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SEC: SR STAR JEE-MAIN Date:03-01-2024

Time: : 09.00Am to 12.00Pm GTM-02 Max. Marks: 300

KEY SHEET
PHYSICS
1) 2 2) 2 3) 3 4) 2 5) 3
6) 1 7) 1 8) 4 9) 1 10) 4
11) 1 12) 4 13) 1 14) 3 15) 4
16) 2 17) 4 18) 1 19) 2 20) 2
21) 6 22) 15 23) 4 24) 6 25) 2
26) 20 27) 363 28) 3 29) 5 30) 6

CHEMISTRY
31) 2 32) 1 33) 2 34) 3 35) 1
36) 4 37) 3 38) 4 39) 4 40) 3
41) 3 42) 4 43) 3 44) 1 45) 2
46) 2 47) 1 48) 4 49) 1 50) 2
51) 4 52) 3 53) 12 54) 8 55) 4
56) 42 57) 13 58) 2 59) 40 60) 3

MATHEMATICS
61) 4 62) 2 63) 2 64) 2 65) 1
66) 2 67) 1 68) 2 69) 3 70) 4
71) 1 72) 1 73) 2 74) 4 75) 4
76) 3 77) 2 78) 4 79) 3 80) 2
81) 1 82) 9 83) 5 84) 0 85) 4
86) 825 87) 1 88) 14 89) 3 90) 0
SOLUTIONS
PHYSICS
128  1000 g N 2  50 g
1. 
100  100  100cm 3
50  50  50cm3
2n 2 19.6
2. Time taken by mango   = 2 second
g 9.8
Distance = vt
5
6  2  3.33 m
18
3. Conceptual
4. Slope = a = - 5 = - μg
Acceleration of the body is the slope of the v-t graph
10
From the graph, slope of line   5
2
So deceleration is 5 m / s 2    5 / 10  0.50
k2 2
5. For a solid sphere , 
R2 5
9.8sin 30
a a  3.5 m / sec 2
2
1
5
Time of ascent is given by
v  u  at
0  1  3.5t
1
t s
3.5
Time of decent
1
t sec.
3.5
Due to symmetry of motion.
2
Total time, T   0.57 s
3.5
pr 3  M 1/2 L3/2   L3/2 
6. T  k 3/2 Dimensions of RHS  3/4
 M 1/8 L0T 3/2
s  MT 
2

Dimensions of L.H.S  Dimensions of R.H.S


 option A
GM
7. The correct option is B
R
Gravitational potential at any inside point is given as
V 
GM
2R 3  
3R 2  r 2 . ….(i)
R 11GM
for r  ,V  
2 8R
M R
Subtracting potential due to cavity of mass M c  and Rc 
8 2
Gravitational potential at center is obtained by substituting r  0 in equation (i)
3GM c

2 Rc
M
3G
11GM  3GM c  11GM 8  V   GM
V    
8R  2 Rc  8R 2
R R
2
8. Conceptual
9. Conceptual
10. y  A sin t   
A A
Here, y  , A sin t    
2 2
 5
So,   t    or
6 6
A
So, the phase difference of the two particles when they are crossing each other at y 
2
5  2
in opposite directions are   1   2   
6 6 3
 mv  4 3
11. Pf  0 ˆj Pi  mv0iˆ  mv0 ˆj
2 5 5
Impulse acting on ball
     4 1 
J  Pf  Pi  J  mv0   i  j 
 5 10 
 p  p2  3 9
12. w   1   v2  v1    10  0.3   10
6 5

 2  4 4
10  0.4
6
0.5  10  0.1
6
T2  T1 
nR nR
 5R     35
105 3.5
U  n    105
 2  nR 4
22 R
  11 105 
nc
nR
105 3.5 c
7
13. u1  u 2 v1.v2  0

u i  gt j  .u  i   gt j   0
1 2

14.
Taking torque about point C
T
 60  20  50  80  100
2
 3 T  100  800
 300 N
15. xCM   xdm
 dm
 x  
1

x  x 2 dx
xCM  0

   x  x  dx
1
2

9
x CM  m
20
v2  u 2
16. Area under a versus x gives
2
 
2
v2  10
  45  v  10 m / s
2
17. 6  2  3  1   3  6 v
x is the maximum extension in the spring
1 1 1 1
 9 1   200  x 2   312   6  2 
2 2

2 2 2 2
 1  e  m1   m2  em1  m1  M
18. V2    u1    u2 Given & M >>m
 m1  m2   m1  m2  m2  m
 m2 
 e
m m 1  e  u   m1  u
 m  M  or  2  0 V2 
m 1  m2  2
M m1 1 2 1 
 m1 
m1 
 1 1 8V  V
V2  1  e  u1  eu2  1    2V    V    3V
 3 3 3
19. In the general expression h  2T cos 
rdg
r 2T 1
 radius of curvature of meniscus formed so h = or R  .
cos  Rdg h
u2
20. Maximum range up the inclined plane  Maximum range down the inclined
g (1  sin  )
u2
plane  The maximum possible distance between the two bullets after they hit
g (1  sin  )
u2 u2 2u 2
the inclined plane  d max   , d max 
g (1  sin  ) g (1  sin  ) g cos 2 
21. Conceptual
22. r  2i  3 j F   pk

  r  F  2 j  3 j   pk   
a 3 3
    x3  5 x  5  3  15
b 2 2
23. 200  f  m  1.5
300  f  m  2.5
In solving m = 100kg
1 1 1
24. cos 2   cos 2   cos 2   1 cos 2   1 
 
4 2 4
  60 0 with z - axis  30 0 with x - y plane
at 3t
25. from figure, a cos 300  at and a sin 300  at  tan 300  
at at
v2 dv v t 3 2
at  3t or
1
 3t  v 2  3t , But at 
dt
 3t or 0
dv  3  tdt or v =
0 2
t
3
 t 4  3t or t 3  4 Given t  22/3 s  n  2
4
Fl 100  l  120l l  l 100 10
26. e l1  l  l2  l   1  
Ay Ay Ay l2  l 120 12
11  11 
Given l2  12  l1  l    l1  l 10
l1
10  10 
l
12l1  12 l  11l1  10 l l1  2 l  l  1  x  2 10 x  20
2
1 1
27. Applying Bernoulli's theorem: P1   gh   v 2  P2  0   (2v) 2
2 2
3 363
Putting the values, 4100  800{ v 2  10}  v  m / s  x  363
2 6
28. Let x mole of the gas be dissociated, x moles of atomic becomes 2x moles of a
monatomic gas after dissociation.
3 5
Internal energy of n moles of an ideal gas = nRT for monatomic gas = nRT for
2 2
diatomic
gas so, (internal energy of 2x moles of monoatomic gas + internal energy of (4 –x) moles
3
of a diatomic gas) – internal energy of 4 moles of a diatomic gas = nRT  given 
2
 2 x  
3RT   5 RT   5 RT  3
  4  x    4    RT on solving x = 3 moles
 2   2   2  2
29. Taking disc element, the required volume is
5 R 3
R R

  r 2 dy    R  y 2  dy 
2

R/2 R/2
24
30. Applying conservation of energy between initial and final states
2 2
1  v  1  mg   mg  6mg 2
2m    k    2mg  , Solving we get v   6m / sec
2 2 2  k   k  k
CHEMISTRY
31. Charcoal
1
32. Screening effect 
Ionization Potential
33. Last electron enters into p - Orbital
34. Both A and R are true but R is not the explanation for A.
35. Only two optically inactive isomers

Br CONH2

1 COOH
4 2
5 3
6

36. CHO COCl


2
37. CO has a single structure i.e., resonance hybrid of the above three structures.
3

38. 2 nodes are possible for 3s orbit.


39. More the number of keto group more is the stability order.
Incase of II structure as the positive charge is present on adjacent carbons it is unstable.
Z2
40. E 2
n
r1 for H  n 2
rn  =
rn n 2
Z
nh 2h
mvr  
2 2
h
V
 ma0
1
K .E   mv 2
2
h2

32 2 ma02
41. 8 mole atoms – 1 mole
0.25 mole atoms ?
0.25 1
 3.125 102
8
42. Equivalent weight is not fixed
43. Conceptual
44. Conceptual
45.
46. Hoffmann elimination followed by reductive ozonylysis.
1
47. Heat of combustion  Stability
48. In order of generate electrophile HNO3 acts as base.

49.

50. Pd / BaSO4 is for syn addition


Br
2
1
3

5
4

51. Cl 7
52.  E2  Elimination 
53. Cr24  1s 2 2s 2 2 p 6 3s 2 3 p 6 3d 5 4s1
For s - orbital electrons l  m  0
 2  2  2  2  2  1  1 = 12
56.14 0.347
54.  1
161.4 0.347
43.86 2.4366
 7
18 0.347
 x  1, y  7
 x  y  1 7  8
55. C4 H10  48  10  58
1000 13
  32  3.586 kg  4 kg
58 2
12.6
Optical purity = 100  42%
56. 30
PV PV
57. 1 1
 2 2
T1 T2
760  V1  749  13 22.4 

273 290
760  V1 736   22.4 

273 290
736 273
V1   22.4 
760 290
V1  0.96842  0.9413  22.4
 0.911 22.4
28  20.42
%N 
22, 400  wt.of organic sample
28  20.42

224  0.2
28  20.42 14  20.42
 
224  0.2 224
 12.76
=13
58. Conceptual
59. H 2   H P  H R  (Enthalpy of product-enthalpy of reaction)
= 10  50 
=40
60. A 
O3 / H 2O
Aldehyde 
on. vap
 A  448 mL at STP
 Cholorocompound  1.53g 
As A undergoes ozonolysis so A is unsaturated Let A is Cn H 2n1Cl
A  vapour
1.53 g 448 mL at STP

1.53
 22400  22400 mL = 76.5g n = 3
448
MATHEMATICS

61. tan 1    sin    cot 1   cos      sin     cos 
2
2  sin   cos     2, 2 
n
  1  1   1 
 n  1  n  2   n  22   n  2k 1  
62. lim     ....  
 n   n   n
n  n 
 
     
 1 
1 1 1 1 1  k   1 

e 
1  2 ..... k 1 2  21 k 
e 2 2 2
e  2 
1
1
2
1
 1  x 2 2
63. f 1  x   e x    e . x3
2 x 
2 1 2 1
x  1   1 2 
3
 1   2
 x  e  3   e  2  3 x  
 x x2 4
f 11
   e   x e
x2

2 x   2  2   
x
1
 1 1  x2  4 6 
 f 11  x   e  x     e  x6  x4 
 4x 4x x   
 x 1
e  1  x 2  2   2  1
 f 11  x    1   e  4 3 2    ,   2
4x  x  x  x  4
64.

x y
Equation of L is  1
2 4
2x  y  4  0 1
1
Equation of L1 is y – 1 =  x  2
2
2y  2  x  2
x  2y  4  0  2
Solving 1 & 2  , 
4 12
5 5 

65. Projection of OA on (4, 3, 0) ; (0, 4, 0)

12 12
The SD is equal to 
4 3 2 2 5
66. Any point  2  1,3  2,6  3
Given 4 2  9 2  36 2  9
3
49 2  9 
7
g  x   x 1
67. fog  x   x  3  x

 f g  x      
2
x 1  3 x 1  5
 f  x   x 2  3x  5
 f  0  5
1 1 1 0 0 1
1 1
68. A  4 6 8  2 2 8  2  A 
2
100 100 99 0 1 99
Adj  2 A   2 A  2 A  23 A
2

1  1 
  23 A   23 A
2
 26.  23    16  4  12
4  2 
69. Use   0 &  3  0
1 2 3
4 3 4  0  3  16  2  4  32   3 16  24   0
8 4 
3  16  8  64  24  0
72
5  72  0   
5
1 2 3
4 3 4  0  27  3  16  2  36  4  32   3 16  24   0
8 4 9 
21
5  21  0  
5
70. 1  t  .2  0
  1  2
Taking dot with 
 .  .1   .2
2
4  6  20   .t  0 10  t 
1
10  t 16  9  25  t 
5
1 1
      2  2    
5 5


 i  2 j  4k   15  4i  3 j  5k   9i  135j  15k
5  .  i  j  k    9i  13 j  15k  .  i  j  k   9  13  15  7
2

71. {x+b} = {x} where b is an integer


1000
 x   
 x  b  1000  x
 x 
b 1 1000 1000
  x    x  x
72.
Statement 2 is a property of an A.P so it is true.
a1  a 4  a7     a16  147
  a1  a16    a4  a13    a7  a10   147
 3  a1  a16   147  a1  a16  49
 a1  a6  a11  a16   a1  a16    a6  a11   2  a1  a16   98
73.

 x  1  x  0
1  x 0  x  1

74. f  x  
x 1 x  2
1  x 2  x  3
Clearly f is discatinuous at x  0,1,2 no.of points = 3
75. Conceptual

76. A (1, 0, 7) B (1, 6, 3)

Midpoint of AB= (1, 3, 5) lies in the line

DR’s of AB (0, 6, -4) the line passing through A and B is perpendicular to the given line

hence B in the mirror image.

Statement II is also true but not a correct explanation of I as there are infinitely many

lines passing through the midpoint of the line segment and one of the lines is

perpendicular bisector
77.

 x  f  x
78. f   Put x  y  1
 y  f  y
f  x  h  f  x
f 1  x   lt
h0 h
f  x  h  xh
1 f  1
f  x  x 
f  x  . lt  f  x  . lt
h0 h h 0 h
 h
f  1    f 1
f  x f  x 1 2 f  x
. lt 
x
  . f 0   f 1 1  2
x h0 h x x
x
79. lt f  2  h   f  2 
h 0

lt a  14  2  h  48  3  22
h 0

a  14  45
a  2011
80. AT  A and B T   B
 A  B  A  B    A  B  A  B 
A2  AB  BA  B 2  A2  AB  BA  B 2
AB  BA
 AB    1 AB
T K

BT AT   1 AB
K

 BA   1 AB
K

 AB   1 AB
K

K is odd
4 cos 3   3cos  cos 3
81.  4 cos 2   3  
cos  cos 
0 0 0 0
cos 27 cos 81 cos 243 cos 729 cos 7290
ꞏ ꞏ ꞏ  1
cos 90 cos 27 0 cos 810 cos 2430 cos 9 0
82. We have x > 1
1
 log8  x 2  x   2.log 1  x  1  0
3 2
1 1
 log 2  x  x   2 log 2  x  1  0
2

3 3
log 2 2  log 2  x 2  x   6.log 2  x  1  0
2  x  1 2  x  1
6 5

log 2 1 1
x  x  1 x
Put x – 1 = y as y > 0
2 y5 2 y5  y  1 2 y5  2 y  y 1
1  0 0 0
y 1 y 1 y 1
2 y  y 4  1   y  1
0
y 1
2 y  y 2  1   y 2  1   y  1  2 y  y  1  y 2  1  1 
  0  y  1  0
y 1   y  1 
 y  1  2 y  y 2  1  y  1  1 y 1
 0   0  y 1  0
y 1 y 1
y  1 x  2
83. f   x   3x 2  3  0  f  x  is increasing

a
 f  3  27 f   0   3; a 1  r   3
1 r
2
a 2  81 a9 r
3

84. Let p  x   a0 x4  a1 x3  a2 x2  a3 x  a4
p1 1  0 p1  2  0
p  x 1
Also lim 2
 1  a4  0, a3  0 and a 2  1, a1  1, a0 
x0 x 4
1 4
 p  x   x  x3  x 2 p  2  0
4
85.

 3 1  5  2   7  3  9  4   11 5   13  6   15  7 
86.
17  8   19  9   2110 

10
   2r  1 r  825
r 1

87. f 1  1
f  2  f  f 1   f  2  f 1   f 1  f 1  2
f  3  f  f  2    f  3  f  2    f  2  f 1
2+1 = 3
1 20 1
Thus f  n   n  f  r   1  2  3  ......  20 

30 r 1 30
1 20  21 
 . 7  1
30 2 7
x  2 y 1 z  6
88. Lines are  
3 2 2
   
x  6 y 1 z  8 c  a b d 
  S.D     
3 2 0 bd

  
b  3iˆ  2 ˆj  2kˆ, d  3iˆ  2 ˆj a  2iˆ  ˆj  6kˆ, c  6iˆ  ˆj  8kˆ

4 2 14
3 2 2
3 2 0 16  12  168 196
    14
ˆi ˆj kˆ 4iˆ  6 ˆj  12kˆ 14
3 2 2
3 2 0

Tr 1 1 1 1 1
 T1  a; T2  a T3  2 a..........T7  6 a
89. Tr 3 3 3 3
a 1
6
 a3
3 243
a a a2 32 1
Tr  Tr 1  r 1  r  2 r 1  2 r 1  2 r 3
3 3 3 3 3

1 1 1

r 1
Tr .Tr 1  3   3  5  ........
3 3 3
3 27
   3.375
1 8
1 2
3
3
 2x  1 
 
Lt f  x   Lt  x 
 sin  x log 2   log 1  x log 4 
x 0 x 0 2

90.  log 2    .log 4


 x log 2  x 2 log 4
 log 2 
3
1
  log 2
 log 2  2 log 2  2
1 
  log 2   0
2 

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