Professional Documents
Culture Documents
SRI CHAITANYA IIT ACADEMY, INDIA 17-03-24_Sr.Super60_Elite, Target & LIIT-BTs _Jee-Main_GTM-23_KEY &SOL’S
CH EM IST RY
31) 4 32) 4 33) 1 34) 4 35) 1
36) 3 37) 1 38) 4 39) 4 40) 2
41) 4 42) 4 43) 4 44) 3 45) 3
46) 1 47) 4 48) 1 49) 1 50) 4
51) 8 52) 7 53) 8 54) 4 55) 5
56) 2 57) 9 58) 10 59) 3 60) 3
M AT H EM AT ICS
61) 4 62) 3 63) 1 64) 4 65) 2
66) 2 67) 3 68) 4 69) 2 70) 2
71) 2 72) 3 73) 3 74) 1 75) 2
76) 1 77) 4 78) 4 79) 1 80) 4
81) 110 82) 198 83) 1 0 84) 1 85) 1
86) 4020 87) 45 88) 3 6 7 89) 5 90) 9
SOLUT ION S
P H YSICS
1. Let r = internal resistance of battery G = resistance of voltmeter
V A
G
Initially V Ir,I V 1
rG rG
After the voltmeter is shunted
V r
Voltmeter 2 and . Ammeter 3
r
RG
r
RG r G
RG RG
V r G
From (2) & (3) 4 , From (1) & (4) r G r (or)G r
rG
V 6
From (1) 2.0V
1 2 1
2. wi 3rad / s 2rad / sec 2 w f ? t 5sec
We know that w f wi T , w f 3 2 5 3 10 13rad / sec
3. Second law of thermodynamics can be explained with the help of example of
refrigeration, as we know that in refrigerator, the working substance extracts heat from
colder body and rejects a large amount of heat to a hotter body with the help of external
agency. No refrigerator can ever work without external supply of electric energy to it.
L 1 E
4. CR Time Velocity
R
0 0 B
2
R
Variation of g with altitude g h g henceg h g
R G
5.
V1 T 500 2
6. V T 1 V2 1000m / s
V2 T2 V2 8
7. Let P be a point an x-axis where the electric field becomes zero.
Let x be the distance of null point from (-2q)
X
L
O
x
+8q -2q x P
L x Lx
2
8q 2q
At P B8q B2q K. K. 2 4 2 L x 2x x L
L x2 x x x
8. V1 A 2 x 12 V2 A 2 x 22
r 1
V2 V/2
W
3
R
T 2T
W 2RT 1 2 W RT 2 2 2
1
2
1 1 1 1 1 1
14. , Put this the sign convention properly
f v u v u f
1 1 1 1 1 1
. Comparing this equation with Y mx c
v u f v u f
Slope m tan 1 135 or 45
1
v
1
f 135
45
1
u
45
45
F
T sin 45
2g
cb 3 a a
24. Centre of mass of remaining sphere, x1 0, where x1 3 where c ,b ,a a
a b3 2 2
a a3 a
. a a
x1 2 83 16 Position of COM ,0
a 7/8 14 14
a3
8
Sec: Sr.Super60_Elite, Target & LIIT-BTs Page 4
Yashpatil TG~ @bohring_bot
SRI CHAITANYA IIT ACADEMY, INDIA 17-03-24_Sr.Super60_Elite, Target & LIIT-BTs _Jee-Main_GTM-23_KEY &SOL’S
I0 2 40
25. I sin 2 Here I0 40 Wm 2 I 1 5Wm2 & 450
8 8
stress 20
26. From the graph Y 10
20 1010 N / m 2
strain 1 10
1 1
E stress strain Y . strain
2
Energy density
2 2
2
20 1010 5 104 25 103 J / m3 E 25 KJ / m3
2
27. If E and W are energy of incident photon and W is the work function of metal surface
K 2 E 2 W 3.5 1.0 2.5
then maximum kinetic energy K = E – W 5
K1 E1 W 1.5 1.0 0.5
28. Here length of solenoid is far greater than the diameter hence we consider it is an infinite
length of solenoid
Magnetic induction inside the solenoid
B I where n 10 / cm
4 107 103 5 10 / 10 2 m
20 104 103 / m B 2 103 T
29. Let V1 & V2 be potentials across A and B respectively
V1 : V2 C2 : C1 V1 : V2 KC : C V1 : V2 K :1 3:1
3 1
V1 10 7.5 V2 10 2.5 Here X Y 7.5 2.5 10V
4 4
30. The particle will move in a circle of radius
mV sin 1.67 10 4 10 sin 60 2 10 2
27 5
r m
Bq 0.3 1.6 1019 3
2 102
2
2 r 3 2
Time period T 107 S
V sin 4 10 sin 60 3
5
CH EM IST RY
31. Cyclohex–2–en–1–ol
32.
Cl
Cl2 Cl
Product (A)
Cl
Cl
Product (B)
33.
H
CH = CH2 CH - CH3 CH3
HF Ring
Expantion
20 C+
Hydride ion
transfer
CH3
CH3
30 C+
+
CH3
34. In polar protic solvent, I is less stable due to less hydrogen bonding it means more
nucleophile.
35. The amino group in Aniline is ortho one para directory and powerful activating group as
NH 2 has strong +M effect
Aniline does not undergo Friedel–Craft’s reaction (Alkylation and acylation) as aniline
will form complex with AlCl3 which will deactivate the benzene Ring
36. Wilkinson catalyst Rh
37. Group
Group-14 E.H
C 2.5
Si 1.8
Ge 1.8
Sn 1.8
Pb 1.9
The E.N values for elements from Si to Pb are almost same. So statement–I is false
38. The correct order of first Ionisation Energy is
Sec: Sr.Super60_Elite, Target & LIIT-BTs Page 6
Yashpatil TG~ @bohring_bot
SRI CHAITANYA IIT ACADEMY, INDIA 17-03-24_Sr.Super60_Elite, Target & LIIT-BTs _Jee-Main_GTM-23_KEY &SOL’S
Li B Be C O N F
On moving from left to right in a period atomic size decrease, eff increases, so ionization
enthalpy increases but presence of half filled and fully filled configuration will make on
ion more stable thus more will be ionization enthalpy thus the order is
Li Be C N O F
39. Conceptual
40. Solid Boron has very strong Crystaline lattice So its melting point unusually high in
group 13 elements
41. Conceptual
42. The maximum number of possible oxidation states of Actinoids are shown by neptunium
(Np) and plutonium (Pu) those octonoids exhibit oxidation states of 3, 4, 5, 6 and 7
2
43. Pb OH 4 Na2CrO4
PbCrO4 NaOH
Dianionic Complex with co-ordination number four
Fe Fi : Fe 3 Ar 3d 5
3
44.
F : Weak field ligand
No.of unpaired C 5
55 2
35B.M
2
V H 2C 6 : V 2 : 3d 3
No.of unpaired e 3
33 2
15B : M
2
Fe H 2O 6 Fe2 : 3d 6
H 2O : Weak field ligand
No.of unpaired e 4
44 2
24 B.M
45. Conceptual
H
46. G H T S H T S T
S
K1 K2
47. B% %, C % %
K1 K 2 K1 K 2
48. K p PCo2
PCo2 107.3 0.13 0.082
49. Conceptual
50. Conceptual
Sec: Sr.Super60_Elite, Target & LIIT-BTs Page 7
Yashpatil TG~ @bohring_bot
SRI CHAITANYA IIT ACADEMY, INDIA
0
17-03-24_Sr.Super60_Elite, Target & LIIT-BTs _Jee-Main_GTM-23_KEY &SOL’S
51. In carbylamine test only aliphatic (or) aromatic I amines are involved.
A, d, e, f, I, j, m , n
52. NH2 O
O
CH3
N NH
NH
N O N O
N O
Cytosine
Thymine Uracil
3N 2N
2N
3 2 2 7 Nitrogen
53. 6 PCl5 P4O10
10 POCl3
54. Correct Statements II ,V ,VI ,VII
KEHe THe 200 1 He 2 KEHe M Ne 2 5 20
55. 25 5
KENe TNe 1000 5 Ne 2 KEHe M He 2 1 4
56.
T f diss
2
2
T f diss
1
Kh
57. OH c C K hC
C
Kw
C 105 P OH 5 PH 9
Ka
58. Conceptual
59. i , vii , viii
60. Conceptual
M AT H EM AT ICS
61. S-I: Since 2x 2x 3 3 is an irrational number so xRx R is reflexive.
3 3
Here ,1 R , but 1, R ,
2 2
So R is not symmetric, not Transitive
1
2 dt
1 1 10t 1
62. Put x 3 I t dt .2 1 5t 2 C
t 1 1 10 1 5t 2 10
2 2
5
t t
1 5 x 2 6x 4
1 C C
5 x 3 2 5 x 3
/2
x sin xdx sin x sin x
63. I dx dx , Put cosx = t
0
1 cos 2
x 2 0
1 cos 2
x 0
1 cos 2 x
dt
0 2
tan 1 t 0
0
1
1 t 2 1
4 4
64. C 8,12 , r 5
h 8 k 12 2 32 84 13
h 16, K 2
4 7 16 49
1 x
O S
R
1 3 4
67. P A P B P G / A ,P G / B
2 7 7
From Baye’s theorem
1 4
P B P G / B .
4
PB / G 2 7
P A P G / A P B P G / B 1 . 3 1 . 4 7
2 7 2 7
x x2 x3 x2 x x x2 x3
a 1 ...... b 1 ....... c 1 ....
Lt 1! 2! 3! 2
1! 2! 3! 2! 4
68.
x 0 sin x
x2.
x
a b c 0 1
a c 0 a c 2
a b c
2 a b c 4 3 a 1,b 2,c 1
2 2 2
1 2 3
72
69. A 4 3 4 0
5
8 4
1 2 3
21
3 4 3 4 0
5
8 9 9
70. 2 z 3i z i
Put z x iy 2 x y 3 i x i y 1
2 x 2 y 3 x 2 y 1
2 2
2
4 x 2 y 3 x 2 y 1 x 2 y2
2 26y 35
3
0
3
13 169 35 169 105 8 13 8
C 0, ,r g f r 0 7
3 9 3 9 3 3 3
1 1 4a
71. x z 1 4a is odd perfect square
2
a 6,12,20,30,42,56 Sum = 166
72. Projection of AB on AC
AB cos 10cos A
c 2 b2 a 2 85
10
2bc 14
x 4 y 0 z 1
73.
2 6 3
P(2,3,4)
Q
Let Q 4 2,6,1 3
Dr’s of PQ 2 2,6 3, 3 3
Dr’s of line 2,6, 3
PQ perpendicular line a 1a 2 b1b 2 c1c 2 0
13
2 2 2 6 3 6 3 3 3 0
49
909 3 101
PQ 2 2 2 6 3 3 3 22 26 49 2 PQ
2 2 2
49 7
74. A BC tan 1 2 tan 1 3 C
23
tan 1 C
1 2 3
tan 1 1 C 0 C tan 1 1 C
4
75. y x 2 1 1
y 3 x 2
3/2 93/2 27 9
Area
6 1
2 2
6a 6 2
a b 12 6 4 8 12 10
76. Mean 9 9 a b 20
8
a 2 b 2 144 36 16 64 144 100
Variable 9.25 81 9.25
8
a 2 b2 218 a 7,b 13
Sec: Sr.Super60_Elite, Target & LIIT-BTs Page 11
Yashpatil TG~ @bohring_bot
SRI CHAITANYA IIT ACADEMY, INDIA 17-03-24_Sr.Super60_Elite, Target & LIIT-BTs _Jee-Main_GTM-23_KEY &SOL’S
a b ab 49 169 91 49 78 127
2 2
3 8 3 16
77. A , ,B 3,4 ,C ,
5 5 7 7
A
(1) (3)
B (2) C
Equation of altitude AD is 3x 2y 5 0 4
Equation of altitude BE is x 4y 13 0 5
Solving (4) & (5),
3 22
We get orthocentre ,
7 7
78. Domain 3, 4,5 Range B f 3 , f 4 , f 5
4 P0 ,3 P1 ,3 P2 1,3,2
79.
M P
6 8 9
4
5 3
7
C
Total = 6+9+7=22
80. n1 50, x1 630, 1 90
n2 40, x2 540, 2 60
n1 12 n2 22 n1n2
2 1
2 x x2
2
n1 n2 n1 n2
81. cos t of the box is
C 15x 2 25x 2 20 4xh 300
y2
1 v2 x c 1 2 x c x 2 y 2 cx
x
Passing (1, 1)
c2 x 2 y 2 2x 0 Centre 1, 0
10
x 3 np 10 1 / 2
85. 2 r 2
3 2x p q 1 / 2 2
8 2
1 3 1 9 5
Independent term is T21 C2 45
10
3 2 81 4 4
86. 3, 7, 11, 15, ……. C.d = 4
1, 6, 11, 16, ……. C.d = 5
Common terms are 11, 31, 51, …..
S20 22 19 20 4020
20
Here a = 11, d = 20
2
87. 32024 32022.32
9 3 3 674
9 27
674
9 28 1
674
9 28k 1 9 28k 9
32024 9 28k 9 9 9
9k
28 28 28 28
dy f / x 2x 5y 2
88.
dx f / y 5x 2y 1
dy 5 d2 y 11
2
dx at1,1 8 dx 1,1 256
x 2 y2 3
89. 1 e ,foci 3,0
16 7 4
144
Eccentricity of hyperbola is
12
2 144
Foci ,0
12
144
3
6
144 324
324 144 180
180 5
2
2b 2 36
L.L.R 5
a 2
90. A AdjA 3I A 3
a AdjA A 9
2
b Adj AdjA A 3 4 81
4