Key sheet for Physics, Chemistry and Mathematics exam

Sec: SR.
IIT_COSC GTM-36 Date: 09-05-21

Time: 3 Hrs Max.Marks: 300
KEY SHEET
PHYSICS
1 1 2 1 3 1 4 1 5 3
6 3 7 2 8 1 9 2 10 1
11 3 12 3 13 2 14 2 15 3
16 3 17 3 18 3 19 4 20 4
21 65 22 4 23 3 24 5 25 3
26 8 27 55 28 4 29 2 30 2
CHEMISTRY
31 3 32 3 33 3 34 4 35 3
36 1 37 1 38 1 39 3 40 3
41 3 42 4 43 1 44 1 45 3
46 3 47 2 48 4 49 2 50 3
51 3 52 3 53 3 54 3 55 8
56 4 57 2 58 100 59 3 60 100
MATHEMATICS
61 4 62 4 63 2 64 2 65 3
66 4 67 2 68 2 69 3 70 2
71 4 72 2 73 4 74 4 75 3
76 1 77 3 78 1 79 3 80 1
81 30 82 141 83 2 84 25 85 56
86 2 87 5 88 524 89 2 90 4
Narayana IIT Academy 09-05-21_Sr.IIT CO SC_ JEE-MAIN_GTM-36_Key & Sol
SOLUTIONS
PHYSICS
vB  vT  gt  vT  9.8  0.5
1.
or vB  vT  4.9 (1)
Further,
vB 2  vT 2  2 gs  vT 2  2  9.8  3
or vB 2  vT 2  58.8 (2)
Solving Eqs. (1) and (2) , we get
vB  vT  12 m / s
2. Angle of repose,
 r tan 1 (  ) tan 1 (0.25)  14
Since 37°>14°, therefore T = 0 and both will slip with an acceleration
a  g sin    g cos 
 10  0.6  0.25  10  0.8
 4m / s 2
3. From work, energy theorem, W  KE
1
 K f  K i  m(v 2f  vi2 )
2
1
 (2)(400  100)  300 J
2
4. Relative velocity of separation = relative velocity of approach
v (as e=1)
2 r
Time of next collision=
v
1 1
5. KE  mVC2  I C  2
2 2
2 V 
2
1 1 1 1 m(2 R) 2 V 2
 mV  mR  2   mV 
2 2
2 2 R  2 2 12 R 2
5
 mV 2
3
6. T  r3
2
2
 T0   r0 
3
   
 T0 / 80   r 
r
r 0
4
Rh
7. cos  
R
SR.IIT_N-SC Page. No. 2
Believe you can and you’re halfway there.

8. When depressed by x from its mean position extra upthrust = restoring force (F)
or F  ( A xg )
since F   x
Oscillations are simple harmonic
F  A g 
Acceleration of block a    x
m  m 
x m
Now T  2  2
a  Ag
9. AP  BP  
   ( AP  BP)
 v  f   f ( AP  BP)
=1800(2.6 - 2.4) = 360 m/s
10. In isothermal process, U  0
V 
W  Q  nRT 1n  f 
 Vi 
25  0.3 
15  103  0.5   T 1n  
3  0.1 
Solving this equation, we get T=360 K
11. Angle of incidence i is small

I max  I1 / I 2  1  9
12.  
I min  I1 / I 2  1  1
x 1
or 3 (x  I1 / I 2 )
x 1
x  2
I
 1 4
I2
i.e.If I2  I0
then I1  4 I 0

I 0  I 0 cos 2
2
2
 
3
 2  yd  2
  
   D  3
D
y 
3d
13. When the particle is to the left of the origin O, the net force F on it is towards O and hence, causes
acceleration a
F is zero for large values of x and also for x = 0

Thus, it must increase to a maximum and fall to zero at O
The acceleration a = F / m, must have the same nature. To the right of O, the net force is to the left
while motion is to the right. Thus, the direction of a is opposite to the particles direction of motion and
is taken as negative. The variation of a with x will follow the same pattern
14.

VA  VB  16V
 4i1  2(i1  i 2 )  3  4i1  16V ...........(1)
Using Kirchhoff’s second law in the closed loop, we have
9  i2  2(i1  i2 )  0 ............(2)
Solving Eqs (1) and (2), we get
i1  1.5 A and i2  2 A
Current through 2 resistor = 2+ 1.5 = 3.5 A
15. Steady state circuit is shown in figure
P P
16. r or r 
Bq q
re  2r
Pe P 
  2  
1  2 
 Pe  P
Now, de-Broglie wavelength
h 1
 
P P
Now as, Pe  P
 e  
or x  1
I 0.98
17.   c   49
I b 0.02
V (across RL )   I b RL
 49  50  106  104  24.5V
18. Given A  3iˆ  kˆ
3
i.e., tan i1   3
1
snell’s law gives
1 sin i1   2 sin i2
i2  45o

The unit vector in the direction of the refracted ray will be

nˆ  1sin 45o iˆ  1cos 45o kˆ
1 ˆ ˆ
or nˆ  (i  k )
2
19.
Let v and  be the linear and angular speeds of the rod after applying an impulse J at B. Then from
impulse = change in momentum
J
We have mv  J or v  ...........(1)
m
I
I  J .
2
2
mI I 6J
or   J . or   ........(2)
12 2 mI
mI
After the given time t  , the rod will rotate an angle
12 J
 6 J    mI  
  t    
 mI   12 J  2
I  I  6 J  J
.     v
6  6  mI  m
J
 | v p | 2v  2
m
20. AB process is isothermal process
1
Therefore T = constant and p 
V
Pressure is decreasing. Therefore volume should increase
In process BC:
p  T , therefore V = constant
Further, p and T both are increasing
CD, process is identical to AB process
21. Car will acquire maximum speed i.e 20 m/s in 20 a with an acceleration of 1 m/s2. In retardation it will
take 10 s. Suppose it moves with constant speed of 20 m/s of t second. Then,

Area of v-t graph = Total displacement

1
or [t  30  t ]  20  1000
2
or t  35s
 Total time of journey
 (30  t)  65s
22. At (3,3), U i  18
At (1,1), Uf U f  2
Now, Ki  U i  K f  U f
or 0  18  K  2
or K  16
23. m2 g  m1 g sin   (m1  m2 )a
24.
C to D v2  2 gx  gt
2
v
 t
g
From A to B, time will become two times
1
Applying, S  ut  at 2 in vertical direction, we have
2

1
 x  (ev 2 )(2 t)   g (2 t) 2
2
2 2
2ev2 2v2
x  
g g
 x  2e(2 x)  2(2 x)
3
 e
4
25.
v1  R1  2v ..(i )
1 R  v1  v ..(ii )
v2  R2 ..(iii )
v2  R2  v ..(iv)
Solving these four equations, we get
v 3v
2  and 1 
2R 2R
 3
 1 
2 1
26. n  n2  n1
27. d max  2 Rh
 2  (6.4  106 )  240
 55.4 103 m
 55.4km
1 1 1 1 1 1
28.     
f v u 60 v 60
v  30 cm
v 1
m 
u 2
30
v0   A2  x 2  m / s
2
VI   m V0
2
1  30  15
VI     m / s
4 2  4
29. d = R cos 37° - R cos 60°
R = 2m

30. Flux passing from the small loop

 i
  BS   0  (a 2 )
 2R 
d  0 a 2  di
e   in volts
dt  2 R  dt
  a2  i 
  0   0   106 (in microvolts )
 2R    
2 1
 (4  107 )(102 ) 2   100  106   2 v
 2  0.1 2  102
CHEMISTRY
31.
32.

33.
34.
Compound is aromatic in ionic form

35.
38. meq.FeSO4 (NH 4 )2 SO4 6 H 2O

 meq. of KMnO4
(n  1)
W
 1 1000  0.1 50; W  1.96 g
392
Hence, % purity of Mohr’s salt
1.96
  100  78.4%
2.5
1 ( Ze)( e)
39. P.E. 
4 0 r
1 (2 e)( e) e2
 
4 0 r 2 0 r
8a a
40. TC  PC  VC  3b
27 Rb 27b 2
41. AB: Isobaric expansion
BC: Isothermal expansion
CD: Isochoric
DA: Isothermal compression

43. For [Ca 2 ], M1 V1  M 2 V2
0.04  50  M 2  200  M 2  0.01
Similarly, for [SO 42 ]
0.008 150 M2  200 M2  0.0001
ionic product (Q )  [Ca 2 ]  [SO 42 ]
 6  106 So Q  K sp
44.
Z
Z e
e
7
7 N 3 7 10  0.7
10
8
8 O 2 8 10  0.8
10
9
9 F 9 10  0.9
10
Z
In case of isoelectronic species as ratio increases ionic size decreases hence size order is
e
N 3  O 2   F 
(1.71 A ) (1.40 A ) (1.36 A )
45. Impurity of Pb in Ag is removed by cupellation

1
Pb  O2 
High
Temperature
PbO( g ) 
2
46.

47. CaCO3  Insoluble in water
Solubility of bicarbonates of IA increases down the group
Solubility of fluorides of IIA
BeF2  BaF2  SrF2  CaF2  MgF2

48. 2 K 2 Cr2O7   O2  2 K 2Cr2O4  Cr2O3
( S2 )

( NH 4 ) 2 Cr2O7   N 2  Cr2O3  4 H 2O
( S1 )
49. All interhalogen compounds are more reactive than halogen (Except F2). Higher reactivity of
interhalogen is due to polarity of bond
50. H 3 BO3  H 2O  [ B(OH ) 4 ]  H 
HBF4  H   BF4 
51. [Mabcd] type square planar complex has three G.I
52. PF3 , CF4 and BeF2 have all the possible B.A. identical
53.
Opposite spin of nuclei in para hydrogen molecule so that it is more stable and lower energy as
compared to ortho H2
54.
55. H 3C  CH * CH  CH * CH  CH * CH  Ph
Total stereoisomer = 23 = 8
56. b,c,e,f
 16 
57. (M )    (22.4)
 5.6 

M  64
64  32  16 x
x2
58. A B  C  D
t 0 1 1
t 1 x 1 x x x
r  k[A]1/2 [B]1/2
dx
  k (1  x)1/2 (1  x)1/2
dt
dx
or  k (1  x)
dt
1  1 
 t  In  
k  1 x 
2.303  1 
t 2
log    100 sec
2.303  10  0.1 
114.8 3.2  40  60
59. 3.05  
n 96500
n  3 0
60. Coagulation value
Number of millimoles of electrolyte required
=
Volume of collodial solution (in litre)
10  0.5
=  1000  100
50
MATHS
61. As the function is defined as  R such that sec2   tan 2   1 ,
When  R ,sec2   tan 2   1  1  1 which is true.
Thus it is reflective
When  R ,sec2   tan 2   1
 1  tan 2     sec 2   1  1
 sec2   tan 2   1   R 
Thus it is symmetric.
When  R  and  R  then
sec2   tan 2   1 and sec2   tan 2  1
From the are two equations,
sec2   tan 2  1   R 

 R  and  R   R 
Thus it is transitive
Hence it is an equivalence relation.
 x x Q
62. Let   x   f  x   g  x   
 x x  Q
If we take any straight line parallel to x-axis which will intersect   x  only at one point.
So, it is one – one.
 x x Q
Also,   x   
 x x  Q
y = x for rational number and y = -x for irrational number.
So, ‘y’ belongs to real number.
 Range = Co – domain
So,   x  is onto
So, f – g is one – one and onto.
63. At x = 0, LHD = 0 and RHD = 0  LHD = RHD at x = 0
At x =2, LHD =  & RHD =   LHD  RHD at x = 2.
f a  h  f a
Note : LHD | x  a  f '  a    Lt 
h 0 h
f a  h  f a
RHD | x  a  f '  a    Lt 
h 0 h
64. ln y  ln  sin x   ln  sin 2 x   .....  ln  sin nx 
y1 1 2 cos 2 x n.cos nx
  .cos x   .... 
y sin x sin 2 x sin x
y1 n n
  K cot kx  y  y  k .cot kx
1
y k 1 k 1
f '  x   e  2 x  1 x  1 

x 1 x 
65. (after simplification)
 1   1 
f '  x   0 in   ,1  f  x  is increasing on   ,1 .
 2   2 
x4 1 2 x  x   x  x  1
4 2 4 2
66.  x 2 x 4  x 2  1 1/ 2 dx   x 2 x 4  x 2  1 1/ 2
   
x  4 x3  2 x 
 x4  x2  1
x4  x2  1
  2 x  x 1 2
4 2
dx  c
x x

1 1
 n!  n 1 2 3 n n
67. Let P  Lim  n   Lim  . . ...... 
 
n  n

n  n n n n
1  1 2 n
 log P  Lim  log  log  .....  log 
n n  n n n
n
1 r
 log P  Lim  log
n 
r 1 n n
1
 log P   log x.dx  1  P  1/ e
0
68.
Required area
1
 d1d 2   r 2
2
2
1  1 
  2 2   
2  2

 2
2
69. Given diff. equation is LDE of the form
dy
 Py  Q . Therefore solution is
dx
y.e     Q.e   dx  c
pdx pdx
 
x
The solution of above DE is y  x   .e 2 x
2
2 x
1  2 x   0  x   ,1
e 1
y ' x 
2 2 
1 
 y  x  is decreasing in  ,1 .
2 
70. ~  p  q  p  ~ q

71. PA  PB  AB
 For PA  PB to be maximum, ‘P’ must be point of intersection of the line joining A and B and
2x  3y  5 .
2 7
 P   h, k    , 
5 5
72. Equation of required circle is
2  2  1 22    1  5   0
x2  y 2  x y
 1 1  1 
1  5
Now, using condition of orthogonality we get 4 
1 
5
 
9
19 23
So, the equation of circle is x 2  y 2 
x y40
2 2
73. y  mx  3m2 (tangent with slope ‘m’ to x 2  12 y )
y  mx  2m  m3 (normal with slope ‘m’ to y 2  4 x )
3m 2  2m  m 3
 m 3  3m 2  2m  0
 sumof slopes = - 3.
74. Tangent to ellipse having slope 2 will be
y  2 x  4a 2  b 2
 It is a normal to circle  (-2, 0) is on it
 0  4  4a 2  b 2  4a 2  b 2  16
4a 2  b 2
  2ab  8  2ab  ab  4
2
75. Let (h, k) = mid – point of chord of x 2  y 2  16
Equation of chord is T  S1
h h2  k 2
i.e., hx  ky  h2  k 2 (or) y x
k k2
x2 y 2
The chord will touch the hyperbola   1 if c 2  16m 2  9
16 9
2
 h2  k 2   h 
2
   16    9
 k   k 
  h 2  k 2   16h 2  9k 2
2
76. P1 : 2 x  y  z  1; P2  3x  y  2 z  2
P1 and P2 represent planes. Solve them to obtain equation by line.
x  0 y  0 z 1
 L1 :  
1 1 1

x0 y0 z0
Also, x = y = z  L2 :  
1 1 1
 Shortest distance between them

  
kˆ. iˆ  ˆj  kˆ  iˆ  ˆj  kˆ   kˆ.2  kˆ  ˆj   1
iˆ  ˆj  kˆ   iˆ  ˆj  kˆ  2 kˆ  ˆj 2
        
77. u   u  w  3v  0   u.w u   u.u  w  3v
  
 2 3 cos  u  3w  3v  
Square both sides, we get

2
 2
   2
2
u 2 3 cos   9 w  12 3 cos  u w cos   9 v
3
 cos 2  
4
sec 2 x  sec x  4 2 sec x
78. y  1
sec x  sec x  4
2
sec x  sec x  4
2
2
 1  AM  GM 
sec x  4 cos x  1
3
  y 1
5
79. x  cx  d  0  ,   ; x 2  ax  b  0  ,  
2
    c,  .  d ,  2  b, 2   a
Now, 2  b  d   2  2     2      ac
80. a1  2a2  3a3  4a4  1000
Applying AM  GM
a1  2a2  3a3  4a4
  a1.a22 .a33 .a44  10
1
10
 a1.a22 .a33 .a44  100 
10
 a1.a22 .a33 .a44  1020

81. x  y  z  F1  6
 m  6  4 1 C4 1  9C3  n  r 1 Cr 1 
x  y  z  t  F2  10
n C51  9C4  n 1 Cr 1 
10 1
n  9C 
20    20  9 4   30
m  C3 

6 r
 1  6
 1
 x   1    Cr  x  
6
82.
 x  r 1  x
 a0  1  C2 . C1  C4 . C2  6C6 . 6C3 = 1 + 30 + 90 + 20 = 141
6 2 6 4
p q r
83. Use row and column operations to generate the term   from the given determinant.
a b c
84. Heart and not Ace = 12
Ace and not Heart = 3
Ace and Heart = 1
E : One Card is heart and other ace
12
C1.3 C1  3C1. 1C1  12C1. 1C1
PE  52
C2

 36  3  12  2 
51.2

1
52.51 52.51 26
 odd in favor = 1 : 25
Odds against = 25 : 1
85. A : A scooter chosen at random found to be good.
B1 : Scooter come from plant I : P( B1 ) = 0.7
B2 : Scooter come from plant II : P( B2 ) = 0.3
P  A / B1   0.8; P  A / B2   0.9
P  B2 / A  
 0.3 0.9  
27

27
 0.3 0.9    0.7  0.8  27  56 83
 b  a  56
86. x 6  x 3  6 x 2  12 x  8   0
 x = 0. 0, 0, 0, 0, 0, 0, 2, 2, 2
2 0 0
 A  0 2 0 8
0 0 2
Now, b11  b22  b33  6
6 0 0
B  0 6 0   B  63
0 0 6 
2 6
adj B B 66  3 
Now,   8  
adj  adj  adjA   A
23
8 8
 q 2p  86  2
87. A E I O U D C T N
_________
A,N,E
A,E, N

N, A,E
3  5C3  1 3!  180  6    30

 5
6
88. By Demoivre’s theorem,
n n
Z n  cos  i sin
1000 1000
 n  1 n 
Now, sin     or  
 1000  2 1000 6
1000 3141.57
n n
6 6
 n  523  n  524
89. From the given conditions we have
2  8 / 3   3   1
 
2 2  1   1
   3,   1/ 3
 10 10 4 
 P  5, 5, 2  , Q   , , 
 3 3 3
 l  PQ  6  l   2
90. Tangent at (2, 2) is y = x
5 3
x y
CC1 : 2  2  2r
0
cos 45 sin 450
5 3 
 C1    r ,  r 
2 2 
5 3
 r 4 r 
2 2
Circle x  y  8 x  6 y  c  0
2 2
25 9
 r 2  25  c   8
4 4
49
c
2
3 49
 6
rac 2 2 32
   4
8 8 8

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Sec: SR.

IIT_COSC GTM-36 Date: 09-05-21

SR.IIT_N-SC Page. No. 2

Believe you can and you’re halfway there.

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F is zero for large values of x and also for x = 0

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The unit vector in the direction of the refracted ray will be

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Area of v-t graph = Total displacement

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30. Flux passing from the small loop

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Compound is aromatic in ionic form

38. meq.FeSO4 (NH 4 )2 SO4 6 H 2O

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45. Impurity of Pb in Ag is removed by cupellation

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f '  x   e  2 x  1 x  1 

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Square both sides, we get

 a1.a22 .a33 .a44  1020

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