Sec: SR.

IIT_*CO-SC(MODEL-A,B&C) GTM-13(N) Date: 11-01-24

Time: 3 HRS JEE-MAIN Max. Marks: 300
KEY SHEET
PHYSICS
1 4 2 3 3 4 4 3 5 4
6 1 7 2 8 4 9 2 10 4
11 4 12 1 13 2 14 1 15 1
16 1 17 1 18 1 19 4 20 3
21 223 22 10 23 6 24 10 25 48
26 5 27 15 28 4 29 5 30 26

CHEMISTRY
31 2 32 2 33 4 34 3 35 3
36 3 37 1 38 1 39 2 40 4
41 2 42 4 43 1 44 3 45 2
46 2 47 2 48 2 49 4 50 4
51 16 52 3 53 45 54 6 55 12
56 6 57 4 58 5 59 25 60 6

MATHEMATICS
61 4 62 2 63 3 64 4 65 1
66 2 67 1 68 2 69 1 70 4
71 4 72 1 73 3 74 4 75 2
76 1 77 1 78 2 79 2 80 4
81 18 82 4 83 6 84 3 85 3
86 16 87 20 88 8 89 5 90 1

For More Material Join: @JEEAdvanced_2024

 Narayana IIT Academy 11-01-24_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-13(N)_KEY&SOL
SOLUTIONS
PHYSICS
E
1. F   E 1V 1T 1 
VT 
  1,   1,   1
2.   MB sin 
 sin 
 1 sin 1  sin 900
  
 2 sin  2  / 2 sin  2
 2  300
Angle of rotation  90  30  600
 mg 1
3. 0.1  2 xdx   mv02
2
2
v0  10 m / s
v02
4. aA 
R
VA  2v0
v A2
RC   4R
aA
l l
5. T  2 ; TM  
g g
Mgl
l 
YA
Mgl
l'  l 
YA
1 A
 l '  l 
Y Mgl
 TM2  A
  2  1
T  Mg
V 
6. WAC  PV0 0 
 V0 
 P0 
2 PV
0 0 ln  0 0 ln  3 
  PV
P
P
P 0
3
7. PV  RT
 T  V 2 
P  R 0 
 V 
dP
0
dV
T
  02    0
V

SR.IIT_*CO-SC Page NO: 2

For More Material Join: @JEEAdvanced_2024

 Narayana IIT Academy 11-01-24_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-13(N)_KEY&SOL
8.

2 
t
T 12
T
t
24
 /2
 Rd cos 
9.  dE 0
 4 0 R 2


E sin  2
4 0 R
0
2 
E 
4 0 R 2 2 0 R
10. Since equivalent capacitance increases, charge on capacitor 4 increases. By KVL, charge on
capacitor 2 decreases.
11. Req  2
For max power, R  2
Eeq
 3  Eeq  6V
2
6
I   1.5 A
4
P0  1.5   2  4.5W
2

12. Inductance can be set to be analogous to mass, as it poses inertia to current change in the electrical
circuit.

2V0  3t

13. VC   1  e 2 RC

3  
2V0  1 
VC  1
3  3 
4V
VC  0
9
VC 2V0
I 
2R 9R
14. V  5  3sin t 
32 59
Vrms  52  
2 2
   ^
15. E  B is along positive Z-direction. B is along positive j direction.

SR.IIT_*CO-SC Page NO: 3

For More Material Join: @JEEAdvanced_2024

 Narayana IIT Academy 11-01-24_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-13(N)_KEY&SOL
 
16.   2 c   c 
2 4
1
 sin  c     2

D
17.  max 
d0  a0
D
 min 
d 0  a0
1 1 1 1 1 1  225
18.  R 2  2   R    
  n1 n2    9 25  16 R
19. Req  6
v0
I  4A
Req
20. Reading = 17+8  0.1-2  0.1=17.6 mm
21. L.C. =0.01 mm, zero error =-0.08 mm
Reading = 2 mm+15  0.01+0.08=2.23 mm
22. f T
2T  0.50  4  10  T  10 N
dv
23. mv P
dt
m v 2 2v0
P
t 2 v0
2
R
I   dI 
R 0
24.  0 r 4 dr

2 0 R 5 2 0 R 4
T 
5R 5
v
25. v1  0
2
2  x0  2 x0  4 x0
Radius of curvature at farthest position  
3 3
2
 v0 
 2  3v02
amin  
4 x0 16 x0
3
2 s cos 
26. Height of capillary rise =
 gR
2 S A cos 
When in A 5cm=
 AgR
2 S cos 
When in B h= B
 BgR
S B  2 S A and  B  2  A
2  2 S A  cos 
h  5cm
2  AgR

SR.IIT_*CO-SC Page NO: 4

For More Material Join: @JEEAdvanced_2024

 Narayana IIT Academy 11-01-24_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-13(N)_KEY&SOL
27. f 0  50 Hz
v
f0 
4l
300
50   l  1.5m
4l
A T  1.5
 A
28. B TA
A 1

B 2
TA  2eV , TB  0.5eV
B  EB  TB  4eV
29. Va  5  10  10  1  Vb
 Va  Vb  5V
30. Energy released = Change in B.E. (7.6 × 4) – [4 × 1.1] = 26 MeV

CHEMISTRY
31. 1.6 gm oxide looses 0.16 gm
80 gm oxide looses = 8 gm ‘O’ = ½ mole of ‘O’
TiO 1   TiO 3  Ti 2O3
 2  2
 2

32. Zn + Ni Zn+2 + Ni
+2
o o
Eº = ENi2 / Ni – EZn2 / Zn
= –0.23 – (–0.76) = + 0.53 V
Positive value shows that the process is spontaneous.
Rest of all (I) (II) (III) combination have negative Eº value.
(I) Eº = –0.44 – (–0.23) = –0.21 V
(II) Eº = –0.76 – (–0.23) = –0.53 V
(III) Eº = –0.76 – (–0.44) = –0.32 V
33. HINT: Assume rate law
r = K[H3AsO4]x [H3O+]y [I–]z
Solving by the help of various experiments
x = 1, y = 2 and z=1
total order = 4
34. Tf  i Kf m
3.72  i  1.86  0.4
i  5 n  4
35. Hint: Due to extra stability of half-filled f-subshell.
36. Co  NH 3 4  ONO 2  Cl =linkage isomers
Co  NH 3 4  NO2  Cl   NO2 = ionization isomers

SR.IIT_*CO-SC Page NO: 5

For More Material Join: @JEEAdvanced_2024

 Narayana IIT Academy 11-01-24_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-13(N)_KEY&SOL
37. C3H8(g) + 5O2 3CO2(g) + 4H2O()
6  B.E. (C  O) 
8  B.E. (C — H)   8  B.E.(O — H) 
CH =  2  B.E. (C — C) –  
 3 | R.E. | of CO2 
 5  B.E. (O  O)   
 4   vap H(H2 O) 
38. X(g)  X+(g) + e–
If I.E. is ionisation enthalpy, then
N0 2E1
 (I.E.) = E1  I.E. =
2 N0
X(g) + e–  X–(g)
If  egH is electron gain enthalpy, then
E2
 2N0(E.A.) = – E2   egH = – .
2N0

39. (A) High spin, d 6 :CFSE=  0.6  2  0.4  4   0  0.4 0

(A) Low spin d 5 ; CFSE =  0.6  2  0.4  5  0  2.00
(B) Low spin d 4 ; CFSE=  0.6  2  0.4  4   0  1.6 0
(C) High spin d 7 ; CFSE=  0.6  2  0.4  5  0  0.8 0
Magnitude of CFSE is maximum in (B)
40.

41. Mass of organic compound = 0.2 g

N
Unused acid required = 40 mL NaOH
10
N N N
40 mL NaOH  40mL H 2 SO4  20mL H 2 SO4
10 10 5

N N
Acid used for absorption of ammonia= (60-20)mL H 2 SO4  40mL H 2 SO4
5 5
1
1.4   40
1.4  N1  V 5 1.4  40
Percentage of nitrogen =    56%
W 0.2 0.2  5
no of bond's in between two atom
42. Bond order of CO2 (by resonance method)=
no of resonating structures
4
i.e., bond order in CO32 (by resonance method)=  1.33
3
1
Bond length 
Bond order

SR.IIT_*CO-SC Page NO: 6

For More Material Join: @JEEAdvanced_2024

 Narayana IIT Academy 11-01-24_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-13(N)_KEY&SOL
43.

44. The compound A, despite a tertiary alcohol, cannot be readily converted into chloride because OH
is present at bridge head. The compound C, allyl alcohol can be readily converted into allyl chloride,
whose formation is responsible for white cloudiness.
45. t  BuO   astearic ally hindered base will give Hofmann elimination as major product. Where
as EtO  will give Saytzeffs product.
46.
solution : B
eletrophilic

aromaticsubstitution 

N  NCl 

47.

 
(A) is not possible because CH 3  CH 2  C H 2 is less stable than CH 3  C H  CH 3
(C) is not possible because acetophenone and CH 3OH cannot be formed.
OH
(D) is not possible because |
CH 3  CH  CH 3
48.

SR.IIT_*CO-SC Page NO: 7

For More Material Join: @JEEAdvanced_2024

 Narayana IIT Academy 11-01-24_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-13(N)_KEY&SOL
49.

50.

2Ze2
51. Velocity of an electron in He+ ion in an orbit = .....(i)
nh
n 2 h2
Radius of He+ ion in an orbit = ....(ii)
42me2 Z
By equations (i) and (ii),
u 83 Z2me4
Angular velocity () = = ....(iii)
r n3 h3
8  (22 / 7)  (2)  (9.108  10 )  (4.803  10 10 )4
3 2 28
= = 2.067 × 1016 sec–1.
(2)3  (6.626  1026 )3
CH3 CH3 Br
| | |
Br2 /hv
52. CH3  C  CH 2  CH3   CH3  C  CH  CH3 (One chiral carbon)
| | 
CH3 CH3
2
53. Number of possible dipeptides is (3) = 9
5x9=45
54. Basicity of H3PO4, H3PO3 and H3PO2 are 3, 2, 1 respectively.
 sum of basicity = 6

55. On dilution (addition of water) pH of the buffer solution will not change therefore x=0 and
x+12=12
56.  M   aq.   e   M  s   2 : E 0  0.52V
M  s   M 2   aq.  2e : E 0  0.34V
____________________________________________________

2M   M  s   M 2 E 0  0.52  0.34  0.18

At equilibrium Ecell  0
0.06
Hence E 0  log k
2
0.18  2
log k  6
0.06

SR.IIT_*CO-SC Page NO: 8

For More Material Join: @JEEAdvanced_2024

 Narayana IIT Academy 11-01-24_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-13(N)_KEY&SOL
57. The molar masses of glucose and urea are 60 g/mol and 180g/mol respectively.
50mL  1.2 g
The number of moles of urea   0.01mol
100mL  60 g / mol
50mL  2.4 g
The number of moles glucose 
100mL  180 g / mol
 0.0067 mol
0.01 mol  0.0067 mol 1000mL
The molar concentration    0.167 M
50 mL  50 mL 1L
The osmotic pressure is   CRT
 0.167 M  0.08 L.atm / mol / K  300 K
 4 atm
58.

SR.IIT_*CO-SC Page NO: 9

For More Material Join: @JEEAdvanced_2024

 Narayana IIT Academy 11-01-24_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-13(N)_KEY&SOL

59. For a zero order reaction ……(1)

 A 0
For zero order reaction K  ……..(2)
2t 1
2

Since  A 0   2M, t 1  1h, K  1

2
 from equation (1)
0.25
t  0.25 h
1
60.

Total six Cl Ax  P  Cleq bonds at 900 to each other

MATHS
61. Consider statement-2
y

z  2i 1
P
1
C

O x

Q is the point on the circle which is nearest to the origin

OQ  OC  CQ = 5  1
Statement-2 is true
Consider statement-1
Point on the circle with maximum argument is 1
1 1
If COP    sin    tan  
5 2
4
and arg  z0   2  tan 1  
3
Statement-1 is false.
63. Let 1 ,  2 and  3 be the roots of f  x   0
Such that 1   2   3 and g  x  takes all values from  6,  
g  x    x  1  6  6
2

 3  7,  2  8, 1  9
 a  b  c  719
Minimum value of a  b  c is 719
1   2   3  a  a  24  a  24
SR.IIT_*CO-SC Page NO: 10

For More Material Join: @JEEAdvanced_2024

 Narayana IIT Academy 11-01-24_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-13(N)_KEY&SOL
1 2   2 3   31  b  b  191
1 2 3  c
 c  504
a  b  c  719
64. Make 1 group of 2 persons, 1 group of 4 persons and 3 groups of 3 persons among 15 persons
15!
(except 2 particular persons) hence the number of ways by grouping method is
2!4! 3! 3!
3

Now we add that 2 persons in the group of 2 persons and thus the number of arrangements of these
15! 15!
groups into cars and autos is  2! 3! 
2!4! 3! 3! 4! 3!
3 3

65. E1 be the event that the answers is guessed

E2 be the event that the answer is copied
E3 be the event that the examinee knows the answer and
E be the event that the examinee answer correctly
1 1
P  E1   , P  E2  
3 6
Assume that event E1 , E2 and E3 are exhaustive P  E1   P  E2   P  E3   1
1
 P  E3  
2
E 1  E  1 E
P    , P    , P    1 (Probability of answering correctly by knowing)
 E1  4  E2  8  E3 
E
P  E3  P  
E 
P 3    E3  
24
 E E  E   E  29
P  E1  P    P  E2  P    P  E3  P  
 E1   E2   E3 
66. P  E   P  2   P  3  P  5   P  7   0.62
P  F   P 1  P  2   P  3  0.50
P  E  F   P  2   P  3  0.35
PE  F   PE  PF   PE  F 
 0.62  0.50  0.35  0.77
68. Let BP=x from the similar triangle properly
A

m2

B P O
m1

AO m2 mm
  AO  1 2
m1 x x
d  AO  m1m2 dx

dt x 2 dt
m
When x  1
2
d  AO  2m
 2 m/s
dt 5
SR.IIT_*CO-SC Page NO: 11

For More Material Join: @JEEAdvanced_2024

 Narayana IIT Academy 11-01-24_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-13(N)_KEY&SOL
1
dx
72. Let I   1
0  5  2 x  2 x 1  e 
2 2 4 x

By kings rule
e 2  4 x dx
1
I  2
0  5  2 x  2 x 1  e 
2 2 4 x

Adding 1 and 2
1
11 1
1 1 1  x
dx dx dx 1
2I      ln 2 2
0 5  2 x  x
5  2 x  2x 2 2
0 11  1
2
2 11 11  1
0
 x    x  
4  2 2  2 0
1  11  1  1  11  1 
2 ln    ln  
2 11  11  1  11  11  1 

 
2

1 11  1
I ln
2 11 10
73.
y

y  x  x3/2

O 1 x
y  x x 3/2

 y  x
2
 x 3  y  x   x 3/ 2
 y  x  x3/2
y  x  x3/2  1, y  x  x3/2  2
1 is an increasing function
2 meets x=axis at x=0,1
1

  x  x    x  x dx
3/ 2 3/ 2
Required area
0
1 1
2  4
 2  x dx  2  x 5/ 2   sq.units
3/ 2

0 5 0 5
74.  x  x   x  which is periodic with period 1.
Statement 2 is true.
Consider Statement 1.
f  x   sin  3 x  3 x   sin 3 x 
1
Using Statement 2, period of f  x  is .
3
Statement 1 is false.

SR.IIT_*CO-SC Page NO: 12

For More Material Join: @JEEAdvanced_2024

 Narayana IIT Academy 11-01-24_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-13(N)_KEY&SOL
st
75. Let 1 term be ‘a1’ and common ratio be ‘r’ then a1  a1r  a1r 2  .....  a1r 100  125
a1 1  r101 
  125  let 0  r  1
1 r
1  1  
101

    1
101
1 1 1 1 1 a1  r    here 1  1
 a   a   2  ...  100    
  a1r a1r a1r 1  r 
r 1 i 1 1
r


1  r  101


1

125

125

125

125

1
a1r 100
1  r  a1r 100
a1  a1r 50   a51   25 5
2 2 2

n log83
 1   1 
76. Last term expansion is cn     
n

 2   33 9 
8
 1 n / 2   1 log3 5
 3log 3 2
  1 
n

  5/3   3 3
 2  3 
5
5 1
 35log3 2  3log3 2  2 5     n  10
2
4

   1  10 2 1 10
6
th
 5 term from the beginning 10
c4 3
2    c4 2 . 22  c4
 2
77. Let the two numbers be a, b
2  4  10  12  14  a  b
x  8
7
 a  b  14  1
x  xi  2 2

 2
 
 n 
 16
i

N  
 460  a  b  16  64   7  a 2  b2  100  2
2 2

From 1 and 2, a  b  2  3
a  8, b  6
78. a sin      sin      b sin      sin    
 2a sin  cos   2a sin  cos 
 a tan   b tan 
 
2a tan 2b tan
2  2 1
2  2
1  tan 1  tan
2 2

b tan c
   2
a tan  b tan  c  tan  2
2 2 2 a
  
From 1 and 2 we get tan
2
a 2
 b 2  c 2   bc  1  tan 2 
 2

2 tan
2  2bc
 sin  
   a  b2  c 2
2
1  tan 2  
2
SR.IIT_*CO-SC Page NO: 13

For More Material Join: @JEEAdvanced_2024

 Narayana IIT Academy 11-01-24_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-13(N)_KEY&SOL

79. Let  tan x  sin x    tan x  sin x    tan x  sin x   .....

y  tan x  sin x   y
 y 2  y   tan x  sin x   0
1  1  4  tan x  sin x 
y
2

Again z  x3  x3  x3  ....
 x3  z  z 2  z  x3  0
1  1  4 x3
z
2

lim
1  1  4  tan x  sin x 
 lim

4  tan x  sin x   1  1  4 x3 
x 0
1  1  4 x 3 x 0

4 x 3 1  1  4  tan x  sin x  
 sin x sin x 
   1  1 4x 3
sin x 1  cos x  1  1  4 x3
 lim 
cos x 1 
 lim 
x 0

x3 1  1  4  tan x  sin x  x 0
 x3 cos x 1  1  4  tan x  sin x 

sin x 2sin 2 x / 2 1 1  1  4 x3 1 11 1

 lim . . .  1. .1. 
x 0 x 4 x / 4 cos x 1  1  4  tan x  sin x 
2
2 11 2
80. Put x  2cos  , y  3sin 
 1 1 
sin 1 1  cos 1  cos   sin   2 
 2 2 
   
sin 1 1  cos 1  cos      2 
  4 
 
1  cos      2  1
 4
   
1  cos      1  cos      1
 4  4
   3
  cos 1 1  2    cos 1  1    
2 2 2 2

81. Let z  x  iy
z  z1   x  10    y  6  i
z  z2   x  4    y  6  i
 z  z1  
arg  
 z  z2  4
 6  y  6  
 tan 1  2

  x  10  x  4    y  6   4
 x2  y 2  14 x 18 y  112  0
z  7  9i   x  7    y  9   x 2  14 x  y 2  18 y  130  112  130  18
2 2 2

SR.IIT_*CO-SC Page NO: 14

For More Material Join: @JEEAdvanced_2024

 Narayana IIT Academy 11-01-24_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-13(N)_KEY&SOL
83. The polynomial is every where differentiable function
 The points of extremum can only be the no.of derivative

The derivative of polynomial is P1  x   a  x  1 x  3   a x 2  4 x  3 
P 1  6
x
 x3 4
P  x    P1  x  dx  6  a   2 x 2  3 x    6
1  3 3
Also P(3)=6  a  3
P  x   x3  6 x2  9 x  2
 P  2   4, P1  0   9
 P  2   P1  0   7  6
x  0 y 1 z  0 x 1 y  0 z  0
84. L1      L2    
1 1 1 , 2 1 1
Any point on L1 and L2 be   ,   1,   and  2   1,  ,   respectively.
2  1       1   
 
2 1 2
On solving   1,   3
A   3, 2,3 , B  1,1,1
AB  4  1  4  3
a  c b d 
 
85. Shortest distance 
bd
Here a  3i  8 j  3k , b  3i  j  k , c  3i  7 j  6k , d  3i  2 j  4k
270
 Shortest distance   270  3 30   30    3
270
n  2 n 2 n  n  1
1   x   1  x 
n
86.  ....
1! 2!
= 1  8 x  24 x 2  ....
 n  8 and  2 n  n  1  48
   2, n  4
Now P  , n    2, 4 
Any line through P cuts the circle x 2  y 2  4 at A and B
 PA.PB  S11  4  16  4  16
87. Combined equation of pair of lines AC and BC can be obtained by homogenizing the hyperbola
x2 y 2
  1 with the help of AB
16 25
A
B

C  0, 0  x

SR.IIT_*CO-SC Page NO: 15

For More Material Join: @JEEAdvanced_2024

 Narayana IIT Academy 11-01-24_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-13(N)_KEY&SOL
2
x 2 y 2  x cos   y sin  
  
16 25  p 
 1 cos   2  1 sin 2   2 xy sin  cos 
2
x2    y    0
 16 p2   25 p2  p2
ACB  900
1 cos 2  1 sin 2 
    0
16 p2 25 p2
20
 p
3
Also Cl=P always perpendicular to given variable line hence variable line always touches a circle of
20
radius p  r   3r  20units
3
f 1  x  g  x   g 1  x  f  x  dx
88. I 

 f  x   g  x   g  x  f  x   g  x 2 
f 1  x  g  x   g1  x  f  x 


 g  x 
2

dx
 f  x  f  x
  1 1
 g  x  g  x
f  x 2tdt
Put 1  t 2  I   2
g  x t  2 t
2  t 
I tan 1  c
2  2
 f  x 1 
 2 tan 1   c
 2g  x  2 
 
 f  x   g  x  
 2 tan 1  c
 2 g  x  
m  2, n  2
m2  n2  8
89. f  x    x    x  2
  x    x  2   x    x   2  2
So f  x  is constant function
It is continuous every where  p  0
 3x 4  2 
q  lt  3
 x  3x  4 
x  8

pq25
90. f  x   10 x   x  1 x  2  x  3 x   
f 12   f  8 
 f 12   f  8   19840  1
19840

SR.IIT_*CO-SC Page NO: 16

For More Material Join: @JEEAdvanced_2024