SRI CHAITANYA IIT ACADEMY, INDIA 20-04-2024_Sr.

C-120_Jee-Mains_ WTM-30_KEY & Sol’S

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur – Hyderabad
Sec: Sr. C-120 Jee Main Date: 20-04-24
Time: 09.30Am to 12.30Noon WTM-30 Max. Marks: 300

KEY SHEET
PHYSICS
1) 1 2) 3 3) 1 4) 1 5) 1
6) 2 7) 4 8) 3 9) 4 10) 1
11) 2 12) 2 13) 3 14) 2 15) 1
16) 3 17) 2 18) 4 19) 4 20) 2
21) 1305 22) 24 23) 9 24) 110 25) 35
26) 60 27) 80 28) 360 29) 8 30) 3
CHEMISTRY
31) 2 32) 2 33) 3 34) 2 35) 4
36) 1 37) 3 38) 1 39) 4 40) 2
41) 4 42) 4 43) 2 44) 4 45) 2
46) 1 47) 1 48) 2 49) 1 50) 1
51) 5 52) 2691 53) 4 54) 4 55) 5
56) 5 57) 7 58) 4 59) 175 60) 6
MATHEMATICS
61) 3 62) 1 63) 3 64) 1 65) 2
66) 1 67) 3 68) 4 69) 2 70) 3
71) 2 72) 2 73) 2 74) 4 75) 2
76) 3 77) 3 78) 2 79) 3 80) 4
81) 0 82) 7 83) 1 84) 4 85) 160
86) 6 87) 1 88) 10 89) 210 90) 5

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SOLUTIONS
PHYSICS
2   40
1.     40cm Separation between two consecutive nodes    20cm
 20 2 2
1
2. At t = 2 s y or x  vt  x  1 1  vt 11 v2  v  0.5m / s
1  ( x  1) 2 
d2y 2
2 d y
3. The correct form of differential eqn. of a wave is v
dt 2 dx 2
4. Conceptual
5. For producing stationary waves, the two transverse waves must be travelling in opposite
directions. Therefore, y1 and y2 is the only combination
6. Tension T in the wire = v 2   (400)2  103  160 N
T (m1  m2 )
Force applied F 
m1
40 kg 20 kg
m1 m2 F
T

(40  20)
 160   240 N
40
1 1
7. Assume  A cos  (i)  A sin  (ii)
a b
On simplifying, we get y  A sin (t   )
ab
Squaring and adding Eqs. (i) and (ii) A 
ab
8. Second overtone means three loops.

A1 A2 A3

 2L
3  L (OR) 
2 3
 3 5 L 3L 5L
Antinodes will be obtained at , , or , and
4 4 4 6 6 6
9. Conceptual

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10. Energy is not propagated in stationary waves

11. Conceptual
 Y0
12. VP max  4V Or Y0  4  f   Or Y0  2 f   4 f   
2
13. 
y2  5 sin 5 t  3 cos 5 t 
5 3 10



3


5
  A 1
This can also be written as y2  10sin  5 t   A1  10 and A2  10  1 
 3 A2 1
14. Conceptual
   
15. x  a sin   t   x1  a cos wt  a sin   t  
 6  2
Therefore, phase difference =  / 2    / 6 =  / 3
16. Conceptual
Mass 102 T 1.6
17. For string,   2.5  102 kg/m Velocity v  
Length 0.4  2.5  102
= 8 m/s For constructive interference between successive pulses.
21 2(0.4)
tmin    0.1 s
v 8
2
18.   .x  k  x   k (v t ) Here vt= distance travelled by insect in given time interval.

(Or)
  (20 )(5 102  5)
 5
19. Conceptual
20. Conceptual
21. Given, mass per unit length,   0.145 g / cm transverse wave equation,
y  0.21sin( x  30t ) From given equation,   30 rad / s , k=1
w 30 T 0.145 103
Speed of wave v    30ms 1 Also v   T  v2  T  (30) 2 
k 1  102
900  0.0145  13.05N 1305  102 N Hence, x  1305

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 2  2
22.   3 f   1.5 x  1.0cm   x   1
2  8 
  16cm v  f   16  1.5  24 cm / s
2 2
 T    30 
23. v  T      104    0.09 N
k  k  1 
0.035 T 77  5.5
24. m kg / m , T  77 N V   110 m / s
5.5 m 0.035
25. Density of wire,   8 103 kg / cm3  8 103 kg / cm3
N
Strain, in the wire,   4.9  104 Young’s modulus of wire is Y  8  1010
m2
1 T
Lowest frequency of vibration in wire will be f  ……(i)
2L M / L
T T T T T
Now,    But  stress  Y  strain=Y  e
 M / L  V  / L  LA.  A A
 
 L 
T Y  1 T 1 Y 
  So, Fore eq (i), frequency will be f  
M /L  2 L ( M / L) 2 L 
1 8  1010  49  10 4
  35 Hz
2 1 8  103
26. When the string is plucked in the middle, it vibrates in one loop with nodes at fixed ends and
an antinode in the middle

N N
A

1
So that,  1 (OR) 1  2  30  60cm
2
27. Given equation of stationary wave is Y  0.6sin(0.157 x)cos(200 t ) comparing it with
general equation of stationary wave, i.e Y  A sin kx cos  t ,
k   2    0.157 2  1 
We get    4 2   0.157  …… (i)
0.157  2 
2 1
And   200  T  s
T 20
As the possible wavelength associate with nth harmonic of a vibrating string, i.e. fixed at
both ends is given as

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2l 
 or l  n   Now, according to question, string is fixed from both ends and oscillates
n 2

in 4th harmonic, so 4    l  2  l (OR) l  2  4 2  8 2 (Using Eq.(i)
2
2
Now   10  l  80m
v
28. Frequency of vibration of a string in nth harmonic is given by f n  n. ……… (i)
2l
Where , V= speed of sound and
l = length of string
Here, f3  270 Hz , l =2 m and n=3
Substituting these values in eq(i) we get
v
 270  3 
2 2
4  270
v   360ms 1
3
29. As wave train moves up over string tension and hence wave speed also charges. Also,
frequency(f) wave train remains constant as it depends only on the source.

2

12 m 6 kg

1

2 kg

T
Now, Using v 

Where , V= wave speed, T= tension in string and  = mass per unit length of string.
Tension T1 at bottom= 2 kg,
Tension T2 at top=(2+6)kg=8kg
If 1 and 2 wavelengths at bottom and top, then
T1
v1 f 1 
 
v2 f 2 T2

T2
 2  1
T1

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 SRI CHAITANYA IIT ACADEMY, INDIA 20-04-2024_Sr. C-120_Jee-Mains_ WTM-30_KEY & Sol’S

8g
 4  8cm
2g
30. Speed of transverse wave over a string.
T
v ……(i)

Where T= tension or force on string
m
And  = = mass per unit length.
l
Also, young’s modulus of string
TI YAl
Y T  ………(ii)
Al l
2 YAl mv 2
From Eqs.(i) and (ii), we have v  or I  …………….(iii)
l YA
Here, m = 6g  6 103 kg , l  60cm
 60 102 m, A  1mm2
 1 106 m 2 ,
Y  15  1011 Nm 2 and v  90ms 1
Substituting these given values in Eq. (iii), we get
2
6  103   90 
I  11 6
 3.24  105 m
15  10  1  10

CHEMISTRY
31. Molar mass of CrCl3H12O 6 is 266.5
It loses 13.5% mass due to water which is 36g.
Therefore, the correct formula is Cr  H 2O 4 Cl2  Cl .2H 2O
32. Two oxygen donor atoms and two nitrogen donor atoms.
33. (i)  Pt(NH3 )6  Cl4 Gives five ions
(ii) Cr(NH3 )6  Cl3 Gives four ions
(iii) Co(H2O)5 Cl Cl2 Gives three ions
(iv) NaCl Gives two ions

34. Cr  H 2O  4 Cl 2  Cl  AgNO3 
 Cr  H 2O 4 Cl 2   AgCl
Number of milli moles of chloride ions = Number of milli moles of AgNO3
 100  0.2  20
35. Conceptual

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36. A Ligand that tends to bind the central atom through two different donor atoms and lead to
the formation of linkage isomers is known as ambidentate ligand, for example: NO2.
37. Correct acidic strength Mn2O7  MnO2  Mn2O3  Mn3O4  MnO
38. IUPAC name is Sodium pentacyanonitrosyl ferrate(II)
39. Conceptual
40. K 2Cr2O7 and KMnO 4 there is no unpaired electrons but exhibit colour due to charge transfer
phenomena.
41. CsI3  Cs  I3
42. I2O5 is strong oxidising agent and used in estimation of CO

43. 2NaOH  Cl2  NaCl  NaClO  H 2O

44. Ka value increases from H2O to H2Te.
45. Bond energy: Cl2  Br2  F2  I2
46. Iodine and oxygen bond is more polar than chlorine and oxygen bond.
47. Due to smaller size in Fluorine it has less electron effinity
48. I2 is having maximum Vander Waal’s force
49. Fluorine having high reduction potential value
50. Fluorine has 1 oxidation state only
(NUMERICAL VALUE TYPE)
51.
CH2 COO
OOC CH2
N CH2 CH2 N
H CH2 COO

52. CO  NH3 6  Cl3  3AgNO3  3AgCl 

Number of moles of Cl = Number of moles of Ag 
0.3  3 0.125  x

267.5 1000
Therefore, X = 26.91 mL
100 X = 2691
53. SCN & NO2 are ambidentate ligands
54. MnO4 is purple in colour, tetrahedral shaped and diamagnetic whereas MnO42 is green in
colour, tetrahedral shaped and paramagnetic.
55. 2MnO4  H2O+KI  2MnO2  2KOH+KIO3
56. Electronic configuration of Cl is [Ne]3s23p5.

In its first excited state, one valence electron of Cl excited to empty 3d orbital and its
electronic configuration becomes [Ne]3s23p43d1.

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In its second excited state, another valence electron of Cl excited to empty 3d orbital and its
electronic configuration becomes [Ne]3s23p33d2.

As there are five unpaired electrons, therefore it can form five bonds. This implies that at the
second excited state of Cl, covalency of Cl is 5.

57. HClO 4 anhydride is Cl 2O 7

58.
heat
Na2 SO3  S  Na2S2O3
2 Na2S2O3  I 2  Na2S4O 6  2 NaI .

7
59. ClO4 bond order   1.75
4
2
60. 2 KMnO4  5H 2C 2 O 4  3H 2 SO4  K 2 SO4 2 Mn SO4  10CO2  8H 2O
Mn 2  has 5 unpaired electrons therefore the magnetic moment is n  n  2
5  5  2   35  5.91  6BM

MATHEMATICS
2 2 2
61.  x  1 1  0  x  1   i   0  x  1  i  x+1  i   0
 1  i   1  i  7 7
x  , So,  15   15   2      2  
  let    let 
 128  i  1  i  1  256
62. x 2  mx  4  0  ,  1,5 1 D  0  m 2  16  0
 m   , 4    4,    2  f 1  0  5  m  0  m   ,5
29 
 3 f 5   0  29  5m  0  m   ,
 5 
b m
 4 1   5  1   5  m   2,10   m   4,5
2a 2

63. 6 x 2  11x    0 Given roots are rational  D must be perfect square

 121  24   2  maximum value of  is 5   1    I
  2 I  3 I   4 I
 5I Number of values = 3

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1 y
64. y  4 y4 5 y 2  20 y  4  0

5 
1  5 y  1
 y 

20  480 20  480
y y Rejected
10 10
2 20
65. 1  x  2 x   a0  a1 x  .....  a40 x 40 Put x  1, 1
20
 a0  a1  a2  ....  a40  4 a0  a1  a2  ....  a40  2 20
19
20! 2  1
 20  2019  a1  a3  ....  a37  2  220  1  20   219  220  21
19
Here a39 
19!
60 60 r r 60 r
66.  3 5
1
4
1
8
 60
Cr 3   5  1
4
1
8
Cr  3 
60
4
r
5 8 For rational terms.
r 60
 k : 0  r  60 0  8k  60 0  k  0  k  7.5
8 8
60  8k
k  0,1,2,3,4,5,6,7 is always divisible by 4 for al value of k.
4
Total rational terms  8 Total terms  61 Irrational terms  53
n  1  53  1  52 52 is divisible by 26.
3n
3 n 3 n
67. 1  x  x    a x 1  x  x  j
j
 a0  a1 x  a2 x 2 .....  a3 n x 3 n
j 0
 3n   3n 1 
 2   2 

a
j 0
2j  Sum of a0  a2  a4 ...... a
j 0
2 j 1  Sum of a1  a3  a5 ......

Put x  1
1  a0  a1  a2  a3 .....  a3 n ………(A) put x  1
1  a0  a1  a2  a3 .....   1 3n a3 n ….(B)
Solving (A) and (B)
 3n   3 n 1 
   
 2   2 
a0  a2  a4 .....  1 a1  a3  a5 .....  0 a
j 0
2j 4 j 0
a2 j 1  1
6
68.  6
Cr . 6C6 r  6C0 . 6C6  6C1. 6C5  .......  6C6 . 6C0
R 0
6 6
Now, 1  x  1  x    6C0  6C1 x  6C2 x 2  ....  6C6 x 6 
C 6
0  6C1 x  6C2 x 2  ....  6C6 x 6  Comparing coefficient of x 6 both sides
6
C0 . 6C6  6C1  6C5  .......  6C6 . 6C0  12C6  924

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100 2 100
 3 1   1   1  1
69.  x  3  1  1 100 C1  x3  3  100 C2  x 3  3   ............ 100 C100  x 3  3 
 x   x   x   x 
No terms  1  2  2..... (100 times)  201
10
10 10  1 1 1 10
70.  ab  bc  ca    abc       Coeff of a10b 7c3  ab  bc  ca 
a b c
10
1 1 1
0 3 7 10!
 co eff of a b c in       120
a b c 3!7!
4 5
71. T5  nC4 a n 4  2b  And T6  nC5a n 5  2b  As T5  T6  0, we get
n 4 n 4 4 n 5 n 5 5 a n  4b 4 n !25 4! n  4 ! a 2n  4
C4 2 a b  C5 2 a b Or n 5 5  . Or 
a b 5! n  5 ! n !2 4 b 5
30 30
72. 1  x   30C0 x 0 30 C1 x1  30 C2 x 2  ........   1 C30 x 30
30
 x  1  30c0 x30  30c1 x 29  .................  30c30
Multiplying (1) and (2) and equating the coefficient of x 20 on both sides, we get required
30
sum is equal to coefficient of x 20 in 1  x 2  , which is given by 30C10 .
73. We have, f  x   x n . So
f 1  x   nx n 1  f 1 1  n
f 2  x   n  n  1 x n 2  f 2 1  n  n  1
f 3  x   n  n  1 n  2  x n 3  f 3 1  n  n  1 n  2 
f n  x   n  n  1 n  2  ...1  f n 1  n  n  1 n  2 ...1
f 1 1 f 2 1 f n 1
 f 1    .... 
1 2! n!
n n  n  1 n  n  1 n  2  n  n  1 n  2  ...1
 1   .... 
1 2! 3! n!
n n n n
 C0  C1  C2  ...  Cn
 2n

n n
r 1 Cr 1 n r 1 1 n
74.    1    1 n 1Cr 1   0  1   n  1  
r 1  r  1 n  1 r 1 n 1 n 1

75. The given expression is the coefficient of x 4 in

4 404 303 202 101
C0 1  x   4C1 1  x   4C2 1  x   4C3 1  x   4C4
101 4 4
 Coefficient of x 4 in 1  x   1
 
 Coefficient of x 4 in  C1 x  101C2 x 2  ....
101

4
 101
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2 2010
76. Put x   ,  2 3       a0  a1  a2 2  ...
 22010  a0  a1  a2 2  a3  a4  ... and 22010  a0  a1 2  a2  a3  a4 2  ...
Adding (1) and (2) , we have 2  22010  2a0  a1  a2  2a3  a4  a5  2a6  .....
1
9   0
9
 1 q  6
77. G.E   px 6  1  ; r    3
 x 3 1 1

6 3
3
Independent term T4  9C3 .P 6 q 3  9C3  p 2 q  Maximum of T4 is 9C3 =84
10 2 10
78. a1 = coefficient of x in 1  2 x  3 x 2  = coefficient of x in  1  2 x   3x 
= coefficient of x in  10 10
C0 1  2 x   10C1 1  2 x  3x 2  ......
9

10 10
= coefficient of x in 10C0 1  2 x  C0 2.10C1  20
9 7
79. 7 9  97   8  1   8  1
  89  9C1.88  9C2 .87  9C3 .86  ...  9C3.8  1  87  7C1.86  7C2 .85  ....  7C6 .8  1
 89  9.88  87  9C2  1 86   9C3  7   85  9C4  7C2   ....  8  9C3  7C6 
 64  79  97 is divisible by 16. Statement-1 is true. Statement -2 is false.
80. 1  ax 
10 10
 2 4
 1  ax   2 1  10C2  ax   10C4  ax   10C6  ax   10C8  ax   10C10  ax 
8 8 10

Number of distinct terms=6
 Statement-1 is false but Statement -2 is obviously true.
2 2007 3 2007
81. 1  x 1  x 
2007
1  x  x  1  x  1  x  1  x   2007

C0  2007 C1  x 3   ......

General term 1  x   1  r 2007

C r x 3r   1 r 2007Cr x3r   1 r 2007Cr x3r 1
2012 2011
3r  2012 r  3r  1  2012 3r  2011 r
3 3
2012 2012
Hence there is no term containing x .So coefficient of x 0
9 11
Cr 1 9 12 1 2035
82.    Cr 1   212  26    m  n  2041
r 1 r  1 12 r 1 12 6
32 2t
83. Let 3232  t 6432  64t  8 2 t   9  1  9k  1 Hence remainder  1
3762
84.  2023  2   2023K1  23762  17 K 2  23762  as 2023  17  17  9 
940
 17 K 2  4  17  1  17K2  4 17K3  1  17 K  4  remainder  4
10 10
85.  r ! r  1 r  2  r  3  9  r  1  8   r  3!  r  1!  8 r  1! r !
r 1 r 1

 13! 12! 2! 3!  811! 1  12.13  12  8.11! 8  8

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 16011! Hence   160

n
n
 1  k  3  k  7  k  15  k  37  k 
86. A Ck               
k 0   2   4   8   16   32  
n n n n n
 1   3   7   15   31 
A  1    1    1    1    1  
 2   4   8   16   32 
  1 5   1 
1  n    1  5n 
1 2 2  1 1
A n     A  n  2n  1 A  1  5 n , Given 63A  1  30
2  1 1 
 n 
 2  1 2 2
 2 
Clearly 5n  30 n6
1  n r 1 r t 
n
1 n n r 
87. G.E  Lt n   Cr  Ct 5   Lt n   Cr 1  5   5r 
n  7 n  7
 r 1 t 0   r 1 
1 n n n
 1 n
 Lt n   Cr 6   nCr 5r 
n  7
r
 Lt
n  7 n  7  6n   1
 r 1 r 1 
10
  1 3 3

10
  x 3   1 1 1   1 1
 1 10
1
  x  12
2
 
 3  x 2
 1    4
     x  1  1    x  x   10c4  1  210
3 2
88.  2 1 1
 x3  x3 1 x  x2    x 2   
  
 
n n n
1 n  n  1  n 1  1
89.
 13
Last term of  2 

1 
2
 is Tn1  Cn 2
n 3
  
 2
n
  Cn  1 n 2  n 2
2 2
log3 8
 1  1   3  log 3 2  2
5 3 5

Also, we have  5    3
3 3   5 3log3 2
3 3
n n 10

Thus,
 1
 2 5
Or
 1

 1
Or
n
 5 Or n  10
n n
22 2 2 25 2
101 4 6 4
 1  10! 13
Now, T5  T41  C4 2 10
  1
3


  4!6! 2
2
   1
4
 
2
1
2

6
 210  2 2  1  2 2   210
3
90.   0,   1,  1,    1  0
2 2
   1 
GE       1  03 2  5
 1  1    1 

Sec: Sr.C 120 Page 12