SRI CHAITANYA IIT ACADEMY, INDIA 11-11-23_Sr.

Elite & Target _Jee-Main_RPTM-12_KEY & Sol'S

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr. Elite & Target(C-120, C-IPL & IPL-IC) JEE-MAIN Date: 11-11-2023
Time: 09.30AM to 12.30PM RPTM-12 Max. Marks: 300
KEY SHEET
PHYSICS
1) 4 2) 2 3) 3 4) 4 5) 4
6) 1 7) 3 8) 2 9) 3 10) 4
11) 2 12) 2 13) 4 14) 1 15) 4
16) 1 17) 4 18) 2 19) 4 20) 2
21) 13 22) 5 23) 4 24) 1 25) 4
26) 1 27) 4 28) 3 29) 6 30) 25

CHEMISTRY
31) 1 32) 3 33) 3 34) 2 35) 2
36) 4 37) 3 38) 3 39) 2 40) 3
41) 3 42) 2 43) 4 44) 3 45) 2
46) 4 47) 1 48) 3 49) 2 50) 2
51) 88 52) 54 53) 239 54) 287 55) 3
56) 3 57) 4 58) 9 59) 18 60) 15

MATHEMATICS
61) 2 62) 4 63) 1 64) 2 65) 3
66) 1 67) 2 68) 2 69) 1 70) 3
71) 1 72) 1 73) 2 74) 3 75) 2
76) 2 77) 2 78) 2 79) 1 80) 3
81) 7 82) 35 83) 18 84) 0 85) 18
86) 17 87) 50 88) 1 89) 244 90) 48

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 SRI CHAITANYA IIT ACADEMY, INDIA 11-11-23_Sr.Elite & Target _Jee-Main_RPTM-12_KEY & Sol'S

SOLUTIONS
PHYSICS
D2 h
1. K ,D 
2m 
h2
K 
2m 2
1
K
m
K D m 4m
 
K mD 2m
2

1
 K D : K  2 :1
2. The linear momemta given by,
p  2mE  2mqV  E  qV 
p m q 4m p .2q p 4 2 2 2
   
pp mp q p mpq p 1 1 1

3. From the figure , it is clear that threshold frequency for the metal is v  5  1014
Work function   hv
 6.6  1034  5  1014  h  6.6  10 34 Js 
 33  1020 J
33  10 20
   2.07eV
1.6  1019
4. Conceptual
5. 1  6ev
2  4.5ev
1242
1  207 nm
6
 2  1  69nm
1 2
6. mv1  E1  0
2

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 SRI CHAITANYA IIT ACADEMY, INDIA 11-11-23_Sr.Elite & Target _Jee-Main_RPTM-12_KEY & Sol'S

 30  0  20
1 2
mv2  E2  0  90  0
2
 80
2
 v  2 1
 1   0 
 v2  80 4
v1 1

v2 2
Dt 
7. 
hc
103  1 4  107 4 10 10
 34
  26  0.202  1016  2  1015
6.6  10  3  10 19.8 10
8

8. f 0  4  1014 Hz

34 (6.63  1034 )  (4  1014 )

W0  hf 0  6.63  10  (4  10 ) J 
14
 1.66eV
1.6  1019
9. 1:1
10. Conceptual
11. Conceptual
12. The KE of emitted photoelectrons varies from zero to maximum value work function
depends on metal used
13. Conceptual
h h 3kT
14.   , v s 
p mv s m
h
 
3mkT
15. Conceptual
16. Conceptual
17. Conceptual
18. Both statements core separately correct
19. In case of Hydrogen atom mass number and atomic number are equal
20. Conceptual
21. Conceptual
22. Conceptual
4
23. m V   3
3
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 SRI CHAITANYA IIT ACADEMY, INDIA 11-11-23_Sr.Elite & Target _Jee-Main_RPTM-12_KEY & Sol'S

m  3
3 3
m1   1   1  1
    
m2   2   4 3  4
V m 4
 1 2
V2 m1 1
24. Conceptual
25. Energy of each photon
200
E  5  1019 J
4  1020
hc

E
6.63  1034  3  108
 19
 4  107 m
5  10
h 6.63  10 34
26. P   1027
 663  10 9

1
F  2 nmv cos e  2  1  1019  1027   1  10 8 N
2
27. P  100  60% of p  60
P 60
E   2  107 N
V 3  10 8

F 2  10 7
Pr essure    3.9  107  4  107 N / m 2
A 4  3.14  (0.2)2
28.   2  10 7 m
hc 6.63  1034  3  103
E  7
 9.945  1018
N 2  10
1  107
number of photons  18
 1  1011
9.945  10
Noof photoeletrons  1  107
q  hq  107  1.6  1019
 1.6  1012 C
Kq 9  109  1.6  1012
V   3  101V
 4.8  10 2

29. Conceptual
30. Conceptual

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 SRI CHAITANYA IIT ACADEMY, INDIA 11-11-23_Sr.Elite & Target _Jee-Main_RPTM-12_KEY & Sol'S

CHEMISTRY
31.  H   CN H   ?
HCN 

Given (i ) HCN  K   OH   K   CN   H 2O; H  12.13KJ

(ii ) H   OH   H 2O; H  57.3KJ

eqn (ii) – eqn(i)=57.3-12.13=45.17KJ

 H (weakacid )  HN (wa  SB)  HN ( SA  SB 

1
32. (1) H 2( g )  O2( g )  H 2O( g ) ; H  68.4 Kcal
2

(2)C( S )  O2( g )  CO2( g ) ; H  94.4 Kcal

(3)C12 H 22O11 (S )  12O2( g )  12CO2( g ) ; H  1350 Kcal

11
Required equation is 12C( S )  11H 2( g )  O2  C12 H 22O11
2

 eqn 2  12 + eqn 1  11 eqn 3-

 94.4 12    68.4 11  1350  535.2Kcal
33. Units for rate of reaction is independent of order of reaction. For any order reaction units
for rate of reaction is mole/lit/time
m
Exp  I 0.05 K (0.1) m (0.2) n 1 1
4.       m 1
Exp  II m
0.1 K (0.2) (0.2) n
2 2

m
Exp  I 0.05 K (0.1) m (0.2) n 1
   1    n  0
Exp  III 0.05 K (0.1) (0.1)
m n
2

Rate = K  A '  B 0  0.05  K (0.1)1 (0.2)0

0.05
K  0.5 Sec 1
0.1
0.693
t1/ 2   1.386 Sec
0.5

35. Molecularity  4 are rare

Order of reaction is derived from rate equation not from chemical equation

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 SRI CHAITANYA IIT ACADEMY, INDIA 11-11-23_Sr.Elite & Target _Jee-Main_RPTM-12_KEY & Sol'S
36. 2 N 2O5( g )  4 NO2( g )  O2( g )

t 0 Pi O O
x
t  30 min ( Pi  x) 2x
2
Pi
at the end ( Pi  Pi ) 2 Pi
2
Pi
At the end total pressure is  2 Pi   2.5 Pi
2

 584.5 mm
 Pi  233.8 mm
P total after 30 min Pi+1.5 x =284.5 mm
x =33.8 & (Pi- x )=200 mm

2.303 233.8
K log  5.21 103 min 1
30 200
2.303 a 2.303  100 
37. K log  log10  
t ax 60  98 

K  3.3  10 4 S 1
38. A catalyst catalyses both forward and backward reactions to the same extent so that
equilibrium reaches earlier
39. Increasing temperature, increase the fraction of molecules which collide with energies
greater than Ea
40. All the 4 C-H bonds in CH4 are identical in bond length
O O O
 H 3 PO3 & H 4 P2O5 have
P H
P O P
HO HO
OH two - OH groups
H
41. OH H

Cl

Cl axial=240PM

P Cl equitorial = 202 PM

Cl

42. Cl

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 SRI CHAITANYA IIT ACADEMY, INDIA 11-11-23_Sr.Elite & Target _Jee-Main_RPTM-12_KEY & Sol'S
43. Except BiF3 all trihalides are covalent.

3Cu 8HNO3 3Cu(NO3)2 2NO2H2O

(dil)
44. Cu 4HNO3 Cu(NO3)2  NO2 H2O
(conc)

45. Tendency to donate lone pair decreases from NH3 to BiH3.

46. I) All 15th group elements does not form P  p bonds

II) Single N-N bond is weaker than single P-P bond.

47. PH3 has lower Boiling than NH3 because PH3 molecules are not associated through
hydrogen bonding.

48. Bond dissociations energy order H 2O  H 2 S  H 2 Se  H 2Te

49. Ozone:

Gas – pale blue

Liquid – dark blue

Solid - purple black

1
50. In KO2 oxidation state of each oxygen is 
2

51.  f H 0cal  Formation of N 2O

1
N  N ( g )  O  O( g )  N  N  O
2

 1   1 
H 0cal   B.EN  N  BEO O    B.EN  N  BEN O   946  (498)    418  607  170 KJ mol 1
 2   2 

Resonance energy  f H 0 (obs)   f H 0 (cal )  82  170  88 KJ mol 1

52. HNO3  NaOH  NaNO3  H 2O

Start 120 40

End 80 0 40 mm

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 SRI CHAITANYA IIT ACADEMY, INDIA 11-11-23_Sr.Elite & Target _Jee-Main_RPTM-12_KEY & Sol'S
 H  40 m. mol  57  103 Jm .mol 1
 40  103  57  103 J .mol 1  2280 J
MS T  2280  1000  4.2  T  2280
2280
T  103  54.286  102
4.2
 54 102 C

 Ea 1.25  104
53.   Ea  1.25 10 4  2.303  8.314  239 KJ mol 1
2.303RT T
r1 C1
54.  ( n  1st order r c)
r2 C2

 1 C1 0.04 2.303 C
  K log 1
 2 C2 0.03 t20  t10 C2

2.303 4  102
K  log  K  287  10 4 min 1
10 3  102

55. PQ

r  K ( P) x
8r  K (2 P ) x
8  (2) x 23  2 x
x3

P4  20 HNO3  4 H 3 PO4  20 NO2  4H 2 O

Basicity of H PO is
56. 3 4 3

57. ZnO , Al2O3 , Sb2O3 , SnO2  amphoteric oxides

N 2O5 , Mn2O7 , SO2  Acidic oxides

N 2O, CO  Neutral oxides

CaO  Basic oxide

58. Gypsum  CaSO4 .2 H 2O  2

Epsom salt  MgSO4 .7 H 2O  7

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 SRI CHAITANYA IIT ACADEMY, INDIA 11-11-23_Sr.Elite & Target _Jee-Main_RPTM-12_KEY & Sol'S
Dead burnt Gypsum  CaSO4  0
O
O OH

P P
HO
O
O O
P
OH
O
cyclotrimetaphosphoric acid

59.  156 & 3  bonds

60. White phosphorus  P4 

P
Bond angle  600
 X
P Atomicity =4
P X 60
   15
Y 4

MATHEMATICS
2  3i sin  1  2i sin  2  7i sin   6sin 2 
61.  
1  2i sin  1  2i sin  1  4sin 2 
Given sin   0    n , n  z
62.
   ,    2
 103   109  ( )103  ( 2 )109
     2 
   1  1
63. Apply modulus on both sides 1  1. 1  4     1  n 2  x 2  y 2
squaring on both sides 2.5.10    (1  n )  x  y
2 2 2

64. Let z  x  iy Given

x  i ( y  1)  ( x  2)  iy
x 2  ( y  1)2  ( x  2) 2  y 2
 x2  y 2  1  2 y  x2  4  4 x  y2
4x  2 y  3  0
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65.
x
log( x  iy )  log r  i tan 1
y
when r  x 2  y 2
log (1  2i )  log 5  i tan 1 2
66.
P  iq  Tan 1 ( x  iy )
P  iq  Tan 1 ( x  iy )
 x  iy  x  iy 
2 P  Tan 1  2 
 1 (x  y ) 
2

 x 2  y 2  2 x cot 2 P  1
67.
200
1 32 
(1  i 3) 200  2200   i 
 2 2 
   
 2200  cos  200  i sin  200 
 3 3 
 1 3
 2200   i 
 2 2 

 2199 1  i 3 
 2199  P  iq 
P  1, q   3
68.

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 (1  2i)(1  2i) 
2
(1  2i )2
12  18i  8i  12
25 1  4  4i  25  3  4i 
 
24  10i 24  10i


 75  100i  24  10i 
(24  10i)(24  10i )
1800  750i  2400i  1000
576  100
2800
Re alPart  
676

69. Statement I: z  i  z  i  Argz   Arg
2

Argz  Arg   1 and Arg z  Arg     2
2
Statement II: z1  z2  z3  6  6
 ( z1  1)  z2  2  z3  3  6
 1  2  3  6  12
z1  z2  z3
Is less than 12
Statement I is true, Statement II is false
i
z m
70. Statement I: 2  m does not represents a circle when 1
z 1 2 2
2
1 2 z 3 9 3
Statement II: Area z z sin   both statements are true
2 3 2 2 4
71. Note that
 8   8   8   8 
  cos    sin      cos    sin  
 11   11   11   11 
  cos  8   sin  8   1
11

10
1   11
Now,   k  0
k 0 1
 Statement -2 is true
 1
We have      10 etc.
 
Thus,
Re    2 3   4   5 
1

2
    2 3   4   5     2   3   4   5 
1 10 1 1
   k  (1)  
2 k 1 2 2
 Statement –I is also correct and Statement –II is a correct explanation for it.
Statement –II is true as it is formula for sun of a G.P.
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72. z k  cos  k   i sin(k )
15
 15   z (1  z 30 
f ( )   Im( z 2 k 1 )  Im   z 2 k 1   Im  2 
k 1  k 1   1 z 
But z 30  cos(30 )  i sin(30 )
When      / 60, z 30  0  i  i
 z (1  z 30 ) 
 f ( )  Im  
 1 z 
2

 1 i 
 Im  
 1/ z  z 
 1 i 
 Im  
 2i sin  
1 1
 Im(1  i) 
2sin  2sin 
73. Statement-II is true, as z 3  a 3  z 3  a 3  z  a
Next,
 z  ab 
3
 a 3  z  ab  a, aw, aw2
Let z1  a  ab, z2  aw  ab
and z3  aw2  ab
We gave z2  z1  a w  1  3a, z3  z2  3a, z1  z3  3a
Thus, statement-I is also true but statement-II is not a correct explanation of statement-I
74. Let z  x  iy, then
x  1  t, y  t 2  t  2
 t  1  x and y 2  t 2  t  2  (t  1/ 2) 2  7 / 4
 y 2  ( x  3 / 2)2  7 / 4.
This represent a hyperbola
75. z  1  z  3  10 the ellipse with foci at (-1,0), and (3,0) and length of major axis 10. Its
centre is (1,0), and its equation is
 x  1
2
y2
 1
25 21
Any point on the ellipse is P (1  5cos  , 21sin  ).
Its distance from A(7,0) is given by
AP 2  (5cos   6) 2  21sin 2 
 25cos 2   60 cos   36  21sin 2 
 21  36  4cos 2   60 cos 
 (2cos   15) 2  152  57
 132  152  57  AP 2  17 2  152  57
 226  225  AP 2  64  57
 1  AP 2  121
 1  AP  11

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 SRI CHAITANYA IIT ACADEMY, INDIA 11-11-23_Sr.Elite & Target _Jee-Main_RPTM-12_KEY & Sol'S
76.

. r. .
a
z1 z
b
z2
Two circles touch each others
z  z1  a  r  1

z  z2  b  r  2

1 2
z  z1  z  z2  a  b
A hyperbola
77. z12  z22  z32  z1 z2  z2 z3  z3 z4  0
 z3  0
z12  z22  z1 z2  0
( z1  z2 )2  3z1 z2  0
a 2  3b  0
a 2  3b
78. As R.H.S is real L.H.S must be real.
n
1 i   i  i 
2

  i
n
Also, is real when n is even 
1 i   1 i 
1  x2 1  1
As x  0 and   x    for x  1.
2x 2 x
Thus, we get only possible value of x is 1
 RHS  1 , thus, least value of n is 4
2 2
79. z1  z 2  z1  z2
2 2
 z1  z2  z1 z2  z1 z2
2 2
 z1  z2  z1 z2  z1 z2
z1 z2
 2( z1 z2  z1 z2 )  0   0
z1 z2
80. As AB=BC=CA, we get
1 1 1
2 z  1  1  2 z  z  and z    z is the point of intersection of circles
2 2 2
z  1/ 2 and z  1/ 2  1/ 2
1
z (1  3i )
4
81. Median of 1, 2, 3, 4, 6 is 3
Mn value
 3 1  3  2  3  3  3  4  3  6
 2 1 0 1 3  7

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 SRI CHAITANYA IIT ACADEMY, INDIA 11-11-23_Sr.Elite & Target _Jee-Main_RPTM-12_KEY & Sol'S
82. 3z  9  7i
 3( z  2  i )  3  4i
 3 z  2  i  3  4i
 3(10)  5
 35
Max value of 3z  9  7i  35
83. Given o,z1, z2 are the vertices of equilateral Triangle , Then
O 2  Z12  Z 21  O( Z1  Z 2 )  Z1Z 2
( Z1  Z 2 )2  3Z1 Z 2
a 2  3(12)
 a 6
 3 a  3  6  18
84. x 3  2 x 2  2 x  1  0 clearly x  1 satisfies the equation
So ( x  1)( x 2  x  1)  0
x  1,   2 ,   are the roots
Sum of 164th power of roots
 (1)164  ( 2 )164  (  )164
 1   328   164
 1   2  0
1  iZ Z (1  iZ )
85. Z1  
1 Z 2 (1  Z )  1
Z (1  Z )
Z
(1  i )(1  i (1  i)
 Z1   1  i
2(1  1  i )  1
3 24
Arg ( Z1 )    Arg ( Z1 )
4 
24 3
   18
 4
86. z  x  iy
x  iy  x 2  y 2  2  8i
x  x 2  y 2  2, y  8
x  x 2  64  2
x 2  64  (2  x) 2  x  15
87.  and  be the roots of the equation x 2  1  2i
 2  1  2i,  2  1  2i
8  8

 5
4 4
  8   8  2 8  2  2  2  50
88. x 4  x 2  1  0   x 2  x  1 x 2  x  1  0
 x   ,  2 where  is imaginary cube root of unity.
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 SRI CHAITANYA IIT ACADEMY, INDIA 11-11-23_Sr.Elite & Target _Jee-Main_RPTM-12_KEY & Sol'S

For x   and  2
 1011   2022   3033  1  1  1  1
For x   and   2 ,
 1011   2022   3033  1  1  1  1
89. z 5  ( z )5  (2  3i )5  (2  3i)5
 2( 5C0 25  5 C2 23 (3i) 2  5 C4 21 (3i ) 4 )
 3(32  10  8  ( 9)  5  2  18)
 244
90. zz ( z 2  z 2 )  350
We z  x  iy
2( x 2  y 2 )( x 2  y 2 )  350
( x 2  y 2 )( x 2  y 2 )  5  5  7
x 2  y 2  25, x 2  y 2  7
x  4, y  3
Asea  8  6  48

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