Sec: SR.

IIT_*CO-SC(MODEL-A,B&C) GTM-11(N) Date: 09-01-24

Time: 3 HRS JEE-MAIN Max. Marks: 300
KEY SHEET
PHYSICS
1 B 2 D 3 C 4 A 5 B
6 C 7 A 8 A 9 D 10 B
11 A 12 C 13 A 14 B 15 A
16 A 17 D 18 C 19 C 20 B
21 45 22 50 23 12 24 5 25 3
26 30 27 245 28 6 29 3 30 4

CHEMISTRY
31 D 32 C 33 B 34 D 35 D
36 A 37 A 38 C 39 D 40 D
41 A 42 A 43 B 44 A 45 A
46 D 47 C 48 B 49 C 50 A
51 4 52 9 53 3 54 75 55 4
56 1 57 446 58 15 59 8 60 4

MATHEMATICS
61 C 62 C 63 A 64 D 65 C
66 B 67 D 68 A 69 C 70 B
71 C 72 C 73 D 74 A 75 C
76 D 77 A 78 D 79 A 80 C
81 7 82 4 83 0 84 0 85 26
86 22 87 3 88 2 89 32 90 12

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 Narayana IIT Academy 09-01-24_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-11(N)_KEY&SOL
SOLUTIONS
PHYSICS
1. The given formula of young’s modulus of elasticity,

5. Current through capacitor

dq d  dV 
ic    CV   C  
dt dt  dt 
di c  d2V 
C 2 
dt  d t 
Current through inductor
iL  1  ic
diL di
 c
dt dt
di di
 VL  L L  L c
dt dt
d2V
VL  LC 2
 3  2  10 6 2
dt
VL  12  V
7. According to given condition    1 t  n for minimum t , n  1
So,    1 tmin  
 
tmin    2
  1 1.5  1
8. For a vibrating string
p T
f 
2l 

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p= no.of loops or no.of of harmonics
For the given problem.
p T = constant or p1 T1  p2 T2
T2 p Mg 5 M 25
Or  1 or  or 
T1 p2 9g 3 9 9
Or M = 25 kg
9. Given, forward resistance, R1  50

11. Given, frequency, f  500 MHz  5 108 Hz

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h h
14. mg   Fb   balance torque about the edge 
2 3

2
18. No of reactions   6.023 1026
235
2  6.023  1026  200 106  1.6 1019
Power output 
235  30  24  60  60
 63.2 MW
19. For closed organ pipe resonating frequency is odd multiple of fundamental frequency
 2n  1 1.5  20
 number overtones heard = 7
21. Let the total height of building be x .

2d 2 x 2d
3x 2 
23. V  E0   dx   2 dx   12dE0  U  qV  12qdE0
0 d 0
d 
P 2  P 10  Q   1  2  10
24. s  ;
Q 3 10Q 1 3 10  Q
10
 20  2Q  30.  Q  5; P  
3
25. Velocity component along x direction after time t is
vx  4v02  v02
qE
vx  t
m
26.

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  c
 90     c
4
 cos   ...... 1
5
sin    sin 
sin  sin 2 
 sin    1  cos 2   cos 2   1 
 2
sin 2  4 sin 2  .4 4
 cos   1    1 
2 5 5 5
1 sin 2  .4 1 1
    sin 2   sin  
5 5 4 2
  30 0

28. Let ‘x’ be the elongation in the springs and  be angular displacement.
 l   l 
 = l  K    x   
 2   2 
ml 2 Kl 2
   
12 2
 6K  m
     T  2
 m  6K
  1 m3 2
29. F   w
2
2 3
 n  hc
30. 1.388 103   
 At  
1.388  103  550

1240 1.6  1019
 4  10 21

CHEMISTRY
2 3
33. Cr is reducing and Mn is oxidizing when both have d 4 configuration. Oxidation state of iron in
ferrates is +6  FeO4  Actinoid contraction is greater from element to element than lanthanide
2

.
contraction,.
34. No. of unpaired electrons in the above species are
4 3
 Fe  CN 6  0  Fe  CN 6  1
3 2
Cr  NH 3 6   3  Ni  H 2O 6   2
Strength of ligands CN  ( strong) > NH3(strong)>H2O(weak)
35. When electron density is pushed from metal atom into -bond, the CO bond is weaken as electrons
enter into anti bonding orbital of CO. With 2 unit negative charge on metal atom -back bonding
from metal to CO increases maximum electron density.
36. Conceptual
40. G o  H o  TSo  E o  (PV)  TSo
Assuming ideal gas behavior,
G o  E o  (n)RT  TSo

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Using the value of R=1.987 cal mol.K, and the fact that 2 mol of gas (D) is produced from 3 mol
(2A+B),
(n)RT  ( 1 mol) (1.987 cal / mol.K)(298 K)  592 cal
G o  2500 cal  (592 cal)  (298 K)(10.5cal / K)  3.09kcal  0.04 kcal
Since the value of G o is positive , the indicated reaction cannot be spontaneous.
41.
m  2 x  6 y  8 z
eq  2 x  6 y  8 z
8
42. The correct sequece of carbocation is II  I  III  IV . Electron releasing stabilizes the carbocation
by dispersal of positive charge. More the number of alkyl groups, the greater the dispersal of positive
charge and the more stable is the carbocation.
43. Propane will not formed as in wurtz reaction two molecules of each reacting species combine with
the removla of NaX.
44. None of the ozonolysis products is chiral.
45. Presence of electron releasing roups,

46. Only aliphatic – OH is substituted by Cl  . This is because in phenol the C  O bond is stabilized by
resonance.
47. In phenyl magnesium bromide, phenyl is attached with that

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48. It is a   keto acid which undergoes decarboxylation in very mild

49.

50. Sugars that have free aldehyde, a ketone, a hemiacetal or a

Hemiacetal can be easily reduced by oxidising agent such as Tollen’s reagent

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 Narayana IIT Academy 09-01-24_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-11(N)_KEY&SOL
51. SOCl2 , PCl3 , PCl5 , RPBr3
52. HNO2, SO2, NO, N2O3, NO2, SeO2, TeO2 can act both as oxidizing and reducing agents
53. 3 & 7 are non-polar
Note : iii, iv,& vi are non-polar molecules
54. 80 gm SO2 18 gm water H2O
?  4.5
6.581015 z 2
55. Number of revolutions per second =
n3
56. 2 H 2 S  2 H 2 g   S 2  g 
2
 0.1x   0.1x 
   
Let x be the degree of dissociation K c  
v   2v 
2
 107
 0.1  0.1x 
 
 v 
3
x
 106 x = 0.01
2v
Degree of dissociation  
0.1x
 x
0.1
1% dissociation of H 2 S
MV 4  500
57. Number of moles of Na  reduced at cathode   2
1000 1000
Mass of amalgam = Mass of 2 mol Na + Mass of 2 mol Hg  2x23  2x200  446g
 A0 
58. Amount of A left in n1 halves =
2n1
Amount of B left in n2 halves =  A0   4  B0 
22  2n1  n2
n1  n2  2
T  n1  t1/ 2 A similarly T  n2  t1/ 2 B
So, n1  3n2
59.

60. a,b,c,g

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MATHS
62. x ydx   x  y  dy
2 3 3

y 2  x 2 ydx  x3dy  y 3 dy
y 2

y6 y6
x 2 y 3 dx  x 3 y 2 dy 1
 dy
y6 y
 x3  1
 d  3    dy  c
 3y  y
x3
 my  c
3 y3
9 y 2  x 2 ydx  x 3 dy   3 y 5 dy
3x 2 ydx  3x3 dy  y 3 dy
63.
f 1  h   f 1  f  1
64. lim 
h 0 h  h 2  3 3

65

66. No of elements A  B  9
No of subsets of A  B with at least two & atmost seven elements is
9 C2  9 C3  9 C4  9 C5  9 C6  9 C7  492

67. V1.V2  0
abc  0
a  2, b  0, c  2 6 ways
a  1 , b  0 , c  1 6 ways
a  2, b  1, c  1 3 ways
a  2, b  1, c  1 3 ways
18 ways
68.  f  x   x  3  a  1 x  1
3 2

 f   x   3 x 2  3  a 2  1  0x  R for f  x  to be invertible

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69. f  x  y   f  x. f  y 
f  x  h  f  x
f '  x   lim
h 0 h
Get f  x   2 x

64 f  6 
Area enclosed 
3 3

70.  c is a root of x 2  ax  b  0  c 2  ac  b  0

71.  Let common difference of A.P. be d.

72. Let eccentricity of conjugate hyperbola be e’

2 3 4 4 1 1 10
73. Required probablity        
6 7 6 8 7 3 21
 21  10
73.

74. There is no change in the standard deviation if each observation is increased by a constant number
whilemean is increased by that number
New mean 30  2  32 and standard deviation =2

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75.

76. n (A) = 3

77.

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 1   11 7   
78. Centroid is M  , , 
 3 3 3 
A  2,3, 5
   5 2   
DR’S AM  , , 
 3 3 3 
For AM to be equally inclined
  7,   10
f f  x   axcbx ; f  2   1 f   2   0; 2ac 4th  1 …(1)
2
79.

80.

h
10
r

dv
 3m3 / min
dt
r 5 1
 
h 10 2
h
r
2
1 h2  h3
v    h 
3 4 12
dv 3 h dh 2
 .
dt 12 dt
dh 4

dt 3
  
1 1 ex
81. I   x 1 3 x dx   dx  1 e  e2 x  e2  dx
1 e e  1 e  e  e .e 
x 2 x

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x

  tan t 
1 2
dt
0
82. lim
x 
1  x2
1
 tan x 
2

 tan x 
1
1 2
x 1
 lim  lim x2
x  2x x  x
2 1 x 2

 2

4
cos ec
1
83. B  t 1  t  dt
1
2

84.

85. P 1  P  2      P  6   1
0.1  0.32  0.21  0.15  0.05  k  1
P 1 or 2   0.1  0.32  0.42
10 5
P  req   
42 21

86. 2n
C3r  2 nCr  2
2n  4r  2  n  2r  1
n   11 
10  r 5   10    22
 nr  2  5

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 Narayana IIT Academy 09-01-24_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-11(N)_KEY&SOL
87. Point of intersection is  0, 2 

0
A 2   x   dx

0

x  
3/ 2

2   12
3
2 

  9    3
2

 4 
88. tan 1  2 
 4r  3 
 
1
 1 
 tan 
3
 r2  
 4
 
 1 
 tan 1 
1
 1 r2  
 4
 1  1
 r  2r  2  
 tan 1     
 1   r 1  r  1  
   
  2  2  
 1  1
 tan 1  r    tan 1  r  
 2  2

 4   1  1 

r 1
tan 1  2    tan    tan 2
 45  3  2 2
1

2 b2 1
89. 1 1 
3 16 2
1  b2  1
1   
3  16  4
b2 3
1 
16 4
b2 1
  b2  4
16 4
Length of minor axis = 4

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2 16 1
1 1 2 
3 b 2
 16  3
1  2  
 b  4
16 1
  b 2  64
b2 4
b8
Length of minor axis = 8
f  x  y f  x  y
90.   4 xy
x y x y
f  x  y f  x  y
  x  y2    x  y 
2

x y x y
f  x  y f  x  y
  x  y    x  y  K
2 2

x y x y
f t  2
x y t t  K f  t   Kt  t 3
t
1
1 1 1
A  x 2  x 3  dx    f  x   x 3  Kx f 1  1
0
3 4 12
f  x   x3 K 0

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