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CHEMISTRY
31 B 32 A 33 D 34 C 35 A
36 D 37 B 38 D 39 C 40 A
41 B 42 C 43 B 44 B 45 A
46 D 47 A 48 D 49 D 50 D
51 15 52 530 53 5 54 180 55 3
56 6 57 22 58 8 59 7 60 4
MATHEMATICS
61 D 62 C 63 B 64 A 65 A
66 B 67 C 68 A 69 A 70 A
71 D 72 A 73 A 74 D 75 A
76 A 77 A 78 D 79 C 80 A
81 441 82 95 83 4 84 3 85 2
86 14 87 3 88 3 89 18 90 1211
x y 0
x z 0
2x 3y z 0
Choice (A) gives x y 2 which is not acceptable. Choose (B) satisfies all the three equations,
hence it is the right choice
2. Let second stone overtakes the first, at time 't' after the first stone was thrown
1 1
gt 2 u t n g t n
2
2 2
un gn 2 / 2
On solving, t
gn u
1 2
and required distance gt
2
Pitch 1mm
3. Least count = 0.01mm 0.001cm
Number of divisions on circular scale 100
zero error 0.03mm
Measurement 3.76 0.03 3.79 mm
4.
mg
N cos mg N
cos
5. By COE loss in gravitational P.E. = gain in K.E. + work against
The graph is non liner i.e there is some dissipative force apart from gravitational force
12. C BA
Energy released m C m A m B C2
BE A BE B BE C
300 1600 1200 MeV 700 MeV
1.52 E E
13. Resistance of bulb, R 0.5 . Current drawn from battery is i
4.5 2.67 0.33 3
E 1 2E
Current drawn from bulb is i b
3 1 0.5 9
2
2E
For maximum intensity, 0.5 4.5W E 13.5V
9
14. Vinitial is to B and E so particle will move in a helical path of non-uniform pitch.
Initial speed is V 2 3V 2 2V
Vy 5V
Final speed is 3V then Vy 5V so t
E
15. Q i dt
1
Area 4 0.1 0.2C
2
15 103 120 i
1
i 103 A
8
22. y x .x 2
2g 2 10
y 8x 2
y 8 0.05 200 104 2 10 2 m
2
y 2cm
6 4 103
23. No. of molecules = area under AB = 800 600 106
2
a dx a dx
2 2
24.
0 0
a area under - x graph
2
3a 2 0
0 4 0
C1C2 1 2 2
25. Cseries C
C1 C 2 1 2 3
Combination can be a maximum charge of 6000C
6000C
Hence, V 9kV
2
F
3
26.
1 1 1
f 15 25
f 37.5cm
R 75cm
3 2 51
28. e 2
3 74 5 44
e
2
3
T1 n1 8 n3 n 2
29. 3 1 13 1
T2 n 2 82 n 2 n2 1
VS MIN VZ
30. IS MIN
RS
VS MIN 50
2 10 3 VS MIN 50 10 60V
5 103
VS MAX VZ
IS MAX
RS
VS MAX 50
12 10 3
5 103
VS MAX 50 60 110V
CHEMISTRY
31. Stability order is I > II > III > IV, because I is neutral, when in II all atoms with
complete octet system while is III is more stable than IV because in case of IV oxygen is positive
with incomplete octet system.
32. On cis-alkene there is syn addition of two-OH groups forming meso compound
33. AgA s Ag A
x xy
A H 2 O HA OH
xy y y
y2
k w 1014
x x y Ksp : 10 104
x y k a 10
1014
OH 9 105 y 105
10
2
10 5
104
A
40. Conceptual
41. Conceptual
42. Conceptual
43. Conceptual
28.7
44. Number of moles of AgCl formula = 0.2
143.5
0.1 mole complex then 0.2 moles of tree Cl
45. K 2 HPO3 do not contain OH group as it is normal salt. The H atom in bond with P atom cannot
participate in hydrogen bonding.
46. Conceptual
47. Conceptual
48. Conceptual
49.
Three unpaired e on Co 2
15BM
3.87 BM
50.
As NH3 combines with H+ of acid the changes to NH4+ which have no doner site.
51.
6 + 3 + 1 + 5 = 15
54. Conceptual
55. Conceptual
P 1
56. YA A PA 72 24
P 3
n2 4
XA 0.4
n1 n 2 4 x
PA P 0 A X A 24 60 X A
X A 0.4
n2 6
5
t 5
1 25 t
57. q Idt 25 t dt t 25 t 2 sin 1
2
0 0 2 2 5 0
25
q 19.63coul.
2 2
19.63
108 96500
I 25 t 2
22 mg
58. 8B g 8A g C s
4V 2V
Initial no. of moles
RT RT
4V 2V
No. of moles at eq. x x x
RT RT
Given that
2V 4V
x
RT RT
4V 2V
x
RT RT
2V
x
RT
Kh ......... 1
Zn 2
MATHS
63. Let m and n be the integral roots.
x 2 ax 6a x m x n
m n a, mn 6a
6 m n mn 0 m 6 n 6 36
Which give the pair 6, 6 , 9, 4 18, 2 , 12, 3 , 36, 1
Total =10
64. let number of balls he scored 0,2,3,4 runs be a, b, c, d respectively.
Then a(0) + b(2) + c(3) + d(4) = 20 and a + b + c + d = 6
a b c d
1 0 0 5
0 2 0 4
0 1 2 3
0 0 4 2
6! 6! 6! 6!
The number of ways is 96
5! 4!.2! 3!2!1! 4!.2!
65. Let property, divisible by 5=A n(A) =200
Divisible by 7=B n(B) = 142
Divisible by 3 =C n( C) =333
n( A B C )
n( A B C )
P ................ 1
sin 2 sin 2
2
x2 y 2 2x 4 y 4 0
37
x2 y 2 5x 4 y 0
4
Equation of common chord is x = 7/4
3
d
4
r 1
9 7
1
16 4
1 7
Equation of the line (1) in the figure is y x
4 4
1 7
Equation of the line (2) in the figure is y x
4 4
1 7 1 7
range of is ,
4 4 4 4
71. since, equation of normal to the parabola x 4 y 2 is y tx 2at at 3
2 1
y tx t t 3
16 16
It passes through (0, 33)
t t3
33 t 3 2t 528 0
8 16
t 8 t 2 8t 66 0 t 8
1 1
Now, P at 2 , 2at 64, 2 8 4,1
16 16
Parabola : y 4 x y
2
y 2 4 y 4 x y 2 4 x 1
2
Equation of directrix: x 1 1 x 2
So, distance of point = 6
Note: instead of normal one can use applications of derivative to find nearest point.
72. Here P, P n {1, 2,,...., 50}
Now P can take values
2,3,5,7,11,13,17,19,23,29,31,37,41,43,47
We can calculate no, of elements in R, as
2, 20 , 2, 21 , 2, 22 .. 2, 25
5,5 ... 5, 5
0 2
7, 7 ... 7, 7
0 0
47, 47 , 47, 47
0 1
n R2 2 15 30
n R1 n R2 38 30 8 .
73. Applying R2 R2 R1 R3 R3 R1
x x x
Then f x d d 1 2d
d d 1 2d
Again applying C2 C2 C1 , then
x d x
f x d 0 1 2d
d 0 1 2d
d (d 2d 2 d 2d 2 ) 2d 2
2
f x dx 4 2d .2 4 d 2 1 d 1
2
As
0
74.
0
x 2 ( x a)
From the graph, Area = a 2 .dx
a
dy
75. e x e x dx e y e x e x c e y e x e x c
ey
36 k a d 1
2
76.
300 k a 2 2
596 k a d 3
2
x
both are equal
5 5
11C6 . 11C . 6
6 5
1
1 1
2
79. Let m 1
6
& m
6
So,
6
9 9
1
Here sec .sec
m 1 m 1 cos .cos
9
sin( ) 9
= 2 2 tan tan
m 1 cos .cos m 1
9
2 tan( m tan (m 1)
m 1 6 6
9 8
2 tan( ) tan 2( cot tan )
6 3
4 1
tan cot tan or 3
3 3
So, ,
6 3
s6 3 2
sin( x sin x ) x sin x 1 cos x
80. lim lim lim
x 0 sin( x tan x ) x 0 x tan x x 0 1 sec 2 x
sin x
x 1
lim
x 0 tan x 2
2 sec 2 x.
x
81. D = -a, D1 = -2(a – b + 6)
D2 = -2a - b + 6, D3 = 6 – b
For unique solution, b 0
fi x
2
Variance = 50 =
xi 15 25 35
fi 2 x 2
fixi 30 25 x 70 100 21
x 4 x x4
fi
x 25 2
50
225 2 625 x 35 2 2
25
2
4 x
450 625 x 2450
25
2
50
4 x
2900 625 x
50 625
4 x
675 4 x 2900 625 2700 675 x 2900 625 x
50 x 200 x4
dv 1 2 1 2
84. Acceleration = 48t 72t 72 t
2
dt 3 2
1 1
Which is maximum when t 0, i.e t sec
3 3
2 2 2
85. r a r b r c sin 2 sin 2 sin 2 2
4 2 14
3 2 2
3 2 0 196
86. S.D
14
14
i j k
3 2 2
3 2 0
87. Given expression is equivalent to
1 ( n 1) ( n 1)
2 2
tan 2
tan 1 (n 1) 2 tan 1 ( n 1)2
1 (n 1) (n 1)
2
1
3cos ec 2 x 2 cot x.cos ecx dx
2 cos ecx 3cot x
2
3cos ec x 2 cot x.cos ecx dx
2
1 sin x
c
2cos ecx 3cot x 2 3cos x
3
89. tan
3
x sin 2 3x 2sec 2 x sin 2 3x 3 tan x sin 6x dx
6
3
4 tan 3 x sec 2 x 4
2
sin 3xdx 6 tan 4 x sin 3 3x cos x dx
6
1 1
tan 4 x sin 4 3x 3
2 6 18
11
r 11
r
90. b cos 2 sin 2
r 1 24 r 1 2 24
11
(12 r ) 11
2 r
r 1
sin 2
24 r 1
sin a
24
11
r
Similarly d cot 3
r 1 24
11
r
r 1
tan 3
2 24
11
(12 r ) 11 3 r
r 1
tan 3
24 r 1
tan c
24
11
r r
Also a b sin 2 cos 2
r 1 24 24
11
1 11 and log 2 d c 2c d log d c 1
r 1
a b3 11 a b 33ab a 3 b 3 a b
3 2
3 a b ab a b a b 113 112
3 2
1210