Sri Chaitanya IIT Academy Key Sheet for JEE Main Physics, Chemistry, and Maths

Sri Chaitanya IIT Academy., India.
A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant

ICON Central Office – Madhapur – Hyderabad
Sec: Sr.Super-60 & ICON All Jee-Main Date:19-07-2021
Time: 09.00Am to 12.00 GTM-40 Max.Marks:300
Key Sheet
PHYSICS
1 4 2 1 3 2 4 3 5 1
6 2 7 3 8 3 9 3 10 1
11 1 12 3 13 2 14 1 15 1
16 2 17 3 18 1 19 4 20 1
21 0.04 22 43.5 to 44.5 23 1.20 24 0.50 25 13.00
26 6.60-6.70 27 1.50 28 4.50 29 49.00 30 2.67
CHEMISTRY
31 1 32 3 33 4 34 1 35 2
36 4 37 2 38 3 39 2 40 4
41 2 42 1 43 2 44 2 45 1
46 2 47 3 48 4 49 1 50 4
51 8.00 52 3.00 53 1.00 54 1.00 55 4.00
56 1.00 57 1.00 58 1.00 59 3.00 60 2.00
MATHEMATICS
61 4 62 2 63 2 64 3 65 1
66 2 67 3 68 2 69 4 70 3
71 1 72 1 73 2 74 4 75 4
76 1 77 1 78 4 79 4 80 2
81 10 82 3.00 83 4.00 84 2.00 85 8.00
86 3.00 87 19 88 1.00 89 1.00 90 1.00
Sri Chaitanya IIT Academy 19-07-2021_Sr.Super60 & ICON All_Jee-Main_GTM-40_Key & Sol’s
SOLUTIONS
PHYSICS
1. Sol.
dv dv dx
f   ( a  bx )  .  a  bx
dt dx dt
 vdv  ( a  bx)dx
v x x
 0 vdv  a 0 dx  b0 x dx
2
a a a2
so vat x  a / b  2a   b    
b b b
a
 vmax 
b
2. Sol. For particle P, motion between A and C will be an accelerated one while between
C and B a retarded one. But in any case horizontal component of it’s velocity will be
greater than or equal to v on the other hand in case of particle Q, it is always equal to v.
horizontal displacement of both the particles are equal, so t P  t Q .
 mg 
3. Sol. Tension at the ends of the chain    sin  and tension at the mid-point
 2 
 mg   mg 
C   cot    
 2   2 tan  
4. Sol. Horizontal component of velocity i.e., u cos a remains unchanged. At highest point
vertical component of velocity is zero. Let vy be the vertical component of velocity at
the desired instant.
1
 The desired work done W  mv 2y
2
1 
 mu 2 cos2  tan 2
2 2
5. Sol. Let the sphere of mass M and radius R be struck horizontally at a height h from the
floor, as shown in the figure,
v
The sphere will roll without slipping when  
R
Angular momentum of sphere about its centre of mass is
2  v 
Mv(h  R)  I    MR 2  
5  R 
Sec: Sr.Super-60 & ICON All Page 2

 2 2
 For a sphere I  MR 
 5 
The sphere will roll without slipping with a constant velocity and no loss energy when
7
h  R.
5
V
6. Sol. Conserving angular momentum m  (V1 cos 60o )  4 R  m  V2  R; 2  2 Conserving
V1
GMm 1 GMm 1 1 1 3 GM
energy of the system   mV12    mV22 V22  V12 
4R 2 R 2 2 2 4 R
1 GM
or V12 
2 R
1 8000
V1  64  106  m/s
2 2
2T cos 2TR
7. Sol. h '  
r g g
r 2 2T 2 r
   r '2  r'
2 rg r g 2
8. Sol. As the ball ascends upwards in addition to weight, air friction also acts downwards.
Hence the initial magnitude of acceleration will be greater than magnitude of acceleration
due to gravity. So the only possible option is
 h 
9. Sol.  
 5R 
10. Sol. For an adiabatic process, PV   K
3
Here,   and K  constant
2
3/2
PV  K
3
log P  logV  0 log K
2
P 3 V
  0
P 2 V
V  2  P  2 2 4
 100      100      
V  3  P  3 3 9
4
 Volume decreases by about % .
9
11. Sol. Displacement-time equation of the particle will be
X  A cos t
Given that x1  A cos 
and x2  A cos 2
x x A(cos  cos3 )
Now, 1 3 
2 x2 2 A cos 2
2 A cos 2 cos 

2 A cos 2
 cos 
2 x x 
or T where   cos1  1 3 
  2 x2 
12. Sol. The situation is shown in the fig. Both the source (engine) and the observer (Person
in the middle of the train) have the same speed, but their direction of motion is right
angles to each other. The component of velocity of observer towards source is v cos 45
and that of source along the time joining the observer and source is also v cos 45 . There
is number relative motion between them, so there is no change in frequency heard. So
frequency heard is 200 Hz.
13. Sol. Let us complete the sphere. Electric field due to lower part at A  electric field due
to upper part at B  E (given)
Electric field due to lower part at B = electric field due to full sphere – electric field due
to upper part
kQ 1  (4 / 3) R 3 R
 2
E 2
E E
(2 R) 4 0 4R 12 0
dv
14. Sol. Ex    (6 x  4)
dx
E y  0 Es  0
At origin, E x  4

Thus, electron will experience force in the direction opposite to electric field i.e., in + x
direction.
l l
15. Sol. R1  , R2  As A1  A2 so R1  R2
A1 A2
In series H  I 2 RT H  R; H1  H 2
V2 1
In parallel H  t H  ; H1  H 2
R R
e
16. Sol. Here    100
E
40 e 4 2
  
100 E 10 5
2 E 2  200
e   80V
5 5
200  80
 10 
R
10 R  120
 R  12
17. Sol. Radius r of particle in spiral path at any time when velocity is v
mv v qB
r    Constant
qB r m.
Angular momentum L  mvr  qBr 2 decreases as r decreases
If particle is moving in a plane then its velocity and acceleration will be in that plane. The
force on the particle will also be in that plane. It means magnetic field should be
perpendicular to that plane.
18. Sol. Condition for maxima is
d sin   n
n  0.50 
sin    n   0.25n
d  2.0 
As sin q lies between – 1 and 1, so we wish to find all values of n for which | 0.25|  1
These values are 4,  3,  2,  1, 0,  1,  2,  3, 4. For each of these are 2 different
values of q except for – 4 and +4. A single value of q, 90 and 90 , is associated with
n  4 and n  4 respectively. Thus there are 16 different angles in all and therefore 16
maxima.
19. Sol. From the following figures it is clear that real image (I) will be formed between C
and O

20. Sol. Resultant current is super-position of two currents i.e., I (instantaneous total
current)  6  I 0 sin t
DC ammeter will read average value
AC ammeter will read
2
 6  I 0 sin 2 t 
 36  12 I 0 sin t  I 02 sin 2 t
( I 0 sin t  0)
21. Sol. Number of photons falling per second:
103
Np  34 8
 2.5  1015
6.6  10  3  10
5000  1010
Let N e is the number of photoelectrons emitted per second.
q Nee I 0.16  106
 I   Ne   19
 1012
t 1 e 1.6  10
Percentage of photons producing photoelectrons
N 1012
 e  100   100  0.04
Np 2.5  1015
22. Sol. If d is the distance of closest approach given, then the angular momentum
 mvd  10 33 Js
1
E  mv 2  1 MeV  1.6  1013 J
2
Distance of closest approach
1033
d
1.6 2  1020
1 100
  10 13  fm  0.44 fm
1.6 2 1.6 2
23. Sol. As we know current density J  nqv
 J e  ne qve and J h  nh qvh
J n v 3 / 4 ne 5 n 6
 e  e e    e 
J h nh vh 1 / 4 nh 20 nh 5
I
24. Sol. T  2
MB
B   A  
25. Sol.  B p  d   4  0 ,  BQ  d   150 ,
A C

C  A 
Now  BP  d  should be one third of  Q  d
B
B C

 4  0  5 0  4  0  0 I
 I  13 A
26. Sol. a  r , m  4kg
20  f  4a
20 r  fr  0.02
 a  6.7 m/s 2
1
27. Sol. mVm2  15  103
2
Vm  0.150 m/s
A  0.150 m/s
0.150 0.150
gL  3
L  1.5
100  10 0.1
28. Sol. Effective height of the bird as seen by the fish, Y
 y  my '
dY dy dy '
 
dt dt dt
4 dy '
9  3
3 dt
 Actual velocity of bird
 4.5 ms 1
I 9I I 9
29. Sol. From figure I1  and I 2   2
4 64 I1 16

 I2   
  1  9 1
I I    10 49
By using max   1 
I min  I 2   9  1
 1   1
 I1   16 
30. Sol. The complete cyclic process can be visualized as made up of two cycles, i.e., cycle
AEBA (clockwise) and cycle BDCB (counter-clockwise). Work done by the gas during
the cycle AEBA should be positive,
 Total work done by the gas
W  W1  W2  3kJ  0.33kJ  2.67 kJ
CHEMISTRY
31. Sol. Pb  PbO 2  2H 2SO 4  2PbSO 4  2H 2O
The reaction is balanced by the loss and gain of 2 moles of electron per mole of Pb and
2M
hence, E H 2SO4  M
2
m n co  28  n co2  44
32. Sol. d   1.5 
v 0.0821  300
(n co  n co2 ) 
1
7.055
 n co  n co
8.945 2
Alkali will absorb all CO 2 . Hence, final pressure is due to CO.
= 335.1 mm
33. Sol. Area  P2  V  P2  4  49.26 L  atom
V 4
Now, correct work, w  nRT.ln 2   P2V2 .ln
V1 2
 49.26  0.693   34.137 L  atom
1
34. Sol. (a) c  O 2  CO;
2
9.0 4.5
H  75kcal
(b) C  O2  CO 2
2 2
H  95 kcal
Heat evolved  95  2  190
(c) C  O2  CO2
2.5 2.5
Heat evolved  95  2.5  237.5
35. Sol. 2NO(g)  Cl 2 (g)  2NOCl(g)
Initial partial pressure 2P0 P0 0
Equ. Partial pressure 2P0  2x P0  x 2x
From question, (2P0  2x)  (P0  x)  2x  1

(2x) 2 13
 KP  2
 atm 1
(2P0  2x) (P0  x) 256
36. Sol. en  H 2 O  enH   OH  ; K b1  8.1  105
(0.09  x)M (x  y)M (x  y)M
37. Sol. [H  ]left  Kb  C  1.8  105  0.01  C1M

Kw 1014
[H  ]right    C2 M
Kb  C 5
1.8  10  0.01
Net cell reaction, assuming as concentration cell:
0.06 C
E cell  0  .log 1  0.465V
1 C2
38. Sol.
39. Sol. Po  P  X1  Po
10  0.2  P o … (1)
o
20  X1  P … (2)
From (1) and (2): X1  0.4  X 2  X solvent  0.6
40. Sol. From (2) and (3): order with respect to I   1
From (1) and (3): order with respect to ClO   1
From (3) and (4): order with respect to OH   1
1
x
41. Sol.  K  Pn
m
1
 0.2  K  (4) n (1)
1
0.5  K  (25) n (2)
0.6 3
Hence, moles of N 2 adsorbed per gm of iron  
28 140
42. Sol. Theory based.
43. Sol. Hoffman elimination.
44. Sol. Carbocation stability matters in Electrophilic addition reaction.
45. Sol. Inversion takes place in SN 2
47. Sol. Electronegativity is defined for bonded atoms.

48. Sol. XeO3 has bond order  2
49. Sol. I3 is linear.
51. Sol. Conceptual
52. Sol. Gabriel phthalimide synthesis is used to prepare 1° aliphatic/alicyclic amine in
common. Hence amine which can synthesised by Gabriel phthalimide synthesis method
is : (A) Me, CH-CH,-NH, (B) CH,CH,NH, (C) Ph-CH,-NH,
53. Sol.  -sulphur and  -sulphur are diamagnetic.
S2-form is paramagnetic.
54. Sol. SF6 is inert towards hydrolysis
 answer is 1
Distance travelled by compound
55. Sol. R f 
Distance travelled by solvent
on chromatogram distance travelled by compound is  2 cm
Distance travelled by solvent = 5 cm
2
So R f   4  101  0.4
5
56. Sol.   COOH group present in
57. Sol. Cs is used as electrodes in the photoelectric cell.

58. Sol. If number of lattice points are N
then effective octahedral voids = N
So, octahedral voids / lattice site = 1
59. Sol. Total number of stereoisomers in [Co(ox) 2 Br(NH 3 )]2  i.e.  [M(AA) 2 ab]2 

 cis is optically active isomers and trans is optically inactive isomer
 Hence total isomers is = 3
60. Sol. T f  i  k f  m
12.2
0  ( 0.93)  i  1.86   1000
122  100
1 1 
 1    1  1
2 n 
n2
MATHEMATICS
61. Sol. S ( x,2)  0 given two identical solutions x = 1.
 line y  2 is a tangent to the circle S(x, y) = 0 at the point (1, 2) and S(1, y) = 0
gives two distinct solutions y = 0, 2
 Line x = 1 cut the circle S(x, y) = 0 at points (1, 0) and (1, 2)
 equation of the circle is ( x  1)2  y ( y  2)  0
x2  y 2  2 x  2 y  1  0
62.
2
63. Sol. f ( x)  2sin   4cos( x   )sin x.sin   cos(2 x  2 )
 2sin 2   cos(2 x  2 )  2cos( x   )cos( x   )  2cos 2 ( x   )
 
 f 2 ( x)  f 2   x   cos 2 2 x  sin 2 2 x  1
4 
sin x 4  x 4 cos x 4  x 20 sin t  t cos t  t 5
64. Sol. lim 4
 lim 2 t
{Let x 4  t}
x 0 x 4 (e 2 x  1  2 x 4 ) t  0 t (e  1  2t )
 t3 t5   t2 t4  5
 t    .......   t 1    ......   t t 3 t3 t 5 t 5
3! 5! 2! 4!      ....  t 5
 lim  2
 
3 4
  lim 6 2 5! 4 4!
t 0  4t 8t 16t  t 0 8t
t  1  2t     ....  1  2t  2t 3   ...
 2! 3! 4!  3!

1 1
 
1  3 1
 6 2 
2 12 6
65. Sol. The function is not differentiable at two points between x     & x     also
 
function is not continuous at x  and x   hence at four points function is not
2 2
differentiable.
a0 x n 1 a1x n a2 x n 1 an 1x 2
66. Sol. Consider the function f ( x )     .......   an x.
n 1 n n 1 2
Then f (0)  0 and f (1)  0
Hence f '( x )  0 has at least one solution in (0, 1)
cos4 x dx
67. Sol. I  3
sin x(sin 5 x  cos5 x)3/5
cos 4 x dx
 3/5

sin 6 x 1  cot 5 x 
3
 1
1 dt 1 t 5 1 2
  3/5
  C   (1  cot 5 x ) 2/5  C  A  5, B  and AB  2
5 t 5  3 1 2 5
5
68. Sol. Putting x  t in m,
0 2
| sin( t ) | | sin t |
m (  dt )   dt
 t  1  t  1
    2     2
2 0
2 2
| sin t | | sin t |
m dt {If x  I ; then [ x]  [ x]  1}    dt  n
 t 1  t  1
0
    1  2     2
0
1 1 1 1
69. Sol. lim    .......... 
n  4n 2 4n 2  12 4n 2  22 4 n 2  ( n  1) 2
70. Sol. The curve is y 2  4 y  x  5  0
Equation of tangent at P (2, 3) is
1
3 y  2( y  3)  ( x  2)  5  0
2
1
y  6  x 1 5  0
2
 5
if intersects x-axis at Q(-4, 0) and the line x = 1 at S 1, 
 2
25 2 1 16
  1    10   2
4 3 4 3
 15  6  9
71. Sol. y  c1 cos 2 x  c2 cos 2 x  c3 sin 2 x  c4

c c
 y  c1 cos 2 x  2 (1  cos 2 x)  3 1  cos 2 x   c4
2 2
That means there are two independent parameters. Thus the order of differential equation
will be 2.
(34 )log9 5  33log3 6 6
72. Sol. N [7log7 25  (53 ) log5 2 ]
409
3
3log3 25  3log3 6 (25  6 6)(25  6 6)
N [25  6 6] ; N 
409 409
N 1
log 2 N  log 2 1  0
73. Sol. Since equation has imaginary roots
Hence equations ax 2  bx  c  0 & 5 x 2  12 x  13  0 have both common roots
a b c
    k ( say )
5 12 13
a  5k , b  12k , c  13k
 a 2  b 2  25k 2  144k 2  169k 2  (13k ) 2  c 2
 a2  b2  c2
 ABC is right angled triangle.
74. Sol. log 6 ( abc )  6  (abc)  6
b 36
Let a  and c  br  b  36 and a   r  2, 3, 4, 6, 9, 12, 18
r r
 a  b  c  36  9  144  189
75. Sol. Coefficient of x 4 is (1  5 x  9 x 2  .......)(1  x 2 )11
 (1  5 x  9 x 2  .......)(1  11x 2  11C2 ( x 2 ) 2  ........)
Coefficient of x 4 is 11C2  9  11  17  55  99  17  171
76. Sol. Conceptual
77. Sol. Total number of ways = 7!
favorable number of ways = 7! – 2. (6!)
7! 2(6!) 2 5
 probability  1 
7! 7 7
78. Sol. Since AB = B and BA = A
 A and B both are idempotent
( A  B) 2  A2  AB  BA  B 2  A  B  A  B  0
 A  B is nilpotent
3( z ) 2
79. Sol. z 3  0 Let z  rei
|z|
 r e  3re i 2  0
3 i 3
Since ‘r’ cannot be zero

 r 2ei 5  3 which will hold for r  3 and 5 distinct values of ' '
Thus there are five solution.
80. Sol. Conceptual
81. Sol.  CP  CR
| h  k  10 |
 h
2
h  k  10  h 2 ….. (i)
 CP  CQ
 h  k  10  h  k  6
h  k  2 …. (ii)
Put in (i), we get
h4 2  k h2  k 24 2
 hk  28 2
 a  2, b  8
 a  b  10
82.
83. Sol. Let (h, k) be the mid-point of the chord of the circle x 2  y 2  4
So, by mid point form, equation is T  S1
hx  ky  h 2  k 2
2
 h2  k 2   h  2 2 2 2 2
    4    16  ( x  y )  4 x  16 y
 k   k 
84. Sol. | x  1|  2[ x]  3{x}
(i) if x  1, then x  1  2[ x ]  3{x}
[ x]  {x}  1  2[ x]  3{x}
 0  1  [ x]  4
 1  [ x]  3
 possible value of [x] are 1 and 2
1
If [ x]  1, then {x} =  x 3/ 2
2
(ii) x  1 , then the equation becomes

1  [ x]  { x}  2[ x]  3{ x}
2{x}  3[ x]  1
1 11
i.e.  [ x]  1which is not possible  x  3 / 2, are the only solutions
3 4
2
 9 
85. Sol. d  ( x1  x2 )   2  x12  
2 2
 x2 
Let y12  2  x12  x12  y12  2
9
y2   x2 y2  9
x2
d  shortest distance between two curves will be along the common normal y = x
 d2  4  4  8
86. Sol. Drawing the graph of y  f ( x )
Clearly the range of y  f ( x ) is [1, 3]
When 2  x  1,{ f ( x )}  0
1
When 1  x  0, { f ( x )} will have the value of for one value of x.
2
1
When 0  x  1, { f ( x)} will have the value of for one value of x.
2
1
When 1  x  2, { f ( x)} will have the value for one value of x.
2
1
Hence the total number of values of x for which { f ( x)}  are 3.
2
87. Sol. x  y  z  w  25
Let x  y  z  w  a  25 such that a  0 ….. (i)
x  1  t1  t1  0
y  2  t2  t2  0
z  t3  t3  0
w  4  t4  t4  0
a  1  t5  t5  0
put in equation (i)
( 1  t1 )  (2  t2 )  t3  (4  t4 )  (1  t5 )  25
2
| adj B | | adj ( adj A) | | A |(31) | A |3
88. Sol.   3 
|C | | 5A | 5 | A| 125
| adj B |
Now | A|  5  1
|C |
tan   tan  sin(   
89. Sol. 
1  tan  tan  cos(   

sin(   
2
2 tan  cos(   
 sin 2   
1  tan 2  sin 2 (   
1
cos 2 (   )
 sin(    cot(   

cos 2 (     sin 2 (   
sin 2  sin 2

1  sin 2 sin 2
 R.H .S .
 3sin 2   tan    6 tan    tan  
90. Sol. tan 1    tan 1    tan 1  2 
 tan 1  
 5  3cos 2   4   8  2 tan    4 
 3tan  tan  
  
1 4  tan 
2
4  3tan 2  
 tan  2
   2
 1   tan 1 (tan  )  
 3tan    16  4tan  
 1 2 
 16  4 tan  

Sri Chaitanya IIT Academy Key Sheet for JEE Main Physics, Chemistry, and Maths

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Sri Chaitanya IIT Academy Key Sheet for JEE Main Physics, Chemistry, and Maths

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Sri Chaitanya IIT Academy., India.

A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI

A right Choice for the Real Aspirant

Sec: Sr.Super-60 & ICON All Page 2

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37. Sol. [H  ]left  Kb  C  1.8  105  0.01  C1M

Sec: Sr.Super-60 & ICON All Page 9

57. Sol. Cs is used as electrodes in the photoelectric cell.

Sec: Sr.Super-60 & ICON All Page 10

Sec: Sr.Super-60 & ICON All Page 11

71. Sol. y  c1 cos 2 x  c2 cos 2 x  c3 sin 2 x  c4

Since ‘r’ cannot be zero

Sec: Sr.Super-60 & ICON All Page 13

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