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CHEMISTRY
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MATHEMATICS
61 1 62 2 63 4 64 1 65 3
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PHYSICS SOLUTIONS:-
1.
m
l l
1
F
m F m F m
Gm 2 4Gm 2
F1 2
3l 3l2
2
R
2. h
2
GMm 4 4
F1 2
F 72 32N
R 9 9
R
2
4 4
G r 3 r 3
3. F 3 3
r2
Fr 4
4. Gravitational force is independent of medium between the two masses.
M
G m
GMm GMm 8 7GMm
5. F1 and F2 2
2
2R
2
2R 3R 36R 2
2
F2 7
F1 9
1
6. E inside 0 and E out
r2
GM GM 3GM
7. V
a a a
2
8. FG FCPF
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Gm 2 mv 2 a
3 r
a2 a 3
3
Gm
V
a
1
9. gh g
100
g 1
2
G
h 100
1
R
h
1 10 H 9R
R
2h d
10. g h g 1 ;g d g 1
R R
2h d
g 1 g 1
R R
2h x
R R
2h x
11. Conceptual
g
12. gh 2
h
1
R
h
1 3
R
h 2R
g
13. gd
4
d g
g 1
R 4
d 3
R 4
3R
d
4
4
14. g RGS
3
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g S
3
15. g eg g
5
3
g R 2 g
5
2g
R2
5
2g
5R
dL
GMm GMm
16. F dF 2
dx
d Lx d L d
17.
2
GM g M R
g 2 M M E
R gE ME R M
18.
Gm M G 3m M
F 2
;FH 3F
R R2
19. Inside Spherical shell,
E0
F0
20.
GM 1
g 2
g 2
R R
g R
% 2 %
g R
1 1 1
21. E G 2 2 2
1 2 4
1
E G
1 1
4
4G 12G
E E
3 9
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g 4g
22. gA 2
1 9
1
2
1 g
g B g 1
2 2
g A 4g 2 8
gB 9 g 9
u 2 sin 2
23. RE R
gE
u 2 sin 2 5R
RP
gP 4
gP 4 8
g E 5 10
GM
24. V 3X 3
2
V 3 3G
1 2 2 3 1 3
25. U G
4 6 10
15 3
U G
10
9G
U
5
2
gE ME R M ME 1
26. 5
g M MM R E M M 16
ME
80
MM
3
g pole g R2 cos 2 R 2
4
3
cos
2
30
G 90
28. E1 10G
9
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G 160
E2 10G
16
GMmx
29. E at x F m E at x
2 3/2
R 2
x
GM
30. U 4
L
2
32GM
L
CHEMISTRY SOLUTIONS:-
31. Pt & Rh gauge is used as catalyst in air oxidation of NH3 to NO in Ostwald process of
manufacturing of HNO3
32. Conc. HNO3 forms protective oxide film on the surface of metals like Fe, Cr, Al, etc
33. PCl5 4H 2 O H3 PO4 5HCl
36.
KI solution is buffered with a borate buffer (pH=9.2)
I2 so liberated is estimated using standard hypo solution,
2Na2S2O 3+I2→Na2S4O 6+2NaI;
By Knowing the strength of I2, strength of Ozone can be estimated
37. PCl5(s) [PCl4 ] [PCl6 ] both are +5
39. Distillation can give only 68% concentration as it forms an azeotropic mixture.
Conc. H 2SO4 is used as dehydrating agent to increase purity to 98%
40. P 5HNO3 H3 PO 4 5NO 2 H 2 O
I 2 10HNO3 2HIO3 10NO 2 4H 2 O
50. Most acidic is H2Te as acidity increases down the group and H2O is thermally most
stable.
51. PCl3+3H2O→H 3PO3+3HCl
Number of moles required to neutralize H3PO 3 = 2
Number of moles required to neutralize HCl = 3
Total number of moles of NaOH required to neutralize the solution =5
52. Only Phosphonic acid has those bonds
53. Only Au, Pt noble metals are inert to HNO3.
54. X =1, Y=2
55. PCl3, AsCl3, P4O9 can produce so
56. Only S2O72- doesn’t have S-S bond
57. C6H12O6 6C
58. At equal volumes, if 2x is the volume of O3, O2 volume will reduce to 100-3x and thus
100-3x = 2x, i.e., x =20 and volume of ozone will be 2x = 40
59. 2 I 2 9O3
I 4 O9 9O2
60. H 2S2O 2 is Thiosulphurous acid, H 2S2O3 is thiosulphuric acid, H2S2O 4 is dithionous acid,
H 2S2O 5 is disulphurous acid having S-S bond, H2S2O6 is dithionic acid, other two have no
S-S bond.
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MATHEMATICS SOLUTIONS:-
x2 y2
61. 1 2
a2 b
x a x a a 2
y2 b2
NA NA ' a 2
2
2
PN b
x2 y 2
62. For hyperbola 1
a 2 b2
x2 y2
Since SS' does not subtend a right angle at any point on the hyperbola 1 0 , no
4a 2 b 2
real point of intersection of the circle and this hyperbola exists.
radius of circle < 2a
be < 2a
7
1<e<
2
63. Let equation of directrix be
y 2x C
It passes through centre(2, 3) of the circle.
C 1
Directrix y 2x 1
1 cos 2 sin 2
2
r2 2 a2 b
1 sin 2 co s 2
Similarly 2
r2 2 a b2
1 1 1 1 1 1
2
2 2 2 cos 2 2 2
r1 r2 a b a b
91 25m 2 9
2m
91 25m 2 9
1
2m 1 m
2
66. Equation of tangent to the ellipse having slope ’m’ is
y mx 16m 2 b 2
Solving it with the hyperbola xy 8
x mx 16m 2 b2 8
Or mx 2 16m 2 b 2 x 8 0
Since line is tangent to the hyperbola, above equation must have equal roots.
D 0
16m 2 b 2 32m 0, m R
2
32 4 16 b 2 0
b 2 16
b 4
xh yh
67. Equation of tangent at P is 1
a 2 b2
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2
yk a
x 1 2
b h
Putting in equation x 2 y 2 a 2
y 2 k 2 2yk a 4 2 2
1 4 2 2 y a
b b h
k2a4 2ka 4 a4
y 4 2 1 2 2 y 2 a 2 0
2
b h b h h
1 1 y1 y 2
y1 y 2 y1 y 2
2ka 4
2 2
4 b h2 2
a a h
h2
2ka 2
b2 a 2 h 2
2k 2k 2
2
2
h k k
b2 1 2 b2 2
a b
x
68. Equation of tangent at P ct,c / t is ty 2c or x t 2 y 2ct
t
1
Slope of tangent
r2
Equation of perpendicular to this tangent from (0,0) is y t 2 x
2
Squaring (1), x t 2 y 4c 2 t 2
69. Let h, k be the midpoint of the chord of the circle x 2 y 2 16 . The equation of the
chord will be
hx ky h 2 k 2
h h2 k2
Or y x y mx C
k k
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x my a 1 m 2
And x my a 1 m2
On solving (i) and (ii)
a
R
2
1 m2 1 m2 , 2ma
1 m2 1 m2
Let R h, k
a2 a2m
hk
4m
1 m 1 m 2
2 2
2hk
m
a2
Putting value of m in (i), we get
2hk 4h 2 k 2
h k a 1
a2 a4
a 4 x 2 a 2 4x 2 y 4 0 , Which is the required locus
71.
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Equation of tangent at P is
3sec x 4 tan y 12 0
12
CN
9sec 2 16 tan 2
Equation of normal at P is
4 cos 3y cot 25
25
CM
16cos 9cot 2
2
1
Area of CPN, A CM,CN
2
1 25 / 12
2 144 81cos ec2 256sin 2 144
9 16 144
Max value of 81 cosec2 256sin 2 2.144
1 24 12 1 25 12 25
A MAX
2 4 144 2 2 12 4
4A 25
72.
x2 y 2
Equation of normal at point P a sec , b tan on hyperbola 1 is
a2 b2
a cos bco a 2 b 2
a 2 b2
G ,0
a cos
S ae, 0
SP e a sec a
a 2 b2 a 2 e2
SG ae ae e e a sec a
a cos a cos
SG / SP e 6
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73. Product of perpendiculars drawn from foci upon its any tangent is 9.
b2 9
x2 y 2
If angle between asymptotes of hyperbola 2
2 1 is 120 ,
a b
b 1
tan 30
a 3
a 2 3b2 27
Required locus is director circle of the hyperbola and which is
x 2 y 2 27 9 or x 2 y 2 18
b
If tan 60 is taken, then
a
2 b2 9
a 3
3 3
b
74. Equation of asymptotes of hyperbola is y x
a
Intersection of asymptotes with ellipse are
a b a b
and ,
2 2 2 2
So length of the chord PQ
2 2
a a b b
2 2 2 2
2 a 2 b 2 units.
k
h
2
y ' 2 x 0, which is the required locus.
8
76. Any point of xy 8 is P 8t ,
t
x y
Equation of the tangent at P is 1
16t 16
8 8t
1 16t 16
Area of the triangle . . 16
2 8 8t
77.
2 2
C 2 t1 t2 , 0 and D 0,
t2 t1
4
Now AC BD 4t2 2
t12
79.
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CS r 1
CS' r 3
CS CS' 2
Locus of C is hyperbola with (-4, 0) and (4, 0) as foci.
Here 2a= 2, so ae = 4
And 2ae = 8, so ae = 4
b 2 a 2 e2 1 15
2a b
80. The point P is a sec , b tan , i.e., P ,
6 6 6 3 3
x y
Equation of tangent P is 1
3a 3b
2
1 3a
Area of the triangle 3b 3a 2
2 2
b
4
a
b2
e2 1 17
a2
x 2 y2 a 2 b 2
b2
e12 1
a2
3r 2 2
1 2
2 5r
3 2
1
5 5
b2
e2 2 1
a2
3 8
1
5 5
8 2
So, 4e2 2 e12 4 6
5 5
1 1 1
m AB , m BC , m AC
t1 t 2 t 2 t3 t1 t 3
ACB 90
1
t 32
t1 t 2
Slope of AB t 32
1
Slope of tangent at C
t 32
x2
Equation of chord of contact of y 2 1 is
2
x
T 0 or y 1
2
x
or y 1 1
2
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x
y y 1 0
2
Above is a family of straight lines, which passes through the point of intersection of
y 1 0 and x 2y 0 or 2, 1 x1 , y1
x1
1 2 1 3
y1
x y
Tangent at P is sec tan 1
3 4
x y
It meets in Q
3 4
3 4
Q is ,
sec tan sec tan
x y
It meets in R
3 4
3 4
R is ,
sec tan sec tan
32 4 2 32 42
CQ.CR 25
sec tan sec tan
2 2
85. 3
2 x 2 2 y 2 4 3 2
x2 y2
2
2
1
3
2
If m is the slope of tangent to this hyperbola,
a 2 m2 b2 0
2
2 m 2 3 2 0
2
m2 2 1
2 2
m 2 2 1 / 2 3 / 4
2
3 2
m
4
3
m
4
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8m 6
x2 y2
86. The equation of a hyperbola of the series is 1
a2 2 ,
Where is a parameter. The asymptotes of this hyperbola are x / a y /
x2
y2 '
x ' a y1
2 2 1 and y
1 1
2
2
a
y' 2 x ' 2 '2 1 1 x '2 y ' 2 2x ' y '
i.e., 1 and y 2 2 2 2
2 2 a a
The second relation gives on simplification,
2 4x ' 2 y ' 2 a 2
y '2
x '2
2
4x ' 2 x '2 a 2
2
By the first relation. Hence, the locus of P is y 2 x 2 4x 2 x 2 a 2 .
4 x1 4 y1
sec and tan
2 x1 y
2
1
2
3 x12 y12
2 x2 y2
Required locus is x 2 y 2 16
4 9
Or y 2 4y 4 0
Or y 2
x 3
Thus two curves touch each other 3, 2 .
We have two lines which are tangent from P to hyperbola which touch hyperbola at one
point and circle at two points.
We have two lines through P and parallel to the asymptote which intersect the
hyperbola at one point and circle at two points.
We have one line from point P and (3, 2) and one from point P and (-3, 2).
We have one line tangent to circle at point P which intersects hyperbola at two
points.
So in total we have seven lines.
x 2 y2
89. 1
a 2 b2
Let the point R(a sec , b tan ).
x sec y tan
Equation of tangent 1
a b
1
p dis tan ce from C origin
sec tan 2
2
a2 b2
ab cos
p
b a 2 sin 2
2
RS aesec a
RS' aese a
RS RS' 2aesec
2
Now RS RS' 4a 2 e 2 sec 2
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b2 b 2 b 2 a 2 sin 2
2 2
a 1 2 a 1
p a 2 b 2 cos 2
2 b2 2
a 1 2 2
tan
a cos
2 2 b2
a sec 1 2
a
a 2 e2 sec2
k 4
90. We know that PN is the angle bisector of focal radii SP and S' P
SP SN
S' P S' N
SN S' N SN S N SS'
'
SP S P SP S' P SP S' P
2
SP 1
6 6. 3
SN 2