\\Resonsnce® Educating for better tomorrow Time: 3 Hrs. JEE MAIN (FST-3) Exam Date: 29.12.23 Section: JP+IR Max. Marks = 300 PART-A (41- A) PHYSICS SECTION — A Multiple Choice Questions: This section contains 20 multiple choice questions, Each question has 4 choices (1), (2), (3) and (4), out of which ONLY ONE is correct. Marking Scheme: +4 for correct answer, 0 if not attempted and -1 in all other cases. ‘A Wedge with a rough groove in the shape of a quarter of a circle is kept on a smooth table (see figure). A disc is placed in the groove with a small clearance. Friction exists between groove and disc. The wedge is moved with an acceleration 9. If disc is to remain stationary relative to groove at the position shown, the coefficient of friction required can be. Qi — “= @* @t a2 2 ‘ i 10 ‘The rod of constant cross section area but having different density of material along its length is moving with ‘constant acceleration in horizontal direction (Figure-1). Stress verses distance x from left end of rod graph is shown (Figure-2). Attwo sections 1 & 2 angle of tangent in stress verses x graph are ai = 37° and a2 = 53°, If density of rod at section-1 is 9 grn/cm® then find the density of rod at section-2 in grn/cm Stress afte Foust (1) 12 2) 16 @)2 (4) 24 Page No: 1In a stack of three polarizing sheets the first and third are crossed while the middle one has its axis at 45° to the axes of the other two. The fraction of the intensity of an incident unpolarized beam of light that is transmitted by the stack is am ga rat 4 8 cect aan het Ra Ew Geto araeq 8 caf gear A wea ora cri A set S 45° aio oe fers 8) syfta srafta vor yor A diver a ae sie ot dt axel @ ora FS aE ern — «12 13 314 (4) v8 ‘Two uniform solid spheres A and B of same material, painted completely black and placed in free space separately where no radiation is incident on spheres. Their radii are R and 2R respectively and the dominating wavelengths (wavelength corresponding to which spectral emissive power is maximum) in their spectrum are observed to be in the ratio 1 : 2. Which of the following is not correct. (1) Ratio of their temperatures is 2:1 (2) Ratio of their emissive powers is 4: 1 (3) Ratio of their rates of heat loss is 4:1 (4) Ratio of their rates of cooling is 32: 1 2) ye art ate shel Acer Baar werd @ a gy 8 an gaa) ples @ eran et ae gat rare A FHS TSI GAT 2) SST Fea aM Rw 2Re an ge Wags S Waa Fw ofa asa eeatea at srnars seas ehagT eTHT aaa 8) wr sega 1:28) FTA a ata Rac wa ae ar (1) 5 creat or orga 2:18 (2) seas em wT orga 4:18 Qs on wea aqM 418 | Get we as Aw agUT It If the surface of a metal is successively exposed to radiation of 2, = 350 nm and 2, = 450 nm, the maximum speed of photoelectrons is halved. The work function of this metal is closest to (given h=662 « 10%J-s) ae Fre arg BY Ie sar A, = 350 nm wee BH PAPI BT A, = 450 nm eee wy fate a wienita ox Ren ara at safle Saag hi wr sites ar are” Rafe or sr a ona B) ag wT ord worm oer & — (Rar & h=6.62 x 10%J-s) (1)1.8eV (2)25eV (3)48ev (4)3.9eV AA plane wave of monochromatic light falls normally on a uniform thin fm of oll which covers @ glass plate. The wavelength of source can be varied continuously. Complete constructive interference of reflected lights from air—thin film interface and thin film — glass interface is observed for 2, = 5000 A and 2, = 10000 A and for no other wavelength in between. If refractive index of oil is 1.25 and that of glass is 1.5, the thickness of flm (in ym) is wt ate BY cory aT Ser ew eH wee ae GoeMte eTer a eT ATT et By at a winded sree oR a wed 81 cata wee 8 swale cen ae_wta wae a sera ae wT ple rnd carr, 2, = 5000 A wat 2, = 10000 A % feng tear omen & fore wer wf over ote Et 1 af da a arate 1.25 8 aon aa an amenity 1.52, a1 da BH wea A ters (um a) e — (1)0.2 (2)0.1 (3)08 (4) 0.4 The shape of a wave propagating in the positive x or negative x- direction is given by y = 1 t=Oandy= at t= 1s where x and y are in meters. The shape of the wave disturbance ‘does not change during propagation. Find the velocity of the wave. (1)1 mis in positive x direction (2) 1 mis in negative x direction @) ‘ mis in positive x direction @) ‘ mis in negative x direction 1 error Ream aT seo Ream A ay wah gs ae A ora t=O wy= ara @ ont @ er te isay y= ee arr A ooh oe x cen y tee FB) ce a ae S chest eT A EA Va-arex? = ae acer 8) ae aT AT Ba TASTE (1) mis, etree x fren (2) 1 mis, aor x Fe A (3) 4 mis, errr x een 8 (4) eva, seo x fee 2 Page No: 210. 1. ‘A spherical insulator of radius R is charged uniformly with a charge Q uniformly distributed throughout its volume and contains a point charge *. located at its centre. Which of the following graphs best represent quaitatvely, the variation of elec eld intensity E wth stance r from the centre Ye ThareR R Pome Eas, aE Q ant wApl ara A ye ws S satiate Bae ore fg ter 2 eb ar we ee we 81 Fier AA ove a, ga da Een de a gr @ yal vida @) veftia oat & — E a) VA @I/] E A particle of specific charge o moving with a certain velocity v enters a uniform magnetic field of strength B directed along the negative Z-axis entending from x = r, tox =f. The minimum value of v required in order that the particle can just enter the region x> ris ew oars arte (eMta/eaM) wr BH van a a BAT gon Gada oa BA waU wore) gaa da A Ren sear Zoe A oi 8 eH ae xe, Tx =r, Tw Sa Go AL VT AER A wT eT aeg a or x> ry A wer we A ? (1) or,B Rolin B @)otr,-1)B (4) 02-8 2 A solid disk of radius R is suspended from a spring of linear spring constant k and torsional constant c, las shown in figure. In terms of k and o, what value of R will give the same period for the vertical and torsional oscillations of this system? Ww R from a cha aoa a teh fala Praciw k wen met Fraaiw (torsional constant) ¢ at fet GT ‘acorn wm %, er fe fos F cant was) koe S Tal 4, RG fo ae @ foe GaN cori cet ARIE! EIoril (torsional oscillations) #1 sacra Wa er 7 ! Re r E if E @ E @ af @ LE ‘Two long straight cylindrical conductors with resistivities p, and p, respectively are joined together as shown in figure. The radius of each of the conductor is a. If a uniform total current I flows through the conductors, the magnitude of the total free charge at the interface of the two conductor is (oy Pa Mey (1) zero a (3) e911 P;—Pol (4) E91 (0) + P2) BRT ARE py Te py} TA, MA ae Seo aTerH arya oS aa Bp acy rere a roa at) a ga We aaM aM Tare) a a vata a fa ae wl ott aed wae we BE Ga aren or afar e — (ore (gy Wes=eadlee i (3) &1 1p: Pal (A) &91 (Py + Po) Page No: 312. 13, 14, 15. The figure shows a conical container of half-apex angle 37° filed with certain quantities of kerosene and water. The force exerted by the water on the kerosene is approximately — (Take atmospheric pressure = 10° Pa) fra & orefeht wt 37° gare ora wef & forage Arar A aes ae oa AY By 81 Te ‘arr aR oe aT rar aa aT & — aTgATEdia Ta = 108 Pay Pe 10a ‘onl Kerosene ff ange Ry=08 am Se By10 (1)3 x 107N anton (3)2*107N (4) 5 1071N The half-life of substance X is 45 years, and it decomposes to substance Y. A sample from a meteorite was taken which contained 2% of X and 14% of Y by quantty of substance. If substance Y is not normally found on a meteorite, what is the approximate age of the meteorite? (1) 270 years (2) 225 years (3) 180 years (4) 135 years ward Xa oreo 48 av @, cea ae vert YA avatar dha @) ser fies wT gw aE AAT Ten @ ere Xr 29 gear Yan 1496 (aereh aA eta an) rT rT BY ARE ere Y ea les A era are ora @, at seer five a oenra oH far 2 2 (1)270 a4 (2)225 04 (3) 18004 (4) 135 a4 What is net force on the small dipole inside the capacitor i the plates are separated by tom? dienes & ova wa gy hye W Ga aa fern ta Gai S wa GA tom t 2 vey (ON @)4N @8Nn (4) 16 N A uniform circular ring of radius R is fixed in plane. A particle is placed on the axis of the ring at a distance much greater than R and allowed to fall towards the ring under the influence of the ring’s gravity. The particle achieves a maximum speed v. The ring is replaced with one of the same (linear) mass density but radius 2R, and the experiment is repeated. What is the new maximum speed of the Particle? Pron R@) CORE aaa aa A eas @1 Vw ou aca A om RRA aE afte Gl w TaN Tee wen tea & yea S gaa 4 fel S fore ears | om A fewars ae v8) ae eT UH GA eT a erent ae 4) ard & Fa Aro 2R ecu War I SAM crea Bi sre or A sm aT wm er ? py 2) av (4) av Page No: 416. 47. Consider the following ideal diode circuit. Which of the graph given below is a correct representation of Vout (Va — Vs) ? (Input and output voltage is in volt) ara fea wa saeeh crabs for oe fra aifty! AT A a TAT AM Vas (Va— Vo) #1 wel wT a waftia oxar 2? (Praeh cen Fria fava dee 4 21) 1ka sv ‘V= 10 sin(2xt) | Vou » Be 1, mM 4 a>, time * "time * “—aA TT JUAN SW 3)~ 4] (4) 4] In an astronomical telescope in normal adjustment a straight black line of lenght L is drawn on just right side of objective lens. The eye-piece forms a real image of this line. The length of this image is |. The angular magnification of the telescope is : FRE WRIA A RUA A, Pel aida Gade $ aque da dhe ae ae ote w Lava we oh aa ten feet ag 2) AR ga Wea ten & ante offers anh 8) offeA M TE | & ah greeter om aha netia 2: L @ett “ @t 4) Ear 1 1 Page No: 518. 19. 20. Four students measure the height of a tower. Each student uses a different method and each measures the height many different times. The data for each are plotted below. The measurement with highest precision is an ftari ye aR a Sarg aga 81 sete faerif =f faa seats a aor 8 ger wedw are aT ag Garg fishies 8) wete are fea wa ates Ate omefera 8) sere ofkgeat Bay eT Known Hoight (aie Sarg) 38 8 ‘Number of Trials Gert @) gem) Number of Tals Gut A ea) 7 tana ti Ty Hea Sa 5. Known Height oS. Known Height ago amen |e ame sa) ‘BEE 20- BE 20- 250 25 er ee) Pade Height ($2) (mm) Height (Tg) (m) wy w av (il el 4) Three waves A, B and C of frequencies 1600 kHz, 5 MHz and 60 MHz, respectively are to be transmitted from one place to another. Which of the following is the most appropriate mode of communication : (1) A is transmitted via space wave while B and C are transmitted via sky wave. (2) Ais transmitted via ground wave, B via sky wave and C via space wave. (3) B and C are transmitted via ground wave while A is transmitted via sky wave. (4) B is transmitted via ground wave we while A and C transmitted via space wave, am weil A, Baer C A aHgftai mE 1600 kHz, 5 MHz a4 60 MHz @, a) & ye wo At I ae Waka 81 g1e Wa & fey, svysa one ehh (QA Sl SeRO ails al ARI ae B TAI SI aR SETA aM BRI 2)A wr eH HAT ARI Gen Bar a OTA aA aT Ya Cw aM. al a aR (3) Been C a HARM ae ART eH Aw FAH, SHIR aA PT (4) B 1 eager aaa aR ce A se Cat aT ala ea ANT A steel rod is 4.000 om in diameter at 30°C. A brass ring has an inner diameter of 3.992 em at 30°C. In order that the ring just slides onto the steel rod, the common temperature of the two should be approximately (dgyau= 11 ¥ 10-°/°C and tyyags= 19 * 10-PC) WS Wa A VS 1 AI 30°C w 4.000 cm 21 yw shret BM sey wI sIFaRH RT 3O%C WE 3.992 cm ti aa @ vs w Se eer & fey, ee or Grafs aes (rT) er aAeY — (asa = 11 * 10- €PC aalt atea= 18 x 10°C) (1) 250°C (2) 280°C (3) 300°C (4) 350°C Page No: 6SECTION -B Numerical Value Type Questions: This section contains 10 questions. In Section B, attempt any five questions out of 10. The answer to each question is a NUMERICAL VALUE. For each question, write the correct numerical value (in decimal notation, truncated/rounded-off to the second decimal place; e.g. 06.25, 07.00, -00.33, -00.30, 30.27, -27.30). Marking Scheme: +4 for correct answer, 0 if not attempted and -1 in all other cases. 21. A rigid equilateral triangular plate ABC of side 2 m, is in motion in the x-y plane as shown in figure. At the instant shown in the figure, the point B has velocity v, - (31 +8))m/s and the plate has angular Velocity o = 2irad/s. Ifthe speed of point A is 4u (in mis), then find u 2m yun A ys Wray Pry we ABC, xy ce A aidete & Sen RH Pra A wafer va 81 ReargER Pea a eer we fy Bar aT vis 8jm/s TEN we wr white Aa = akrads 81 aR Ry Aw 37 4u (mis 4) @, at ua AT are AAT x - a 22. A ball is thrown obliquely into the air. At a certain moment, the balls velocity has an angle of 60° with the horizontal, with an upwards motion. Four seconds later, the angle is of 30° with horizontal, with downward motion. Determine the sum of magnitude of height (in m) ascended and descended during this time interval. Given g = 10 m/s®. Ignore air drag on the ball. ww te en § feet Sat on 2) fern fear an, SR A oe OTe Be Ae wT aT Aft a GOT win wae 81 4 dows wea aE By Ato B 307s ora Boa Ag A on A aA By A wa aa serie 4 ae ae cea fen 4 oo ae Aa aa @) ag Sagal wr a (m 4) aa Ff = 10 mis? & ae ear wr aftr ew #1 23. Inthe given electrical circuit both capacitors are identical. One of the capacitor is charged to voltage of Vo volt. Now switch S is closed, Value of induced emf in inductor is + volt at the moment when energy in inductor is equal to half of total energy stored in capacitors. The ais of ais. fea a Farge after & et sents ree G1 yw seta WY Fe Vo the Ta aft Rear eT Bt Rea S@ ae ay fem one 81 wakes a oes fee Tew wa oa Me ane, wa am t oe Ga ¢ ‘woll, dental A yafad |e Gal Ht smh 8) aw ae B — © c +i Vo s L “tt Page No: 724, In hydrogen atom, the binding energy of an electron in the ground state is E1, then the frequency of revolution of the electron in the ni" orbit is “<=. Here x and y are integers. Find the value of x ego ey A yp aR ota stags A der Gol Er 81 aR nh wen A ae om we eT A arate Se ta caer y gate tah er a ar wa 25. A satelite is describing a circular orbit around a planet of radius R. The altitude of the satelite above surface of planet is 3R and its speed is Vo. To place the satellite in an elliptical orbit which will bring it closer to the planet, its velocity is reduced from Vo to Vo, when fi < 1. The smallest permissible value of f if satellite is not to crash on the surface of planet is | , find k. We ome, R for S wi we Sani aww ae sore 8) we A wae A Roa wee OTE aT AA Votl gH Swe Bed GarOR wer A watts wea S ferq FAT AT Vow MEIEX PVo far TAT eI ep <1 8 oR some Ay WA ae oe #1 pat eM wee en fF & Re se ah ae @ cae a8 eat mT a wr 26. The free end of the string wound on the surface of a solid cylinder of mass M = 1kg & radius R= im is pulled up by a force F as shown. If there is sufficient friction between cylinder & floor then the upper limit to the angular acceleration(in rad/s®) of the cylinder for which it rolls without slipping is: (g= 10mis?) Ww waht om yea ft M = tkg SOT Raim fom & che dar wt wae we alee Fa a faarger eer orer 81 aft torr a wel er goer wai wi 8, oa da S ah aT Ht aro vier 8a? Fer eh Aree ae er fre ae ae we aH (g = 10mis*) F M 27. A particle is oscillating in a straight line about a centre O, with a force directed towards O. When at a distance ‘x’ from O, the force is mnéx where 'm’ is the mass and ‘n’ is a constant. The amplitude is a= 15 em. When at a distance ,/3 ° from O the particle receives a blow in the direction of motion Which generates an extra velocity na. Ifthe velocity is away from O at the time of blow and the new amplitude becomes ky/3 om, then find k. WS oH $2 OF URE Ew Wa a A che wea & RaW a A eT OF ate 81 a wT ON Seg oe 8 oer ao oe ae mn ate EET im caMTA an yw aan & san a= 1S emt) a wr Od ah VES we bch wor ae Ren A yw srewr are wea B fore sea A na Te eat Bi aR ere ores wR BH ATO GA TRH A a TAT GAM KT om A TT 8 at k st AE 28. In the given figure an object’ O ' is kept in air in front of a thin plano convex lens of radius of curvature 410 cm. Its refractive index is 3/2 and the medium towards right of plane surface is water of refractive index 4/3. What should be the distance ‘x ' (in cm) of the object so that the rays become parallel finally. weft aA 108. awe Prom & ww vad THael—saa Sar S Uy war A Ww HY Ow We Be sraectaes 32 & a WH TH STA sire a TOT 4/3 sro or OTB Te AT GET x 3) fart art athe seat | Pet we a oT x Page No: 829. 30. 34. 32. A solid conductor sphere having a charge Q is surrounded by an uncharged concentric conducting hollow spherical shell. Let the potential difference between the surface of the solid sphere and that of the outer surface of the hollow shell be 30V. If the shell is now given a charge ~30, the new potential difference between the same two surfaces is x V Find the value of x Q area a cre wee ater oprah aesta oretw acta ora fer 81 eT ca ate Bh ace ve Grad tite cra aA aed aoe H Hey forareR 30V 81 ate oa acta ste FH -30 onde S feat Te oh eri ar aoe & ta fray xv et oT & cox BAe a aT ‘The time period of a satellite of earth is 5 hours. If the separation between the earth and the satellite is increased to 4 times the previous value, the new time period becomes (in hrs). gett & we ome wr aradara Save 8) aie gel a cone Soa Gl URPPID am a 4 A aw AUT one & at ae smracerrs (are #) er CNA = Atomic masses : [H = 1, D = 2, Li=7, C= 12, N= 14, O= 16, F = 19, Na=23, Mg = 24, Al=27, Si=28, P= 31, $= 32,Cl 52, Mn = 55, Fe = 56, Cu= 635, Zn = 65, As SECTION - A Multiple Choice Questions: This section contains 20 multiple choice questions. Each question has 4 choices (1), (2), (3) and (4), out of which ONLY ONE is correct. Marking Scheme: +4 for correct answer, 0 if not attempted and -1 in all other cases, For H-atom some spectral lines were observed as shown. (n; to ns are successive shells). If 'E" belongs to visible region, then correct statements for the following transition. E ns a =—™ ns lay ns Ea ms (A) There cannot be any line in UV region (B) Band D lines belongs to Infrared region. (C) Line having shortest wavelength is A (D) Line having least energy is C (1) (A), (B) and (C) (2) (A) and (8) (3) (C) and (0) (4) (A), (8), (C) and (0) ‘Consider the first order reaction : A ——» 2B. Which of the following figure correctly describes the rate of disappearance of A(r)) and rate of appearance of B(r2) with time? fre vere wife af afifean oe far fed -A — 28. fer 4 a si ata wa S TAS fags ah A x(n) UBS eA A a(n) A WA GET wee? 2)r t> s t + @r 4) me me _———_, > > Page No: 933. 35. 36. 37. ‘An ideal solution is prepared from A and B (both are volatile). The total vapour pressure of the solution is oat Where Pi and P) are vapour pressures of pure A and B respectively. a +P5 [Pi ePS]. If x4, xe represents mole fraction of A and B in solution respectively and ya, ye represents mole fraction of A and B in vapour phase. If yx = 1/2 then the value of xis : we oral Ret Aga B (St arena) a aa ant eas a yA aT ZAP or PR A en Py PA Ye Ace BS am ara &) [P, -Ph] AR xa, xomae Read a Acer Bs sta Mer 81 em ys, youre: are sree A A car B® Are Prt 81 af ya = 1/2 14 xa wT ATE PA Ps 1) 1 ya @)1- 3 4 ()1-y (2)1-ys OR Oe AG = AH~TAS and AG = AH + [2 then (= oan ane] S29)] ae ( AG = AH ~TAS «HAG = AH (2 L=( as nF s x cal (4) #nEF ct Oe ay (8) -0FE. (4) +neF. Pyrolusite is MnO, used to prepare KMnO,. Steps are, MnO,» Mnoz- —-» Mno; Steps | and Il are respectively : (A) fuse with KOH, air and electrolytic oxidation. () fuse with KOH, KNO, and oxidation by Os (C) fuse with cone. HNO,, air and electrolytic reduction, (0) dissolve in H,0 and oxidation MnO, oRRigaise &, fra) KMnO, Fi 4 syed ea E 1 os gH HOR MnO,—!-+ Mno3- 1 minog 8 | ceat re & — (A) KOH, ag} eer sit en egasedta sifaeorent | (8) KOH, KNO, % Hr Hr Get Oo arr sitar (©) ars HNO, ary @ ener eirert aoa Reegasrarestta sneer | (D) H,0 4 face wean ae sitar | (1A) 8.8) Ase 8) (6) 8 (0) (4) (©) & (0) 2g of a mixture of CaCO, and MgCO, requires 2 g of H,SO, for complete reaction. Determine % of MgCO, in the mixture — (A) 89 % 11% (C) 78% (0) 22% How many moles of K,Cr,O, are needed to oxidise 1 mole of Fe, ,,O, in acidic medium : (A) 0.79 moles (B) 0.283 moles (C) 0.263 moles (D) 0.158 moles Page No: 1038. 39, 40. at. 42. 43. Which of following ions do not exist together in aqueous solution : (A) Pb, F (8) TP, F (C) Both (A) and (B) —_(D) None of these To prepare a butfer solution of pH = 4.04, amount of Barium acetate to be added to 100 mL of 0.1 M acetic acid solution [pKo(CHsCOO") = 9.26] is (1) 0.05 mole (2) 0.025 mole (3) 0.1 mole (4) 0.005 mole PH = 4.04 & abe THM & fay 01M Ufifew ara S 100 mL & we aftay yftee SI fren ay Tal AFI @ [pKo(CHsCOO>) = 9.26] (1) 0.05 ster (2) 0.025 tet (3) 0.1 te (4) 0.005 rer In which of the following, lewis dot structure are written with correct formal charge. Which is the correct increasing order of bond length ? (A) Cl, > F,>0,>N, (8)F,>Cl,>0,>N, (C)N,>0,>F,>Cl, (0)Cl,>N,>0,>F, The value of crystal field splitting (Ao) for [Ti(H20)d]** is 243 KJ mol’. The crystal field stabilization energy (CFSE) in this complex is : (in KJ mol) TTi(HO)P* # fay ees aa Rarer wail 243 KJ mot, ge aga A Brea Aa wane oa (CFSE) (KJ mot) (1)-145.8 (2)-97.2 (3)-291.6 (4)-243 Nodal plane(s) for d,2_,2 orbital is/are (A) YZ plane (B8)ZXplane (C) Both (A) and (B) (0) None of these Page No: 1144. 45. 46. 47. . co, og (oHi00%0, 4 PhoHs + (CH:CO)20 axe HH eg CO Product Ris (1) Cinnamic acid (2) Mandelic acid (3) Phthalic acid (4) Phenyl acetic acid Cy p HO", g (CHCO%0, 3 PhOHs + (CH:CO}.0 Fore “+g oR Order of pKa values for following acids is — fret rit pKa sre ar aH & — (a) CHs-COOH (b) O.N-CH, ~COOH (c) NC-CH,-COOH (d) MeO- CH, -COOH ()b>a>e>d (2)a>d>e>b ()a>d>b>c (4)b>c>d>a In the complex K,Fe[Fe(CN),] (A) both Fe atoms are in the + 2 oxidation state (B) both Fe atoms are in +3 oxidation state (C) itis diamagnetic (D) itis a high spin complex Final product ofthe given reaction is Fret ative or seer seure 8 — Bey Me, (0 CHCHO. £40 Oe ae Br 4 « @) HO-CH-CHs CH-CHO CH=CHO HO-CH-CHs 8 @) DDT is prepared by reaction between chlorobenzene and chloral in presence of HzSO. then what product will be form by reaction between phenol and acetone in presence of H:SOs ? af H2SO. & suftefa 4 aeinta-cia cen geilta S ser sifu 8 ODT era ara B, a HeSOs A sakefs 4 ria sen hela S Her aff a Hara ses eT ? “e ro)-on{)-o1——aynwo-{B)-E{0)-on CHs OH ° I I @) 1o{O)-e-0H (4) (yoo crt Cs Page No: 12. In the above reaction final major product is sme afar 9 iP Gear sears & — OH (Noe dH-cHe-cHO @) ct ocx HO (3) CHO 50. Which is correct order regarding the dipole moments of the following molecules ? Fret ompi & fags ongeit & viel a aterm a aA 8 7 Aicieciececiecta cai SESE eynn{O)-0:<0N{O)-N0r anerirciccioe SECTION -B Numerical Value Type Questions: This section contains 10 questions. In Section B, attempt any five questions out of 10. The answer to each question is a NUMERICAL VALUE. For each question, write the correct numerical value (in decimal notation, truncated/rounded-off to the second decimal place: e.g. 06.25, 07.00, -00.33, -00.30, 30.27, -27.30). Marking Scheme: +4 for correct answer, 0 if not attempted and -1 in all other cases. “The reaction CH.(g) + Ch(g) —> CH:Cl(g) + HCKg) has 4H = -25 keal. The bond energies of C-Cl and H-CI bonds are 84 and 103 kcal respectively. The ratio of bond energies of C-H and CL-CI bonds is x: y. Ix: y =9: 5, from the given data, what is the bond energy of Cl-Ci bond? aftr CHa(g) + Ch(g) —> CHsCl(g) + HCK(g), AH = -25 keal var @ C-Cl cen H-Cl # ay ‘wal are 84 cent 103 keal # C-H ven CLCLae wh de oul x:y4 Ba x:y=9:58 aa fa ma wast & CLClau wat am 2? 52. 250 mL of hard water having hardness due to CaSO. is passed through anion exchange resin (R(OH)2) and water coming out of resin required 20 mL of 0.001 M H2S0, for its titration. Thus, hardness of water in ppm of CaSOx is : (Molecular weight of CaSOs = 136 g) We GaN Ta $ 250 mL A wakeat CaSOuS oR @, gw acoA APT SI ROY) @ sari roan sear er TB aE PT (aT) TF TAMIA FA 0.001 MH2SO. wT 20 mL sTTET e a Fa A war CaSO. TH ppm & (CaSOuT suka ZAM = 136 9) 53. The numbers of structural isomers of C,H, is : 54, The number of sigma bonds in Mna(CO)r0 is Mno{CO)wo % rH ait FH Heat t— 55. A diatomic molecule has a dipole moment of 1.2 D. If the bond length is 1.0 * 10-8.cm, what % of electronic charge exists on each atom : we aera ary wr qa MIME 1.2081 a wa ag 1.0% 10% om & at vole WAT, Ge ware oder wr ear safes Sefer eT Page No: 1356. 57. 59. 60. Teme tacton fucose nan aqua altn is =8. The may of oon ee rae ar ea sts = ry se Find the value of E°, ‘0.651 205 given that: Ej qo = + 0.50V B60; qo: = #068 V (Report your answer by multiplying 100) Bo; rio; MAT aie RTE Rem Ta 8: £6. gg: #+0.50V Foo; go 7 F066V (100 8 yon ae sive GeR Af) If molecular mass of the final product D is (W) then report your answer as (W/3) in the following reaction aR aan 8 ra aT See D ar SOE (W), ct ste Se (WI) wa a Afora — Ba 5 A Jere tevedisiere =e OH i on CH»-CH-CH; (A) +(B) 2 If molecular mass of the final product B (Consider product having higher molecular mass) is W than report your answer as W/10 in given reaction? Consider molecular mass of carbon = 12, hydrogen = 1, oxygen = 16, iodine = 127 aft RS TTS B GAT SOR TT GIR) wT sna KAT WS a OT TER WHO TT are ;we oe & faa a wa sR ol SRI Sse (ora = 127) 2, BERT = 1, siteeors = 16, aT Amongst the following, the total number of the compounds soluble in aqueous NaOH is fea ad adiftal @ ota NaOH 4 fda aifret a ga wen saga e9ega8s Me 6 © ao” Page No: 14PART-C (4PI- C) (MATHEMATICS SECTION — A Multiple Choice Questions: This section contains 20 multiple choice questions. Each question haas 4 choices (1), (2), (3) and (4), out of which ONLY ONE is correct. Marking Scheme: +4 for jm dx mee t - a (yo 2) Fz @) 5 m2 Fe 62. _Funetion f(x) is defined such that f(x) Je II=t1}46 x2 then identity the INCORRECT option? K+, x2 (1) (2) is non-2 oq a Rewer BY Wea? Sx+1, xs2 (1) foo, x= 2.9% sameriia aA #1 (2) f(@), x= 2.92 wag Bh 3 (3) 100, x= 258 wari 21 3) Jrooax= 42 a 63. fz, 2, 2 are three points lying on the circle fz) = 2 then the minimum value of [zi + 2a? + |zo + 2s)? + [es + zis equal to AFR 2s, Za, Za ATA FG FA fe] = 2 Aer B, a far + zof? + fae + zal? + fas + zal? HT ATH TA were a (me 12 15 (4)24 64. Number of point of minima of the polynomial y= 10x*— 24x + 15x*— 40x? + 108 is(are) equal to ? y= 10x® — 24x9 + 15x!— 40x? + 108 3 Ate feqal a dem & 2 (14 (22 (3)3 (4)4 65. ty=2sin' Vi=x ~sin(@Vx—x" ) where. x < (0.2) then 2Y is equal to af y= 2sin-! Vi=x = sin(2vx—x? ) viel x € { 0, SY aa 8 - 2 — 8) xa? : vx-x? 4) (10 (2) 66. Let A and B are two points (1, 0) and (3, 0) and P is a variable point on y-axis then maximum value of angle APB is equal to APH A sie B &t fy (1, 0) she (3, 0) & veM Pew a Fg & oh yor wee ca Bm APB a sitters AP agree & - (n2zde (2) 30° (345° (4) 60° 67. Let f(x) and g(x) are twice differentiable functions such that f(x). a(x) = 1 forall x and f (x) and g(x) are never equal to zero then 1% _ 9°0%) is equal to Foo ~ goo APT ACK) He g(x) St are rar wT AT NHR B AH A(x). gfx) = 1 AA xd Fry TET EG) she g'Ge) wR 2h) Page No: 15 4) age No! @) 1”)68. 69. 70. m1. 72. 73. 4. 75. 76. A variable chord PQ of y? = 4ax subtends a right angle at its vertex then the locus of point of intersection of normals at P and Q will be wae y? = 4ax #) YH aX char PQ oh gad eit we Gael aah 8 aa Pale QU siftera & wise fry a fry va 8 - (1) y? = 4a(x- a) (2) y? = Ba(x- 4a) (3) y= 12a(x-8a) (4) y’ = 16 alx - 6a) 0 i\(a b) (a b) Let s- nen AV(E S)-(2 Spaeder). wae i-V=7. then he numbers of 2tnt ‘number in the set S is. (4) 14 (2) 10 (3) 15 (4) 12, isjek and é then the value of af jek gen 6-4 +3]+7k aR PxB= 6x6 gen 7.5-2.5 8 a at 25 (3)15 40 100 YC, Cj09.(150-i) = k Ceo then value of k is equal to a 0S s00 FA KB A ATA @ - 10 Ye ye0 (150-1) = a (1) 50 (2) 100 (3) 120 (4) 150 If, Qand R are three points with co-ordinates (1,4), (4,2) and (m, 2m 1) respectively then the value of m for which PR + RQ is minimum will be equal to ae Pate Rae ry & foraeh PALM aH: (1,4), (4,2) ate (m, 2m — 1) 8 aed mT APT eT wa PR+ RO "pKa 7 OF 5 7 18 @Q> as oF? Consider a circle in xy-plane with diameter 1, passing through the origin O and through the point Ali, 0). For any point B on the circle. Let C be the point of intersection of line OB with the vertical line through A. If Mis the point on the line OBC such that OM and BC are of equal length then the locus of point Mas B varies is given by the equation arate yar 8 gat Porrar ara 1 # yey OS quran # ate Ag AI, 0) a A yee & gH we Prt frg BS VAS OM at settee tar wy, Tar OB S Tr afte fry C8) ae MtarI OBC TH era Rg @ sa OM sik BC aragar away & aa Bax & fag MS Hea Rey oI AGIA Rat AT a. ()xbe+y¥)-¥=0 @yr=x By=20e+¥) (4) Peaxty In the given data, the mean of square of deviation about 10 is 25. The variance of same data is 16. If mean of the data is greater than 10 then actual mean of data is (10 @)13 @)7 (4) None of these £82 WY red F106 ards Raa & all or war 258 aa gE seed ER 168 A stewed wT HEI 10 @ afte & aa areal am aaite Heat - (1)10 (2) 13 a7 (4) 5 a wg aa A cure in the x-y plane is given by the parametric equation x = +t+ 1, y=f-t +1, where parameter t varies over all real numbers then the number of straight line passing through (0, 0) which are tangent to the curve are 'n’ and sum of slopes of these tangents is k then n + k is equal to yard Aye am frre wrefere whewrx=P+t+1,.ysP-t+1 wel wh arate wensl wt gras @ 74 (0,0) 8 TERA arch wees Tans A sean’ 8 ot aw a ent der 2 ae gr ere tant a WaUnnal Br ale ke Gan +k HT ATT aay z - (1)3 @)4 @) z 4) Consider a system of equations x+ay+z=0 bx+ y+ bi x+by+z where a and b « {-2,—1,1, 2} then number of ordered pair (a, b) for which system will have infinite solution is(are) (yt (25 @)7 (4) None of these Page No: 16 16 3‘cos(sin x)—costtanx) 77. Jim 1, where £ is a non-zero finite number then value of n + /is equal to lim S2SSO 7) CSE) 6 re care RR eo Ba m + CH ATT TER - 5 9 M2 QF a4 > 78. Aparabola whose axis is parallel to x-axis passes through three points (2, 0),(0, area enclosed by the parabola and line x — 2y— 8 = 0 is equal to We wae fora ser set S Taree # sen di fyait (2, 0),(0, -1) site (6, 1) & aa Wace shy tar x-2y-8208 uRag dawa aa 8 - 125 64 108 41 oe @ > o> as 1) and (6, 1) then 79, Ifx=5and The contrapositive ofthis statement is (1) ifx—2y=9 then x= -2 (2) Ifx~2y 49 then x+ Sand y+-2 (8)Ifx—2y +9 then x5 ory>-2 (4) Ifx—2y + 8 then either x + 5 or y= aft x= S cen y=—22, ah x—2y= 9a we or HfdURRaRer B— (1) aft x= 2y = 9 cea x= 5 ae y=-2 (2) af x=2y2 9a x2 SaeM y+ 2 (3) aft x-2y+9aa x4 5a y4-2 (4) aft x-2y+ aa a dt xeSary=-2 80. The eccentricity of ellipse 14x? 4xy + 11y? = 60 will be equal to Siege 1432 — any + y= 60 Seca aR e - 1 1 1 a) 2) 1 3) 2 4) OF az @> a) SECTION -B Numerical Value Type Questions: This section contains 10 questions. In Section B, attempt any five questions out of 10. The answer to each question is a NUMERICAL VALUE. For each question, write the correct numerical value (in decimal notation, truncated/rounded-off to the second decimal place: ¢.g. 06.25, 07.00, -00.33, -00.30, 30.27, -27.30). Marking Scheme: +4 for correct answer, 0 if not attempted and -1 in all other cases. 81. Let f(x) be a function defined for x < R such that f(x) — 6F(x) + 11f(x)- 6 =0 Vx € R. Itis also given that (x) is discontinuous at x = 0 only then number of such possible function f(x) will be equal to APR Gat fo) TH xe RG ay gH Gen & * Fx) — 6x) + 11x) -6=0Vxe Rae Rar ra © PR fe), Baa x =O ME KRHA & aa wa Ax) S enfs wa wT we Ter eh - 82. For each positive integer n let the set Snis defined as follows Si = (1), S2 = (2.34), Ss = {5.6,7,8, 9) Ifthe sum of all the integers in set Sn is equal to 1729 then number of element in set Sy is equal to ? Foe crore yoie nd fey aye S.A THR wet eA Si = (1}, So= 234), So = (56,78, ae WATT SoH eh Quiet wr densa 17298 Ta WATT SoH sac H vie TUR 7 83. The number of sequences of length five with 0 and 1 as terms which contains at least two consecutive Osis Ost 1a) wera a dia rag & ogee A een ehh fer ow a oA at maT OF - 84. Ifa, fy ae roots of + 2x2 + 94-+3 = Othen value of {—*-) at 3 a AR a, py ir 98 +28 43x43 08 as toe (2) +(4) +(S) ar are 27 +1) y 85. _Leta triangle is formed by selecting 3 vertices of cuboid having length of edges are 3, 4 and 5. Find the probability that triangle formed is right angled triangle given that one side of triangle is 5 units. ‘ara era freA ous a ATEN 3,4 LS BA Ae viel we qa we yw Pry war GATAT saftepen sie afew arr aa Ay THVT & fora yw qo S gH ze - 86. For a regular octagon inscribed in a circle of radius 1, the product of the distances from a fixed vertex to other seven vertices is equal to. Yo we ay oh soe From S gad ocean ar es fet cw a a ay at A Gel ow apres art AG Page No: 1787. Let z:, z2, zs be complex numbers such that | z| = [zo| = |zs| = 1 and zi + zo] =V/2 and jer + 23] = V3 then minimum possible value of jazz + (1 — a)zs - zif? will be equal to (where ae R) FIAT 2s, 22, 25 A wit ieee ser wae B fH | zi] = fea] = zs] = 1 eM f2i+ 20] = V2 We fart 2s) =V3 Wa faze + (1 —ajzs — 2a)? BI RTA AM et (wT ae R) 88. Let f(x) be a diferentiable function which satisfies the equation f(x) = - fft)tant at-+ [tanoe—t) at ° ° 2 then foxdxis equal to 7 ar f(x) sewer wet eI BA fe) = Jfeotant dts ftange—t) dt a frooden at 8 ° a = 2 89. A curve is represented parametrically by the equations x = e' cos t and y = e' sin t where t is a 2 paar, ante vate ot © at pit wet = 0 r 2 Wo aa arti woe x= ecos tah y=elsint wel tur 8, oe SY ar wr fg t= One x & 90. The area bounded between y= sin-! x and y= 2 cos~! x and y-axis is al y= sin! xaiity = 2e0s-*xafte yore tag Sara 8 - Page No: 18