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Elite & Target(C-120, C-IPL & IPL-IC)_Jee Mains_RPTM-4 _KEY & Sol'S
Sri ChaitanyaIITAcademy.,India.
A.PT.S KARNATAKA TAMILNADU MAHARASTRA DELHI RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.Elite & Target(C-120, C-IPL & IPL-IC) JEE-MAIN Date: 09-09-2023
Time: 09.30Am to 12.30Pm RPTM -4 Max. Marks: 300
KEY SHEET
PHYSICS
1) 4 2) 1 3) 4 4) 4 5) 4
6) 2 7) 3 8) 3 9) 2 10) 3
11) 1 12) 2 13) 1 14) 4 15) 4
16) 4 17) 2 18) 1 19) 2 20) 1
21) 10 22) 25 23) 50 24) 7 25) 1
26) 40 27) 50 28) 12 29) 210 30) 25
CHEMISTRY
31) 3 32) 4 33) 1 34) 4 35) 4
36) 3 37) 1 38) 3 39) 2 40) 3
41) 1 42) 1 43) 2 44) 1 45) 1
46) 3 47) 1 48) 3 49) 2 50) 1
51) 3 52) 10 53) 4 54) 12 55) 6
56) 9 57) 5 58) 2 59) 2 60) 3
MATHEMATICS
61) 2 62) 4 63) 1 64) 1 65) 3
66) 4 67) 1 68) 2 69) 3 70) 4
71) 2 72) 4 73) 4 74) 1 75) 1
76) 4 77) 1 78) 4 79) 2 80) 2
81) 3 82) 4 83) 1 84) 0 85) 2
86) 1 87) 6 88) 1 89) 2 90) 2
SOLUTIONS
PHYSICS
f μ mg V u 20 0
1. We have a= = =μg Also, a 4m / s
m m t 5
4
So, μg=4 = 0.4
10
μMg
2. Retardation due to friction= =μg
M
v2 u2 16
Now, s= = =2m
2a 0.4 10 2
10 f 4( M 2kg , a 2m / s 2 , 30 0 given) f 6 N
F 10 6 4 F 20 N
kg
g
2k
mv 2
T sin ...........(i )
r
T cos mg ...........(ii )
v2
From equation (i) & (ii) we have, tan
rg
v 2 rg 450
7.
1
K .EX P.EX K .EY P.EY mV 2 mgR cos sin V 2 2 gR cos sin
2
mV 2 2
At Y, =mg sin NY 0 2mg cos sin mg sin sin cos
R 3
1 1
8. By work-energy thorem W K W m(v 2f vi2 ) W 1 (162 42 )
2 2
1
W 240 W 120 J
2
9. Position , x 3t 2 5
dx d (3t 2 5)
Velocity, V = v v 6t 0
dt dt
At t = 0 V=0
Sec:Sr.Elite& Target(C-120, C-IPL & IPL-IC) Page 3
SRI CHAITANYA IIT ACADEMY, INDIA 09-09-2023_Sr.Elite & Target(C-120, C-IPL & IPL-IC)_Jee Mains_RPTM-4 _KEY & Sol'S
u K
10. F rˆ 3 rˆ
r r
14.
P F .v ma at ma 2 t asu 0
2
v mv 2 t
m 1 t 21
As a v1 / t1
t1 t1
km 5
v 7.2 7.2 2 m /s
15. h 18
Slope is given 1 in 20
1
\ sin
20
When man and cycle moves up then component of weight opposes it motion i.e.
F mg sin
1
So power of the man P F v mg sin v = 100 9 .8 2 98 Watt
20
16. When two bodies have same momentum then lighter body possess more kinetic energy
2
because E P
2m
1
\ E when P = constant
m
17. P F.vand unit of power is Watt.
18. The work done on the spring against the restoring force is stored as potential energy in
both conditions when it is compressed or stretched.
19. Conceptual
20. Suppose the roller is pushed as in figure (b). The force F is resolved into two
components, horizontal component FH which helps the roller to move forward, and the
vertical component acting downwards adds to the weight. Thus weight is increased. But
in the case of pull [fig (a)] the vertical component is opposite to its weight. Thus weight is
reduced. So pulling is easier than pushing the lawn roller.
v2
21. From, tan
rg
v2 10×10
r = =10m
g tan 10×tan450
u2 (10 )2
22. S 25 m
2 g 2 0 . 2 10
v rg 0 . 5 500 10 50 m / s
23.
W F.r (5ˆi 3 ˆj 2kˆ ).(2ˆi ˆj) 10 3 7 J
24.
Second condition
Initial velocity = u/2, Final velocity = 0
2
From v 2 u 2 2ax Þ 0 u 2ax
4
2 2
\ x u u 8 s 2 s / 3 1 cm
4 2 a 4 2 3u
v
100 m 30 m 20 m
26.
Sec:Sr.Elite& Target(C-120, C-IPL & IPL-IC) Page 5
SRI CHAITANYA IIT ACADEMY, INDIA 09-09-2023_Sr.Elite & Target(C-120, C-IPL & IPL-IC)_Jee Mains_RPTM-4 _KEY & Sol'S
Ball starts from the top of a hill which is 100 m high and finally rolls down to a horizontal
base which is 20 m above the ground so from the conservation of energy
1
mg (h1 h2 ) mv 2
2
Þ v 2 g(h1 h2 ) 2 10 (100 20) 1600 40 m/s .
27. F.B.D. of the block is shown in the diagram Since, block is at rest,
fr mg 0 ....(i)
F-N=0 ....(ii)
fr
F
m
N
mg
fr N
mV 2 max mV 2 max
28. f s , max mg Vmax Rg
R R
V2,max R2 R2 48 4
So, V2,max V1,max 15 15 12
V1,max R1 R1 75 5
29. Given,
Force,F=(5y+20) j
10
5 y2 6 5
Work done, W= F .dy W 5 y 20 dy 20 y 36 20 6 210
0 2 0 2
30. Loss in potential energy=gain in kinetic energy Take zero potential energy at table, initial
potential energy = 2 10 1 20J
3
Final potential energy= 3 10 45 J
2
K 25
Sec:Sr.Elite& Target(C-120, C-IPL & IPL-IC) Page 6
SRI CHAITANYA IIT ACADEMY, INDIA 09-09-2023_Sr.Elite & Target(C-120, C-IPL & IPL-IC)_Jee Mains_RPTM-4 _KEY & Sol'S
CHEMISTRY
31. SN1 reaction involves formation of carbocation intermediate. This reaction is favoured in
polar solvents . It involves racemization if reactant is optically active
32. Correct assertion The bond enthalpies of the two O H bonds in H O H are not equal.
Correct reason This is because electronic environment around O in not same after
breakage of one O H bond
33. The thermal Stability of carbonates increases down the group. Hence Li2CO3 is least stable
Due to small size of Li strong polarising power distorts the electron cloud of CO32-High
lattice energy of Li2O than Li2CO also favours the decomposition of Li2CO3
Correct Assertion KCN reacts with methyl chloride to give the mixture of methyl cyanide
and methyl isocyanide in which methyl cyanide predominates because of stable C C
bond in methyl cyanide.
Correct Reason This reaction proceeds through S N 2 mechanism, in which OH ion attacks
at 1800 to the halogen atom of 2-bromooctane which leads to the inversion of
configuration.
36. The bond formed between C of benzene ring and halogen is more stable because of
resonance it has partial double bond character. So, rate of reaction towards nucleophilic
substitution is slow. This substitution is facilitated by the presence of electron
withdrawing group at ortho and para position because electron density is high at these
positions.
Compound (ii) and (iii) both has one electron withdrawing group but in compound (i)
electron withdrawing NO2 group is present at ortho position, so rate of reaction in
compound (ii) is more than that of (iii) while (i) has no electron withdrawing group.
37. Density is directly related to molecular mass Higher the molecular mass higher w the
density of the compound. Among the four given compounds he molecular mass is
38. Conceptual
39. Conceptual
40. Conceptual
42. Conceptual
44. Presence of electron withdrawing group at Ortho and para positions increases rate of
reaction Carbanion formed is stabilized by resonance and the negative charge appearing
at Ortho and para positions with respect to the halogen substituent is stabilized by NO 2
group Electron withdrawing group at meta position does not influence the rate of the
reaction.
45. Conceptual
46. Among the given options Be2 ion has highest hydration enthalpy. It is because hydration
enthalpy increases with decrease in size of ions i.e.the smaller size of cation, more will be
the hydration enthalpy of ion.
47. Dipole moment is defined as the measure of polarity of a chemical bond between two
atom in a molecules i.e. separation of two opposite electrical charges.
48. In CuSO4. 5H 2O four water molecule are co-ordinated to Cu 2 and onehydrogen bonded
with SO42
49. Conceptual
50. Conceptual
53. R O R NaBH 4
NaH B2 H 6
55. Conceptual
56.
total noof
. bonds
B.O.
total resonating structures
5
for PO43 1.25
4
x
B.O. of CO 3 3 1.25
2
x 8.5
57.
Cl CH CCl3
Cl
59. Conceptual
60. Conceptual
MATHEMATICS
63.
x2 t
t A B
(t 1)(t 9) t 1 t 9
1 1
A ,B
8 8
1 1 1 1 1
I 2
8 x 1 x 9
2
dx tan 1 ( x 2 1) tan 1 ( x 2 9) C
8 3
xe x 2e x
I
x3 xe x
64.
3 x 2 xe x e x 3x 2 3e x
dx
x 3 xe x
3 x 2 xe x e x
x3 xe x dx 3dx
3 x 2 xe x e x dx dt
dt
3n x C
t
x3 xe x
n t 3n x C n 3 C
x
ex
n 1 2 C
x
1 cos 2 x
65. I sec 2 x 1dx dx
cos 2 x
2 sin x
2 cos 2 1
dx put cos x t sin xdx
dt
I 2 2t 2 1
2 dt 1 1
n t t 2 C n cos x cos 2 x C
2 1
2 2 2
t2
2
n 2 cos x cos 2 x n2 C
x2 1 2 x 1 2 x 1
66. I ex 2
dx e x 2
dx e x C
(x 1) (x 1) x 1 (x 1) x 1
2
x 1
f (x)
x 1
2 4 12 4
f '(x) , f ''(x) , f ''(x) , f ''(2)
(x 1) 2
(x 1) 3
(x 1) 4
27
2
( x) ( x ) 1 ( x)
67. I d log .log log C
f ( x) f ( x) 2 f ( x)
68.
1 x2
sec 1 1 x 2 tan 1 x, cos 1 1
2 tan x
1 x
2
tan
1
e tan x
x 2 tan 1 x dx
2
I 1
1 x2
1
tan 1 x z dx dz
x x2
e z ( z 2 2 z )dz e z .z 2 C
1
e tan x
(sec 1 1 x 2 ) 2 C
1 1 x 1 4sin 2 1 cos 2
69. x 1 x dx, put x cos 2 cos 2 tan ( 4sin cos )d cos 2 d 2 cos 2 d
2 sec 2 1 d
1 1 x2
n cos 1 x
x
C
f (x)
1
1 1
f (x) n 2 cos 1 1 n sec 2 tan 2
1
2
2
tan x(sin x) 2022 2022 tan x(sin x) 2023 cos xdx 2022(sin x) 2022 dx C tan x(sin x) 2022 C
71.
1
1 cos x sin x dx
3 3
2
I
3
sin 2 x
2
3 1
(cos x sin x)dx
2 2
sin sin 2 x
3
3 1 3 1
cos x cos x sin x sin x dx
2 2 2 2
2sin x cos x
6 6
cos x sin x
6 6
dx
2sin x cos x
6 6
1 dx dx
2
sin x cos x
6 6
1 x x
n tan n tan C
2 2 12 4 2 12
x
tan
1 2 12 C
n
2 x
tan
2 6
72.
s in 2 x.cos 2 xdx
( s in 3 x cos 3 x) 2
s in 2 x cos 2 xdx
cos 6 x(1 tan 3 x) 2
tan 2 x sec2 xdx
(1 tan 3 x) 2
1 dz 1 1
2 C C
3 z 3z 3(1 tan 3 x)
1 tan 3 x z
3 tan 2 x sec 2 xdx dz
73.
1
2
I cos x cos5 xdx
1 sin 5 x
sin x C
2 10
2,10
74.
1
32
I sin 32 xdx
1
cos 32 x C
1024
2
b 4ac b 2
ax bx c a x
2
2a 4a
75. dx dx
2
ax bx c b
2
a x K
2
2 a
4ac b 2
where K 2 0, which will have an answer of the type
4a
b
x
1
.
1
tan 1 2a C
1
a K/ a K / a
x A
or tan 1 C1
B
76. Since,
cot 1 x tan 1 x
2
1 x
2 tan
2t an 1x d (tan 1 x) C
n 2
2
x 3 dx
I
x
2
x2 1 2
x
2 2
77. Put x 2 2 1 t 2 x 3 dx dt
x x
1 dt
I t C
2 t
78.
dx
2 4
x 4
x sin 3
cos 3 x
cos
3
4
cos 3 x
2
sec xdx
4
tan 3 x
2 x12 5 x9 2 x12 5 x9
79. (3x5 x3 1)3 dx ( x15 (3 x 2 x 5 )3
3 x 2 x 5 t
2 5
6 dx
3 2 5
x 2 x 5 3 3 6 dx dt
(3 x x ) x x
dt 1 1
3
2 C 2
C
t 2t 1 1
23 2 5
x x
10
x
C
2(3 x x 3 1)
5
2
5 5
2 x 2 dx 2 x dx
2
2 2
5
x x2 2x
5
80. 2 2 sin 1 C
2 4 5
K 4
1 x2
81. sec1 1 x 2 tan 1 x,cos 1 1
2 tan x( for x 0)
1 x
2
1
e tan x
2
I (tan 1 x)2 2 tan 1 x dx
1 x
1
tan 1 x z dx dz
1 x2
e z ( z 2 2 z )dz e z .z 2 C
1
e tan x
(sec 1 1 x 2 )2 C
5sin x dx
I
sin x 2 cos x
82. Now,5sin x (sin x 2 cos x ) (cos x 2 sin x )
1 , 2
1
1 x
1 1 2 e x dx
x
I e x dx
x x
83.
1 2
tan x z
sec 2 xdx dz
z5 tan 5 x
z 4 dz C C
5 5
tan 5 x
0 x6 C
5
1
a , b 0 ab 0
5
dx
2
1 3
2
x
2 4
1 3 2x 1
85. x tan tan
2 2 3
3
dx sec 2 d
2
3
sec 2 d
2 8 3
9
9
sec 4
16
8 3 1
1 cos 2 d
9 2
4 3 sin 2
C
9 2
4 3 2 3
sin 2 C
9 9
4 3 2x 1 1 2x 1
tan 1 2 C
9 3 3 x x 1
4 3 1
a b
9 3
43 2 6
3a 2b 2
9 3 3
cos 2 d
2 tan
sin 2
1 tan 2
2x 1
2
3
1 4x2 1 4x
3
2x 1
2
2
3
4x 4x 4
3
3 2x 1
2 x2 x 1
x cos x
I x sec xdx
( x sin x cos x) 2
86.
x cos x dx
( x sin x cos x)2
x sin x cos x t
x cos xdx dt
dt 1 1
t 2
t x sin x cos x
x cos x
I x sec x dx x sec tan x sec x
( x sin x cos x ) 2
dx
I
x (1 nx)(2 nx)(3 nx)
1
87. nx t dx dt
x
dt
(t 1)(t 2)(t 3)
1 1 1 1 1
dt
2 (1 t ) t 2 2 t 3
1 1
n 1 nx n 2 nx n 3 nx C
2 2
p 1, q 2, r 3
I x x (1 x x log x)dx
let x x 1 t ( x 1)nx nt
( x 1) 1
nx dx dt
x t
88.
x 1 xnx
x x 1 dx dt
x
x x (1 x xnx)dx dt
I dt t C x x 1 C
cos x sin x z
( sin x cos x)dx dz
dz 2
sin 1 C
9 z2 3
sin x cos x
sin 1 C
3
1
A 1, B
3
1 1
1 1 2 dz
z 12 2
z dz z 1 1
90. I 4 dz put z v 1 2 dz dv
z 1 1 1
2
z z
z2 2
z z 2
z
dv
v 2
2
1 v
tan 1 C
2 2
x 1
x x x
1 1 C
tan
2 2