51. We have, a  b  c  11, ab  bc  ca  38 and abc  40
 b2  c 2  a 2   c 2  a 2  b2   a 2  b2  c 2 
     
cos A cos B cos C  2bc  2ca  2ab 
   
a b c a b c
b c a c  a b a b c
2 2 2 2 2 2 2 2 2
a b c
2 2 2
(a  b  c)2  2(ab  bc  ca )
    
2abc 2abc 2abc 2abc 2abc
(11)  2(38)
2
121  76 45 9
   
2  40 80 80 16
52.  1  1 1
  sin A  1   sin A   2 Then , sin B  2
 sin A  sin A sin B
1  1  1   1 
and sin C   2   sin A   1  sin B   1  sin C   1  27
sin C  sin A   sin B   sin C 
 1   sin A  sin A  1 
  sin A   1  27 Or     27
 sin A   sin A 
53. C B b c bc 1
b cos 2  c cos 2  (1  cos C )  (1  cos B)   (b cos C  c cos B)
2 2 2 2 2 2
bc 1 a  b  c 100
  a   50
2 2 2 2
54. cos A cos B  sin A sin B  cos A sin B  sin A cos B  2  cos( A  B)  sin( A  B)  2
 cos( A  B)  1 sin( A  B)  1  A  B, so a  b sin 2 A  1
1 1

ab
 A  450 , B  450 , C  900  2 2  2
c 1

Sec: Jr.C-120 Page 10